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  <front>
    <journal-meta><journal-id journal-id-type="publisher">SE</journal-id><journal-title-group>
    <journal-title>Solid Earth</journal-title>
    <abbrev-journal-title abbrev-type="publisher">SE</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Solid Earth</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1869-9529</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/se-10-1355-2019</article-id><title-group><article-title>Fault-controlled dolomitization in the Montagna dei Fiori Anticline (Central
Apennines, Italy): record of a dominantly <?xmltex \hack{\break}?>pre-orogenic fluid migration</article-title><alt-title>Fault-controlled dolomitization in the Montagna dei Fiori Anticline </alt-title>
      </title-group><?xmltex \runningtitle{Fault-controlled dolomitization in the Montagna dei Fiori Anticline }?><?xmltex \runningauthor{M. Mozafari et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Mozafari</surname><given-names>Mahtab</given-names></name>
          <email>mahtab_mozafari@yahoo.com</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Swennen</surname><given-names>Rudy</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-1528-526X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Balsamo</surname><given-names>Fabrizio</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-1931-466X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2 aff3">
          <name><surname>El Desouky</surname><given-names>Hamdy</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Storti</surname><given-names>Fabrizio</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-2809-9471</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Taberner</surname><given-names>Conxita</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>NEXT – Natural and Experimental Tectonics Research Group – Department
of Chemistry, Life Sciences<?xmltex \hack{\break}?> and Environmental Sustainability, University of
Parma, Italy</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Department of Earth and Environmental Sciences, KU Leuven, Leuven, Belgium</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Geology Department, Faculty of Science, Menoufia University, Menoufia,
Egypt</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Shell Global Solutions International B.V., Amsterdam, the Netherlands</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Mahtab Mozafari (mahtab_mozafari@yahoo.com)</corresp></author-notes><pub-date><day>20</day><month>August</month><year>2019</year></pub-date>
      
      <volume>10</volume>
      <issue>4</issue>
      <fpage>1355</fpage><lpage>1383</lpage>
      <history>
        <date date-type="received"><day>15</day><month>December</month><year>2018</year></date>
           <date date-type="rev-request"><day>3</day><month>January</month><year>2019</year></date>
           <date date-type="rev-recd"><day>26</day><month>May</month><year>2019</year></date>
           <date date-type="accepted"><day>17</day><month>July</month><year>2019</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2019 </copyright-statement>
        <copyright-year>2019</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://se.copernicus.org/articles/.html">This article is available from https://se.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://se.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://se.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e150">The Lower Jurassic platform and basinal deposits exposed in the
Montagna dei Fiori Anticline (Central Apennines, Italy) are pervasively
affected by dolomitization. Based on the integration of field work,
petrography, and geochemistry, two fault-related dolomitization events were
recognized and interpreted as having occurred before and during the
Apenninic orogeny. Fluid inclusion analysis indicates moderate
to elevated salinity values of 3.5 to 20.5 and 12.8 to 18.6 eq. wt % NaCl in the first and the second event, respectively. The estimated
salinities, in combination with <inline-formula><mml:math id="M1" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values and <inline-formula><mml:math id="M2" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios,
suggest significant involvement of evaporitic fluids in both events, most
likely derived from the underlying Upper Triassic Burano Formation. In
addition, the <inline-formula><mml:math id="M3" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios up to 0.70963 suggest the circulation of
deep-sourced fluids that interacted with siliciclastic rocks and/or the
crystalline basement during the dolomitization events.</p>
    <p id="d1e204">Two major dolomite types (D1 and D2) were recognized as pertaining to the
first event, both postdated by high-amplitude bed-parallel stylolites,
supporting a syn-burial pre-layer-parallel shortening dolomitization. A
possible geodynamic framework for this dolomitization event is Early Jurassic to Late
Jurassic rift-related extensional tectonism. The second dolomitization event
(D3, D4, and D5) is characterized by a temperature upturn (up to
105 <inline-formula><mml:math id="M4" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) and interpreted as associated with the inflow of
hydrothermal fluids, possibly related to major changes in the permeability
architecture of faults during early- to syn-thrusting and folding activity.
Based on the timing of deformation in the Montagna dei Fiori Anticline, the
second dolomitization event likely occurred in Late Miocene to Pliocene
times. The findings regarding characteristics and timing of dolomitization
here illustrates the long-term controlling role of the evaporitic
detachments in the dolomitization process. This study shows that the Mg-rich
fluids that were most likely derived from evaporites may prime the
tectonically involved successions for repeated dolomitization, and hence the
formation of potential reservoirs during sequential tectonic modifications
(extensional vs. compressional).</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e225">Fault-controlled dolomitization has been the focus of attention in many
studies during the last decades due to its influential role in modifying the
petrophysical properties of rocks, and hence anisotropy, in fluid migration
pathways, and ultimately on reservoir quality (e.g., Purser et al., 1994;
Montanez, 1994; Zempolich and Hardie, 1997; Vandeginste et al., 2005; Davies
and Smith, 2006; Sharp et al., 2010). The mechanical and hydrological
behavior of fault zones are in turn influenced by fluid–rock interactions
and diagenetic modifications (e.g., Gale et al., 2004; Laubach et al.,<?pagebreak page1356?> 2010;
Clemenzi et al., 2015; Ferraro et al., 2019). It follows that the mutual
interplay between fault activity and fluid–rock interaction can trigger
dolomitization of carbonates when exposing to Mg-saturated or oversaturated
fluids and, consequently, variations in physicochemical properties of
fluids through time and space.</p>
      <p id="d1e228">Leaking or sealing behaviors of fault zones during deformation are key
controls for fault-related fluid circulation. A detailed understanding of
such an interplay is thus necessary to improve our capability of making
reliable predictions of fault-related dolomitization in carbonate
reservoirs. Studying outcrop analogs provides fundamental support to meet
this requirement and the opportunity to assess the spatial distribution of
dolomitized zones, and individual diagenetic events, in 3-D (e.g., Swennen et
al., 2012; Dewit et al., 2014; Bistacchi et al., 2015).</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><label>Figure 1</label><caption><p id="d1e233"><bold>(a)</bold> Simplified regional map (modified after Ghisetti and Vezzani,
1997) showing the tectonic outlines of the Central Apennines and the study
area (rectangle). <bold>(b)</bold> Schematic geological map of the Montagna dei Fiori
Anticline showing the distribution of dolostones (modified after Storti et
al., 2017a). <bold>(c)</bold> Lithostratigraphical column of the successions exposed in
Montagna dei Fiori (modified after Mattei, 1987; Di Francesco et al., 2010;
Storti et al., 2018). Letter B stands for the Bugarone Formation.
Lithologies are mentioned in the text. Note that the thickness of the
non-outcropping formations (Triassic evaporites and the crystalline
basement) is not to scale. <bold>(d)</bold> Regional geological transect across present-day Central Apennines and the Adriatic Sea (modified after Fantoni and
Franciosi, 2010) with vertical exaggeration of <inline-formula><mml:math id="M5" display="inline"><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>:</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula>. The dashed rectangle
indicates the Montagna dei Fiori Anticline region.</p></caption>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f01.png"/>

      </fig>

      <p id="d1e266">The Lower Jurassic to Lower Cretaceous Umbria-Marche passive margin
carbonate succession, in the Central Apennines (Italy), is intensely
affected by localized dolomitization both in the onshore fold-and-thrust
belt and in the offshore foredeep and foreland areas (e.g., Murgia et al., 2004;
Pierantoni et al., 2013). The dolomitized intervals which are the focus of
this study are well exposed in the core of the Montagna dei Fiori Anticline,
where the dolomitized Lower Jurassic intervals (Calcare Massiccio, Bugarone,
and Corniola formations) and their relationships with fault zones allow us to
study the mutual influence between deformation structures and dolomitized
intervals (Fig. 1). These intervals, known as the Castel Manfrino dolostones
(Crescenti, 1969; Mattei, 1987; Koopman, 1983), have been previously studied
by Ronchi et al. (2003) only at its reference section, exposed at the Castel
Manfrino location (Fig. 1b) in the central sector of the Montagna dei Fiori
Anticline (Fig. 2). A fault-controlled dolomitization model and the
relative timing of dolomitization were proposed by the latter authors based
on the homogenization temperatures obtained from microthermometry of the
fluid inclusions, and their relation with the thermal history of the area
studied. However, no clear relation between dolomitization and structural
evolution of the Montagna dei Fiori Anticline on a local scale was provided
to confidently link the occurrence of dolomitization to a particular
tectonic event. Moreover, the nature and origin of the dolomitizing fluids
were not well constrained. Recent re-evaluation of dolostone distribution in
the Montagna dei Fiori Anticline (Storti et al., 2017a) showed that the
dimension of the dolomitized geobodies (Fig. 2) is much more significant
than what was previously mapped by Mattei (1987). Dolostones are distributed
within fault damage zones and in the laterally adjacent carbonate rocks, and
in intersection areas between fault sets, for a total area in map view of
more than 1.5 km<inline-formula><mml:math id="M6" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> (Storti et al., 2017a).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><?xmltex \currentcnt{2}?><label>Figure 2</label><caption><p id="d1e280"><bold>(a, b)</bold> Geological map of the central sector of the Montagna dei
Fiori Anticline and cross section oriented parallel (a–b) to the hinge line
representing the tectonostratigraphic architecture of the faulted anticline
(modified after Storti et al., 2017a). The stereonets (Schmidt equal area
projection lower hemisphere) provide the attitude of the extensional faults.
The locations of the corresponding field sites are indicated by letters. (c)
At this location, well exposed N–S-striking extensional fault zones offset
the dolomitized Corniola Formation. The fault zone is characterized by
near-horizontal stylolites localized in the footwall damage zone (4 fault
data). (d, e, and f) These locations consist of mostly <inline-formula><mml:math id="M7" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> E–W-striking extensional fault zones. Particularly the boundary fault zones
delimiting Calcare Massiccio Formation in the main horst block is evident
(site d: 20 fault data; site e: 24 fault data; site f: 9 fault data). (g and
h) At these locations, dip-slip slickenlines support major extensional
movements related to the Montagna dei Fiori Fault. Contractional deformation
structures are preserved in the bed-perpendicular stylolites, shear surfaces,
and tension gashes arranged as S–C arrays (site g: 21 fault data; site h: 14
fault data). Equal area projection, lower hemisphere.</p></caption>
        <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f02.png"/>

