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<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing with OASIS Tables v3.0 20080202//EN" "journalpub-oasis3.dtd">
<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0" article-type="research-article">
  <front>
    <journal-meta><journal-id journal-id-type="publisher">SE</journal-id><journal-title-group>
    <journal-title>Solid Earth</journal-title>
    <abbrev-journal-title abbrev-type="publisher">SE</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Solid Earth</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1869-9529</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/se-12-2087-2021</article-id><title-group><article-title>Coupled dynamics and evolution of primordial and recycled heterogeneity in Earth's lower mantle</article-title><alt-title>Modeling primordial and recycled mantle heterogeneity</alt-title>
      </title-group><?xmltex \runningtitle{Modeling primordial and recycled mantle heterogeneity}?><?xmltex \runningauthor{A.~J.~P.~Gülcher et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff3">
          <name><surname>Gülcher</surname><given-names>Anna Johanna Pia</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-5999-3463</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2 aff1">
          <name><surname>Ballmer</surname><given-names>Maxim Dionys</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-8886-5030</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Tackley</surname><given-names>Paul James</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-4878-621X</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Institute of Geophysics, Department of Earth Sciences, ETH Zürich, Zürich, Switzerland</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Department of Earth Sciences, University College London, London, UK</institution>
        </aff>
        <aff id="aff3"><label>🏅</label><institution><?xmltex \bgroup\itshape?>Invited contribution by Anna Johanna Pia Gülcher, recipient of the EGU Geodynamics Outstanding Student Poster and PICO Award 2019.<?xmltex \egroup?>
    </institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Anna J. P. Gülcher (anna.guelcher@erdw.ethz.ch)</corresp></author-notes><pub-date><day>14</day><month>September</month><year>2021</year></pub-date>
      
      <volume>12</volume>
      <issue>9</issue>
      <fpage>2087</fpage><lpage>2107</lpage>
      <history>
        <date date-type="received"><day>1</day><month>December</month><year>2020</year></date>
           <date date-type="rev-request"><day>16</day><month>December</month><year>2020</year></date>
           <date date-type="rev-recd"><day>26</day><month>July</month><year>2021</year></date>
           <date date-type="accepted"><day>2</day><month>August</month><year>2021</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2021 </copyright-statement>
        <copyright-year>2021</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://se.copernicus.org/articles/.html">This article is available from https://se.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://se.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://se.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e116">The nature of compositional heterogeneity in Earth's lower mantle remains a long-standing puzzle that can inform about the long-term thermochemical evolution and  dynamics of our planet. Here, we use global-scale 2D models of thermochemical mantle convection to investigate the coupled evolution and mixing of (intrinsically dense) recycled and (intrinsically strong) primordial heterogeneity in the mantle. We explore the effects of ancient compositional layering of the mantle, as motivated by magma ocean solidification studies, and of the physical parameters of primordial material.
Depending on these physical parameters, our models predict various regimes of mantle evolution and heterogeneity preservation over 4.5 <inline-formula><mml:math id="M1" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula>. Over a wide parameter range, primordial and recycled heterogeneity are predicted to co-exist with each other in the lower mantle of Earth-like planets. Primordial material usually survives as medium- to large-scale blobs (or streaks) in the mid-mantle, around 1000–2000 <inline-formula><mml:math id="M2" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> depth, and this preservation is largely independent of the initial primordial-material volume. In turn, recycled oceanic crust (ROC) persists as large piles at the base of the mantle and as small streaks everywhere else. In models with an additional dense FeO-rich layer initially present at the base of the mantle, the ancient dense material partially survives at the top of ROC piles, causing the piles to be compositionally stratified. Moreover, the addition of such an ancient FeO-rich basal layer significantly aids the preservation of the viscous domains in the mid-mantle.
Finally, we find that primordial blobs are commonly directly underlain by thick ROC piles and aid their longevity and stability.
Based on our results, we propose an integrated style of mantle heterogeneity for the Earth involving the preservation of primordial domains along with recycled piles. This style has important implications for early Earth evolution and has the potential to reconcile geophysical and geochemical discrepancies on present-day lower-mantle heterogeneity.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e144">The lower mantle is the largest geochemical reservoir in the Earth's interior and controls the style of mantle convection and planetary evolution. Despite efficient stirring by vigorous convection over billions of years, the Earth's lower mantle appears to be chemically heterogeneous on various length scales <xref ref-type="bibr" rid="bib1.bibx1 bib1.bibx111" id="paren.1"><named-content content-type="pre">e.g.,</named-content></xref>. Knowing the distribution of this heterogeneity is key for assessing Earth's bulk composition and thermochemical evolution, but this remains a scientific challenge that requires cross-disciplinary efforts.</p>
      <?pagebreak page2088?><p id="d1e152">On relatively small scales (<inline-formula><mml:math id="M3" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M4" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>), the concept of a “marble cake” mantle has gained wide acceptance, emphasizing that much of the mantle is made out of recycled oceanic lithosphere, deformed into narrow streaks of depleted and enriched compositions (Fig. 1a). Partial melting in the upper mantle creates heterogeneity between basaltic (magma) and harzburgitic (residue) end-members, forming a physically and chemically layered oceanic lithosphere. Subsequent injection into the mantle during subduction causes a non-equilibrated mantle that is a mechanical mixture of basalt and harzburgite <xref ref-type="bibr" rid="bib1.bibx1 bib1.bibx17 bib1.bibx76 bib1.bibx118" id="paren.2"/>. Additional small-scale heterogeneity is introduced into the mantle by recycling of continental material through subduction and/or delamination. Such influxes of felsic material to the deeper Earth have been used to explain the heterogeneous isotopic compositions of mantle-derived rocks, particularly in terms of trace elements <xref ref-type="bibr" rid="bib1.bibx52 bib1.bibx60 bib1.bibx97" id="paren.3"/>.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><?xmltex \def\figurename{Figure}?><label>Figure 1</label><caption><p id="d1e179">Several conceptual models of mantle compositional structure with heterogeneity on various scales. For explanations regarding these heterogeneity styles, the reader is referred to the text: <bold>(a)</bold> “marble cake” mantle, modified following <xref ref-type="bibr" rid="bib1.bibx118 bib1.bibx116" id="text.4"/>; <bold>(b)</bold> thermochemical piles, modified after <xref ref-type="bibr" rid="bib1.bibx28" id="text.5"/>; and <bold>(c)</bold> viscous “blobs”, modified after <xref ref-type="bibr" rid="bib1.bibx9 bib1.bibx7" id="text.6"/>.</p></caption>
        <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://se.copernicus.org/articles/12/2087/2021/se-12-2087-2021-f01.png"/>

