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  <front>
    <journal-meta><journal-id journal-id-type="publisher">SE</journal-id><journal-title-group>
    <journal-title>Solid Earth</journal-title>
    <abbrev-journal-title abbrev-type="publisher">SE</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Solid Earth</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1869-9529</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/se-9-191-2018</article-id><title-group><article-title>Deeply subducted continental fragments – Part 2: Insight from petrochronology in
the central Sesia Zone (western Italian Alps)</article-title>
      </title-group><?xmltex \runningtitle{Deeply subducted continental fragments -- Part~2}?><?xmltex \runningauthor{F.~Giuntoli et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Giuntoli</surname><given-names>Francesco</given-names></name>
          <email>francesco.giuntoli@gmail.com</email>
        <ext-link>https://orcid.org/0000-0003-1999-5725</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Lanari</surname><given-names>Pierre</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-8303-0771</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Burn</surname><given-names>Marco</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Kunz</surname><given-names>Barbara Eva</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-9492-1497</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Engi</surname><given-names>Martin</given-names></name>
          
        </contrib>
        <aff id="aff1"><institution>Institute of Geological Sciences, University of Bern, Baltzerstrasse
1 + 3, 3012 Bern, Switzerland</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Francesco Giuntoli (francesco.giuntoli@gmail.com)</corresp></author-notes><pub-date><day>26</day><month>February</month><year>2018</year></pub-date>
      
      <volume>9</volume>
      <issue>1</issue>
      <fpage>191</fpage><lpage>222</lpage>
      <history>
        <date date-type="received"><day>11</day><month>August</month><year>2017</year></date>
           <date date-type="rev-request"><day>4</day><month>September</month><year>2017</year></date>
           <date date-type="rev-recd"><day>13</day><month>December</month><year>2017</year></date>
           <date date-type="accepted"><day>12</day><month>January</month><year>2018</year></date>
      </history>
      <permissions>
        
        
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://se.copernicus.org/articles/.html">This article is available from https://se.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://se.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://se.copernicus.org/articles/.pdf</self-uri>
      <abstract>
    <p id="d1e112">Subducted continental terranes commonly comprise an assembly of subunits that
reflect the different tectono-metamorphic histories they experienced in the
subduction zone. Our challenge is to unravel how, when, and in which part of
the subduction zone these subunits were juxtaposed. Petrochronology offers
powerful tools to decipher pressure–temperature–time (<inline-formula><mml:math id="M1" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M2" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M3" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>) histories of
metamorphic rocks that preserve a record of several stages of transformation.
A major issue is that the driving forces for re-equilibration at high
pressure are not well understood. For example, continental granulite terrains
subducted to mantle depths frequently show only partial and localized
eclogitization. The Sesia Zone (NW Italy) is exceptional because it comprises
several continental subunits in which eclogitic rocks predominate and
high-pressure (HP) assemblages almost completely replaced the Permian
granulite protoliths. This field-based study comprises both main complexes of
the Sesia terrane, covering some of the recently recognized tectonic subunits
involved in its assembly; hence our data constrain the HP tectonics that
formed the Sesia Zone. We used a petrochronological approach consisting of
petrographic and microstructural analysis linked with thermodynamic modelling
and U–Th–Pb age dating to reconstruct the <inline-formula><mml:math id="M4" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M5" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M6" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> trajectories of these
tectonic subunits. Our study documents when and under what conditions
re-equilibration took place. Results constrain the main stages of mineral
growth and deformation, associated with fluid influx that occurred in the
subduction channel. In the Internal Complex (IC), pulses of fluid percolated
at eclogite facies conditions between 77 and 55 Ma with the HP conditions
reaching <inline-formula><mml:math id="M7" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 GPa and 600–670 <inline-formula><mml:math id="M8" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. By contrast, the