      </fig>

      <p id="d1e298">The structural pattern of the Montagna dei Fiori Anticline documents the
overprinting of extensional and contractional deformation along major fault
zones. The preserved structural framework in this anticline provides an
opportunity to study the direct but complex regional tectonic controls on
dolomitization in carbonate successions undergoing multiple deformation
events, from rifting to folding and thrusting. This contribution integrates
new petrographic, geochemical, and microthermometric analyses with
structural studies (Storti et al., 2018) to characterize the temporal record
of fault-controlled diagenetic phases and, more specifically, dolomitization
in the carbonatic succession outcropping in the Montagna dei Fiori
Anticline. These findings might be of relevance for exploration and
reservoir quality prediction in the region of the Apennines and the Southern
Alps, both onshore and offshore. Moreover, this work provides additional
evidence of the potential influence of fluids derived from evaporitic
detachment levels in modifications of geochemical trends and petrophysical
properties of the overlying carbonate rocks.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Geological setting</title>
      <p id="d1e309">The Montagna dei Fiori Anticline is a NNW–SSE-striking thrust-related fold
located at the mountain front of the Central Apennines (Fig. 1). The
geodynamic evolution of the Apennines has been proposed to be the result of
the superposition of NE–SW compression (in present-day geographic
coordinates), related to the convergence of the Eurasian and African plates
since Late Cretaceous times (Elter et al., 1975; Dewey et al., 1989;
Patacca et al., 1992), on a rifting-related tectonosedimentary architecture
produced by Early Jurassic extension (e.g., Centamore et al., 1971). In such
a framework, the Central Apennines developed during Miocene to
“Plio-Pleistocene” times (e.g., Parotto and Praturlon, 1975; Barchi et al.,
1998; Mazzoli et al., 2002; Bollati et al., 2012).</p>
      <p id="d1e312">The Central Apennines involves the Umbria-Marche succession, which
essentially includes Triassic to Miocene carbonates and marls, covered by
Miocene to Pliocene syn-orogenic clastic sediments (Fig. 1). The
pre-orogenic succession, from bottom to top, includes Late Triassic
evaporites, dolomites, and limestones of the Burano Formation, which the basal
detachment runs within its evaporitic interval (Ghisetti and Vezzani, 2000);
Early Jurassic to Late Jurassic platform and basinal limestones and dolostones
(Calcare Massiccio, Corniola, Rosso Ammonitico, Calcari a Posidonia, and
Calcari ad Aptici formations); and Cretaceous to Early Miocene basinal
carbonates (Maiolica, Marne a Fucoidi, Scaglia, and Biscaro formations). In
general, the lower part of the Burano Formation is overlaid by the
fluvio-deltaic siliciclastic rocks of the Verrucano Formation (Middle Triassic to Late
Triassic) (Tongiorgi et al., 1977; Ghisetti and Vezzani, 2000; Tavani et
al., 2008). Nevertheless, the existence of these siliciclastic rocks in the
Montagna dei Fiori area is not yet proven. Syn-orogenic deposits include
Miocene marls and turbiditic sandstones (Marne con Cerrogna and Laga
formations) (Artoni, 2013, and references therein).</p>
      <p id="d1e315">The deposition of the Calcare Massiccio Formation (Hettangian to Sinemurian),
with a total thickness varying between 300 and 700 m (Pialli, 1971), records
an important extension pulse in the evolution of Tethyan rifting. The lower
part of this formation, which was interpreted as having been deposited
in a peritidal environment, consists of peloidal pack- to grainstones in
alternation with peloidal wacke- to packstones including horizons of algal
bindstones (Calcare Massiccio A; Brandano et al., 2016). The upper part is
made up of beds of skeletal and coated grain wacke- to grainstones (Calcare
Massiccio B; Brandano et al., 2016). It corresponds to lower to middle shelf
depositional environments, characterized by a general deepening-upward
trend. Overall, the Early Jurassic rifting led to the growth of the Calcare
Massiccio Formation in a carbonate platform setting, followed by faulting
and drowning, and development of pelagic intrabasins filled by syn-rift
sediments (Fig. 1c; Bernoulli et al., 1979; Santantonio and Carminati, 2011).
The syn-rift<?pagebreak page1359?> sediments include pelagic limestones of the Bugarone and
Corniola formations. Condensed pelagic limestones of the Bugarone Formation
(Lower Pliensbachian to Lower Tithonian; “Bugarone Group” in Pierantoni et al.,
2013) occur at the top of the Calcare Massiccio Formation where it formed
fault-controlled highs marking the regional drowning of the carbonate
platform (Santantonio and Carminati, 2011). The pelagic limestones of the
Corniola Formation (Sinemurian to Toarcian; Colacicchi et al., 1975; Morettini
et al., 2002; Bosence et al., 2009; Marino and Santantonio, 2010; Brandano
et al., 2016) occur within the fault-controlled (half)grabens in lateral
continuation with the Calcare Massiccio Formation. The Corniola Formation in
the lower part consists of turbiditic lobes which originated from tectonic
brecciation of the Calcare Massiccio Formation. The upper part consists of a
well-bedded pelagic mudstone with chert nodules (Di Francesco et al., 2010).</p>
<sec id="Ch1.S2.SSx1" specific-use="unnumbered">
  <title>Structural framework</title>
      <p id="d1e323">The Montagna dei Fiori Anticline is intersected by two major fault
categories (Storti et al., 2018), which based on the chronological order
include the following. Firstly, <inline-formula><mml:math id="M8" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> E–W- and <inline-formula><mml:math id="M9" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> N–S-striking fault
zones showing extensional kinematics bounding the major outcrops of Calcare
Massiccio and dominantly affecting the Jurassic rocks older than the
Maiolica Formation (Fig. 2a; e.g., sites 1 to 4). Overprinting relations
indicate that <inline-formula><mml:math id="M10" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> E–W deformation structures are systematically
younger than the <inline-formula><mml:math id="M11" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> N–S ones. Similar trends were observed in
syn-rift fault zones in other anticlines of the Central Apennines (e.g., Cooper and Burbi, 1986; Alvarez, 1989; Chilovi et al., 2002). Such a
tectonosedimentary inheritance was involved in the growth of the Montagna
dei Fiori Anticline, which initiated during the Late Miocene (Mazzoli et
al., 2002; Artoni, 2003) and progressively evolved into the upper thrust
sheet of a well-developed antiformal stack until Plio-Pleistocene times
(e.g., Mazzoli et al., 2002; Calamita et al., 1994; Artoni, 2013). The
second set of faults is a major structural feature trending parallel to the
Montagna dei Fiori Anticline and dissecting it is the Montagna dei Fiori
Fault, a NNW–SSE-striking extensional fault system cutting at a high angle
through the folded footwall rocks, typically at the forelimb–crest
transition (Figs. 1, 2). This fault consists of two partially overlapping
main fault zones with an extensional stratigraphic separation exceeding 900 m, and juxtaposes intensely deformed Late Miocene sediments in the hanging
wall against dolomitized and undolomitized Lower Jurassic and Cretaceous
limestones in the footwall (Figs. 1 and 2). The development of the Montagna
dei Fiori Fault has been alternatively interpreted as either a pre-folding (e.g.,
Calamita et al., 1994; Mazzoli et al., 2002; Scisciani et al., 2002) or
late-folding (Ghisetti and Vezzani, 2000) feature. More recently, the origin
of the Montagna dei Fiori Fault has been ascribed to the mutual interaction
between horizontal shortening and uplift and episodic gravitational
re-equilibration during antiformal stacking underneath the anticline during
Plio-Pleistocene times (Storti et al., 2018). The dolomitized intervals are
exposed in the damage zones of both aforementioned fault categories.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Methodology</title>
      <p id="d1e363">The fieldwork covered an area of over 4 km<inline-formula><mml:math id="M12" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> to delineate the
distribution of dolostones. The stratigraphic and deformational features of
dolostones were analyzed in more than 60 outcrops. The distribution of
dolomitized intervals as well as their cross-cutting relationships with
bedding planes, stylolites, veins, and faults was documented and sampled.
For petrographic analyses, 130 polished thin sections were studied with
standard petrographic methods (transmitted and UV-fluorescent light
microscopy). Dolomite crystal morphology and texture is based on the
classification proposed by Sibley and Gregg (1987).</p>
      <p id="d1e375">The rock slabs and thin sections were stained using Alizarine Red S and
potassium ferricyanide (Dickson, 1966) to discriminate dolomite from calcite
and evaluate their iron content. Cold-cathode cathodoluminescence (CL) microscopy
was carried out on representative thin sections (<inline-formula><mml:math id="M13" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">80</mml:mn></mml:mrow></mml:math></inline-formula>) at KU Leuven
university (Belgium) using a Technosyn cathodoluminescence device (8–15 kV, 200–400 <inline-formula><mml:math id="M14" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>A gun current, 0.05 Torr vacuum, and 5 mm beam width).</p>
      <p id="d1e398"><inline-formula><mml:math id="M15" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M16" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> analysis were carried out on 117 samples. To ensure the sampling quality and avoid physical mixing of
different diagenetic phases, the thin section images were mapped and the
sampling targets were determined. Nevertheless, some diagenetic phases could
not be isolated due to their sequential overgrowth and small size. Powder
samples (150–200 <inline-formula><mml:math id="M17" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>g) were obtained by applying a New Wave Research
micromilling device and a dental drill at KU Leuven university (Belgium).
The analysis was conducted at Parma University (Italy) and the
Friedrich-Alexander-Universität (Erlangen-Nürnberg, Germany)
laboratories using Finnigan DeltaPlus V and Thermo Finnigan 252 mass
spectrometers, respectively. The carbonate powders were reacted with 100 %
phosphoric acid at constant temperature of 75 <inline-formula><mml:math id="M18" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Several
additional <inline-formula><mml:math id="M19" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> reference gases (NBS18, NBS19, MAB99, and a pure Carrara
marble) with known isotopic ratios were analyzed during the measurements to
determine the <inline-formula><mml:math id="M20" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M21" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of the sample.
Reproducibility was checked by replicate analysis of laboratory standards
and was better than <inline-formula><mml:math id="M22" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn></mml:mrow></mml:math></inline-formula> ‰ for <inline-formula><mml:math id="M23" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>
and <inline-formula><mml:math id="M24" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.2</mml:mn></mml:mrow></mml:math></inline-formula> ‰ for <inline-formula><mml:math id="M25" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> at Parma
University and <inline-formula><mml:math id="M26" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.04</mml:mn></mml:mrow></mml:math></inline-formula> for <inline-formula><mml:math id="M27" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M28" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.05</mml:mn></mml:mrow></mml:math></inline-formula> ‰ for <inline-formula><mml:math id="M29" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> at
Friedrich-Alexander-Universität. Oxygen isotope composition of dolomites
was corrected using the acid fractionation factors given by Rosenbaum and
Sheppard (1986). Duplicate homogeneous samples were measured in both labs for
interlaboratory reproducibility. All carbon and oxygen values are reported
in per mill, relative to the Vienna Pee Dee Belemnite (V-PDB).</p>
      <?pagebreak page1360?><p id="d1e574">A total number of 21 samples were analyzed for their <inline-formula><mml:math id="M30" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula>
ratios. The analyses were conducted at the Department of Analytical
Chemistry, Ghent University (Belgium) and at the Vrije Universiteit
Amsterdam (the Netherlands). NIST SRM 987 was used as the international Sr
standard in both labs. At Ghent University, 15 sample powders (20 mg) were
collected using a dental drill device. The <inline-formula><mml:math id="M31" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratio
measurements were performed using a Thermo Scientific Neptune
multi-collector inductively coupled plasma mass spectrometer
(MC-ICP-MS) instrument. Within the external precision, repeated
analyses of the international Sr standard yielded an average
<inline-formula><mml:math id="M32" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratio of <inline-formula><mml:math id="M33" display="inline"><mml:mrow><mml:mn mathvariant="normal">0.710271</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.000023</mml:mn></mml:mrow></mml:math></inline-formula> (2 SD,  <inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">43</mml:mn></mml:mrow></mml:math></inline-formula>), in
agreement with the accepted <inline-formula><mml:math id="M35" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratio of 0.710248 for this
reference sample (Thirlwall, 1991). At Vrije Universiteit Amsterdam, six
sample powders (2–3 mg) were collected using a New Wave Research
micromilling device. Analyses were performed using a Thermo Electron Triton
plus thermal ionization mass spectrometry (TIMS) instrument. In order to monitor and document the system's
performance, repeated analyses of the international Sr standard (<inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">58</mml:mn></mml:mrow></mml:math></inline-formula>)
were carried out on load sizes of 10  and 100 ng which yielded average
<inline-formula><mml:math id="M37" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios of <inline-formula><mml:math id="M38" display="inline"><mml:mrow><mml:mn mathvariant="normal">0.710245</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.000022</mml:mn></mml:mrow></mml:math></inline-formula> (2SD) and
<inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:mn mathvariant="normal">0.710242</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.000008</mml:mn></mml:mrow></mml:math></inline-formula> (2SD), respectively. In both labs mass
discrimination correction was performed via internal normalization using
Russell's exponential law and the accepted value (0.1194; Steiger and Jager,
1977) of the invariant <inline-formula><mml:math id="M40" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">88</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratio.</p>
      <p id="d1e753">Fluid inclusion microthermometry analysis was performed on 11 doubly
polished wafers (80–130 <inline-formula><mml:math id="M41" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m in thickness). Measurements were carried
out at Parma University (Italy) using Linkam THMSG-600 and Linkam
MDS-600 heating–cooling stages coupled with a Leica DM 2500 microscope.
The final melt (Tm<inline-formula><mml:math id="M42" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:math></inline-formula>) and homogenization temperatures (<inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">h</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) were
reproducible within 0.5 and 5 <inline-formula><mml:math id="M44" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, respectively. The
stages were calibrated by synthetic Syn Flinc<sup>™</sup>
fluid inclusion standards. A
100<inline-formula><mml:math id="M45" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> objective was used during the microthermometry runs of the small
inclusions. The microthermometry data were collected following the fluid
inclusion assemblage (FIA) approach described in Goldstein and Reynolds (1994) for carbonate minerals. The inconsistent homogenization temperatures
and salinities obtained for these fluid inclusions, within the framework of
an individual fluid inclusion assemblage (FIA) described by Goldstein and
Reynolds (1994), indicate possible re-equilibration (stretched) of these
inclusions and thus are not used in the interpretations. It is common for
small inclusions (&lt; 3 <inline-formula><mml:math id="M46" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m) to remain in an all-liquid monophase at
room temperature due to their metastability (Goldstein and Reynolds, 1994).
Thus, to eliminate the possible role of metastability, the samples were
placed in a freezer for several days following the procedures described in
detail by Goldstein and Reynolds (1994). All-liquid inclusions remained
unchanged and no vapor bubble was developed within them, which discards the
metastability effect. In order to properly observe the phase transitions and
determine the final melting temperature of ice in the all-liquid inclusions,
they were rapidly heated up to <inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mspace linebreak="nobreak" width="0.25em"/><mml:mn mathvariant="normal">200</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M48" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C to stretch
and nucleate a bubble at room temperature (Goldstein, 1990). The salinities
are reported in equivalent weight percent NaCl (eq. wt % NaCl) and were
calculated based on the equation of Bodnar (1993). The homogenization
temperatures obtained in all-fluid inclusion assemblages indicate the
minimum temperatures at which the fluids could have been trapped (Goldstein
and Reynolds, 1994). No correction was made for pressure effects on
entrapment temperatures since no data regarding the exact depth and pressure
of entrapment are available. In the absence of independent thermal indicators
such as the Conodont Alteration Index (CIA) and vitrinite reflectance (VR), the
accuracy of pressure correction cannot be well constrained (Slobodník
et al., 2006), and thus no correction was made for pressure effects on
homogenization temperatures.</p>
      <p id="d1e832">In order to perform high-resolution petrography, scanning electron
microscope (SEM) and back-scattered scanning electron microscope (BSEM)
analyses were conducted using a JEOL 6400 scanning electron microscope (SEM)
equipped with an Oxford EDS (energy dispersive system). Operating conditions
were 15 kV and 1.2 nA, electron beam about 1 <inline-formula><mml:math id="M49" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m in diameter, and 100 s
counting time; errors are <inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:math></inline-formula> %–5 % for major elements and <inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> %–10 % for minor components. The analysis focused mainly on detecting
possible dolomite crystals inside the bed-perpendicular stylolites
affecting the Cretaceous Scaglia Formation.</p>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Results</title>
<sec id="Ch1.S4.SS1">
  <label>4.1</label><title>Field observation and distribution of the dolomitized bodies</title>
      <p id="d1e878">There is no evidence of dolomitization in the overlying and immediate
surrounding successions of the Calcare Massiccio, Bugarone, and Corniola
formations (e.g., Maiolica and Scaglia formations), though the base of
Maiolica Formation is reported as dolomitized in the Central Apennines
onshore (e.g., Pierantoni et al., 2013) and offshore areas (Murgia et al.,
2004).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><label>Figure 3</label><caption><p id="d1e883"><bold>(a)</bold> Field photograph showing the deformed Scaglia Formation in the
hanging wall (HW) and brecciated, dolomitized Calcare Massiccio Formation in
the footwall (FW) of the Montagna dei Fiori Fault. The red arrow indicates
the sense of fault movement. <bold>(b)</bold> A hand specimen from the deformed Scaglia
Formation showing abundant pressure solution seems (TS), indicated by
arrows, cross-cutting calcite veins (C2). <bold>(c)</bold> A transmitted light
photomicrograph of the dolomitized, brecciated Calcare Massiccio Formation.
Note all the breccia fragments are composed of dolomite (D4 here).</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f03.jpg"/>