      </fig>

      <p id="d1e208">On larger scales (10–100 s of <inline-formula><mml:math id="M5" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>), compositional heterogeneity may be preserved by delayed mixing of this marble cake with either intrinsically dense or intrinsically strong materials. Intrinsically dense materials may accumulate as piles atop the core–mantle boundary (CMB), as illustrated in Fig. 1b. In particular, the two large low-shear velocity provinces (LLSVPs) in the deep Earth are commonly thought to have resisted mantle mixing due to their thermochemical origin, with an excess density of a few percent compared to pyrolitic material <xref ref-type="bibr" rid="bib1.bibx45" id="paren.7"/>. Hypotheses regarding the composition of these dense piles involve recycled oceanic crust (ROC) <xref ref-type="bibr" rid="bib1.bibx17 bib1.bibx49 bib1.bibx65" id="paren.8"><named-content content-type="pre">e.g.,</named-content></xref>, ancient dense material <xref ref-type="bibr" rid="bib1.bibx63 bib1.bibx100 bib1.bibx12 bib1.bibx67" id="paren.9"><named-content content-type="pre">e.g.,</named-content></xref>, or a combination of the two <xref ref-type="bibr" rid="bib1.bibx100 bib1.bibx6" id="paren.10"><named-content content-type="pre">e.g.,</named-content></xref>.</p>
      <p id="d1e237">On the other hand, intrinsically viscous domains may survive mantle convection and be preserved as “blobs” in the mid-mantle over long timescales <xref ref-type="bibr" rid="bib1.bibx71 bib1.bibx9 bib1.bibx7 bib1.bibx40" id="paren.11"/>, such as plums in the mantle “plum pudding” (Fig. 1c).
The physical properties (e.g., high viscosity) required for long-term preservation of these blobs are thought to be caused by an enrichment in the strong lower-mantle mineral bridgmanite (Mg, Fe)SiO<inline-formula><mml:math id="M6" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> (i.e., stabilized by an enrichment in silica).
During crystallization of a deep magma ocean at high pressures, MgSiO<inline-formula><mml:math id="M7" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> bridgmanite is the relevant liquidus phase over a wide range of conditions and may hence be fractionated, potentially giving rise to such ancient heterogeneity in the mantle <xref ref-type="bibr" rid="bib1.bibx30 bib1.bibx11 bib1.bibx117" id="paren.12"/>.
These viscous domains in the mid-mantle may potentially reconcile recent seismic observations of mid-mantle heterogeneity <xref ref-type="bibr" rid="bib1.bibx36 bib1.bibx57 bib1.bibx114" id="paren.13"><named-content content-type="pre">e.g.,</named-content></xref>, as well as cosmochemical and geochemical observations that indicate that the lower mantle hosts an ancient primordial reservoir that is potentially enriched in SiO<inline-formula><mml:math id="M8" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> with respect to the upper mantle <xref ref-type="bibr" rid="bib1.bibx56 bib1.bibx77" id="paren.14"><named-content content-type="pre">e.g.,</named-content></xref>. This regime has been successfully reproduced in 2D spherical annulus convection models with composition-dependent rheology <xref ref-type="bibr" rid="bib1.bibx40" id="paren.15"/>. Various styles of primordial heterogeneity preservation were found as a function of its physical parameters, and the survival of sharp-to-diffuse primordial domains in the mid-mantle was proposed for planet Earth <xref ref-type="bibr" rid="bib1.bibx40" id="paren.16"/>. However, the employed rheology was simplified, and the models did not produce Earth-like tectonic behavior. Moreover, none of the models explicitly predicted the formation of thermochemical piles in the lowermost mantle, which are perhaps the most evident heterogeneities in Earth's lower mantle <xref ref-type="bibr" rid="bib1.bibx95 bib1.bibx17 bib1.bibx66" id="paren.17"><named-content content-type="pre">e.g.,</named-content></xref>.</p>
      <p id="d1e295">Many studies have explored the formation and preservation of either ROC (intrinsically dense) or primordial (intrinsically dense and/or viscous) heterogeneity, but only a few (if any) have quantified mantle dynamics in the presence of different types of heterogeneity with distinct physical properties <xref ref-type="bibr" rid="bib1.bibx82 bib1.bibx67" id="paren.18"><named-content content-type="pre">e.g.,</named-content></xref>. Understanding the interplay between recycled and primordial heterogeneity is critical to validate, falsify, and/or integrate the various views on chemical heterogeneity in Earth's mantle (Fig. 1).
The goal of the present contribution is to investigate mantle dynamics in the presence of different types of heterogeneity with distinct physical properties (i.e., intrinsically viscous and dense) using Earth-like numerical models of mantle convection. We establish multiple regimes of chemical heterogeneity that are dependent on the rheological properties of primordial material. The coexistence of viscous, primordial blobs in the mid-mantle with dense recycled (and possible ancient) piles in the lowermost mantle is robustly predicted in many of our experiments. This coexistence is surprisingly largely independent of the initial compositional layering set-up. Based on these results, we propose that Earth's mantle is in a hybrid state between marble cake and plum pudding heterogeneity styles. Finally, the results are put into context with recent discoveries from geochemistry and seismology and the long-term evolution of Earth.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Methods</title>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Numerical technique and
boundary conditions</title>
      <p id="d1e318">In this study, we model mantle convection in two-dimensional spherical annulus geometry using the finite-volume code StagYY <xref ref-type="bibr" rid="bib1.bibx99 bib1.bibx46" id="paren.19"/>.
Free-slip and isothermal boundary conditions are employed at the top and bottom boundaries, with the surface temperature fixed to 300 <inline-formula><mml:math id="M9" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> and that of the CMB fixed to 4000 <inline-formula><mml:math id="M10" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>. The numerical experiments are purely bottom heated (i.e., no internal heating).
StagYY solves for the conservation equations for mass, momentum, energy, and composition on a staggered grid for a compressible fluid with an infinite Prandtl number. The computational domain is decomposed in 512 <inline-formula><mml:math id="M11" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 96 cells, in which around 1.2 million tracers, tracking composition and temperature, are advected (25 tracers per cell). We further impose vertical grid refinement near the boundary layers and near 660 <inline-formula><mml:math id="M12" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> depth. The size of grid cells therefore varies between 40 and 80 <inline-formula><mml:math id="M13" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> in the horizontal direction and between 10 and 35 <inline-formula><mml:math id="M14" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> in the vertical direction.
Resolution tests were carried out with up to double the number of grid cells in each direction and up to 50 tracers<?pagebreak page2089?> per cell (Supplement S2). In these tests, we did not observe any significant changes in the dynamics and heterogeneity styles of our models. In fact, lower-mantle heterogeneity is slightly to moderately increased with increasing resolution <xref ref-type="bibr" rid="bib1.bibx40" id="paren.20"><named-content content-type="pre">as in</named-content></xref>. Our estimates of heterogeneity preservation thereby remain conservative.</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Rheology</title>
      <p id="d1e385">In our models, the assumed viscous deformation mechanism is diffusion creep. Viscosity is governed by a simplified temperature-, pressure-, and composition-dependent Arrhenius-type viscosity law (Newtonian rheology):
            <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M15" display="block"><mml:mrow><mml:mi mathvariant="italic">η</mml:mi><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>,</mml:mo><mml:mi>P</mml:mi><mml:mo>,</mml:mo><mml:mi>c</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">η</mml:mi><mml:mtext>0</mml:mtext></mml:msub><mml:mo>⋅</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>c</mml:mtext></mml:msub><mml:mo>⋅</mml:mo><mml:mi>exp⁡</mml:mi><mml:mfenced close=")" open="("><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mtext>a</mml:mtext></mml:msub><mml:mo>+</mml:mo><mml:mi>P</mml:mi><mml:mo>⋅</mml:mo><mml:msub><mml:mi>V</mml:mi><mml:mtext>a</mml:mtext></mml:msub></mml:mrow><mml:mrow><mml:mi>R</mml:mi><mml:mo>⋅</mml:mo><mml:mi>T</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mtext>a</mml:mtext></mml:msub></mml:mrow><mml:mrow><mml:mi>R</mml:mi><mml:mo>⋅</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mtext>0</mml:mtext></mml:msub></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M16" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">η</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the reference viscosity at reference temperature <inline-formula><mml:math id="M17" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M18" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1600</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M19" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>) and zero pressure; <inline-formula><mml:math id="M20" display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mi mathvariant="normal">a</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M21" display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">a</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are the activation energy and volume, respectively; <inline-formula><mml:math id="M22" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> is the absolute temperature; <inline-formula><mml:math id="M23" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> is the pressure; and <inline-formula><mml:math id="M24" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> is the gas constant (8.314 <inline-formula><mml:math id="M25" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M26" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mol</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M27" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M28" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M29" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>). The composition dependency of viscosity is considered through prefactor <inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, which can be phase dependent (<inline-formula><mml:math id="M31" display="inline"><mml:mrow><mml:mo>≠</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> for primordial and post-perovskite compositions; see Table 1 and Sect. <xref ref-type="sec" rid="Ch1.S2.SS5"/>). All physical and rheological parameters used in this study are listed in Table 1. In cases where a grid cell contains a mixture of compositions, the overall cell viscosity is calculated as a mass-weighted geometrical average of the viscosities of different compositions <xref ref-type="bibr" rid="bib1.bibx101" id="paren.21"><named-content content-type="pre">as in, e.g.,</named-content></xref>.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e642">A summary of the physical properties used in the numerical simulations of this study. UM stands for upper mantle, LM stands for lower mantle, and PPV stands for post-perovskite. As we solve for compressible convection, the adiabatic temperature, thermal conductivity, thermal expansivity, density, and heat capacity are pressure dependent, following a third-order Birch–Murnaghan equation of state <xref ref-type="bibr" rid="bib1.bibx102" id="paren.22"/>. The asterisk (*) notes the parameters that are varied between the models.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Property</oasis:entry>
         <oasis:entry colname="col2">Symbol</oasis:entry>
         <oasis:entry colname="col3">Value</oasis:entry>
         <oasis:entry colname="col4">Units</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Mantle domain thickness</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M32" display="inline"><mml:mi>D</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">2890</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M33" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Primordial layer thickness*</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">1568–2230</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M35" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Gravitational acceleration</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M36" display="inline"><mml:mi>g</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">9.81</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M37" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M38" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">s</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M39" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Surface temperature</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>s</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">300</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M41" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CMB temperature</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>CMB</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">4000</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M43" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Reference viscosity</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M44" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">η</mml:mi><mml:mtext>0</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">5 <inline-formula><mml:math id="M45" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M46" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">20</mml:mn></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M47" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Pa</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M48" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">s</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Lower-mantle viscosity contrast</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M49" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>LM</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">1</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Primordial lower-mantle viscosity contrast*</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">10–500</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">PPV viscosity contrast</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>ppv</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">10<inline-formula><mml:math id="M52" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Primordial buoyancy ratio*</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M53" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">0.07–0.78</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Reference temperature</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M54" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>0</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">1600</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M55" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Initial reference temperature</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M56" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>0,ini</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">1900</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M57" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Activation energy – UM and LM</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M58" display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mtext>a</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">140</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M59" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kJ</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M60" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mol</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M61" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Activation energy – PPV</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mtext>a,PPV</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">100           <inline-formula><mml:math id="M63" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kJ</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M64" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mol</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M65" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Activation volume – UM and LM</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M66" display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mtext>a</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">1.8 <inline-formula><mml:math id="M67" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M68" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M69" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">cm</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M70" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M71" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mol</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M72" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Activation volume – PPV</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mtext>a,PPV</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">1.4 <inline-formula><mml:math id="M74" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M75" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M76" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">cm</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M77" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M78" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mol</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M79" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Yield stress</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M80" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mtext>yield</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">30</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M81" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Mpa</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Yield stress depth derivative</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M82" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">τ</mml:mi><mml:mtext>yield</mml:mtext><mml:mo>′</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">0.01</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M83" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">MPa</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M84" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">MPa</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M85" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Surface-specific heat capacity</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mtext>P,0</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">1200</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M87" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi></mml:mrow></mml:math></inline-formula>/(<inline-formula><mml:math id="M88" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M89" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Surface thermal conductivity</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M90" display="inline"><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">3</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M91" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi></mml:mrow></mml:math></inline-formula>/(<inline-formula><mml:math id="M92" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M93" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Surface thermal expansivity</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mtext>0</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">3 <inline-formula><mml:math id="M95" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M96" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M97" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M98" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">1</mml:mn></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e1538">The effective rheological properties of lower-mantle materials may be well represented by our relatively low effective activation energy and volume <xref ref-type="bibr" rid="bib1.bibx121" id="paren.23"><named-content content-type="pre">e.g.,</named-content></xref>.
For upper-mantle materials, the applied rheological parameters are significantly smaller than lab measurements <xref ref-type="bibr" rid="bib1.bibx59 bib1.bibx51" id="paren.24"/>. In our Newtonian rheology formulation, low activation energies can account for the effects of grain size or stress-dependent rheology <xref ref-type="bibr" rid="bib1.bibx17 bib1.bibx110 bib1.bibx121" id="paren.25"><named-content content-type="pre">e.g.,</named-content></xref>. Low values of activation volume may result in reduced mechanical decoupling of the lithosphere and asthenosphere in our models, although our choice of yield stress (Table 1) allows for the development of stiff, mobile plates in our models (see below).</p>
      <p id="d1e1555">In order to obtain plate-like behavior at the surface, we assume that the material deforms plastically once a critical pressure-dependent yield stress is reached <xref ref-type="bibr" rid="bib1.bibx98 bib1.bibx22" id="paren.26"><named-content content-type="pre">as in</named-content></xref>. Plate-like behavior is determined using the same diagnostics as in <xref ref-type="bibr" rid="bib1.bibx98" id="text.27"/>, measuring plateness <inline-formula><mml:math id="M99" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> (the degree to which surface deformation is localized) and mobility <inline-formula><mml:math id="M100" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> (the extent to which the lithosphere is able to move). For details regarding these diagnostics, the reader is referred to Supplement S3. Plate-like behavior occurs for <inline-formula><mml:math id="M101" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> close to 1 and <inline-formula><mml:math id="M102" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> close to or larger than 1 <xref ref-type="bibr" rid="bib1.bibx98" id="paren.28"/>.</p>
</sec>
<?pagebreak page2090?><sec id="Ch1.S2.SS3">
  <label>2.3</label><title>Mantle composition, phase changes, and melting</title>
      <p id="d1e1606">The composition in our modeled mantle has three lithological end-member components: harzburgite, basalt, and primordial material. Each tracer carries either a primordial-material composition or a mechanical mixture of harzburgite and basalt (hz and bs).
Harzburgitic and basaltic mantle materials are treated as a mixture of olivine and pyroxene–garnet systems <xref ref-type="bibr" rid="bib1.bibx83" id="paren.29"><named-content content-type="pre">for details, see</named-content></xref>, following a parametrization based on mineral physics data <xref ref-type="bibr" rid="bib1.bibx53 bib1.bibx86" id="paren.30"/>.
Primordial material is not defined in terms of a specific mineral composition but solely through its material properties. It corresponds to a bridgmanite-enriched material with a (Mg <inline-formula><mml:math id="M103" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> Fe) <inline-formula><mml:math id="M104" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Si ratio of <inline-formula><mml:math id="M105" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> 1.0 and is thought to represent cumulates resulting from the fractional crystallization of a magma ocean in the early Earth <xref ref-type="bibr" rid="bib1.bibx55 bib1.bibx30 bib1.bibx117" id="paren.31"/>.
Phase transition parameters and physical properties for each mineral system and for primordial material are given in Table 2.
The density profiles of the mantle materials are shown and discussed in Supplement S1.2. Our reference primordial material roughly corresponds to Mg<inline-formula><mml:math id="M106" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">0.88</mml:mn></mml:msub></mml:math></inline-formula>Fe<inline-formula><mml:math id="M107" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">0.12</mml:mn></mml:msub></mml:math></inline-formula>SiO<inline-formula><mml:math id="M108" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> (Mg number of 0.88) or any other material with the same density profile (Supplement S1.2).
The modeled mantles are initialized with a bottom primordial layer below a <inline-formula><mml:math id="M109" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> pyrolitic layer (see Sect. <xref ref-type="sec" rid="Ch1.S2.SS4"/> below). The initial chemical density difference between such a primordial and pyrolitic layer stabilizes chemical stratification, while the thermal density difference destabilizes chemical stratification. The competition between the two is expressed as the non-dimensional buoyancy ratio <inline-formula><mml:math id="M110" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> <xref ref-type="bibr" rid="bib1.bibx42 bib1.bibx24" id="paren.32"/>:
            <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M111" display="block"><mml:mrow><mml:mi>B</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">T</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">T</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M113" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are the appropriate thermal and compositional density contrasts, <inline-formula><mml:math id="M114" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> is the thermal expansivity, <inline-formula><mml:math id="M115" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula> is the lower-layer density, and <inline-formula><mml:math id="M116" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> is the super-adiabatic temperature contrast between surface and CMB. <inline-formula><mml:math id="M117" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> is calculated for relevant lower-mantle depths, taking depth-dependent parameters <inline-formula><mml:math id="M118" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula> (density of primordial material), <inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M120" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> at 1500 <inline-formula><mml:math id="M121" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> depth. Accordingly, our reference model with a Mg number of 0.88  corresponds to a buoyancy number of 0.28.</p>