External Complex (EC) records a lower pressure peak of <inline-formula><mml:math id="M9" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.8 GPa for 500 <inline-formula><mml:math id="M10" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C at <inline-formula><mml:math id="M11" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 63 Ma. The juxtaposition of the
two complexes occurred during exhumation, probably at <inline-formula><mml:math id="M12" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.8 GPa
and 350 <inline-formula><mml:math id="M13" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C; the timing is constrained between 46 and 38 Ma. Mean
vertical exhumation velocities are constrained between 0.9 and 5.1 mm year<inline-formula><mml:math id="M14" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>
for the IC, up to its juxtaposition with the EC. Exhumation to the surface
occurred before 32 Ma, as constrained by the overlying Biella Volcanic Suite,
at a mean vertical velocity between 1.6 and 4 mm year<inline-formula><mml:math id="M15" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. These findings
constrain the processes responsible for the assembly and exhumation of HP continental subunits, thus adding to our understanding of how
continental terranes behave during subduction.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p id="d1e245">The behaviour of continental crust subducted to high-pressure (HP)
conditions is far from fully understood (Rubatto and Hermann, 2001; Brun and Faccenna, 2008; Kylander-Clark et al.,
2008; Malusà et al., 2011; Angiboust et al., 2017). Seismic tomography beneath collisional orogens
shows that large slab parts reached mantle depths (e.g. Lippitsch et al.,
2003; Replumaz et al., 2010; Zhao et al., 2015), but the source of such
remnants is hard to assess because the rocks cannot be directly
investigated. However, orogens that contain exhumed continental HP rocks
offer opportunities to investigate some of the tectono-metamorphic
processes involved, notably those responsible for the return flow of
continental fragments back to the surface.</p>
      <p id="d1e248">In recent studies on the western Alps, the combination of tectonic and
numerical modelling studies (e.g. Yamato et al., 2008; Faccenda et
al., 2009) with the reconstruction of pressure–temperature–time (<inline-formula><mml:math id="M16" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M17" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M18" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>)
paths (e.g. Rubatto et al., 2011; Regis et al., 2014) has led to two possible endmember scenarios for the subduction of
continental domains to HP conditions. The units could have essentially
experienced tectonic slicing, followed by accretion to overlying continental
units, thus assembling complexes composed of different tectono-metamorphic
slices (e.g. Vitale Brovarone et
al., 2013; Angiboust et al., 2014; Manzotti et al., 2014; Regis et al., 2014). Alternatively, units could have been eroded or
ablated in the subduction channel, which lost coherence and experienced
substantial mixing, leading to diverse and complex <inline-formula><mml:math id="M19" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M20" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M21" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths (e.g. Tao
and O'Connell, 1992; Stöckhert and Gerya, 2005; Warren et al., 2008; Keppie
et al., 2009; Roda et al., 2012). The distinction between these two
endmember scenarios is important to understand the evolution of deeply
subducted continental domains and possibly their palaeogeographic provenance.</p>
      <p id="d1e294">Crucial questions related to continental HP units in orogens include the following: how
rapidly were they subducted and to what depth? When and how fast were they
exhumed? What <inline-formula><mml:math id="M22" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M23" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M24" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> trajectories did they experience? When and how did
fluids affect these continental fragments? To shed light on these questions,
the sequence of metamorphic stages recorded in suitable samples needs to be
analysed in detail (Engi et al., 2017). <inline-formula><mml:math id="M25" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M26" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M27" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths promise insight
into details of these fundamental tectonic processes. Petrochronological
studies in the western Alps have helped to constrain exhumation rates of
Alpine HP and ultra-HP continental domains. Calculated rates vary from a few
millimetres
(e.g. Zucali et al., 2002; Regis et al., 2014, for the internal part of the
Sesia Zone, SZ) to a few centimetres per year (e.g. Rubatto and Hermann,
2001,
for Dora Maira ultra-HP massif). In detail, some studies found that, after a