        </fig>

      <p id="d1e900">Dolomitized intervals are folded in the forelimb of the Montagna dei Fiori
Anticline and are abruptly truncated by the Montagna dei Fiori Fault, which
juxtaposes them against intensely foliated Scaglia, Bisciaro, and Marne con
Cerrogna formations (Figs. 2 and 3). The distribution of dolomitized
intervals is wider in the Salinello creek (Figs. 1b, 2a), perhaps due to a
better exposure. In the Corano Quarry location, dolomitization occur in the
Calcare Massiccio and Bugarone formations only as meter-sized dolostone
geobodies in the footwall of the Montagna dei Fiori Fault (Fig. 4). The map
pattern (Fig. 2) of dolostones indicates that their distribution is
maximized in the Castel Manfrino to Osso Caprino hill area and fades out both
southward and eastward.</p>
      <?pagebreak page1361?><p id="d1e904">The lateral extent of dolomitization is gradual. In some outcrops,
dolomitization fronts show irregular outlines following, but also
cross-cutting, bedding surfaces (Fig. 5). Dolomitized intervals vary in
thickness from a few meters to hundreds of meters affecting the totality of the
exposed Calcare Massiccio and the lower part of Corniola Formation, where no
clay interlayers are present. In the Calcare Massiccio Formation,
dolomitization does not follow a systematic pattern. In the northern side of
the Osso Caprino hill (Fig. 2), the top of formation is dolomitized but
moving toward the Salinello creek and a thick non-dolomitized limestone is
exposed. The same situation occurs on the opposite side of the creek and to
the east of Castel Manfrino.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><?xmltex \currentcnt{4}?><label>Figure 4</label><caption><p id="d1e909">Field photographs (Corano Quarry) showing the field relations
between dolostones (only D3 here), host limestones, and the Montagna dei
Fiori Fault. <bold>(a)</bold> Panoramic view showing the spatial relationship between
limestones and dolostones (orange) in the damage zone of the Montagna dei
Fiori Fault (F). Note that the limestones and including dolostones of the
Calcare Massiccio and Bugarone formations on the footwall (FW) and marly
limestones of the Scaglia Formation on the hanging wall (HW) are intensely
deformed. <bold>(b)</bold> Plan view of the dolomitized Calcare Massiccio limestone in the
footwall damage zone, intersected by calcite veins (C1) which are partially
dolomitized and affected by bed-perpendicular stylolites (arrows). <bold>(c)</bold> Distinct transition (dashed line) between dolomitized and undolomitized
Calcare Massiccio limestone in the footwall damage zone.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f04.jpg"/>

        </fig>

      <p id="d1e927">Dolomitized intervals in the Corniola Formation have a darker color relative
to the host rock and are systematically more fractured than the hosting
limestone. High-amplitude (&gt; 1 mm) bed-parallel stylolites are
clearly visible in both limestones and dolostones (Fig. 5). However, in some
dolostones only ghosts of stylolite traces can be seen. No apparent porosity
could be observed in host rock limestones but the dolostones locally contain
porosity, appearing as millimeter- to centimeter-sized pores. Dolostone
breccias in fault cores are typically clast supported, with angular and
millimeter- to centimeter-sized fragments (Fig. 3c), changing to crackle
breccia (Woodcock and Mort, 2008) away from the main slip surface. In the
proximity of the main slip surface, dolostone fragments are sporadically
cross-cut by millimeter-sized dolomite veins. The breccia fragments, where
cemented, are commonly surrounded by calcite cement.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><label>Figure 5</label><caption><p id="d1e932">Field photograph <bold>(a)</bold> and a simplified sketch <bold>(b)</bold> of field site d
showing a dolomitic pocket (grey color) and its relation with bed-parallel
stylolites within the Calcare Massiccio Formation (hammer is 40 cm long).
Note C1 is the only calcite cement here.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f05.jpg"/>

        </fig>

</sec>
<sec id="Ch1.S4.SS2">
  <label>4.2</label><title>Petrography</title>
<sec id="Ch1.S4.SS2.SSS1">
  <label>4.2.1</label><title>Early calcite cementation</title>
      <p id="d1e962">The early diagenetic products in the studied intervals are generally
nonferroan calcite cements. The first calcite cements precipitated
following a phase of bioclast micritization (sensu Bathurst, 1975) in
grain-supported intervals. In chronological order they include the following: (1)<?pagebreak page1362?> fibrous
cements (FC) riming the bioclasts, mostly in the peloidal facies of the
Calcare Massiccio Formation (Fig. 6a). These cements are dark-brown to
non-luminescent under cathodoluminescence; (2) mosaic cements (MC) commonly
fill the intergranular pore spaces (Fig. 6b) and also occur as syntaxial
overgrowths on echinoderm fragments. They exhibit deformation twinning and
show a well-developed brown and orange concentrically zoned
cathodoluminescence pattern (Fig. 6c and d). They contain only monophase
all-liquid inclusions. All of these cements are postdated by dolomites and
high-amplitude bed-parallel stylolites (Fig. 6b).</p>
</sec>
<sec id="Ch1.S4.SS2.SSS2">
  <label>4.2.2</label><title>Dolomitization</title>
      <p id="d1e973">All the dolomite types are nonferroan and dominantly fabric destructive.
Dolomitization developed in all the facies types of the Calcare Massiccio
and the overlaying Bugarone formations, but only at the lower part of the
Corniola Formation which consists of resedimented Calcare Massiccio breccias
(turbiditic lobes).</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F6" specific-use="star"><?xmltex \currentcnt{6}?><label>Figure 6</label><caption><p id="d1e978">Undolomitized and dolomitized Calcare Massiccio Formation in field
site d. <bold>(a)</bold> Transmitted light image showing a micritic peloid rimmed by
fibrous cements (FC) which are overgrown by mosaic cements (MC). <bold>(b)</bold> Transmitted light image showing mosaic cements (MC) in a peloidal limestone
overprinted by high-amplitude bed-parallel stylolites (dotted white line).
Note the core of some of the peloids is partially cemented as well. <bold>(c, d)</bold> Transmitted light and corresponding cathodoluminescence image, respectively,
of FC and MC cements. <bold>(e)</bold> Transmitted light photomicrograph showing D1
crystals (arrows) lining a fracture which is cemented by C1. The fracture is
in turn affected by a bed-parallel stylolite. <bold>(f)</bold> Cathodoluminescence image
showing D1 scattered in the host rock and riming the fracture. <bold>(g, h)</bold> Transmitted light and corresponding cathodoluminescence image, respectively,
showing part of a bed-parallel stylolite (dotted white line) overprinting D1
and D2 crystals.</p></caption>
            <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f06.jpg"/>