<?xmltex \floatpos{t!}?><table-wrap id="Ch1.T2" specific-use="star"><?xmltex \currentcnt{2}?><label>Table 2</label><caption><p id="d1e1837">Parameters for the phase transitions for the olivine, pyroxene–garnet, and primordial systems. The primordial system is parameterized to fit the density profile of a mechanical mixture of 40 % basalt and 60 % harzburgite from <xref ref-type="bibr" rid="bib1.bibx118" id="text.33"/> in the upper mantle (see Supplement S1.2). These parameters include the depth and temperature at which the phase transition occurs, the density jump across the phase transition (<inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>pc</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>), and the Clapeyron slope (<inline-formula><mml:math id="M123" display="inline"><mml:mi mathvariant="italic">γ</mml:mi></mml:math></inline-formula>).
The olivine and pyroxene–garnet system parameters are similar to previous studies <xref ref-type="bibr" rid="bib1.bibx102" id="paren.34"><named-content content-type="pre">e.g.,</named-content></xref>.
Finally, the reference bulk modulus for each individual layer of a system is shown as <inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mtext>0</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, which is increased to 230 <inline-formula><mml:math id="M125" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">GPa</mml:mi></mml:mrow></mml:math></inline-formula> for primordial material in the lower mantle, as discussed in Supplement S1.2. </p></caption><oasis:table frame="topbot"><oasis:tgroup cols="6">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Depth</oasis:entry>
         <oasis:entry colname="col2">Temperature</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M126" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">ρ</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">Phase change</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M127" display="inline"><mml:mi mathvariant="italic">γ</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M128" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mtext>0</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M129" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">GPa</mml:mi></mml:mrow></mml:math></inline-formula>);</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">(<inline-formula><mml:math id="M130" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">(<inline-formula><mml:math id="M131" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col3">(<inline-formula><mml:math id="M132" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M133" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M134" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col4">width (<inline-formula><mml:math id="M135" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col5">(<inline-formula><mml:math id="M136" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">MPa</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M137" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M138" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col6">depth range (<inline-formula><mml:math id="M139" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row rowsep="1">
         <oasis:entry namest="col1" nameend="col5">Olivine (<inline-formula><mml:math id="M140" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">surf</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">3240</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M141" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M142" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M143" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) </oasis:entry>
         <oasis:entry colname="col6">163; 0–410</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">410</oasis:entry>
         <oasis:entry colname="col2">1600</oasis:entry>
         <oasis:entry colname="col3">180</oasis:entry>
         <oasis:entry colname="col4">25</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M144" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>2.5</oasis:entry>
         <oasis:entry colname="col6">85; 410–660</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">660</oasis:entry>
         <oasis:entry colname="col2">1900</oasis:entry>
         <oasis:entry colname="col3">435</oasis:entry>
         <oasis:entry colname="col4">25</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M145" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>2.5</oasis:entry>
         <oasis:entry colname="col6">210; 660–2740</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">2740</oasis:entry>
         <oasis:entry colname="col2">2300</oasis:entry>
         <oasis:entry colname="col3">61.6</oasis:entry>
         <oasis:entry colname="col4">25</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M146" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>10</oasis:entry>
         <oasis:entry colname="col6">210; 2740–2890</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry namest="col1" nameend="col5">Pyroxene–garnet (<inline-formula><mml:math id="M147" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">surf</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">3080</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M148" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M149" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M150" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) </oasis:entry>
         <oasis:entry colname="col6">163; 0–40</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">40</oasis:entry>
         <oasis:entry colname="col2">1000</oasis:entry>
         <oasis:entry colname="col3">350</oasis:entry>
         <oasis:entry colname="col4">25</oasis:entry>
         <oasis:entry colname="col5">0</oasis:entry>
         <oasis:entry colname="col6">130; 40–300</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">300</oasis:entry>
         <oasis:entry colname="col2">1600</oasis:entry>
         <oasis:entry colname="col3">100</oasis:entry>
         <oasis:entry colname="col4">75</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M151" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>1.0</oasis:entry>
         <oasis:entry colname="col6">85; 300–720</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">720</oasis:entry>
         <oasis:entry colname="col2">1900</oasis:entry>
         <oasis:entry colname="col3">350</oasis:entry>
         <oasis:entry colname="col4">75</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M152" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>1.0</oasis:entry>
         <oasis:entry colname="col6">210; 720–2740</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">2740</oasis:entry>
         <oasis:entry colname="col2">2300</oasis:entry>
         <oasis:entry colname="col3">61.6</oasis:entry>
         <oasis:entry colname="col4">25</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M153" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>10</oasis:entry>
         <oasis:entry colname="col6">210; 2740–2890</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry namest="col1" nameend="col5">Primordial (<inline-formula><mml:math id="M154" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">surf</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">3075</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M155" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M156" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M157" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) </oasis:entry>
         <oasis:entry colname="col6">163; 0–40</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">40</oasis:entry>
         <oasis:entry colname="col2">1000</oasis:entry>
         <oasis:entry colname="col3">260</oasis:entry>
         <oasis:entry colname="col4">25</oasis:entry>
         <oasis:entry colname="col5">0</oasis:entry>
         <oasis:entry colname="col6">145; 40–380</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">380</oasis:entry>
         <oasis:entry colname="col2">1600</oasis:entry>
         <oasis:entry colname="col3">130</oasis:entry>
         <oasis:entry colname="col4">75</oasis:entry>
         <oasis:entry colname="col5">1.675</oasis:entry>
         <oasis:entry colname="col6">85; 380–660</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">660</oasis:entry>
         <oasis:entry colname="col2">1900</oasis:entry>
         <oasis:entry colname="col3">450</oasis:entry>
         <oasis:entry colname="col4">50</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M158" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.575</oasis:entry>
         <oasis:entry colname="col6">230; 660–2740</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2740</oasis:entry>
         <oasis:entry colname="col2">2300</oasis:entry>
         <oasis:entry colname="col3">61.6</oasis:entry>
         <oasis:entry colname="col4">25</oasis:entry>
         <oasis:entry colname="col5">10</oasis:entry>
         <oasis:entry colname="col6">163; 0–410</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e2512">Changes in composition, carried on tracers, arise from melt-induced differentiation.
Tracers in the basalt–harzburgite space undergo partial melting as a function of composition, pressure, and temperature, which generates basaltic oceanic crust and a complementary depleted residue (for details, see <xref ref-type="bibr" rid="bib1.bibx83" id="altparen.35"/>).
Tracers of primordial composition undergo “melting” once they cross the relevant solidus of pyroxenite melting <xref ref-type="bibr" rid="bib1.bibx87" id="paren.36"/>. This solidus is used as pyroxenes are<?pagebreak page2091?> the low-pressure polymorphs of bridgmanite. During such a “melting” episode, the primordial tracer is converted into a tracer with 40 % basalt and 60 % harzburgite, and its primordial flag is removed. Any melting and related degassing would likely reduce, or even destroy, the ancient isotopic fingerprint of the previously primordial material <xref ref-type="bibr" rid="bib1.bibx39" id="paren.37"/>. The <inline-formula><mml:math id="M159" display="inline"><mml:mrow><mml:mn mathvariant="normal">40</mml:mn><mml:mo>:</mml:mo><mml:mn mathvariant="normal">60</mml:mn></mml:mrow></mml:math></inline-formula> basalt <inline-formula><mml:math id="M160" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> harzburgite ratio is used as it corresponds to a (Mg <inline-formula><mml:math id="M161" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> Fe) <inline-formula><mml:math id="M162" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Si ratio of <inline-formula><mml:math id="M163" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> 1.0, such as that in bridgmanite.
Due to this tracer conversion, the final composition of the non-primordial mantle (from here on termed “ambient mantle”) <inline-formula><mml:math id="M164" display="inline"><mml:mrow><mml:msubsup><mml:mi>f</mml:mi><mml:mtext>bs,amb</mml:mtext><mml:mtext>final</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> evolves over time as primordial material is processed (melts) in the upper mantle:
            <disp-formula id="Ch1.E3" content-type="numbered"><label>3</label><mml:math id="M165" display="block"><mml:mtable class="split" rowspacing="0.2ex" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:msubsup><mml:mi>f</mml:mi><mml:mtext>bs,amb</mml:mtext><mml:mtext>final</mml:mtext></mml:msubsup></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:mfenced close=")" open="("><mml:mrow><mml:msubsup><mml:mi>f</mml:mi><mml:mtext>bs,amb</mml:mtext><mml:mtext>ini</mml:mtext></mml:msubsup><mml:mo>⋅</mml:mo><mml:msubsup><mml:mi>V</mml:mi><mml:mtext>amb</mml:mtext><mml:mtext>ini</mml:mtext></mml:msubsup><mml:mo>+</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mtext>bs,prim</mml:mtext></mml:msub><mml:mo>⋅</mml:mo><mml:msubsup><mml:mi>V</mml:mi><mml:mtext>prim,molten</mml:mtext><mml:mtext>final</mml:mtext></mml:msubsup></mml:mrow></mml:mfenced><mml:mo mathsize="2.5em">/</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mfenced open="(" close=")"><mml:mrow><mml:msubsup><mml:mi>V</mml:mi><mml:mtext>amb</mml:mtext><mml:mtext>ini</mml:mtext></mml:msubsup><mml:mo>+</mml:mo><mml:msubsup><mml:mi>V</mml:mi><mml:mtext>prim,molten</mml:mtext><mml:mtext>final</mml:mtext></mml:msubsup></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:math></disp-formula>
          where <inline-formula><mml:math id="M166" display="inline"><mml:mrow><mml:msubsup><mml:mi>f</mml:mi><mml:mtext>bs,amb</mml:mtext><mml:mtext>ini</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> is the initial bulk composition of the ambient mantle with volume <inline-formula><mml:math id="M167" display="inline"><mml:mrow><mml:msubsup><mml:mi>V</mml:mi><mml:mtext>amb</mml:mtext><mml:mtext>ini</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M168" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mtext>bs,prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is the conversion factor of primordial material into bs–hz space (<inline-formula><mml:math id="M169" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.4</mml:mn></mml:mrow></mml:math></inline-formula>) and <inline-formula><mml:math id="M170" display="inline"><mml:mrow><mml:msubsup><mml:mi>V</mml:mi><mml:mtext>prim,molten</mml:mtext><mml:mtext>final</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> is the total volume of primordial material that has melted during model evolution (<inline-formula><mml:math id="M171" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mfenced close=")" open="("><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msubsup><mml:mi mathvariant="italic">χ</mml:mi><mml:mtext>prim</mml:mtext><mml:mtext>pres</mml:mtext></mml:msubsup></mml:mrow></mml:mfenced><mml:mo>⋅</mml:mo><mml:msubsup><mml:mi>V</mml:mi><mml:mtext>prim</mml:mtext><mml:mtext>ini</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> with a primordial preservation factor of <inline-formula><mml:math id="M172" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">χ</mml:mi><mml:mtext>prim</mml:mtext><mml:mtext>pres</mml:mtext></mml:msubsup><mml:mo>=</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:msubsup><mml:mi>V</mml:mi><mml:mtext>prim</mml:mtext><mml:mtext>final</mml:mtext></mml:msubsup></mml:mrow><mml:mrow><mml:msubsup><mml:mi>V</mml:mi><mml:mtext>prim</mml:mtext><mml:mtext>ini</mml:mtext></mml:msubsup></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:math></inline-formula>).</p>
</sec>
<sec id="Ch1.S2.SS4">
  <label>2.4</label><title>Initial set-up of the models</title>
      <p id="d1e2790">The initial mantle temperatures are calculated from an adiabat with a potential temperature of 1900 <inline-formula><mml:math id="M173" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> together with the top and bottom boundary layers and small random perturbations. The resulting temperature profile is <inline-formula><mml:math id="M174" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> 300 <inline-formula><mml:math id="M175" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> warmer than that Earth's present-day geotherm. Such high initial mantle temperatures are applied to roughly mimic the thermal evolution of the mantle, with high vigor of mantle convection and near-surface melting that likely occurred in the early Earth <xref ref-type="bibr" rid="bib1.bibx26 bib1.bibx48" id="paren.38"><named-content content-type="pre">e.g.,</named-content></xref>.</p>
      <p id="d1e2821">In terms of composition, our models are initialized as simplified two-layered (and for selected cases, three-layered) profiles, motivated by a fractional-crystallization sequence of the magma ocean <xref ref-type="bibr" rid="bib1.bibx55 bib1.bibx30 bib1.bibx11 bib1.bibx117" id="paren.39"/>.
Similar to previous work <xref ref-type="bibr" rid="bib1.bibx40" id="paren.40"/>, we impose a bridgmanitic “primordial” material layer in the lower mantle with layer thickness <inline-formula><mml:math id="M176" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> (1568–2230 <inline-formula><mml:math id="M177" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>). By including randomly distributed 5 % pyrolitic “noise” in this primordial layer, the layer does not represent a pristine fractional-crystallization end-member cumulate. The upper mantle is initially a mechanical mixture of 15 % basalt and 85 % harzburgite, i.e., close to pyrolitic composition (Supplement S1.1).
For some models, a third layer is added just above the CMB (150, 200, or 250 <inline-formula><mml:math id="M178" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> thick) for which we impose the same physical properties as for basalt. This intrinsically dense layer is thought to represent an iron-enriched material, e.g.,<?pagebreak page2092?> originating from the last cumulates from a crystallizing basal magma ocean <xref ref-type="bibr" rid="bib1.bibx113" id="paren.41"><named-content content-type="pre">e.g.,</named-content></xref> or from ancient crust that settled at the CMB <xref ref-type="bibr" rid="bib1.bibx31" id="paren.42"/>.</p>
</sec>
<sec id="Ch1.S2.SS5">
  <label>2.5</label><title>Parameter study</title>
      <p id="d1e2875">In this study, we systematically investigate the styles of chemical heterogeneity in the mantle as a function of the physical properties of primordial material. The physical properties explored are the intrinsic density (FeO enrichment in (Mg, Fe)SiO<inline-formula><mml:math id="M179" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>) and viscosity contrast (silica enrichment) relative to pyrolite <xref ref-type="bibr" rid="bib1.bibx7 bib1.bibx40" id="paren.43"><named-content content-type="pre">as in</named-content></xref>. The density profile of primordial material is shifted throughout the mantle, which intrinsically changes the initial buoyancy ratio <inline-formula><mml:math id="M180" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> between the models (varying between 0.07 and <inline-formula><mml:math id="M181" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> 0.57, as per Eq. <xref ref-type="disp-formula" rid="Ch1.E2"/>). The approximate Mg number of the primordial material thereby ranges from 0.9 to 0.86 (Supplement S1.2). We further impose a viscosity contrast <inline-formula><mml:math id="M182" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">prim</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M183" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in Eq. <xref ref-type="disp-formula" rid="Ch1.E1"/>) between primordial and pyrolitic mantle material in the lower mantle that is motivated by the high intrinsic strength of bridgmanite relative to ferropericlase <xref ref-type="bibr" rid="bib1.bibx119 bib1.bibx38" id="paren.44"/>.</p>
      <p id="d1e2936">Additionally, we varied the initial conditions of chemical layering in the models (Supplement S1.1). The initial layer thickness of primordial material <inline-formula><mml:math id="M184" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> was changed such that the final composition of the ambient (i.e., convecting) mantle is similar for all cases, with a target value of a 25 % basalt <inline-formula><mml:math id="M185" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> 75 % harzburgite mechanical mixture (<inline-formula><mml:math id="M186" display="inline"><mml:mrow><mml:msubsup><mml:mi>f</mml:mi><mml:mtext>bs,amb</mml:mtext><mml:mtext>final</mml:mtext></mml:msubsup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.25</mml:mn></mml:mrow></mml:math></inline-formula>). This value is appropriate for the Earth, particularly if considering that the ambient lower mantle may be moderately enriched in ROC compared to the upper mantle in the present day <xref ref-type="bibr" rid="bib1.bibx79 bib1.bibx72 bib1.bibx120" id="paren.45"><named-content content-type="pre">e.g.,</named-content></xref>. As <inline-formula><mml:math id="M187" display="inline"><mml:mrow><mml:msubsup><mml:mi>f</mml:mi><mml:mtext>bs,amb</mml:mtext><mml:mtext>final</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> for any given model depends on the extent of primordial-material processing over time, which creates basaltic materials through near-surface melting (Eq. <xref ref-type="disp-formula" rid="Ch1.E3"/>), <inline-formula><mml:math id="M188" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is set to a different value for a given combination of parameters <inline-formula><mml:math id="M189" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M190" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>. The applied <inline-formula><mml:math id="M191" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> ranges from 1569  to 1844 <inline-formula><mml:math id="M192" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> (i.e., 60 vol %–75 vol %   of the lower mantle) between the models. These choices for the initial conditions of our models lead to final ambient-mantle bulk compositions of <inline-formula><mml:math id="M193" display="inline"><mml:mrow><mml:msubsup><mml:mi>f</mml:mi><mml:mtext>bs,amb</mml:mtext><mml:mtext>final</mml:mtext></mml:msubsup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.24</mml:mn></mml:mrow></mml:math></inline-formula>–0.26, i.e., very close to our target value for all cases.
In order to calculate these appropriate values for <inline-formula><mml:math id="M194" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> in the first place, we ran an additional suite of test models with a constant initial volume of primordial material. From the predictions of these test models and Eq. (<xref ref-type="disp-formula" rid="Ch1.E3"/>), the appropriate values for <inline-formula><mml:math id="M195" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> for each case of the main model suite were computed. For more details on this approach and the results of the test suite, see Supplement S4.</p>
      <p id="d1e3085">Finally, we compare model outcomes of the selected cases which include a thin, dense FeO-rich layer just above the CMB (three-layered models) with those of corresponding models in the main model suite (two-layered model).</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Results</title>
      <p id="d1e3097">We have conducted a total of 119 numerical experiments for this study. The relevant model parameters and selected output variables of each case are summarized in Supplement Tables S1 and S2. We first describe the various heterogeneity styles identified in the models (Sect. <xref ref-type="sec" rid="Ch1.S3.SS1"/>) and their dependence on composition-dependent rheological parameters (Sect. <xref ref-type="sec" rid="Ch1.S3.SS2"/>). We then discuss how initial compositional layering affects mantle dynamics and chemical heterogeneity preservation (Sect. <xref ref-type="sec" rid="Ch1.S3.SS3"/>). Finally, we focus on a specific heterogeneity style and analyze the characteristics of the distinct chemical mantle domains and how they are linked to mantle flow (Sect. <xref ref-type="sec" rid="Ch1.S3.SS4"/>).</p>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Mantle heterogeneity styles</title>
      <p id="d1e3115">Our results reveal different styles of long-term convection and mixing in the mantle. We label these regimes in line with previous work on variable styles of primordial heterogeneity preservation <xref ref-type="bibr" rid="bib1.bibx40" id="paren.46"/> as regimes I–III.
For all main models, primordial and ROC heterogeneity can coexist in a fully convecting mantle (partial heterogeneity preservation, regime III), with several distinct preservation styles (Fig. 2).
A subset of the test experiments predicted various styles of stable chemical layering (regime II), which are summarized in Sect. <xref ref-type="sec" rid="Ch1.S3.SS3"/> and discussed in more detail in Supplement S4.
In contrast to previous work <xref ref-type="bibr" rid="bib1.bibx40" id="paren.47"/>, we do not observe any models with pervasive convective mixing of ROC and primordial mantle materials (regime I) in this study.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F2" specific-use="star"><?xmltex \currentcnt{2}?><?xmltex \def\figurename{Figure}?><label>Figure 2</label><caption><p id="d1e3128">The left columns show mantle sections for all sub-styles in regime III (partial chemical heterogeneity) at 4.5 <inline-formula><mml:math id="M196" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula> model time; <inline-formula><mml:math id="M197" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M198" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula>, and <inline-formula><mml:math id="M199" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> are as labeled. The right columns show the corresponding profiles of primordial fraction, basaltic fraction, temperature, and viscosity. These profiles are radially averaged and time-averaged (4.25–4.5 <inline-formula><mml:math id="M200" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula>). The shaded region indicates the range for all models in any given sub-style. Dashed lines refer to the case shown in panel <bold>(a)</bold>.</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://se.copernicus.org/articles/12/2087/2021/se-12-2087-2021-f02.png"/>