first phase of rapid exhumation up to lower crustal levels, exhumation rates
markedly decreased to a few millimetres per year (Rubatto and
Hermann, 2001; Yamato et al., 2008).</p>
      <p id="d1e340">Generally speaking, how much of the subduction history is recorded in a
sample is related to what processes triggered mineral recrystallization or
equilibration. Several studies (e.g. Etheridge et al., 1983; Rubie, 1986; Austrheim, 1987; Erambert and Austrheim,
1993; Oliver, 1996; Pennacchioni, 1996; Engi et al., 2018) proposed that fluid influx triggers
deformation and mineral reactions in deeply subducted high-grade (granulite
and amphibolite facies) domains. It is of interest to know when this
happened in the <inline-formula><mml:math id="M28" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M29" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M30" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> evolution, notably whether it occurred early, during
subduction, or only late, upon exhumation (e.g. Konrad-Schmolke
et al., 2011).</p>
      <p id="d1e365">We present a field-based study emphasizing <inline-formula><mml:math id="M31" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M32" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M33" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> data and discuss their
implications on such first-order questions. Datasets from a well-defined
multidimensional analysis, i.e. pressure–temperature–time–deformation–space,
are essential as a reference frame for numerical modelling studies. Our
petrochronological approach highlights the complex and heterogeneous
tectono-metamorphic evolution in a polydeformed continental terrane. A key
requirement in this approach is to establish reliable links between age data
(<inline-formula><mml:math id="M34" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>) and the <inline-formula><mml:math id="M35" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M36" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions of mineral formation (e.g. Buick
and Holland, 1989; Schenk, 1989; Scott and St-Onge, 1995; Liati and Gebauer, 1999; Rubatto
and Hermann, 2001; Foster et al., 2004; Janots et al., 2009; Rubatto et al., 2011; Gasser et al.,
2012; Donaldson et al., 2013; Mottram
et al., 2014; Regis et al., 2014). In this study, mutual inclusion relationships of the main
mineralogical phases in the datable accessory minerals, along with
microstructural analyses, were used to bracket mineral age data to <inline-formula><mml:math id="M37" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M38" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions. The
study area is the central SZ, located in the western Alps (Aosta Valley, Italy). <inline-formula><mml:math id="M39" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M40" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M41" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> data are reconstructed for the eclogite facies Internal Complex
(IC)
and, for the first time, for the epidote blueschist facies External Complex (EC). These data
allow us to constrain the juxtaposition of the two complexes, which occurred
under HP greenschist facies conditions, and to determine exhumation rates
for the IC and for the assembly of the SZ.</p><?xmltex \hack{\vspace{-3mm}}?>
</sec>
<sec id="Ch1.S2">
  <title>Geological setting</title>
      <p id="d1e453">The Alps are an orogen that has developed since the Cretaceous due to the
subduction of the European Plate below the Adriatic Plate, with subsequent
continental collision (e.g. Dewey et al., 1989; Rosenbaum et al.,
2002; Beltrando et al., 2010; Handy et al., 2010; Schmid et al., 2017). The
SZ is located in the western Alps (Fig. 1a) and regarded as a
rifted portion of the Adriatic Margin that experienced subduction to HP
conditions (e.g. Dal Piaz, 1999). At present, it is bounded by two
tectonic lineaments: the Insubric Line to the SE and the Gressoney Shear
Zone to the NW. The Insubric Line is a major fault system of
Oligocene–Neogene age that separates the SZ from the southern Alpine domain,
which represents the Adriatic Margin and shows but a weak Alpine imprint at
sub-greenschist facies. An important complex in the southern Alps is the
Ivrea Zone, consisting of amphibolite to granulite facies metasediments,
mantle peridotites, and mafic intrusives. It is proposed to represent a cross
section through the lower pre-Alpine crust (e.g. Bertolani, 1954, 1959;
Rivalenti et al., 1975; Zingg, 1983; Quick et al., 2003). Analogies
between the pre-Alpine metamorphism of the IC (Giuntoli
and Engi, 2016) of the SZ and the Ivrea Zone have been repeatedly emphasized
(e.g. Dal Piaz et al., 1972; Compagnoni et al., 1977). The
Gressoney Shear Zone is a greenschist shear zone (e.g.
Wheeler and Butler, 1993; Babist et al., 2006) that separates
the SZ from units derived from the Piemonte–Liguria Ocean that experienced
blueschist-to-eclogite facies metamorphism during the Alpine orogeny (e.g.