          </fig>

      <p id="d1e1006">The two first dolomite types (D1 and D2) are the dominant dolomite types in
the studied outcrops. These dolomites are distributed within the damage
zones of the <inline-formula><mml:math id="M52" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> N–S and E–W Jurassic rift-related extensional
faults and, in places, displaced by them (Fig. 2a, site 1). The third and
fourth dolomite types (D3 and D4) are mainly observed within the damage zone
of the Montagna dei Fiori Fault (NNW–SSE) and appear only as dolomitic
pockets locally replacing the host rock and overgrowing D1 and D2 at the
proximity of the <inline-formula><mml:math id="M53" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula>N–S and E–W extensional faults. The fifth
dolomite type (D5) is found only within the brecciated zones associated with
the Montagna dei Fiori Fault damage zone. The distinctive petrographic
features of the recognized dolomite types are summarized below:</p>
      <?pagebreak page1365?><p id="d1e1024">Dolomite 1 (D1) is a replacive dolomite which commonly appears as dispersed
rhombs and aggregates, and locally rims fracture walls cemented by calcite
(Fig. 6e and f). D1 postdates the micritic envelopes and early calcite
cements, and predates high-amplitude bed-parallel stylolites (Fig. 6g and h). The crystals are fine-to-medium sized (&lt; 350 <inline-formula><mml:math id="M54" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m) with
planar-e and planar-s textures consisting of relatively turbid (rich in host rock solid inclusions) well-developed crystals. They show red
luminescence when viewed under cathodoluminescence.</p>
      <p id="d1e1035">Dolomite 2 (D2) is a replacive dolomite (Fig. 7a and b), infrequently
occluding existing pore spaces. Like D1, it also predates high-amplitude
bed-parallel stylolites (Fig. 6g and h). D2 generally exhibits a closely
packed texture with no or little intercrystalline porosity. The crystals are
medium-to-coarse sized (<inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M56" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m) with planar-s to nonplanar
textures. They include a turbid core followed by a transparent rim and trace
quantities of saddle dolomite developing sweeping extinction. In some
crystals, one additional turbid zone rich in host rock solid inclusions and
fluid inclusions of mostly monophase is present. Cathodoluminescence
observations enabled us to recognize the presence of D1 in their turbid cores.
D2 crystals are characterized by zones of bright red-pink luminescence
separated by purple luminescence zones (Fig. 7b).</p>
      <p id="d1e1056">Dolomite 3 (D3) is present as small localized bodies in the Calcare
Massiccio (at the Castel Manfrino reference section), in the Corniola
Formation (at the Osso Caprino road), and in the Calcare Massiccio and
Bugarone formations (at the Corano Quarry) (Figs. 1b and 2a). In the Corano
Quarry the dolomitized Bugarone and Calcare Massiccio formations are in the
footwall of the Montagna dei Fiori Fault; juxtaposed to the
undolomitized, intensely foliated Scaglia Formation in the hanging wall. The
SEM and BSEM analyses performed on the samples from the immediate adjacent
Scaglia Formation within the aforementioned fault damage zone do not
indicate the presence of any dolomite in this formation. Within the Bugarone
Formation in this fault damage zone, D3 locally cements the millimeter-sized
angular breccias that are in turn affected by fault-parallel stylolites
(Fig. 7c and d). D3 crystals are fine-to-medium sized (&lt; 300 <inline-formula><mml:math id="M57" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m) exhibiting planar-e to nonplanar textures, with minor
development of saddle morphologies of larger crystals (&gt; 500 <inline-formula><mml:math id="M58" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m) with planar-c texture (Fig. 7e to h). The replacive crystals
display a faint core, which compared to previous dolomite types has fewer
solid inclusions. The saddle crystals are occasionally replacive. They
display typical curved and slightly serrated crystal terminations with
sweeping extinction. These saddle dolomites were only observed in the Castel
Manfrino reference section. D3 generally exhibits a dark purple color with
bright orange zones and subzones in core and/or rims when viewed under
cathodoluminescence (Fig. 7e to h).</p>
      <p id="d1e1075">Dolomite 4 (D4) appears as a matrix replacive and dolomite cement
surrounding porosity, and locally replacing D1 and D2 (Fig. 8a to f). D4
also occludes bed-parallel shear fractures and appears along the
bed-parallel stylolites (Fig. 9a to d). In the Castel Manfrino reference
section, some intercrystalline vuggy porosity is filled with fine dolomite
rhombs including D4 with relics of D2 within their core (Fig. 8e and f).
This porosity may be preserved or partially-to-completely filled by calcite
(C4). D4 crystals have a turbid, solid-inclusion-rich core and transparent
rim. They are fine-to-medium sized (&lt; 200–350 <inline-formula><mml:math id="M59" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m), presenting
planar-s and infrequent nonplanar textures. D4 exhibits a distinct
luminescence pattern including a purple zone and an irregular green subzone.</p>
      <p id="d1e1086">Dolomite 5 (D5) occurs as crystals cementing microveins that cross-cut
precursor dolomite types including dolomitic breccia fragments. In cemented
breccias, D5 is postdated by C3. D5 presents a planar-c texture and is
characterized by a bright red luminescence (Fig. 9e and f).</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F7" specific-use="star"><?xmltex \currentcnt{7}?><label>Figure 7</label><caption><p id="d1e1092"><bold>(a, b)</bold> Photomicrographs of transmitted light and
corresponding cathodoluminescence image, respectively, showing the zoned rhombs of D2 with
the remnants of D1 preserved in their cloudy core sampled from dolomitized
Calcare Massiccio Formation in field site d. The pore space is occluded by
D4. <bold>(c, d)</bold> D3 cementing angular breccia fragments of the Bugarone Formation
in the damage zone of the Montagna dei Fiori Fault in the Corano Quarry
site. Note the breccia is overprinted by a fault-parallel bed-perpendicular
stylolite. <bold>(e, f)</bold> Photomicrographs of transmitted light and
corresponding cathodoluminescence image, respectively, showing the euhedral to subhedral
crystals of D3 entirely replacing the matrix and also present as cement
developing a bright subzone and rim sampled from dolomitized Corniola
Formation in Osso Caprino road. <bold>(g, h)</bold> D3 with a saddle crystal outline (SD)
postdating calcite cements (MC) and a zoned D2 crystal. The saddle
morphology is outlined by a dotted white line.</p></caption>
            <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f07.jpg"/>

          </fig>

</sec>
<sec id="Ch1.S4.SS2.SSS3">
  <label>4.2.3</label><title>Late calcite cementation</title>
      <p id="d1e1120">Four generations of calcite postdating dolomitization and distributed only
within the fault damage zones have been identified (Figs. 10 and 11):</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F8" specific-use="star"><?xmltex \currentcnt{8}?><label>Figure 8</label><caption><p id="d1e1125">Photomicrographs from transmitted light and
corresponding cathodoluminescence of dolomite types. <bold>(a, b)</bold> The
cross-cutting relationship between D3 and D4 sampled from dolomitized
Corniola Formation in Osso Caprino road is shown. Note the presence of D3 within the
core of dolomite crystals overgrown by D4. <bold>(c, d)</bold> Successions of dolomite
types sampled from dolomitized Calcare Massiccio Formation in field site f.
Note the green CL color of D4 crystals. Typically, luminescent dolomites are
known to show yellow or orange-to-red colors (Machel et al., 1991). Green
luminescence in carbonates including dolomite have been attributed by a
number of researchers to the incorporation of three valent rare-earth
elements (REE) such as Dy<inline-formula><mml:math id="M60" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> and U<inline-formula><mml:math id="M61" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> as luminescence activators
within their crystal lattice (Luczaj and Goldstein, 2000). Another
possibility is the emplacement of <inline-formula><mml:math id="M62" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Mn</mml:mi><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, with yellow luminescence, in
<inline-formula><mml:math id="M63" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Ca</mml:mi><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> sites with blue luminescence in the dolomite crystal lattice
instead of preferential incorporation in the <inline-formula><mml:math id="M64" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Mg</mml:mi><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> site (Sommer, 1972;
Amieux, 1982; Walker et al., 1989; Habermann et al., 1999). Accordingly,
non-stoichiometric Ca-rich poorly ordered dolomites may favor <inline-formula><mml:math id="M65" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Mn</mml:mi><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>
incorporation into their <inline-formula><mml:math id="M66" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Ca</mml:mi><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> site. <bold>(e, f)</bold> Vuggy porosity rimmed by D4
(green CL). Note the porosity is filled with fine dolomite rhombs including
traces of D2 in their core and D4 overgrowths.</p></caption>
            <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f08.jpg"/>

          </fig>

      <p id="d1e1238">Calcite 1 (C1) occurs only in Calcare Massicio limestones and dolostones and
is represented as centimeter-sized veins with thicknesses that do not exceed
1.5 cm. It is not clear whether the fracture opening and calcite
precipitation was simultaneous (as shown in Ukar and Laubach, 2016). These
veins are strata-bound bed-perpendicular with irregular fracture walls,
exhibiting white color in the outcrops. They are present within the syn-rift-related extensional fault damage zones, postdating the first dolomite type
(D1) and abutted by high-amplitude bed-parallel stylolites. C1 usually shows
blocky to elongated crystal morphologies and displays well-developed
deformation twinning planes (Type II of Burkhard, 1993). This calcite
exhibits concentric zonation and brown zones alternate with orange
luminescence zones (Fig. 11a and b).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9" specific-use="star"><?xmltex \currentcnt{9}?><label>Figure 9</label><caption><p id="d1e1244">Photomicrographs showing transmitted light and
corresponding cathodoluminescence images of D4 and D5 in relation to
stylolites and fracturing. <bold>(a, b)</bold> D4, exploiting a bed-parallel stylolite
that cross-cuts D1 and D2 sampled from dolomitized Calcare Massiccio
Formation in field site d. <bold>(c, d)</bold> A subhorizontal fracture cemented by D4
sampled from dolomitized Corniola Formation in field site f. <bold>(e, f)</bold> D5
microveins (arrows) intersecting all the predating dolomite types in the
footwall brecciated zone of the Montagna dei Fiori Fault, sampled from
dolomitized Calcare Massiccio Formation in Castel Manfrino site.</p></caption>
            <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f09.jpg"/>

          </fig>

      <p id="d1e1262">Calcite 2 (C2) exclusively occurs in the intensely deformed Scaglia
Formation within the fault damage zones (Fig. 11b, c and d) and correspond
to tension gashes associated with stylolites (sensu Nelson, 1981). The
thicknesses of these veins do exceed 1 cm. They are usually discontinuous
and branch to several microveins (thickness &lt; 1 mm) when their tips
are not intersected by stylolites. C2 veins are mostly recorded in foliated
shear deformation zones with well-defined S–C fabrics, exhibiting blocky,
elongated to fibrous shapes with strongly developed tightly spaced
deformation twinning planes (Type II of Burkhard, 1993). C2 displays brown-to-orange luminescence with locally darker sector zones. The brown-to-orange
luminescence characteristic of C2 is similar to those of encasing Scaglia
host rocks (Fig. 11c and d).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F10" specific-use="star"><?xmltex \currentcnt{10}?><label>Figure 10</label><caption><p id="d1e1267">Field photographs showing the major calcite vein settings
observed in Montagna dei Fiori. <bold>(a)</bold> Cross-sectional view of bed-normal
calcite vein 1 (C1) abutting bed-parallel stylolites in folded beds of the
Calcare Massiccio Formation. <bold>(b)</bold> Plan view of the calcite vein 2 (C2)
intensely affecting the deformed Scaglia (Rossa) Formation. <bold>(c, d)</bold> Cross-sectional view of the Scaglia Formation intensely affected by
pressure solution seams of tectonic origin crossed over by populations of
bed-perpendicular calcite veins (C3) in en echelon extensional arrays.</p></caption>
            <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f10.jpg"/>