        </fig>

<sec id="Ch1.S3.SS1.SSS1">
  <label>3.1.1</label><title>General geodynamic trend</title>
      <?pagebreak page2094?><p id="d1e3193">All experiments in the first model suite are characterized by whole-mantle convection and moderate compositional heterogeneity preservation in the lower mantle after 4.5 <inline-formula><mml:math id="M201" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula> of model evolution. Plate-like tectonic behavior is displayed for most of their evolution (Supplement S3).
Their evolution commonly starts as a two-layered convective system that is sustained for several 100 <inline-formula><mml:math id="M202" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Myr</mml:mi></mml:mrow></mml:math></inline-formula>. Almost immediately, weak downwellings develop from the cold top thermal boundary layer and are deflected at the compositional interface in the mid-mantle. The onset of convection in the lower layer is delayed with respect to the upper layer. However, progressive heating and cooling of the lower and upper layers promotes a whole-mantle overturn at <inline-formula><mml:math id="M203" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> 0.2–1 <inline-formula><mml:math id="M204" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula>. During this overturn, much of the primordial material in the lower mantle may reach the upper mantle and can subsequently be processed by extensive near-surface melting. Consequently, basaltic crust is formed that can re-enter the mantle through subduction.
Moreover, the strong primordial material is separated into several blobs and/or streaks that are slowly eroded and entrained by the convecting pyrolitic mantle over time. The final extent of heterogeneity differs between the models, and the following four sub-regimes are established.</p>
</sec>
<sec id="Ch1.S3.SS1.SSS2">
  <label>3.1.2</label><title>Viscous blobs (regime III.B)</title>
      <p id="d1e3236">In many numerical experiments, primordial material is ultimately preserved as blobs in the mid-mantle. Here, the primordial material is neutrally buoyant (Supplement S1.2) and relatively stable. Deformation due to mantle convection is mainly focused along narrow upwelling and downwelling conduits (Fig. 2a, b), and blobs are variably preserved in poorly mixed regions in between. These blobs periodically rotate and/or are displaced laterally as they are passed by sinking slabs. Occasionally, two blobs coagulate or are separated again as the convection patterns reorganize through time. When slabs reach the CMB they push away basaltic piles to the side, disconnecting the otherwise continuous basaltic layer at the base of the mantle. The final lower-mantle primordial (<inline-formula><mml:math id="M205" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">χ</mml:mi><mml:mtext>prim</mml:mtext><mml:mtext>LM</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula>) and ROC (<inline-formula><mml:math id="M206" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">χ</mml:mi><mml:mtext>ROC</mml:mtext><mml:mtext>LM</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula>) heterogeneity range from 8 vol % to 40 vol % and 1.5 vol % to 6 vol %, respectively. This style of material preservation is similar to that described in <xref ref-type="bibr" rid="bib1.bibx7 bib1.bibx40" id="text.48"/> and is here established with the presence of ROC (as piles atop the CMB and marble cake streaks throughout the mantle).</p>
</sec>
<sec id="Ch1.S3.SS1.SSS3">
  <label>3.1.3</label><title>Marble cake mantle (regime III.M)</title>
      <p id="d1e3276">In this style, the final mantle composition is characterized by the preservation of a relatively large amount of ROC (4.5 vol %–6.5 vol %) and low primordial heterogeneity (<inline-formula><mml:math id="M207" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> vol %). In addition to large ROC piles in the lowermost mantle, chemical heterogeneity takes the form of thin streaks of recycled and primordial material in an otherwise well-mixed mantle. Ultimately, the mantle is mostly made up of a marble cake with both ROC and primordial streaks (Fig. 2c).</p>
</sec>
<sec id="Ch1.S3.SS1.SSS4">
  <label>3.1.4</label><title>“Diffuse” primordial domains (regime III.D)</title>
      <p id="d1e3297">Here, primordial heterogeneity is not preserved as coherent blobs or streaks (e.g., with sharp boundaries as in regime III.B or III.M) but is rather diffusely distributed throughout much of the lower mantle (Fig. 2d). Even though no discrete primordial domains are sustained in the convecting mantle, significant amounts (2 vol %–7 vol %) of primordial heterogeneity can survive in the lower mantle for 4.5 <inline-formula><mml:math id="M208" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula> model time. As in regime III.B, ROC is preserved as piles in the lowermost mantle, as well as streaks throughout the mantle. Aside from these additional structures, regime III.D is similar to the diffuse-domain regime detected in <xref ref-type="bibr" rid="bib1.bibx40" id="text.49"/>.</p>
</sec>
<sec id="Ch1.S3.SS1.SSS5">
  <label>3.1.5</label><?xmltex \opttitle{Metastable primordial piles (regime \textit{III.P})}?><title>Metastable primordial piles (regime <italic>III.P</italic>)</title>
      <p id="d1e3323">In some numerical experiments, primordial material is preserved as large primordial blobs and streaks that are mostly confined to the lowermost mantle (Fig. 2e). Initial model evolution differs from the main geodynamic trend as hot upwellings form in a delayed manner, and even when these upwellings reach the compositional interface, a double-layered convective system is maintained for several 100 <inline-formula><mml:math id="M209" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Myr</mml:mi></mml:mrow></mml:math></inline-formula>. Gradually, the two-layered system breaks down as subducting slabs break through the lower layer, and in return hot upwellings, including primordial material, reach upper-mantle depths. Large viscous blobs are confined to, or settle near, the CMB due to their relatively large negative buoyancy. Some of the blobs are occasionally pushed up from the CMB by convective currents and intermittently float through the mid-mantle. In contrast to other partial heterogeneity styles, short intervals with low mobility occur in this sub-regime (Supplement S3). With the addition of the presence of dense ROC heterogeneity (1.5 vol %–4 vol %) throughout the lower mantle as thin streaks, this regime is similar to previously described as metastable piles (regime III.P) in <xref ref-type="bibr" rid="bib1.bibx40" id="text.50"/>.</p>
</sec>
</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Influence of physical parameters of primordial material</title>
      <p id="d1e3346">The regime diagram shown in Fig. 3 pinpoints the parameter space where the various heterogeneity styles discussed above are identified. The viscous blobs heterogeneity style (III.B) occurs for the majority of the parameter space (<inline-formula><mml:math id="M210" display="inline"><mml:mo lspace="0mm">≈</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M211" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">20</mml:mn></mml:mrow></mml:math></inline-formula> and variable <inline-formula><mml:math id="M212" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula>), while the total volume of the preserved blobs strongly depends on the intrinsic viscosity contrast <inline-formula><mml:math id="M213" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>. High <inline-formula><mml:math id="M214" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> results in a delayed overturn, more localized deformation, and slow entrainment of primordial material by the convecting mantle (Figs. 3, 2a).
In contrast, low <inline-formula><mml:math id="M215" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> causes an earlier overturn, increases convective vigor and mixing, and prevents large primordial domains from being sustained in the convecting mantle: a marble cake mantle (III.M) occurs for low <inline-formula><mml:math id="M216" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula>, while primordial material is diffusely distributed throughout the mantle (III.D) for moderate to large <inline-formula><mml:math id="M217" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula>.
In a narrow parameter space (high <inline-formula><mml:math id="M218" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M219" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> of approximately <inline-formula><mml:math id="M220" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">0.45</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M221" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">300</mml:mn></mml:mrow></mml:math></inline-formula>, respectively), metastable, primordial “piles” settle due to their intrinsic negative buoyancy (regime III.P).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3"><?xmltex \currentcnt{3}?><?xmltex \def\figurename{Figure}?><label>Figure 3</label><caption><p id="d1e3467">Summary of key results as a function of physical parameters of primordial material for model suite 1 (see text). The vertical axis represents the initial buoyancy ratio <inline-formula><mml:math id="M222" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula>, defined at 1500 <inline-formula><mml:math id="M223" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> depth (Sect. 2 and Supplement S3), or the corresponding Mg number of primordial material. The horizontal axis gives the viscosity contrast <inline-formula><mml:math id="M224" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> between primordial and pyrolitic material in the lower mantle. The fraction of primordial heterogeneity (<inline-formula><mml:math id="M225" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">χ</mml:mi><mml:mtext>prim</mml:mtext><mml:mtext>LM</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula>, red) and ROC (<inline-formula><mml:math id="M226" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">χ</mml:mi><mml:mtext>ROC</mml:mtext><mml:mtext>LM</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula>, blue) in the lower mantle is averaged between 4.25 and 4.5 <inline-formula><mml:math id="M227" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Myr</mml:mi></mml:mrow></mml:math></inline-formula> model time (for definitions, see Supplement S1.3). The circle denotes the reference model in this study. Regime boundaries are established based on the style of mantle evolution and chemical heterogeneity: (III) partial heterogeneity preservation as marble-cake mantle (M), marginally stable piles (P), viscous blobs (B), or diffuse domains (D).</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://se.copernicus.org/articles/12/2087/2021/se-12-2087-2021-f03.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Influence of initial layering</title>
<sec id="Ch1.S3.SS3.SSS1">
  <label>3.3.1</label><title>Primordial layer thickness</title>
      <p id="d1e3552">The model suite discussed above was also run with a fixed primordial layer thickness (<inline-formula><mml:math id="M228" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">2230</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M229" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, i.e., extending from the CMB up to the top of the lower mantle, as in <xref ref-type="bibr" rid="bib1.bibx40" id="altparen.51"/>). The details regarding this model suite are described in Supplement S4. As a summary, the final ambient mantle composition greatly varies between the models, as very different amounts of primordial material are processed (as expected from Eq. <xref ref-type="disp-formula" rid="Ch1.E3"/>). There is also more variety in geodynamic behavior, as two additional sub-styles of<?pagebreak page2095?> stable chemical layering (regime II) are identified (see Fig. S7): two-layered convection with an undulating primordial layer preserved for large <inline-formula><mml:math id="M230" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> (II.T) and post-overturn ROC layering for low <inline-formula><mml:math id="M231" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M232" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> (II.R). Although these regimes are not relevant for present-day Earth, they may be relevant for mantle dynamics within other (exo)planets with slightly different bulk composition, e.g., enhanced in silica.
Comparisons of models with equal <inline-formula><mml:math id="M233" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M234" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> in both model suites allows us to identify the effect of a different primordial layer thickness on model behavior. Selected model outputs are presented in Fig. 4. Final ROC heterogeneity is increased for most models with more primordial material initialized (Fig. 4a–b), and sub-regime boundaries are slightly shifted as primordial domains are more coherent in comparison with lower <inline-formula><mml:math id="M235" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> models (Supplement S4).
Most notably, the fraction of initialized primordial material that is preserved after 4.5 <inline-formula><mml:math id="M236" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula> of mantle stirring (<inline-formula><mml:math id="M237" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">χ</mml:mi><mml:mtext>prim</mml:mtext><mml:mtext>pres</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula>) is similar in both cases or even lower in models with more primordial material initialized (Fig. 4c–d). Moreover, the final internal temperature of all experiments in the test model suite are systematically lower than those the main model suite.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><?xmltex \currentcnt{4}?><?xmltex \def\figurename{Figure}?><label>Figure 4</label><caption><p id="d1e3662">Output quantities time-averaged between 4.25 and 4.5 <inline-formula><mml:math id="M238" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula> for the main model suite <bold>(a, c, e)</bold> and test model suite <bold>(b, d, f)</bold>: <bold>(a–b)</bold> primordial preservation factor <inline-formula><mml:math id="M239" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">χ</mml:mi><mml:mtext>prim</mml:mtext><mml:mtext>pres</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> in vol % of initialized primordial material, <bold>(c–d)</bold> average mantle temperature, and <bold>(e–f)</bold> convective vigor. The horizontal axis represents the primordial viscosity contrast <inline-formula><mml:math id="M240" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, while colors denote different <inline-formula><mml:math id="M241" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> used in the models.</p></caption>
            <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://se.copernicus.org/articles/12/2087/2021/se-12-2087-2021-f04.png"/>

          </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><?xmltex \def\figurename{Figure}?><label>Figure 5</label><caption><p id="d1e3728">Temporal evolution of the radially averaged compositional profiles of selected models. Models with variable <inline-formula><mml:math id="M242" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> (main model suite) are on the left, and their corresponding model with fixed <inline-formula><mml:math id="M243" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M244" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">2230</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M245" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, test model suite) is on the right for given <inline-formula><mml:math id="M246" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M247" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>: <bold>(a–b)</bold> <inline-formula><mml:math id="M248" display="inline"><mml:mrow><mml:mi>B</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.28</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M249" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula>; <bold>(c–d)</bold> <inline-formula><mml:math id="M250" display="inline"><mml:mrow><mml:mi>B</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.35</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M251" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">50</mml:mn></mml:mrow></mml:math></inline-formula>; <bold>(d–e)</bold> <inline-formula><mml:math id="M252" display="inline"><mml:mrow><mml:mi>B</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.21</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M253" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">30</mml:mn></mml:mrow></mml:math></inline-formula>. The dotted black line indicates the onset of the compositional overturn. In the test model suite 0 (but not in the main suite), significant amounts of primordial material immediately reach the upper mantle after the overturn. </p></caption>
            <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://se.copernicus.org/articles/12/2087/2021/se-12-2087-2021-f05.png"/>

          </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><?xmltex \currentcnt{6}?><?xmltex \def\figurename{Figure}?><label>Figure 6</label><caption><p id="d1e3890">Snapshots during the compositional overturn phase for three models with equal <inline-formula><mml:math id="M254" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> (0.28) and <inline-formula><mml:math id="M255" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> (100) but a different initial compositional layering (as shown on the bottom left). The panels provide the potential temperature field and a zoom-in on the compositional field. </p></caption>
            <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://se.copernicus.org/articles/12/2087/2021/se-12-2087-2021-f06.png"/>

          </fig>

      <?pagebreak page2096?><p id="d1e3917">Figure 5 shows the temporal evolution of the radially averaged compositional profiles for selected experiments in both model suites. The compositional overturn (vertical dashed black line in Fig. 5) occurs later for models with a thicker primordial layer, as convective instabilities form less rapidly in the upper thinner layer to drive the overturn. Moreover, with a primordial-dominated lower mantle, primordial material is immediately swept to upper-mantle depths during the overturn while being displaced by the slabs that sink into the lower mantle (left panels of Fig. 5). Subsequent melting of primordial material and crustal recycling leads to a quick buildup of basaltic piles in the lowermost mantle. In contrast, a thinner primordial layer (left panels of Fig. 5) detaches from the CMB during the overturn and is swept to mid-mantle depths without immediately reaching the upper mantle. At these depths, the primordial material remains relatively stable.
Melting of primordial material, crustal recycling, and ultimately the formation of ROC piles underneath is thereby delayed.
This discrepancy between mantle dynamics and the extent of melting affects the subsequent thermal evolution of the models: melting is an efficient mechanism to remove heat from the mantle by transporting heat from the interior to the surface and enhancing the plates' mobility <xref ref-type="bibr" rid="bib1.bibx81 bib1.bibx69" id="paren.52"/>. Thereby, the lower extent of melting in models with a thinner bridgmanitic layer can explain their higher internal temperatures (Fig. 4c).
The dynamic behavior described above can also be seen in Fig. 6, which shows detailed dynamics of selected models during the compositional overturn.</p>
</sec>
<sec id="Ch1.S3.SS3.SSS2">
  <label>3.3.2</label><title>Additional basal FeO-rich layer</title>
      <p id="d1e3931">We further explore several additional cases that include an additional FeO-rich layer just above the CMB as an initial condition (Supplement S1.1). The results of these cases are summarized in Supplement Table S1. The imposed material properties of the FeO-rich layer are the same as for basalt (i.e., intrinsically dense; see Supplement S1.2). Notably, the ancient dense basal layer aids the preservation of bridgmanitic primordial material over time (higher <inline-formula><mml:math id="M256" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">χ</mml:mi><mml:mtext>prim</mml:mtext><mml:mtext>pres</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula>). During the compositional overturn, the FeO-rich layer remains at the base of the mantle, while the bridgmanitic material is swept to mid-mantle depths (Fig. 6c). Significant amounts of heat can be retained in this negatively buoyant layer that acts an insulating boundary layer above the core. Plumes readily form on top of this layer and are less hot than those otherwise directly forming above the CMB, resulting in a less vigorous compositional overturn and thus an increased coherency of primordial domains.
Downgoing slabs separate the initially laterally connected dense layer into distinct piles, and they also transport ROC to the lowermost mantle, which is then added to the piles of ancient FeO-rich material (see last the two panels of Fig. 6c). The incoming ROC material is cooler and thus denser than the hot ancient FeO-rich material. Accordingly, it sinks through the ancient layer to settle directly above the CMB. Over time, much of the ancient FeO-rich material is progressively entrained by mantle upwellings and ultimately processed by near-surface melting. Only a small fraction is preserved after 4.5 <inline-formula><mml:math id="M257" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula>, preferably located in the uppermost parts of some thermochemical piles (Fig. 7). The general trend in these piles is aging upwards: the youngest, most recently subducted (cool) ROC material is at the bottom, with progressively older ROC material progressing upwards, and the ancient (hot) FeO-rich material at the very top. Thereby, the piles are thermally stratified, and internal small-scale convection occurs in the lowermost, dense layer. Ultimately, the coexistence of large, coherent bridgmanitic<?pagebreak page2097?> primordial domains with basaltic piles (ROC and ancient) is robustly predicted, even for low <inline-formula><mml:math id="M258" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> (Supplement S5).</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F7"><?xmltex \currentcnt{7}?><?xmltex \def\figurename{Figure}?><label>Figure 7</label><caption><p id="d1e3968">Final snapshots (at 4.5 <inline-formula><mml:math id="M259" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula>) of composition for selected models, <inline-formula><mml:math id="M260" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M261" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula>, as stated in the panels. The models are initialized with a 200 <inline-formula><mml:math id="M262" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> thick FeO-rich basal layer (pink) overlain by a <bold>(a)</bold> 1546 and <bold>(b)</bold> 1514 <inline-formula><mml:math id="M263" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> thick primordial layer. The panels also show a zoom-in on the formation age of ROC within the piles (defined as <inline-formula><mml:math id="M264" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mtext>bs</mml:mtext></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">0.6</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M265" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>pot</mml:mtext></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">2000</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M266" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>). The formation age quantifies the time since the last melting episode.</p></caption>
            <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://se.copernicus.org/articles/12/2087/2021/se-12-2087-2021-f07.png"/>