Bucher et al., 2005; Negro et al., 2013).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><caption><p id="d1e458"><bold>(a)</bold> Simplified tectonic map of the western Alps (modified
from Manzotti et al., 2014). <bold>(b)</bold> Tectonic sketch of the study area
(modified from Giuntoli and Engi, 2016) with sample locations and <inline-formula><mml:math id="M42" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M43" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M44" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>
data (this study). <bold>(c)</bold> Cross section through the study area (location
shown
in <bold>a</bold>) with projection of the studied samples. Foliation
traces: violet indicates the eclogite facies foliation (S2) of the IC, dark
green indicates the composite epidote blueschist–HP greenschist facies
foliation (S2 <inline-formula><mml:math id="M45" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> S3) of the EC, and dark green indicates the greenschist
facies mylonitic foliation (S4) at the IC–EC contact. BSZ: Barmet Shear
Zone;
PLO: Piemonte–Liguria oceanic unit (modified from Giuntoli and Engi,
2016).</p></caption>
        <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f01.jpg"/>

      </fig>

      <p id="d1e507">Recently, the central Sesia Zone has been subdivided into an IC and an EC (Giuntoli and Engi, 2016; Fig. 1b, c).
The IC corresponds, as a whole, to the Eclogitic Micaschist
complex
of Williams and Compagnoni (1983) and Passchier et al. (1981). In detail, however, the IC comprises several eclogitic sheets with a
thickness of a few kilometres, each of them characterized by an alternance of
bands and elongate bodies of mica schist, eclogite, ortho- and paragneiss,
and leucogneiss. The main foliation of this complex is of eclogite facies.
Several deformation phases locally overprint this foliation at retrograde
blueschist and greenschist facies conditions (details in Giuntoli
and Engi, 2016).</p>
      <p id="d1e510">The EC corresponds to the Gneiss Minuti and the 2DK complexes of previous
authors. It comprises kilometre-thick tectonic sheets of leuco- to mesocratic
orthogneiss with minor paragneiss, calc–mica schist, impure quartzite, and
marble separated by lenses preserving Permian high-temperature (HT)
metamorphic relics (2DK; Carraro et al., 1970; Dal Piaz et al., 1971; Giuntoli and Engi, 2016). The main composite foliation reflects HP greenschist, at
most epidote blueschist facies; these are the highest Alpine metamorphic
conditions recorded by this complex. The HP foliation is affected by
subsequent greenschist facies deformation. Juxtaposition of the two
complexes involved a greenschist facies shear zone (Barmet Shear Zone in
Giuntoli and Engi, 2016); the subunits in each complex are thin sheets
that range in thickness from 0.5 to 3 km.</p>
      <p id="d1e514">Based on <inline-formula><mml:math id="M46" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M47" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M48" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths determined by petrochronological techniques,
Rubatto et al. (2011) and Regis et al. (2014)
recognized two tectono-metamorphic subunits in the IC: a more internal
subunit, called Druer slice, experienced eclogite facies conditions with a
pressure of 1.9–2 GPa and temperatures of <inline-formula><mml:math id="M49" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 550 <inline-formula><mml:math id="M50" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
at around 85 Ma, then followed by exhumation. A more external subunit,
called Fondo slice, experienced a first stage at eclogite facies, with
pressures of 1.7–1.8 GPa and temperatures between 520 and 550 <inline-formula><mml:math id="M51" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
at around 75 Ma, then followed by an intermediate lower-pressure stage
(<inline-formula><mml:math id="M52" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> &lt; 1.6 GPa and <inline-formula><mml:math id="M53" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> &lt; 520 <inline-formula><mml:math id="M54" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) at around 68 Ma, and a
second HP stage (<inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:mi>P</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 1.4–2 GPa and <inline-formula><mml:math id="M56" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 550 <inline-formula><mml:math id="M57" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) at around 65 Ma, followed by retrograde decompression. For
the EC in the central Sesia Zone, no <inline-formula><mml:math id="M58" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M59" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M60" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> data are available so far.</p>
      <p id="d1e635">A number of studies have produced additional age data for the Sesia Zone,
using various methods, notably for the U–Th–Pb, Rb–Sr, and Ar–Ar systems;
results are summarized in Table 1 of Compagnoni et al. (2014). These age data span from 85 to 62 Ma for the eclogite facies
metamorphism in the IC, but apart from those detailed above, none of the