          </fig>

      <?pagebreak page1368?><p id="d1e1285">Calcite 3 (C3) occurs as cement, filling the Montagna dei Fiori main fault
plane and isolated veins within its damage zone. These veins are
centimeter sized with thicknesses of less than 2 cm. The breccias are
generally clast supported but locally C3 cements the brecciated
fault infillings containing angular fragments of host rock limestones,
dolostones, and earlier calcites. In the brecciated zones, C3 always
passively overgrows D5 in fractures and never cuts it. C3 exhibits a
translucent white color in hand specimen. The crystals are blocky with no or
weakly developed deformation twinning planes and are characterized by a
dark-orange-to-brown luminescence with distinct darker sector zones (Fig. 11e and f).</p>
      <p id="d1e1288">Calcite vein 4 (C4) exists as centimeter-sized isolated veins, pore filling,
and breccia cements postdating all the preceding dolomites and
calcites in the Montagna dei Fiori main fault plane. The breccia fragments
are usually dolostones. C4 has a translucent white color in hand specimen
with blocky crystal morphology and no evidence of subsequent deformation
(e.g., deformation twinning planes), and is characterized by distinct
concentric zonation (Fig. 11g and h).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e1295">Stable carbon and oxygen isotopes, <inline-formula><mml:math id="M67" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios, and fluid
inclusion microthermometry data (not pressure corrected) of host rocks and
diagenetic phases in the Montagna dei Fiori Anticline. Stable carbon and
oxygen isotopes values are expressed in ‰  V-PDB and
salinity values in eq. wt % NaCl.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="7">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" namest="col2" nameend="col3" align="center">Stable isotopes </oasis:entry>
         <oasis:entry colname="col4">Sr isotopes</oasis:entry>
         <oasis:entry rowsep="1" namest="col5" nameend="col6" align="center">Fluid inclusion microthermometry </oasis:entry>
         <oasis:entry colname="col7"/>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M68" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M69" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M70" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5">Th (<inline-formula><mml:math id="M71" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>
         <oasis:entry colname="col6">Salinity</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M72" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Calcare Massiccio Fm.</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.4</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M74" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M75" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.6</mml:mn></mml:mrow></mml:math></inline-formula> to 0.0</oasis:entry>
         <oasis:entry colname="col4">0.70766</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Corniola Fm.</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M76" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.0</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M77" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M78" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3.1</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M79" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.4</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">0.70725</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Scaglia Fm.</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M80" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.0</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M81" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M82" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.2</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M83" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.0</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">0.70784–0.70791</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">D1</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M84" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M85" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.9</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">0.70789</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula>–50</oasis:entry>
         <oasis:entry colname="col6">3.5 to 11.3</oasis:entry>
         <oasis:entry colname="col7">27</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CV1</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M87" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.6</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M88" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4.7</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M90" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.7</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">0.70773</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">D2</oasis:entry>
         <oasis:entry colname="col2">–</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula>–50 to 71</oasis:entry>
         <oasis:entry colname="col6">7.9 to 20.5</oasis:entry>
         <oasis:entry colname="col7">37</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">D3</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M92" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.0</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.6</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.8</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M95" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.9</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">0.70859–0.70964</oasis:entry>
         <oasis:entry colname="col5">70 to 73</oasis:entry>
         <oasis:entry colname="col6">9.2 to 16.9</oasis:entry>
         <oasis:entry colname="col7">9</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">D4</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M96" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.4</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M97" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M98" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3.0</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M99" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">0.70790</oasis:entry>
         <oasis:entry colname="col5">79 to 105</oasis:entry>
         <oasis:entry colname="col6">12.8 to 18.6</oasis:entry>
         <oasis:entry colname="col7">7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CV2</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M100" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.2</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M101" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M102" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.7</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M103" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.6</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">0.70779–0.70787</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CV3</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M104" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M105" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.4</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.2</mml:mn></mml:mrow></mml:math></inline-formula> to 0.0</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M107" display="inline"><mml:mrow><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula>–50</oasis:entry>
         <oasis:entry colname="col6">4.5 to 9.7</oasis:entry>
         <oasis:entry colname="col7">9</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CV4</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M108" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.8</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M109" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>4.9</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M110" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9.4</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M111" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9.1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula>–50</oasis:entry>
         <oasis:entry colname="col6">0.17 to 3.0</oasis:entry>
         <oasis:entry colname="col7">19</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <?xmltex \floatpos{p}?><fig id="Ch1.F11" specific-use="star"><?xmltex \currentcnt{11}?><label>Figure 11</label><caption><p id="d1e2066"><bold>(a)</bold> Cathodoluminescence and transmitted light (inset) images
showing blocky-to-elongated crystals of C1 with zoned CL pattern in the
Corano Quarry site. <bold>(b)</bold> Transmitted light image showing intensely twinned C1
crystals overprinted by euhedral to subhedral crystals of D3 in the Corano
Quarry site. Photomicrographs of transmitted light and
corresponding cathodoluminescence image: <bold>(c, d)</bold> C2 in the Scaglia Formation
abutted by a bed-perpendicular stylolite (indicated by white arrows and
dashed line) in the Corano Quarry site. The crystals display blocky to
fibrous morphologies, deformation twinning, and a similar orange
luminescence pattern similar to the adjacent host rock. <bold>(e, f)</bold> C3 cementing
the breccia fragments in the damage zone of the Montagna dei Fiori Fault.
The crystals are blocky and show faint deformation twinning. They are
brown-orange with distinct darker luminescence sector zones. <bold>(g, h)</bold> C4
presents as a cement within a polygonal pore space rimmed by dolomite,
sampled from dolomitized Calcare Massiccio Formation in field site f. Note
the blocky crystals, absence of deformation twinning, and distinct concentric
luminescence zonation pattern. C4 is corroded and followed by a late
telogenetic calcite.</p></caption>
            <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f11.jpg"/>

          </fig>

</sec>
</sec>
<?pagebreak page1369?><sec id="Ch1.S4.SS3">
  <label>4.3</label><title>Geochemistry</title>
<sec id="Ch1.S4.SS3.SSS1">
  <label>4.3.1</label><title>Carbon and oxygen stable isotopes</title>
      <?pagebreak page1371?><p id="d1e2105">The carbon and oxygen stable isotopic data (<inline-formula><mml:math id="M113" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M114" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>) of host rocks, dolomites, and calcites are given in Table 1 and
shown in Fig. 12a and b. The marine stable isotopic compositions reported
by Veizer et al. (1999) were used as marine reference values. Accordingly,
Lower Jurassic marine limestones are characterized by <inline-formula><mml:math id="M115" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>
values of <inline-formula><mml:math id="M116" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M117" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">4.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and <inline-formula><mml:math id="M118" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>
values of <inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.0</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB. The <inline-formula><mml:math id="M121" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of the marine dolomites are known to be
3 ‰–4 ‰ V-PDB more enriched than those of cogenetic
marine limestones (Land, 1980; Major et al., 1992; Horita, 2014). In order
to avoid data ambiguity due to physical mixing, this analysis was not
separately performed on early calcite cements (FC and MC). The <inline-formula><mml:math id="M122" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M123" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values were measured on bulk samples of host rock
limestones. Both <inline-formula><mml:math id="M124" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M125" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of the host
rocks are within the expected range of the Lower Jurassic marine limestones
but the Corniola host rocks show slightly lower values comparing to those of
Calcare Massiccio. In the Calcare Massiccio host rocks, the <inline-formula><mml:math id="M126" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> values plot between <inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.4</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and <inline-formula><mml:math id="M128" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.1</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and
<inline-formula><mml:math id="M129" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values are within the range of <inline-formula><mml:math id="M130" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.6</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and
0.0 ‰ V-PDB. The <inline-formula><mml:math id="M131" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> values in the
Corniola host rocks are <inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.0</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and <inline-formula><mml:math id="M133" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ while the
<inline-formula><mml:math id="M134" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values are <inline-formula><mml:math id="M135" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3.1</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M136" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.4</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB.
The <inline-formula><mml:math id="M137" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M138" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of the Scaglia host rocks
range between <inline-formula><mml:math id="M139" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.0</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and <inline-formula><mml:math id="M140" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.3</mml:mn></mml:mrow></mml:math></inline-formula> ‰ for <inline-formula><mml:math id="M141" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>
and <inline-formula><mml:math id="M142" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.2</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M143" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.0</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB for <inline-formula><mml:math id="M144" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>.
The values obtained are characterized in the mean range of Upper Cretaceous
to Paleogene marine limestones (Veizer et al., 1999; <inline-formula><mml:math id="M145" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.0</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to
<inline-formula><mml:math id="M146" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">4.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ for <inline-formula><mml:math id="M147" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M148" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4.0</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to
<inline-formula><mml:math id="M149" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.0</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB for <inline-formula><mml:math id="M150" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>).</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F12"><?xmltex \currentcnt{12}?><label>Figure 12</label><caption><p id="d1e2553">Overview of the <inline-formula><mml:math id="M151" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M152" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of
dolomites <bold>(a)</bold> host rocks from Montagna dei Fiori as well as calcite veins <bold>(b)</bold>. The stable isotope value of Lower Jurassic marine limestones based on
Veizer et al. (1999) is indicated by a dashed rectangle in subset B. The
<inline-formula><mml:math id="M153" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of the marine dolomites are considered to be
3 ‰–4 ‰ V-PDB higher than those of marine limestones
(Land, 1980; Major et al., 1992; Horita, 2014). <bold>(c)</bold> Cross plot of
<inline-formula><mml:math id="M154" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios and corresponding <inline-formula><mml:math id="M155" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of
host rocks, dolomites, and calcite veins compared with Lower Jurassic marine
carbonates <inline-formula><mml:math id="M156" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> (dashed rectangle) framework reported by
McArthur et al. (2012).</p></caption>
            <?xmltex \igopts{width=233.312598pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f12.png"/>

          </fig>

      <p id="d1e2662">The <inline-formula><mml:math id="M157" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> values of C1 are between <inline-formula><mml:math id="M158" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.6</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and
<inline-formula><mml:math id="M159" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.1</mml:mn></mml:mrow></mml:math></inline-formula> ‰, which plot within the range of reference values
(Jurassic) but are slightly lower than the surrounding host rock values. The
<inline-formula><mml:math id="M160" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values are between <inline-formula><mml:math id="M161" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4.7</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and
<inline-formula><mml:math id="M162" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.7</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB, which are lower than those of
reference and host rock values.</p>
      <p id="d1e2733">The <inline-formula><mml:math id="M163" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> values of all dolomite types (<inline-formula><mml:math id="M164" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.6</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to
<inline-formula><mml:math id="M165" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.4</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">‰</mml:mi></mml:mrow></mml:math></inline-formula>) fall within the range of host rocks and
Jurassic marine limestones (Veizer et al., 1999). The <inline-formula><mml:math id="M166" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>
shows a wider range of values, overlapping but also lower than host rocks
(<inline-formula><mml:math id="M167" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M168" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.9</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB) and those expected for the
Lower Jurassic marine dolomites. The majority of values plot between <inline-formula><mml:math id="M169" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰
and <inline-formula><mml:math id="M170" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB. The small size and overgrowth nature
of certain dolomite types (e.g., D2 and D5) limit their proper isolation for
geochemical analyses. Only one sample from D1 dolomite could be measured for
<inline-formula><mml:math id="M171" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M172" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values, showing <inline-formula><mml:math id="M173" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and
<inline-formula><mml:math id="M174" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.9</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB, respectively. The <inline-formula><mml:math id="M175" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>
and <inline-formula><mml:math id="M176" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of D3 dolomite range from <inline-formula><mml:math id="M177" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.0</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to
<inline-formula><mml:math id="M178" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.6</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and <inline-formula><mml:math id="M179" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.8</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M180" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.9</mml:mn></mml:mrow></mml:math></inline-formula> ‰
V-PDB, respectively, with values lower than those of the host rock.</p>
      <p id="d1e2940">D4 dolomite has <inline-formula><mml:math id="M181" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> values between <inline-formula><mml:math id="M182" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.4</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and
<inline-formula><mml:math id="M183" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰, and <inline-formula><mml:math id="M184" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of <inline-formula><mml:math id="M185" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3.0</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to
<inline-formula><mml:math id="M186" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB. The <inline-formula><mml:math id="M187" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M188" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of C2 are <inline-formula><mml:math id="M189" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.2</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M190" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.1</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and <inline-formula><mml:math id="M191" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.7</mml:mn></mml:mrow></mml:math></inline-formula> ‰
to <inline-formula><mml:math id="M192" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.7</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB, respectively. The <inline-formula><mml:math id="M193" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> values of C3 are between <inline-formula><mml:math id="M194" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and <inline-formula><mml:math id="M195" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.4</mml:mn></mml:mrow></mml:math></inline-formula> ‰,
and the <inline-formula><mml:math id="M196" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values cover a range of <inline-formula><mml:math id="M197" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.2</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to
0.0 ‰ V-PDB. The <inline-formula><mml:math id="M198" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M199" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of C4 are <inline-formula><mml:math id="M200" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.8</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M201" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">4.9</mml:mn></mml:mrow></mml:math></inline-formula> ‰ and <inline-formula><mml:math id="M202" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9.4</mml:mn></mml:mrow></mml:math></inline-formula> ‰
to <inline-formula><mml:math id="M203" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9.1</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-PDB, respectively. The <inline-formula><mml:math id="M204" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>
values are slightly higher but the <inline-formula><mml:math id="M205" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values are considerably
lower compared to preceding calcite generations and the measured values from
host rocks.</p>
</sec>
<?pagebreak page1372?><sec id="Ch1.S4.SS3.SSS2">
  <label>4.3.2</label><?xmltex \opttitle{{$\protect\chem{{}^{{87}}Sr/^{{86}}Sr}$} ratios}?><title><inline-formula><mml:math id="M206" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios</title>
      <p id="d1e3254">Samples from host rocks (i.e., Calcare Massiccio and Corniola formations),
dolomites (D1, D3, and D4), and the Scaglia Formation in juxtaposition with
the dolostones were analyzed for their <inline-formula><mml:math id="M207" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> isotopic ratios.
The obtained ratios versus <inline-formula><mml:math id="M208" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of the analyzed samples
are shown in Fig. 12c. The <inline-formula><mml:math id="M209" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios obtained from the Calcare
Massiccio and Corniola limestones are 0.70766 and 0.70725 (<inline-formula><mml:math id="M210" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:math></inline-formula>),
respectively, which is in agreement with the values of the Lower Jurassic
marine carbonates (0.70704–0.70768) reported by McArthur et al. (2012). CV1
shows a value equal to 0.70773.</p>
      <p id="d1e3320">All the dolomite types display higher <inline-formula><mml:math id="M211" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios when
compared to the host rocks and reference values of the Lower Jurassic marine
carbonates. D1 (replacive) and D4 cements show a similar narrow range with
values between 0.70784 and 0.70790. The two D3 samples
(replacive and cement) display higher <inline-formula><mml:math id="M212" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios (0.70858
and 0.70963, respectively). The <inline-formula><mml:math id="M213" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios obtained for dolomites do
not show covariation with corresponding <inline-formula><mml:math id="M214" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values. The
radiogenic Sr analysis was not performed on D2 and D5 since the physical
mixing with other dolomite types could not be avoided.</p>
      <p id="d1e3393">The <inline-formula><mml:math id="M215" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios of the three marly limestone samples of
Scaglia Formation are 0.70784 to 0.70790. The C2 veins in Scaglia Formation
show similar ratios of 0.70779 and 0.70787. These values fit within the
limits of values assigned by McArthur et al. (2012) for the
Cenomanian to Bartonian (Scaglia age) marine carbonates (0.70730–0.70790).</p>
</sec>
</sec>
<sec id="Ch1.S4.SS4">
  <label>4.4</label><title>Fluid inclusion microthermometry</title>
      <p id="d1e3424">The overview of microthermometry measurements is given in Table 1 and
Fig. 13a to c. All the measured fluid inclusions are primary and occur in
growth zones. Based on optical and fluorescence microscopy analysis of
wafers, all the inclusions are aqueous monophase (liquid) or have two phases
(liquid and vapor) with relatively consistent L:V ratios of 10 %–15 % within
a single FIA (fluid inclusion assemblage). Special care was taken to avoid
the samples that occasionally displayed scattered mottled luminescence that
may indicate recrystallization.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F13" specific-use="star"><?xmltex \currentcnt{13}?><label>Figure 13</label><caption><p id="d1e3429">Overview of microthermometry analysis of primary inclusions in
Montagna dei Fiori. <bold>(a)</bold> Frequency distribution of the Tmice (<inline-formula><mml:math id="M216" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)
in dolomite types. <bold>(b)</bold> Frequency distribution of the Th (<inline-formula><mml:math id="M217" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) in
dolomite types. <bold>(c)</bold> Salinity (eq. wt % NaCl) versus Th (<inline-formula><mml:math id="M218" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) of
dolomite and calcite phases. <bold>(d)</bold> Isotopic fractionation diagram from Land (1983) used to determine the isotopic composition (‰
V-SMOW, Vienna Standard Mean Ocean Water) of parental fluids in equilibrium with dolomites in Montagna dei
Fiori.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f13.png"/>