          </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8" specific-use="star"><?xmltex \currentcnt{8}?><?xmltex \def\figurename{Figure}?><label>Figure 8</label><caption><p id="d1e4066">Each panel shows a 2D histogram that relates several selected output quantities of a representative model displaying both primordial blobs and dense piles underneath (regime III.B, model <inline-formula><mml:math id="M267" display="inline"><mml:mrow><mml:msub><mml:mi>M</mml:mi><mml:mtext>300dD</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, Fig. 2a). For six time steps (4.25–4.5 <inline-formula><mml:math id="M268" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula> with steps of 0.05 <inline-formula><mml:math id="M269" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula>), selected quantities were calculated for each radial column in the model: pile height <inline-formula><mml:math id="M270" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>pile</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, formation age of pile material <inline-formula><mml:math id="M271" display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mi>g</mml:mi><mml:msub><mml:mi>e</mml:mi><mml:mtext>pile</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, mid-mantle primordial-material fraction <inline-formula><mml:math id="M272" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, mid-mantle radial velocity <inline-formula><mml:math id="M273" display="inline"><mml:mrow><mml:msub><mml:mi>v</mml:mi><mml:mtext>z</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, and mid-mantle temperature anomaly <inline-formula><mml:math id="M274" display="inline"><mml:mrow><mml:mi>d</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula>. Thermochemical pile thresholds are <inline-formula><mml:math id="M275" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mtext>bs</mml:mtext></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">0.6</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M276" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>pot</mml:mtext></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">2000</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M277" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>. Mid-mantle is defined as the depth range 1000–2000 <inline-formula><mml:math id="M278" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>. The formation age of pile material is volume-averaged over the full pile thickness and weighted by the basaltic fraction. Each row in the histograms is normalized by the total counts of the row. For rows in greyscale, the number of counts in these rows represents less than 1 % of the total counts.</p></caption>
            <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://se.copernicus.org/articles/12/2087/2021/se-12-2087-2021-f08.png"/>

          </fig>

</sec>
</sec>
<sec id="Ch1.S3.SS4">
  <label>3.4</label><title>Relating dense piles, viscous blobs, and mantle dynamics</title>
      <?pagebreak page2098?><p id="d1e4218">Finally, we analyzed the potential relationship between dense piles, viscous blobs, and mantle dynamics for a model that displays both piles and blobs (model <inline-formula><mml:math id="M279" display="inline"><mml:mrow><mml:msub><mml:mi>M</mml:mi><mml:mtext>300dD</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, regime III.B, illustrated in Fig. 2a).
Figure 8 shows 2D histograms relating selected model output quantities with one another, including pile characteristics (pile height, formation age of pile material) and mid-mantle characteristics (primordial-material fraction, radial velocity, and temperature anomaly over a 1000–2000 <inline-formula><mml:math id="M280" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> depth range).
Several relations between these parameters can be inferred:
first, the presence of primordial material in the mid-mantle is related with little radial dynamics (near-zero <inline-formula><mml:math id="M281" display="inline"><mml:mrow><mml:msub><mml:mi>v</mml:mi><mml:mtext>z</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, Fig. 8a). Similarly, most piles are stable at near-zero radial velocity, although thick (<inline-formula><mml:math id="M282" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M283" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>) piles are also stabilized in regions of upwellings.
Second, the absence of primordial domains (<inline-formula><mml:math id="M284" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mtext>prim</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>, bottom rows in Fig. 8e, f) and piles (<inline-formula><mml:math id="M285" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mtext>pile</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>, bottom rows in Fig. 8e, f) is associated with columns of cool downwellings (<inline-formula><mml:math id="M286" display="inline"><mml:mrow><mml:msub><mml:mi>v</mml:mi><mml:mtext>z</mml:mtext></mml:msub><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula> and d<inline-formula><mml:math id="M287" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>).
Third, the presence of a large amount of primordial material in the mid-mantle is associated with positive temperature anomalies (Fig. 8b), and thus large primordial blobs (high <inline-formula><mml:math id="M288" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>) are typically slightly warmer than average (also see Fig. 2a, b). There is also a slight positive correlation between pile height and mid-mantle temperature anomaly: large piles are often related to overlying warm primordial blobs (see below).
Although the histograms remain scattered, there is a slight positive trend in formation age of pile material versus mid-mantle primordial fraction and formation age versus pile height (Fig. 8c, g), indicating that piles containing older material are more often overlain by primordial domains than younger piles and that old ROC tends to be preserved near to top of the piles (see above).
Finally, Fig. 8d and h indicate a spatial relationship (in radial direction) between the presence of primordial material in the mid-mantle and the height of the underlying ROC material. Even though this relationship is not strict, it indicates that the highest ROC piles tend to be centered just below the largest primordial blobs. This configuration away from upwellings and downwellings (Fig. 8b, f) appears to promote the coupled preservation of both these thermochemical domains.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Discussion</title>
<sec id="Ch1.S4.SS1">
  <label>4.1</label><title>Styles of mantle mixing</title>
      <p id="d1e4354">Many of the identified dynamic styles of primordial-material preservation in our prior study <xref ref-type="bibr" rid="bib1.bibx40" id="paren.53"/> are here established in the presence of plate-like behavior and recycling of oceanic crust into the deep mantle. This indicates that primordial-material preservation robustly occurs for significant rheological contrasts, regardless of tectonic behavior or the presence of dense, recycled materials in the lower mantle. This study even shows the robustness of primordial-material preservation with respect to initial layering set-up. Despite no detection of models in which both primordial and recycled materials are efficiently mixed throughout the mantle (regime I in <xref ref-type="bibr" rid="bib1.bibx40" id="altparen.54"/>), we expect such a behavior to occur for small rheological contrasts of primordial material in combination with lower-density anomalies of ROC than modeled here <xref ref-type="bibr" rid="bib1.bibx82" id="paren.55"/>.
Indeed, different ROC properties may affect the segregation, accumulation and survival of ROC in the deep mantle <xref ref-type="bibr" rid="bib1.bibx17 bib1.bibx49 bib1.bibx83 bib1.bibx78" id="paren.56"><named-content content-type="pre">e.g.,</named-content></xref>.</p>
      <?pagebreak page2099?><p id="d1e4371">All of our numerical experiments are run in 2D geometry. Admittedly, the planform of mantle flow is different for 3D than for 2D geometry <xref ref-type="bibr" rid="bib1.bibx32 bib1.bibx25" id="paren.57"/>. An additional toroidal component of mantle flow in 3D can enhance  mixing relative to mantle flow in 2D with its rather simple geometry of convection. In terms of the preservation of intrinsically strong heterogeneity, however, we expect competing effects to occur: on one hand, coherent blobs may be difficult to preserve in the presence of toroidal and poloidal flow components <xref ref-type="bibr" rid="bib1.bibx32" id="paren.58"/>; on the other hand, mantle flow may be more efficiently guided around viscous blobs in 3D than in 2D geometry <xref ref-type="bibr" rid="bib1.bibx75" id="paren.59"/>. In addition, sheet-like upwellings in 2D can enhance mixing. Indeed, several studies showed that for high Rayleigh number convection models, the different geometry of boundary layer instabilities between 2D and 3D does not significantly modify the timescale or the regime of mixing <xref ref-type="bibr" rid="bib1.bibx18 bib1.bibx85" id="paren.60"><named-content content-type="pre">e.g.,</named-content></xref>, although it is uncertain whether this would be the case in the presence of composition-dependent rheology as modeled here.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9"><?xmltex \currentcnt{9}?><?xmltex \def\figurename{Figure}?><label>Figure 9</label><caption><p id="d1e4390">Sketch of our proposed style of present-day mantle heterogeneity in the Earth. Recycled crustal material (ROC, dark blue) is present throughout the mantle as marble cake streaks, with enhancement in the mantle transition zone (between 410 and 660 <inline-formula><mml:math id="M289" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> depth). Moreover, the dense ROC material settles at the CMB to form thermochemical piles. Any ancient basal layer may be preserved within these piles, here proposed to be on the roof of the piles as predicted by our models (see Fig. 8). Finally, primordial (Mg, Fe)SiO<inline-formula><mml:math id="M290" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>-enriched material is preserved as blobs and streaks that reside in the mid-mantle (dark green) due to its intrinsic strength (BEAMS: bridgmanite-enriched ancient mantle structures, <xref ref-type="bibr" rid="bib1.bibx7" id="altparen.61"/>).</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://se.copernicus.org/articles/12/2087/2021/se-12-2087-2021-f09.png"/>

        </fig>

      <p id="d1e4420">The relevance of each regime for terrestrial planet evolution depends on the actual initial compositional profile of the mantle at the onset of long-term solid-state convection. The initial conditions of our models are mainly motivated by an enrichment of a thick, basal layer in (Mg, Fe)SiO<inline-formula><mml:math id="M291" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> bridgmanite (and hence in silica with respect to the overlying mantle). This may occur due to fractionation during magma ocean or basal magma ocean (BMO) crystallization <xref ref-type="bibr" rid="bib1.bibx63" id="paren.62"><named-content content-type="pre">e.g.,</named-content></xref>. Indeed, bridgmanite is the liquidus phase in a magma ocean over a wide compositional and pressure range <xref ref-type="bibr" rid="bib1.bibx54 bib1.bibx15" id="paren.63"><named-content content-type="pre">e.g.,</named-content></xref>. Alternatively, incomplete core–mantle equilibration during the last stages of planetary accretion <xref ref-type="bibr" rid="bib1.bibx27 bib1.bibx58" id="paren.64"/> or disproportionation of FeO during core formation <xref ref-type="bibr" rid="bib1.bibx35 bib1.bibx3" id="paren.65"/> may have promoted the formation of (bridgmanite-enriched) heterogeneity in the lowermost mantle.
Moreover, chemical transfer between the outer core and the (basal) magma ocean in a hot early Earth may have caused delivery of SiO<inline-formula><mml:math id="M292" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> to the BMO and extraction of iron from the BMO into the core, stabilizing bridgmanite as the primary liquidus phase during prolonged periods of BMO crystallization <xref ref-type="bibr" rid="bib1.bibx107" id="paren.66"><named-content content-type="pre">e.g.,</named-content></xref>. Indeed, various studies have proposed SiO<inline-formula><mml:math id="M293" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> exsolution from the core during secular cooling of the Earth or Earth-like planets <xref ref-type="bibr" rid="bib1.bibx4 bib1.bibx50 bib1.bibx43 bib1.bibx91" id="paren.67"><named-content content-type="pre">e.g.,</named-content></xref>.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <label>4.2</label><title>A recipe for Earth's lower mantle: marble cake plus plum pudding</title>
      <p id="d1e4485">For Earth, geodynamic styles that predict the coupled preservation of primordial material and ROC, such as regimes III.D (diffuse primordial domains), III.M (marble cake mantle), and III.B (viscous blobs), can potentially explain a wide range of geophysical, geochemical, and geological observations.
First, these geodynamic styles are consistent with whole-mantle convection operating on Earth, which is motivated by seismic tomographic images of recently (<inline-formula><mml:math id="M294" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">200</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M295" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Myr</mml:mi></mml:mrow></mml:math></inline-formula>) subducted lithosphere in the lowermost mantle <xref ref-type="bibr" rid="bib1.bibx109" id="paren.68"><named-content content-type="pre">e.g.,</named-content></xref> and deep-rooted plumes that rise through the entire mantle <xref ref-type="bibr" rid="bib1.bibx34" id="paren.69"/>. Second, they all include the existence of thermochemical piles in the lowermost mantle, which are robustly featured in seismic tomographic studies as two antipodal, anomalously slow domains (LLSVPs) just above the CMB. <xref ref-type="bibr" rid="bib1.bibx66 bib1.bibx89 bib1.bibx106" id="paren.70"><named-content content-type="pre">e.g.,</named-content></xref>.
Third, coupled preservation of primordial and recycled materials in the models agrees with the geochemical record of igneous rocks carrying the footprint of both (old) recycled crust <xref ref-type="bibr" rid="bib1.bibx16 bib1.bibx52 bib1.bibx14" id="paren.71"><named-content content-type="pre">e.g.,</named-content></xref> and primordial mantle sources, such as <inline-formula><mml:math id="M296" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">182</mml:mn></mml:msup></mml:math></inline-formula>W <inline-formula><mml:math id="M297" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M298" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">184</mml:mn></mml:msup></mml:math></inline-formula>W and <inline-formula><mml:math id="M299" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">142</mml:mn></mml:msup></mml:math></inline-formula>Nd <inline-formula><mml:math id="M300" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M301" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">144</mml:mn></mml:msup></mml:math></inline-formula>Nd isotopic anomalies and/or high <inline-formula><mml:math id="M302" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula>He <inline-formula><mml:math id="M303" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M304" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msup></mml:math></inline-formula>He ratios <xref ref-type="bibr" rid="bib1.bibx56 bib1.bibx105 bib1.bibx90 bib1.bibx88" id="paren.72"><named-content content-type="pre">e.g.,</named-content></xref>. The specific isotopic fingerprints of the different mantle reservoirs predicted by our models (e.g., primordial and recycled) and the subsequent sampling thereof by mantle plumes remain key topics for future research.
Finally, the plate-like behavior displayed by the numerical models agree with various geological indicators of plate tectonics operating on Earth for at least several billions of years before present day <xref ref-type="bibr" rid="bib1.bibx62" id="paren.73"><named-content content-type="post">and references therein</named-content></xref>.</p>
      <?pagebreak page2100?><p id="d1e4611">Out of the likely geodynamic styles (diffuse domains, marble cake mantle, and viscous blobs), the primordial blobs style (III.B) is most commonly predicted (Fig. 3). Model predictions for this sub-regime are also consistent with the stagnation of some slabs in a depth range that is similar to primordial-domain roofs, while other slabs readily sink into the deep mantle <xref ref-type="bibr" rid="bib1.bibx36" id="paren.74"/>, as seen in Figs. 2, 7, and videos in the Supplement <xref ref-type="bibr" rid="bib1.bibx41" id="paren.75"/>. Furthermore, the presence of viscous domains in the mid-mantle may explain the observation of sharp seismic velocity contrasts in the uppermost lower mantle (850–1100 <inline-formula><mml:math id="M305" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> depth), usually occurring away from major upwellings and downwellings <xref ref-type="bibr" rid="bib1.bibx57 bib1.bibx114" id="paren.76"/>. Moreover, such bridgmanite-rich regions would suppress the average effects of the pressure-induced spin transition of iron in ferropericlase on seismic properties <xref ref-type="bibr" rid="bib1.bibx23 bib1.bibx79" id="paren.77"/>. Indeed, a recent study noted the absence of the expected signal of this spin transition for pyrolitic compositions at mid-mantle depths in global seismic profiles <xref ref-type="bibr" rid="bib1.bibx94" id="paren.78"/>, corroborating the presence of bridgmanite-rich regions in a depth range as predicted here.
Finally, in terms of seismic tomography, the lack of clear evidence for primordial domains in the mid-mantle may be related to a trade-off between the seismic effects of their compositional (intrinsically fast bridgmanite, <xref ref-type="bibr" rid="bib1.bibx115" id="altparen.79"/>) and thermal (slightly warmer than the ambient mantle) anomalies.</p>
      <p id="d1e4641">Although various alternative hypotheses have been put forward to explain each of the observations above, a hybrid style of present-day Earth mantle heterogeneity as predicted here can provide a unified explanation for these various geochemical and geophysical observations. This hybrid style is illustrated in Fig. 9 and includes the coexistence of viscous primordial material and dense ROC material in a convecting mantle, with several primordial streaks and/or blobs forming a larger composite bridgmanitic structure (100 s–1000 <inline-formula><mml:math id="M306" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>) around which convective flows are organized. Except for very large <inline-formula><mml:math id="M307" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mtext>prim</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, this prediction is somewhat different from that in <xref ref-type="bibr" rid="bib1.bibx7" id="text.80"/>, who predict large coherent blobs. ROC material is present as marble-cake streaks throughout the mantle with local enhancement in the mantle transition zone (MTZ) and at the CMB (i.e., forming thermochemical piles) <xref ref-type="bibr" rid="bib1.bibx80 bib1.bibx120" id="paren.81"><named-content content-type="pre">as in</named-content></xref>. Piles in this regime are mostly of recycled origin but may include ancient FeO-enriched material that is preserved near their top if a FeO-rich basal layer ever existed in the early Earth.
In this scenario for mantle composition and structure, the upper mantle is on average pyrolitic, while the lower mantle is significantly more enriched in silica, in line with previous studies <xref ref-type="bibr" rid="bib1.bibx79 bib1.bibx5 bib1.bibx72 bib1.bibx120" id="paren.82"><named-content content-type="pre">e.g.,</named-content></xref>.</p>
</sec>
<sec id="Ch1.S4.SS3">
  <label>4.3</label><title>Thermochemical pile layering</title>
      <p id="d1e4684">Thermochemical piles formed in our models comprise of ROC with varying formation ages. For models including an ancient FeO-rich basal layer, piles consist of both recycled and ancient materials (e.g., a “basal melange”, <xref ref-type="bibr" rid="bib1.bibx100" id="altparen.83"/>). Towards the roof of the piles, the formation age of ROC increases, while the overall ROC content decreases (Fig. 7). A radial distinction into regions of a high- and low-ROC content within piles was also found by <xref ref-type="bibr" rid="bib1.bibx78" id="text.84"/>. For a high buoyancy ratio of basaltic material, the thermochemical piles consist of a high-density basal layer covering nearly the entire CMB, overlain by high-topography piles with a much lower fraction of ROC <xref ref-type="bibr" rid="bib1.bibx78" id="paren.85"/>, as is the case for the thermochemical piles in our models.
Moreover, in our experiments, ancient FeO-rich material survives for several billion years at the roof of some piles (Fig. 7). Compositional layering of ancient versus recycled domains within LLSVPs has been previously  proposed <xref ref-type="bibr" rid="bib1.bibx6 bib1.bibx107" id="paren.86"/>, albeit with an inverted maturity gradient as found here.</p>
      <p id="d1e4699">Chemical layering strongly depends on the density profile and rheological properties of the material that makes up the thermochemical piles, which remain poorly constrained. We modeled the ancient FeO-rich basal layer to have the same physical properties as ROC. Final preservation of an ancient basal layer would be advanced, and the maturity gradient potentially inverted, if the layer were enriched in FeO or SiO<inline-formula><mml:math id="M308" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> relative to ROC. Such an enrichment may or may not occur depending on the formation scenario of the ancient basal layer, e.g., the style of magma ocean crystallization <xref ref-type="bibr" rid="bib1.bibx63 bib1.bibx8" id="paren.87"><named-content content-type="pre">e.g.,</named-content></xref> or core–mantle interaction <xref ref-type="bibr" rid="bib1.bibx50 bib1.bibx107" id="paren.88"><named-content content-type="pre">e.g.,</named-content></xref>.
Moreover, ancient crustal rocks may have different chemistry and hence density at lower mantle depths than young basalts <xref ref-type="bibr" rid="bib1.bibx47" id="paren.89"><named-content content-type="pre">e.g.,</named-content></xref>, which may also affect the layering sequence as seen in our models.</p>
</sec>
<sec id="Ch1.S4.SS4">
  <label>4.4</label><title>Linking recycled piles, primordial blobs, and mantle dynamics</title>
      <p id="d1e4734">The slight positive correlation between pile height and overlying primordial material (Fig. 8) differs from the previously conceptional model proposed in <xref ref-type="bibr" rid="bib1.bibx8" id="text.90"/>, in which the authors suggested that dense mantle material ideally piles up in zones of convergence atop the CMB, free from overlying viscous blobs (BEAMS).
As we find piles to comprise of older material when overlain by primordial blobs (Fig. 8d, h), we infer that primordial domains can shield piles from any incoming subducted material and aid their longevity. The presence of primordial domains in the mid-mantle may therefore constrain the shapes and spatial fixity of LLSVP piles <xref ref-type="bibr" rid="bib1.bibx103 bib1.bibx29" id="paren.91"/>.</p>