        </fig>

      <p id="d1e3478">D1 contains dominantly monophase aqueous inclusions with sizes greater than
5 <inline-formula><mml:math id="M219" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m. All the inclusions froze at <inline-formula><mml:math id="M220" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">65</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M221" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">49</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M222" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. The
first melting (Te) was detected between <inline-formula><mml:math id="M223" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">22</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M224" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">19.3</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M225" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. The
final ice melting (Tm) appeared at temperatures between <inline-formula><mml:math id="M226" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">7.7</mml:mn></mml:mrow></mml:math></inline-formula> and
<inline-formula><mml:math id="M227" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M228" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Applying the equation of Bodnar (1993), the
obtained final melting temperatures correspond to salinity ranges of 3.5 to
11.3 eq. wt % NaCl.</p>
      <p id="d1e3578">D2 is characterized by the presence of monophase and infrequent two-phase
inclusions generally within their growth zones. The homogenization
temperature of two-phase inclusions varies between 58 and 71 <inline-formula><mml:math id="M229" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C.
Upon cooling, a complete freezing of the fluid phase is reached at <inline-formula><mml:math id="M230" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">56</mml:mn></mml:mrow></mml:math></inline-formula> to
<inline-formula><mml:math id="M231" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M232" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. The first ice melting temperature was distinguished at
<inline-formula><mml:math id="M233" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">22</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M234" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. The final ice melting temperatures fall within <inline-formula><mml:math id="M235" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">17.5</mml:mn></mml:mrow></mml:math></inline-formula>
and <inline-formula><mml:math id="M236" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M237" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, corresponding to salinities between 7.9 and
20.5 eq. wt % NaCl.</p>
      <p id="d1e3668">D3 is commonly inclusion poor. The measurable inclusions were detected and
examined only in saddle dolomite crystals. These crystals contain only
two-phase aqueous inclusions. Their homogenization temperatures are within
the narrow range of 70 to 73 <inline-formula><mml:math id="M238" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. The complete freezing and first
ice melting temperatures could not be distinguished but the final ice
melting temperature occurred at temperatures between <inline-formula><mml:math id="M239" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13</mml:mn></mml:mrow></mml:math></inline-formula> and
<inline-formula><mml:math id="M240" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M241" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C equal to salinity ranges of 9.2 to 16.9 eq. wt % NaCl.
The first melting temperatures of fluid inclusions in D1, D2, and D3 were
about <inline-formula><mml:math id="M242" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">21</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M243" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, suggesting a <inline-formula><mml:math id="M244" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>-NaCl fluid system.</p>
      <p id="d1e3742">D4 contains only two-phase aqueous inclusions. The homogenization
temperatures in D4 vary between 79 and 105 <inline-formula><mml:math id="M245" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Complete freezing
of inclusions occurred at temperatures between <inline-formula><mml:math id="M246" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M247" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">54</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M248" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. The first ice melting was detected from <inline-formula><mml:math id="M249" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">35</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M250" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M251" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
indicating the possible presence of divalent cations such as <inline-formula><mml:math id="M252" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Ca</mml:mi><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>
and/or <inline-formula><mml:math id="M253" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Mg</mml:mi><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the fluids (Shepherd et al., 1985; Goldstein and
Reynolds, 1994). The final ice melting temperatures fall within a range of
<inline-formula><mml:math id="M254" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M255" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M256" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C corresponding to salinities of 12.8 to
18.6 eq. wt % NaCl. A couple of inclusions show homogenization
temperatures exceeding 120 <inline-formula><mml:math id="M257" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C with salinities higher than
20 eq. wt % NaCl.</p>
      <p id="d1e3880">No measurable fluid inclusion could be identified in C1 and C2 due to
intense deformation twinning. C3 and C4 contain only primary monophase
aqueous inclusions, indicating an entrapment temperature of below about
40–50 <inline-formula><mml:math id="M258" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (Goldstein and Reynolds, 1994). A complete freezing of
the inclusions in C3 occurred at temperatures between <inline-formula><mml:math id="M259" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula> and
<inline-formula><mml:math id="M260" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">52.5</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M261" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. The first melting temperature was detected at about
<inline-formula><mml:math id="M262" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">21</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M263" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">22</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M264" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, suggesting a <inline-formula><mml:math id="M265" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>-NaCl composition. The
final melting temperatures range between <inline-formula><mml:math id="M266" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6.4</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M267" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.7</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M268" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C,
corresponding to salinities between 9.7 and 4.5 eq. wt % NaCl. The
majority of the values cluster between 7.8 and 5 eq. wt % NaCl.</p>
      <p id="d1e3993">The complete freezing temperatures of the inclusions in C4 fall within
<inline-formula><mml:math id="M269" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">46</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M270" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">35.5</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M271" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. The first melting temperature could not be
determined with confidence but the final melting temperatures were reached
at about <inline-formula><mml:math id="M272" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M273" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M274" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, corresponding to salinities of
0.17 to 3.0 eq. wt % NaCl.</p>
</sec>
</sec>
<sec id="Ch1.S5">
  <label>5</label><title>Discussion</title>
<sec id="Ch1.S5.SS1">
  <label>5.1</label><title>Stable and radiogenic isotopic composition of the parental fluids</title>
      <p id="d1e4072">The <inline-formula><mml:math id="M275" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> values of all dolomite types mimic the range of host
rock and Jurassic marine limestones and, consequently, they can be
interpreted as largely rock buffered. Their <inline-formula><mml:math id="M276" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values are
partly similar to those of their respective host<?pagebreak page1373?> rocks as well as Jurassic
marine reference values but more depleted when compared to the presumable
Jurassic marine dolomites. The relatively depleted <inline-formula><mml:math id="M277" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>
dolomite values could indicate the contribution of heated fluids in
dolomitization process, although they could also relate to recrystallization
of a precursor dolomite by fluids at higher temperature or <inline-formula><mml:math id="M278" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>-depleted dolomite
(Land, 1980, 1985). The absence of distinctive textural evidence in the
analyzed samples such as enlarged crystal size and/or systematic mottled
cathodoluminescence pattern, and their covariation with <inline-formula><mml:math id="M279" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>
values, do not confirm recrystallization (Mazzullo, 1992, and references therein).</p>
      <p id="d1e4139">The oxygen isotope fractionation relation between water and dolomite (Land,
1983) was used to determine the most plausible parental fluids. In order to
avoid erroneous results due to rock-buffered <inline-formula><mml:math id="M280" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values, only
the <inline-formula><mml:math id="M281" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values of dolomite cements, especially from the
bed-parallel veins containing D4 were used. These values may provide the
closest approximation to the <inline-formula><mml:math id="M282" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> signature of the parental
fluids (Barker and Cox, 2011). Accordingly, a <inline-formula><mml:math id="M283" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> value of
<inline-formula><mml:math id="M284" display="inline"><mml:mrow><mml:mo>≈</mml:mo><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M285" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-SMOW (Vienna Standard Mean Ocean Water) was calculated for
D3, while this values increase to <inline-formula><mml:math id="M286" display="inline"><mml:mrow><mml:mo>≈</mml:mo><mml:mo>+</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to
<inline-formula><mml:math id="M287" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">7.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰ V-SMOW for D4 (Fig. 13d). The higher <inline-formula><mml:math id="M288" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> composition of the dolomitizing fluids relative to the Mesozoic
seawater, which is estimated at <inline-formula><mml:math id="M289" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.2</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M290" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> ‰
V-SMOW (Shackleton and Kennett, 1975; Marshall, 1992; Saelen et al.,
1996), is compatible with fluids derived from or that had interacted with
siliciclastic rocks, crystalline basement (Taylor, 1997) and/or
evaporite-derived brines.</p>
      <p id="d1e4272">The <inline-formula><mml:math id="M291" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios obtained for all dolomite types are higher
than the Lower Jurassic marine carbonate values (0.70704–0.70768; McArthur
et al., 2012). Since marine carbonates have very low rubidium (Rb)
concentrations they produce negligible in situ radiogenic <inline-formula><mml:math id="M292" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> after
their deposition (Stueber et al., 1972; Burke et al., 1982). Therefore, the
higher <inline-formula><mml:math id="M293" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios can be explained by the contribution of
fluids originated or interacted with potassium rich siliciclastic rocks
(K feldspars), crystalline basement, and/or stratigraphic levels with higher
<inline-formula><mml:math id="M294" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios (Emery and Robinson, 1993; Banner, 2004). Taking into
account that the Upper Triassic Burano Formation underlying the studied
intervals as the basal detachment has <inline-formula><mml:math id="M295" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios<?pagebreak page1374?> between
0.70774 and 0.70794 (Boschetti et al., 2005), the <inline-formula><mml:math id="M296" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios
(D1 and D4) can partially be explained by their contribution. However, this
contribution cannot justify much higher <inline-formula><mml:math id="M297" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios recorded
in D3, being higher than values reported for Phanerozoic seawater (McArthur
et al., 2012), and the values obtained for the adjacent basinal deposits
(i.e., Corniola and Scaglia formations). Therefore, parental fluids most
likely originated from or had interacted with the siliciclastic rocks
underlying the Burano Formation (Verrucano Formation), if present, and/or
with the crystalline basement with common elevated <inline-formula><mml:math id="M298" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula>
ratios (0.71500–0.72650; Del Moro et al., 1982). The significantly higher
<inline-formula><mml:math id="M299" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios in D3 in comparison with other studied dolomites
indicates a higher influence of <inline-formula><mml:math id="M300" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula>-rich fluids either due
to major changes in the permeability architecture of faults or availability
of such fluids. The lack of any ferroan diagenetic phase minimizes the
interaction of fluids produced by clay transformation or dewatering (i.e.,
smectite to illite transformation; Boles and Franks, 1979).</p>
      <p id="d1e4459">C1 is characterized by <inline-formula><mml:math id="M301" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M302" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values lower
than the host limestones (i.e., Calcare Massiccio), while its
<inline-formula><mml:math id="M303" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratio is similar to them. The salinity and composition
of the parental fluids cannot be inferred here since no measurable fluid
inclusions were found within this cement. The <inline-formula><mml:math id="M304" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratio
being within the range of the corresponding host rocks and the reference
values, points to a rock-buffered system for <inline-formula><mml:math id="M305" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e4546">The <inline-formula><mml:math id="M306" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M307" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values obtained for C2, as well
as <inline-formula><mml:math id="M308" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios, fall within the range of the Scaglia host
rocks, thus reflecting their rock-buffered nature. This interpretation is
further supported by the similar luminescence characteristics of C2 with
that of encasing Scaglia host rocks. The fluids from which C2 calcite
precipitated, as expected for tension gashes, were most likely derived from
carbonate dissolution during pressure solution and stylolitization of host
rock, pointing to a closed fluid system in contrast with the subsequent vein
generations.</p>
      <p id="d1e4594">C3 is characterized by <inline-formula><mml:math id="M309" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> values within the Jurassic marine
values but are generally lower than the host rocks, while their <inline-formula><mml:math id="M310" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>
values partially overlap both the hosting limestones and dolostones.
Microthermometry of fluid inclusions revealed only monophase aqueous
inclusions and thus precipitation at relatively low temperature (<inline-formula><mml:math id="M311" display="inline"><mml:mrow><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula>–50 <inline-formula><mml:math id="M312" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) with moderate salinity (4.5–9.7 eq. wt % NaCl).
Such levels of salinity can be assigned to evaporated seawater, residual
brines or fluids derived from evaporite dissolution, and thus makes it
difficult here to interpret their exact origin with the available data.</p>
      <p id="d1e4642">C4 is the latest calcite phase, and records the <inline-formula><mml:math id="M313" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and
<inline-formula><mml:math id="M314" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values, respectively enriched and significantly depleted
when compared to their hosting rocks and preceding diagenetic products.
Generally, the enrichment of <inline-formula><mml:math id="M315" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> could suggest <inline-formula><mml:math id="M316" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> outgassing due
to evaporation or pressure changes (Friedman, 1970; Hendry et al., 2015) or
bacterial fermentation (methanogenesis) of organic matter (Hudson, 1977) in
low-temperature diagenetic environments. The homogenization temperature of
C4, being below about 40–50 <inline-formula><mml:math id="M317" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, could support any of these
processes. Their low <inline-formula><mml:math id="M318" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values and fluid inclusions with
salinities similar to, but also significantly lower than, seawater reflect
the contribution of meteoric fluids during precipitation of this calcite.</p>
</sec>
<sec id="Ch1.S5.SS2">
  <label>5.2</label><title>Origin of the dolomitizing fluids</title>
      <p id="d1e4725">The contribution of brines that derived from highly evaporated seawater or
evaporites is suggested by the elevated salinity values obtained from
microthermometry of the fluid inclusions (3.5 to 20.5 eq. wt % NaCl).
Accordingly, two sources that could potentially provide such fluids can be
proposed: (1) fluids related to the Late Messinian evaporites, associated
with the overlying Upper Miocene Laga Formation, and their possible downward
percolation through fault zones by density driven flow and/or seismic
pumping mechanisms (Sibson, 1981; McCaig, 1988, 1990); or their tectonic
involvement into the Apenninic thrust wedge during its propagation
(underthrusting; Lobato et al., 1983); and (2) fluids related to the
underlying detachment horizon of the Burano evaporites (Upper Triassic) and
their upward flow through fault zones during development of the Montagna dei
Fiori Anticline. The first scenario is valid if the dolomitization would
have occurred only from the Upper Miocene time onwards. Moreover, several
researchers (e.g., Vai and Ricci Lucchi, 1977; Bassetti et al., 1998; Roveri
et al., 2001) have shown that the occurrence of primary shallow-water
evaporites, which were dominantly gypsum, was limited only to the western
and central parts of the northern Apennines consisting of thrust-top
marginal basins (Roveri et al., 2001). Hence, the evaporitic horizons
existing within the Laga Formation corresponds to resedimentation (gypsum
debris) of those previously precipitated in the marginal basins. This
interpretation makes the Messinian evaporites an unlikely source of Mg-rich
brines. Taking into account that the maximum burial-related temperature of
the Calcare Massiccio Formation did not exceed 80 <inline-formula><mml:math id="M319" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C in the
Montagna dei Fiori region (Ronchi et al., 2003), it is unlikely that the
downward percolation of relatively low-temperature brines derived from the
Messinian evaporites, located at higher stratigraphic levels, could reach or
exceed the high temperatures recorded in fluid inclusions of the studied
dolomites (D4; up to 105 <inline-formula><mml:math id="M320" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C), given that the homogenization
temperatures reflect the minimum entrapment temperatures (Goldstein and
Reynolds, 1994). Deep circulation of these brines, if they existed, can also
be excluded by the fact that their limited involvement in the thrust wedge
was confined merely to the offshore side of the Montagna dei Fiori region
(Artoni, 2013).</p>
      <p id="d1e4746">Accordingly, the Upper Triassic Burano Formation – the basal detachment –
appears as the most plausible source for the high-salinity brines recorded
in fluid inclusions, and likewise the Mg-rich fluids could have
originated from<?pagebreak page1375?> postevaporite brines associated with them (Carpenter, 1978;
McCaffrey et al., 1987). The fluctuations in salinity may argue for a diverse
range of fault connectivity, different degrees of rock–water interaction, and
contribution of pore waters of lower salinity (e.g., marine or meteoric).</p>
</sec>
<sec id="Ch1.S5.SS3">
  <label>5.3</label><title>Timing and structural controls on the evolution of parental fluids</title>
      <p id="d1e4757">A generalized paragenesis and the relative chronology of dolomitization in
relation to the structural evolution of the Montagna dei Fiori Anticline are
illustrated in Figs. 14 and 15. The structural episodes are based on the
evolutionary stages of the Montagna dei Fiori Anticline suggested by Storti
et al. (2018). The paragenesis is constructed on the basis of direct
evidence recorded during observations at outcrop scale and microscopic
observations (e.g., cross-cutting relationships between diagenetic phases,
stylolites, fractures, and other structural kinematics), and indirect
evidence (e.g., regional geodynamics and burial history).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F14" specific-use="star"><?xmltex \currentcnt{14}?><label>Figure 14</label><caption><p id="d1e4762">Generalized paragenesis of diagenetic phases in relation to
deformational stages and burial history of the Calcare Massiccio Formation
in the Montagna dei Fiori Anticline. The deformational stages are from
Storti et al. (2018) and the burial curve is based on Ronchi et al. (2003).
The burial curve was made based on paleodepth, paleotemperatures,
sedimentation rate, and paleoheat flow.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f14.png"/>