      <p id="d1e4743">Our results further contribute to the ongoing debate about whether thermochemical piles are intrinsically stable features in the deep mantle, which spatially determine mantle convective patterns <xref ref-type="bibr" rid="bib1.bibx29 bib1.bibx104" id="paren.92"/> or are instead pushed around by subduction zones <xref ref-type="bibr" rid="bib1.bibx74 bib1.bibx122" id="paren.93"/>. In our models, piles and blobs both mostly reside well away from lower-mantle downwellings, as they are pushed away from them (videos in the Supplement, <xref ref-type="bibr" rid="bib1.bibx41" id="altparen.94"/>).
Indeed, as noted in previous studies <xref ref-type="bibr" rid="bib1.bibx74 bib1.bibx122 bib1.bibx93" id="paren.95"><named-content content-type="pre">e.g.,</named-content></xref>, we observe that downgoing slabs are mainly controlling the spatial distribution of piles (as well as viscous blobs) and not the other way around.</p><?xmltex \hack{\newpage}?>
</sec>
<?pagebreak page2101?><sec id="Ch1.S4.SS5">
  <label>4.5</label><title>Early Earth shift in mantle dynamics, tectonics, and chemical sampling</title>
      <p id="d1e4770">An interesting prediction of our models involves the breakdown of ancient compositional layering (“overturn”), marking the beginning of whole-mantle convection (see Fig. 6, Supplement S3). The timing of the overturn varies between 0.5 and 2.5 <inline-formula><mml:math id="M309" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula> of model evolution, mainly depending on the intrinsic strength of the primordial layer.
This overturn triggers a shift in surface-tectonic style, as plate-tectonic behavior (<inline-formula><mml:math id="M310" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M311" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula>) robustly occurs in the models following the event. For Earth, a major change in geodynamic style is commonly proposed to mark the onset of “modern-style” plate tectonics <xref ref-type="bibr" rid="bib1.bibx10 bib1.bibx19" id="paren.96"><named-content content-type="pre">e.g.,</named-content><named-content content-type="post">and references therein</named-content></xref>, shifting from either an (episodic) stagnant lid <xref ref-type="bibr" rid="bib1.bibx84 bib1.bibx10 bib1.bibx64" id="paren.97"><named-content content-type="pre">e.g.,</named-content></xref> or a sluggish lid with mostly vertical tectonics <xref ref-type="bibr" rid="bib1.bibx92 bib1.bibx33 bib1.bibx70" id="paren.98"><named-content content-type="pre">e.g.,</named-content></xref> to a mobile-lid style with horizontal plate-like tectonics. Estimates for the timing of this event vary between studies (e.g., 2–3.2 Ga, <xref ref-type="bibr" rid="bib1.bibx62" id="altparen.99"/>, and references therein). According to our model predictions, the breakdown of ancient compositional layering may be related to such a tectonic shift in early Earth.
The related stirring of the mantle during the overturn may have drastically changed upper-mantle composition <xref ref-type="bibr" rid="bib1.bibx96" id="paren.100"><named-content content-type="pre">e.g.,</named-content></xref>, which is likely followed by the oxygenation of the atmosphere, with implications for the evolution of life <xref ref-type="bibr" rid="bib1.bibx2" id="paren.101"/>.</p>
      <p id="d1e4824">Another implication of this geodynamic shift is that deep-rooted mantle plumes can reach the upper mantle for the first time. Accordingly, the geochemical signatures of mafic rocks of this age should carry stronger lower-mantle signatures compared to older mafic rocks. Many geochemical studies indicate a rapid, widespread change in isotopic signatures in basalts around <inline-formula><mml:math id="M312" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> 3 Ga <xref ref-type="bibr" rid="bib1.bibx37" id="paren.102"><named-content content-type="pre">e.g.,</named-content><named-content content-type="post">and references therein</named-content></xref>.
For example, <inline-formula><mml:math id="M313" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">μ</mml:mi><mml:mn mathvariant="normal">182</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>W anomalies in basalts show a steady trend of mostly positive values for rocks of before <inline-formula><mml:math id="M314" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> 3 Ga but display negative values in the modern mantle. This change has previously been attributed to inner-core segregation <xref ref-type="bibr" rid="bib1.bibx91" id="paren.103"/> or the onset of deep slab subduction and recycling of crustal material and sediments <xref ref-type="bibr" rid="bib1.bibx68 bib1.bibx91" id="paren.104"><named-content content-type="pre">e.g.,</named-content></xref>. Here, we propose that it may (additionally) be related to the onset of primordial-material entrainment by mantle plumes via whole-mantle convection. The primordial material could have obtained a negative <inline-formula><mml:math id="M315" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">μ</mml:mi><mml:mn mathvariant="normal">182</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>W signal through SiO<inline-formula><mml:math id="M316" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> exsolution from the core, which has a strongly negative <inline-formula><mml:math id="M317" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">μ</mml:mi><mml:mn mathvariant="normal">182</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>W signature <xref ref-type="bibr" rid="bib1.bibx61" id="paren.105"><named-content content-type="pre">e.g.,</named-content></xref>, to the (basal) magma ocean during rapid initial cooling of the planet <xref ref-type="bibr" rid="bib1.bibx44 bib1.bibx107 bib1.bibx91" id="paren.106"><named-content content-type="pre">e.g.,</named-content></xref>.</p>
      <p id="d1e4909">It must be noted that the modeled thermal evolution of the mantle and related early convective vigor somewhat depends on our parameter choices.
Although our models do not take into account heating from radioactive decay or core cooling <xref ref-type="bibr" rid="bib1.bibx83" id="paren.107"/>, the modeled mantles cool over time with internal potential temperatures from <inline-formula><mml:math id="M318" display="inline"><mml:mn mathvariant="normal">1900</mml:mn></mml:math></inline-formula>  to <inline-formula><mml:math id="M319" display="inline"><mml:mrow><mml:mo>≈</mml:mo><mml:mn mathvariant="normal">1600</mml:mn></mml:mrow></mml:math></inline-formula>–1650 K, consistent with petrological studies on Earth's mantle temperatures over time <xref ref-type="bibr" rid="bib1.bibx47" id="paren.108"/>. A prior study found that early model dynamics differ as a different initial mantle temperature or core temperature is applied, although the ultimate thermal and chemical structure after 4.5 <inline-formula><mml:math id="M320" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">Gyr</mml:mi></mml:mrow></mml:math></inline-formula> does not depend much on these parameters <xref ref-type="bibr" rid="bib1.bibx81" id="paren.109"/>. In particular, the scale of early mantle flow and the geometry of boundary layer instabilities are different when evolving core temperatures and internal heating sources are incorporated <xref ref-type="bibr" rid="bib1.bibx81" id="paren.110"/>.
With our constant core temperature of 4000 K, early Earth's CMB heat flow is likely underestimated and present-day heat flux slightly overestimated.
The presence of internal heating from the decay of radioactive nuclides (or heat-producing elements, HPEs) increases convective vigor and decreases the length scales of mantle flow. On the other hand, it suppresses active hot instabilities and mantle plumes, which instead become diffuse and passive return flows <xref ref-type="bibr" rid="bib1.bibx73" id="paren.111"><named-content content-type="pre">e.g.,</named-content></xref>. Keep in mind that erosion of viscous blobs and the entrainment of primordial material is primarily accommodated by plumes. Nevertheless, considering uniform internal heating is likely to impede preservation, as blobs should heat up and rise into the upper mantle, where they would be efficiently processed. However, HPEs are unlikely to be uniformly distributed. In fact, they are unlikely to be incorporated into bridgmanitic material for a wide range of formation scenarios. For example, bridgmanitic magma ocean cumulates will not incorporate any significant levels of highly incompatible elements, including HPEs <xref ref-type="bibr" rid="bib1.bibx20 bib1.bibx13" id="paren.112"/>. Instead, if most HPEs are partitioned into the dense, final MO cumulates (i.e., such as the ancient FeO-rich basal layer discussed in Sect. 3.3.2), they would be “trapped” in this insulating layer.</p>
</sec>
<sec id="Ch1.S4.SS6">
  <label>4.6</label><title>Model limitations and outlook</title>
      <p id="d1e4966">As in any geodynamic study, the numerical models remain a simplified approximation of nature. For example, our model resolution only allows us to simulate relatively large heterogeneities (on scales of several kilometers or longer). In addition, we do not include any felsic material in our models, which may contribute to lower mantle heterogeneity by recycling of continental material <xref ref-type="bibr" rid="bib1.bibx52 bib1.bibx97" id="paren.113"/>. Furthermore, future investigations are needed to clarify how the heterogeneity styles operate in 3D geometry or in the presence of internal heating sources and core evolution.</p>
      <p id="d1e4972">The work presented here is primarily a numerical study that establishes various feasible regimes of mantle dynamics and heterogeneity mixing and preservation as a function of initial conditions and primordial-material properties. In the future, a thorough integration with inter-disciplinary observations on mantle heterogeneity is needed to further establish the applicability of some of our detected regimes for the Earth's (lower) mantle. For example, model results should<?pagebreak page2102?> be quantitatively compared with seismic constraints: piles are predicted to be anomalously hot and dense, which would leave a clear seismic signature <xref ref-type="bibr" rid="bib1.bibx112" id="paren.114"><named-content content-type="pre">e.g.,</named-content></xref>. On the other hand, bridgmanitic blobs in our models are usually only slightly warmer than typical ambient mantle temperatures (Fig. 8). Therefore, the related seismic anomalies may be much less evident in tomography, particularly when considering that bridgmanite is slightly faster than ferropericlase <xref ref-type="bibr" rid="bib1.bibx108" id="paren.115"/>.
Indeed, seismic tomographic images do not show obvious large-scale seismic anomalies in the mid-mantle, and future studies should aim at establishing the presence or absence of these domains in the present-day Earth, e.g., focusing on seismic anisotropy or out-of-plane reflections.</p>
</sec>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <label>5</label><title>Conclusions</title>
      <p id="d1e4993">We performed a numerical study to investigate the coexistence of different chemical heterogeneity with distinct physical properties in Earth's lower mantle. Our results demonstrate the following conclusions.
<list list-type="bullet"><list-item>
      <p id="d1e4998">Primordial and recycled heterogeneity may coexist in various styles in the mantles of Earth-like planets, depending on their rheological properties (intrinsic density and viscosity).</p></list-item><list-item>
      <p id="d1e5002">The final volume of primordial heterogeneity preserved in the mantle only very weakly depends on the initial thickness of the primordial layer in the range of values explored here (35 vol %–65 vol % of the total mantle).</p></list-item><list-item>
      <p id="d1e5006">The preservation of coherent viscous blobs in the mid-mantle is enhanced by the existence of an ancient FeO-rich basal layer underneath.</p></list-item><list-item>
      <p id="d1e5010">The coupled existence of viscous, primordial blobs in the mid-mantle with dense, recycled (and partially ancient) piles in the lowermost mantle is a robustly predicted over a wide range of parameters.</p></list-item><list-item>
      <p id="d1e5014">The presence of large viscous blobs in the mid-mantle stabilizes the underlying dense thermochemical piles, contributing to their preservation and longevity.</p></list-item></list>
Our results provide a quantitative and dynamic framework for the coupled evolution of recycled and primordial materials in a convecting mantle. For planet Earth, we suggest that the lower mantle may be in a hybrid state between marble cake and plum pudding style of chemical heterogeneity. Such a hybrid mantle structure can reconcile geochemical evidence for ancient rock preservation in the convecting mantle through the present day with seismic evidence for whole-mantle convection. Finally, the breakdown of a stratified system with double-layered convection towards a whole-mantle convective system with plate-tectonic behavior as predicted by our models may be relevant for a major geodynamic shift during the Archean, as is indicated by the geological and geochemical record.</p>
</sec>

      
      </body>
    <back><notes notes-type="codedataavailability"><title>Code and data availability</title>

      <p id="d1e5022">The numerical code is available by reasonable request to  Paul James Tackley. The data corresponding to the numerical experiments of this paper are too large to be placed online, but they can be requested from the corresponding author, as can the input files for all the models of this study.</p>
  </notes><notes notes-type="videosupplement"><title>Video supplement</title>

      <p id="d1e5028">Video Supplements are available at Zenodo under the identifier <uri>https://zenodo.org/record/4767426</uri>
<xref ref-type="bibr" rid="bib1.bibx41" id="paren.116"/>.</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d1e5037">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/se-12-2087-2021-supplement" xlink:title="pdf">https://doi.org/10.5194/se-12-2087-2021-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e5046">AJPG designed the study, conducted the experiments, interpreted the results, and prepared the manuscript. MDB contributed to the study design and interpretation of the results. PJT designed the 3D thermomechanical code and contributed to results interpretation. All authors collaborated and contributed intellectually to this paper.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e5052">The authors declare that they have no conflict of interest.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d1e5058">Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e5064">We thank reviewers Craig O'Neill and one anonymous referee for their thoughtful and constructive comments, as well as  the editors Juliane Dannberg and Susanne Buiter for handling this paper.
All numerical simulations were performed on ETH Zürich's Euler cluster. For 2D visualization of the models, we used the open-source software ParaView (<uri>http://paraview.org</uri>, last access: 10 October 2020). Several perceptually uniform scientific color maps (<xref ref-type="bibr" rid="bib1.bibx21" id="altparen.117"/>, <ext-link xlink:href="https://doi.org/10.5281/zenodo.1243862" ext-link-type="DOI">10.5281/zenodo.1243862</ext-link>) were used to prevent visual distortion of the figures. Finally, the open-source Python module StagPy (<uri>https://stagpy.readthedocs.io/en/stable/</uri>, last access: 17 July 2021) was used for post-processing of the numerical data and production of Fig. 8.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e5081">This research has been supported by the ETH Zürich Foundation (grant no. ETH-33 16-1).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <?pagebreak page2103?><p id="d1e5087">This paper was edited by Susanne Buiter and reviewed by Craig O'Neill and one anonymous referee.</p>
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<abstract-html><p>The nature of compositional heterogeneity in Earth's lower mantle remains a long-standing puzzle that can inform about the long-term thermochemical evolution and  dynamics of our planet. Here, we use global-scale 2D models of thermochemical mantle convection to investigate the coupled evolution and mixing of (intrinsically dense) recycled and (intrinsically strong) primordial heterogeneity in the mantle. We explore the effects of ancient compositional layering of the mantle, as motivated by magma ocean solidification studies, and of the physical parameters of primordial material.
Depending on these physical parameters, our models predict various regimes of mantle evolution and heterogeneity preservation over 4.5&thinsp;Gyr. Over a wide parameter range, primordial and recycled heterogeneity are predicted to co-exist with each other in the lower mantle of Earth-like planets. Primordial material usually survives as medium- to large-scale blobs (or streaks) in the mid-mantle, around 1000–2000&thinsp;km depth, and this preservation is largely independent of the initial primordial-material volume. In turn, recycled oceanic crust (ROC) persists as large piles at the base of the mantle and as small streaks everywhere else. In models with an additional dense FeO-rich layer initially present at the base of the mantle, the ancient dense material partially survives at the top of ROC piles, causing the piles to be compositionally stratified. Moreover, the addition of such an ancient FeO-rich basal layer significantly aids the preservation of the viscous domains in the mid-mantle.
Finally, we find that primordial blobs are commonly directly underlain by thick ROC piles and aid their longevity and stability.
Based on our results, we propose an integrated style of mantle heterogeneity for the Earth involving the preservation of primordial domains along with recycled piles. This style has important implications for early Earth evolution and has the potential to reconcile geophysical and geochemical discrepancies on present-day lower-mantle heterogeneity.</p></abstract-html>
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