        </fig>

      <p id="d1e4771">The occurrence of micritic envelopes and fibrous calcite cements (FC), in
grain-supported stratigraphic levels of the Calcare Massiccio Formation, is
interpreted to be of eogenetic origin (i.e., marine phreatic diagenesis;
Moore, 1989), reflecting an early diagenesis shortly after deposition. The
well-developed brown-and-orange concentric cathodoluminescence pattern of
the succeeding mosaic calcite cement (MC) suggests a progressive shift to
more reducing conditions during precipitation in a phreatic diagenetic
environment (as shown in Li et al., 2017). High-amplitude bed-parallel
stylolites postdate both cements, which confirm their precipitation before
significant burial. The observations made here are in agreement with earlier
work by Giacometti and Ronchi (2000), interpreting that the Calcare
Massiccio Formation was cemented during the early diagenetic stages.</p>
      <p id="d1e4775">D1, C1, and D2 are cut by well-developed high-amplitude bed-parallel
stylolites. The presence of D1 and C1 in bed-perpendicular veins typically cut
by these stylolites (see Fig. 6e to h) support the interpretation that the
first dolomitization event (D1 and D2) took place before significant burial
and stylolite development. The latter and bed-perpendicular veins are
dynamically compatible within the same stress field, which is characterized
by a vertical load-related maximum principal axis of the stress ellipsoid
(Fig. 15a). The dominantly monophase fluid inclusions within D1 and D2 are
in agreement with precipitation temperatures below about 40–50 <inline-formula><mml:math id="M321" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, suggesting a relatively shallow to intermediate burial environment and
hence supporting a pre-Apenninic orogeny age of precipitation from a mix of
formational and extra-formational fluids with elevated <inline-formula><mml:math id="M322" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula>
ratios. The distribution of D1 and D2 localized near the rifting-related
<inline-formula><mml:math id="M323" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> N–S- and E–W-striking extensional faults and even their
displacement along them (Fig. 2a; e.g., site 1) point to the possible
contribution of these faults in occurrence of D1 and D2. These faults
dominantly affect the Jurassic rocks older than the Maiolica Formation which
is attributed to post-rift deposits, therefore suggesting a pre-Maiolica age
for these dolomite types. Although an absolute age cannot be provided, based
on the evidence discussed above, the circulation of Mg-rich fluids during
this dolomitization event was most likely controlled by rifting-related
Jurassic extensional fault zones cutting through the crystalline basement.
Precipitation of D1 and D2 at the lower part of Corniola Formation, which is
known as the syn-rift deposit, discards a pre-rift origin for these
dolomites. The displacement of dolomites along the aforementioned faults is
possibly related to their prolonged activation during the Early Jurassic to Late
Jurassic. In addition to the role of these faults in channelizing the
fluids, their mobilization must have been intensified by some deriving
mechanisms. A thermal convection system derived from high hit flux during
rifting was interpreted by Hollis et al. (2017) to be responsible for
circulation of seawater in a syn-rift dolomitization case in the Hammam
Faraun fault block (Suez Rift, Egypt). In such a scenario, the salinity of the
fluids and their <inline-formula><mml:math id="M324" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios are expected to be more or less
within the range of seawater. Furthermore, this scenario seems unlikely in
the studied area given the lack of a deep aquifer to accommodate the fault
tips and promote the lateral fluid flux from basin to the rift shoulders
and vice versa. Taking into account that D1 and D2 are the volumetrically
more relevant dolomites within the studied intervals, and assuming the
likely role of syn-rift extensional faults (Early Jurassic to Late Jurassic) in their
precipitation, a dominantly syn-rift dolomitization process is proposed for
the dolostones in the Montagna dei Fiori Anticline. Although the CL zonation
pattern observed in D2 may indicate changes in flow condition or fluid
composition, the lack of physical disruptions such as multiple fracturing
suggests external regional controls rather than slip along the same faults
(Eichhubl and Boles, 2000). The absence of pervasive syn-dolomitization
fracturing and brecciation as well as zebra fabrics in these dolomites
perhaps indicate a relatively calm tectonic period during dolomite
development (e.g., Hollis et al., 2017).</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F15" specific-use="star"><?xmltex \currentcnt{15}?><label>Figure 15</label><caption><p id="d1e4834">Sketch showing the successive fault-related diagenetic phases of
most importantly dolomitization, recorded in the carbonate succession
exposed at the core of the Montagna dei Fiori Anticline (not scaled).
Different diagenetic phases are indicated with different colors. <bold>(a)</bold> The
first dolomitization event is pre-orogenic (syn-rift), triggered from the
fluids channelized along Jurassic <inline-formula><mml:math id="M325" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> E–W- and <inline-formula><mml:math id="M326" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> N–S-striking extensional faults. This event occurred during burial
compaction and development of bed-parallel stylolites (BS). It is
represented by scattered dolomite rhombs (D1) followed by calcite
cementation (C1). The dolomitization continued with precipitation of larger
crystals of D2. <bold>(b)</bold> Second dolomitization event: syn-orogenic (early folding/faulting) dolomitization from fluids that migrated from more internal
regions of the thrust belt and were channelized along the basal detachment
level into the fold core. This dolomitization event presents matrix
replacive and cements displaying infrequent saddle outlines (SD) in pore
spaces within bed-parallel veins and shear fractures. These dolostones
postdate compaction but are affected by bed-perpendicular stylolites (TS)
generated by horizontal to subhorizontal layer-parallel shortening related
to the growth of the Montagna dei Fiori Anticline. <bold>(c)</bold> Extensional collapse
of the anticline and development of the Montagna dei Fiori Fault followed
by buttressing of the Scaglia against Calcare Massiccio and Corniola
formations during positive inversion induced by continuing underthrusting at
depth. Precipitation of D5 in microveins and cements in breccia zones,
followed by late-stage calcite cementation in the Montagna dei Fiori Fault
damage zone (C2, C3, and C4).</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://se.copernicus.org/articles/10/1355/2019/se-10-1355-2019-f15.png"/>

        </fig>

      <p id="d1e4866">D3 and D4 both record elevated <inline-formula><mml:math id="M327" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> ratios which account for their
fault-controlled origin. However, their occurrence at the top of the Calcare
Massiccio and overlaying Bugarone Formation (Corano Quarry site), which is
&lt; 1 m thick in the Montagna dei Fiori region and is marked as the final
rift deposit (Cardello and Doglioni, 2015), discards a syn-rift origin for
these dolomites. Moreover, D3 and D4 postdate the development of high-amplitude bed-parallel stylolites. The formation of stylolites requires an
approximate overburden of 600 to 1500 m (Lind et al., 1993; Machel, 1999; Mountjoy
et al., 1999; Schulz et al., 2016), corresponding to a late to post-Maiolica
deposition time (Early Cretaceous time onwards). The presence of D3 and D4
dolomites in bed-parallel fractures and as shear veins (D4) (Fig. 9a and b)
suggests their association with contractional deformations, i.e., the most
likely tectonic regime for explaining bed-perpendicular dilation. Therefore,
the volumetrically<?pagebreak page1376?> minor second stage of dolomite precipitation may possibly
be related to the Late Miocene to post-Miocene compressional tectonics recorded in
this region (e.g., Mazzoli et al., 2002; Artoni, 2013; Storti et al., 2018).</p>
      <?pagebreak page1378?><p id="d1e4888">Dolostones containing D3 and D4 appear commonly as clast-supported breccias
along fault zones pertaining to the Montagna dei Fiori Fault, then
overprinted by fault-parallel stylolites (Figs. 3 and 7). Accordingly, the
occurrence of these dolomites was probably synchronous with the incipient
stages of fault development, predating fault buttressing (Storti et al.,
2018). Homogenization temperatures recorded in D4 (up to 105 <inline-formula><mml:math id="M328" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C),
much higher than the maximum temperatures recorded in the host rocks (below
about 80 <inline-formula><mml:math id="M329" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C; Ronchi et al., 2003), suggest hydrothermal fluid
circulation. The development of the Montagna dei Fiori Anticline at the toe
of the Late Miocene Central Apennines thrust wedge could have favored the
forelandward migration of hydrothermal fluids expelled from the more
internal regions of the belt, similarly to what has been proposed for the
Rocky Mountains foreland (i.e., squeegee flow model; Machel and Cavell,
1999). Such a migration may have possibly favored the precipitation of D4 in
bed-parallel veins, generally considered evidence for syn-compressional
fluid overpressure (Sibson, 2001; Hiemstra and Goldstein, 2015). At this
stage, in addition to dilation of the pre-existing <inline-formula><mml:math id="M330" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> N–S- and
E–W-striking rift-related extensional faults and their possible role in
fluid migration, the excess of pore pressure at the base of the thrust ramp
in the fold hinge and during fold tightening could promote the localization
of the fractures (Smith and Wiltschko, 1996; Ghisetti and Vezzani, 2000),
with fluid migration within this zone and eventually dolomitization. These
fractures could have been corridors that later on formed the incipient NW–SE
Montagna dei Fiori Fault. Their localization at the back limb, cross-cutting
the core, best explains the distribution of D3 and D4 at this locality.
The presence of only D5 within the damage zone of the Montagna dei Fiori
Fault, postdating dolostone brecciation and, in places, cementing breccia
fragments, suggests that D5 dolomite precipitation was associated with the
late-stage evolution of the Montagna dei Fiori Fault, predating late-stage
calcite precipitation. The shift from dolomite to calcite precipitation can
be ascribed to attenuation of Mg-rich fluids and/or calcite saturation. This
condition was perhaps initiated during the late stages of anticline
evolution due to changes in fault conductivity sealing the upward migration
of Mg-rich fluids.</p>
      <p id="d1e4916">The presence of several generations of bed-perpendicular stylolites bounding
and intersecting C2 veins (Fig. 10) supports the postulation that late-stage calcite cements precipitated in close association with the deformation
history of the Scaglia Formation in the hanging wall of the Montagna dei
Fiori Fault (Fig. 3). This deformation occurred during buttressing against
Calcare Massiccio and Corniola formations in the footwall and related to
the positive inversion event induced by thrust-sheet stacking at depth
(Storti et al., 2018). Precipitation of C3 and C4 is interpreted to have
occurred during uplift and cooling as revealed by their relatively low
homogenization temperatures (<inline-formula><mml:math id="M331" display="inline"><mml:mrow><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula>–50 <inline-formula><mml:math id="M332" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) of fluid
inclusions trapped within these cements. Deformation twinning is either
absent or weakly developed, reflecting the lack of significant tectonic
deformation after calcite precipitation. These cements postdate the
dolomitization events, high-amplitude bed-perpendicular and parallel
stylolites, and are precipitated as cements bounding the breccia fragments
within the damage zone of the Montagna dei Fiori Fault. Salinities
calculated from their fluid inclusions, particularly in C4, suggests
precipitation from meteoric waters, which should have been favored during
the late evolutionary stages of antiformal stacking beneath the Montagna dei
Fiori Anticline and eventual late extensional slip along the Montagna dei
Fiori Fault (Storti et al., 2018). The results obtained in this study are in
relative agreement with the earlier work by Ronchi et al. (2003) and Murgia
et al. (2004) in the Central Apennines, assigning dolomitization phases to
the pre- and syn-orogenic deformations, although they did not specify the
direct relation between the local structures and the different types of
dolomite.</p>
      <p id="d1e4939">The textures of the studied dolomites vary from planar-e to nonplanar; the
preponderance of planar dolomite, as in D4, creates a rock with interesting
poroperm characteristics (e.g., Woody et al., 1996; Wilson and Ruppel, 2007;
Wenzhi et al., 2012). This case-study is certainly relevant for many
potential reservoirs elsewhere in the world. Similar multistage burial
dolomitization events enhancing the reservoir quality have been reported
from the carbonate successions of the Jurassic in the Kopet Dagh Basin,
north eastern Iran (Adabi, 2009), and Devonian of the Rainbow subbasin,
western Canada (Qing and Mountjoy, 1989; Lonnee, 1999).</p>
</sec>
</sec>
<sec id="Ch1.S6" sec-type="conclusions">
  <label>6</label><title>Conclusions</title>
      <p id="d1e4951">The Lower Jurassic limestones outcropping at the core of the Montagna dei
Fiori Anticline (Central Apennines, Italy) are massively affected by
dolomitization in damage zones of the pre-orogenic faults inherited from
the Tethyan rifting and the ones formed during the Apenninic orogeny.
Cross-cutting relationships between deformation structures, and results from
optical and cold-cathode cathodoluminescence petrography, fluid inclusion
microthermometry, and isotope geochemistry, support the occurrence of two
major dolomitization events. The first event is interpreted as having
developed during the late stages of Tethyan rifting in the Jurassic and resulted
in volumetrically significant dolostone geobodies. These dolostones are
largely matrix replacive and their precipitation initiated prior to the
significant burial as reflected in their cross-cutting relationship with
bed-parallel stylolites, and by homogenization temperatures in fluid
inclusions that are dominantly below about 40–50 <inline-formula><mml:math id="M333" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. The second
dolomitization event corresponds to volumetrically less relevant replacive
dolomite and dolomite cements occluding fractures. These dolomites
precipitated during hydrothermal fluid circulation associated with
contractional tectonics during the Apenninic orogeny, possibly at the onset
of the growth of the Montagna dei Fiori Anticline (Late Miocene).</p>
      <p id="d1e4963">Dolomitizing fluids in both events were most likely sourced from evaporitic
brines associated to the underlying Burano evaporites and their interaction
with siliciclastic rocks and/or the crystalline basement.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e4970">The data used in this research are not publicly available. The data were provided based on a collaboration between Parma and KU Leuven universities.</p>
  </notes><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e4976">MM participated in fieldwork, performed petrographic and
microthermometric analyses, provided their interpretation, and wrote the
article; RS participated in fieldwork, discussed the results of
the diagenetic study, and critically reviewed the article; FB
contributed to collect and interpret structural data, discussed structural
diagenesis data interpretation, and critically reviewed the article; HED collected <inline-formula><mml:math id="M334" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">87</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">86</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula> data; FS conceived the
research, contributed to collect and interpret structural data, discussed
structural diagenesis data interpretation, and critically reviewed the
article; CT participated in fieldwork, discussed the results of
the diagenetic study and their framing into the proposed structural
evolution, and critically reviewed the article.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e5001">The authors declare that they have no conflict of interest.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e5007">This research was performed thanks  to a collaboration between Parma and KU Leuven universities in the framework of a research project (PT12432 and GFSTE 1100942) funded by Shell Global Solutions International (Carbonate Research Team, now Geology and New Reservoir Types team). We thank Enricomaria Selmo (Parma University) and Michael M. Joachimski (University of Erlangen, Germany) for the stable carbon and oxygen analysis. Gareth Davis (VU Amsterdam, the Netherlands) is thanked for the strontium isotope analysis. Andrea Comelli and Herman Nijs are kindly thanked for the careful preparation of the wafers and thin sections. Luca Barchi is gratefully appreciated for his help in SEM analysis. We acknowledge Anton Koopman for the constructive discussions during field work. We appreciate Daniel Smith (Energie Beheer Nederland, the Netherlands) for the careful reviewing of the article. We are very grateful to reviewers Jim Hendry and Estibalitz Ukar for their suggestions that allowed us to significantly improve the article.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e5012">This research has been supported by the Shell Global Solutions International (Carbonate Research Team) (grant nos. PT12432 and GFSTE 1100942).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e5018">This paper was edited by Elias Samankassou and reviewed by Jim Hendry and Estibalitz Ukar.</p>
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    <!--<article-title-html>Fault-controlled dolomitization in the Montagna dei Fiori Anticline (Central Apennines, Italy): record of a dominantly pre-orogenic fluid migration</article-title-html>
<abstract-html><p>The Lower Jurassic platform and basinal deposits exposed in the
Montagna dei Fiori Anticline (Central Apennines, Italy) are pervasively
affected by dolomitization. Based on the integration of field work,
petrography, and geochemistry, two fault-related dolomitization events were
recognized and interpreted as having occurred before and during the
Apenninic orogeny. Fluid inclusion analysis indicates moderate
to elevated salinity values of 3.5 to 20.5 and 12.8 to 18.6&thinsp;eq.&thinsp;wt&thinsp;%&thinsp;NaCl in the first and the second event, respectively. The estimated
salinities, in combination with <i>δ</i><sup>18</sup>O values and <sup>87</sup>Sr∕<sup>86</sup>Sr ratios,
suggest significant involvement of evaporitic fluids in both events, most
likely derived from the underlying Upper Triassic Burano Formation. In
addition, the <sup>87</sup>Sr∕<sup>86</sup>Sr ratios up to 0.70963 suggest the circulation of
deep-sourced fluids that interacted with siliciclastic rocks and/or the
crystalline basement during the dolomitization events.</p><p>Two major dolomite types (D1 and D2) were recognized as pertaining to the
first event, both postdated by high-amplitude bed-parallel stylolites,
supporting a syn-burial pre-layer-parallel shortening dolomitization. A
possible geodynamic framework for this dolomitization event is Early Jurassic to Late
Jurassic rift-related extensional tectonism. The second dolomitization event
(D3, D4, and D5) is characterized by a temperature upturn (up to
105&thinsp;°C) and interpreted as associated with the inflow of
hydrothermal fluids, possibly related to major changes in the permeability
architecture of faults during early- to syn-thrusting and folding activity.
Based on the timing of deformation in the Montagna dei Fiori Anticline, the
second dolomitization event likely occurred in Late Miocene to Pliocene
times. The findings regarding characteristics and timing of dolomitization
here illustrates the long-term controlling role of the evaporitic
detachments in the dolomitization process. This study shows that the Mg-rich
fluids that were most likely derived from evaporites may prime the
tectonically involved successions for repeated dolomitization, and hence the
formation of potential reservoirs during sequential tectonic modifications
(extensional vs. compressional).</p></abstract-html>
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