datasets report detailed links to petrogenetic conditions. A few age data are
available for the EC, ranging from 46 to 38 Ma, and these are generally
linked to the greenschist facies imprint (Compagnoni et al.,
2014, and references therein).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><caption><p id="d1e640">Thin-section photos illustrating the metamorphic evolution
of the studied samples. Endmember mineral abbreviations used throughout
text and figures are from Whitney and Evans (2010). <bold>(a)</bold> Eclogite
foliation (<inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">ecl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) marked by subparallel phengite,
omphacite, and glaucophane (plane-polarized light). <bold>(b)</bold> Eclogite foliation
marked by the preferred orientation of chloritoid and phengite. Note the
chloritoid crystal (left) is oriented perpendicular to
<inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">ecl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and overgrows it (plane-polarized light). <bold>(c)</bold> Garnet crystal with a bright
pre-Alpine core and darker Alpine rims visible due to fine rutile inclusions
(plane-polarized light). <bold>(d)</bold> Glaucophane crystal with a core displaying pale
blue absorption colour, rimmed by darker blue crossite that marks a
retrograde blueschist stage (plane-polarized light). <bold>(e)</bold> Colourless to pale
green amphibole growing at the expense of omphacite during a retrograde
greenschist stage (plane-polarized light). <bold>(f)</bold> Open folds with chlorite
crystallizing in the hinge zone, marking a retrograde greenschist stage
(plane-polarized light). <bold>(g)</bold> Garnet porphyroclast wrapped by the main
greenschist foliation (<inline-formula><mml:math id="M63" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi mathvariant="normal">gr</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>; note the inner foliation
inside the garnet (<inline-formula><mml:math id="M64" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">int</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>; crossed-polarized light).
<bold>(h)</bold> Brown magmatic allanite surrounded by epidote crystals with
smaller grain size
(plane-polarized light).</p></caption>
        <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f02.jpg"/>

      </fig>

<?xmltex \hack{\vspace{-3mm}}?>
</sec>
<sec id="Ch1.S3">
  <title>Sampling strategy and petrochronological approach</title>
      <p id="d1e730">To document the polyphase history of the Sesia Zone, we reconstructed
detailed <inline-formula><mml:math id="M65" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M66" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M67" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths for five samples taken in the IC and two samples in the
EC. Of over 100 samples checked, a very small percentage fulfilled the
requirements for such a study. In the EC, in particular, suitable material
to quantify <inline-formula><mml:math id="M68" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M69" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M70" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> conditions using the present methods turned out to be very rare.
This is mostly due to the fact that orthogneiss, the dominant rock type in
the EC, is lacking in minerals suitable to obtain the Alpine <inline-formula><mml:math id="M71" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M72" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M73" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> path, as
discussed by Giuntoli and Engi (2016). Nevertheless, the samples
analysed provide constraints to derive a <inline-formula><mml:math id="M74" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M75" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M76" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> path for the EC as well,
allowing us to determine when and at what conditions the two complexes were
juxtaposed.</p>
      <p id="d1e819">All samples were taken in key areas of the mapped structures and were
collected oriented, in order to keep the link between the meso- and
microstructural evidence. Samples were carefully studied using optical and
(where needed) scanning electron microscopy (SEM) to reconstruct their
microstructural and metamorphic evolution. Once a relative chronology was
established, selected growth zones of mineral phases were analysed with an
electron probe microanalyser (EPMA) as a basis to perform thermodynamic
modelling. <inline-formula><mml:math id="M77" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M78" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> data were linked to fabric elements, using textural criteria.
Geochronology was performed with laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), targeting specific growth zones of
accessory phases that were separated after noting their microstructural and
geochemical context. It turned out to be critical to analyse each growth
zone separately to link the age (<inline-formula><mml:math id="M79" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>) to a specific metamorphic stage (<inline-formula><mml:math id="M80" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M81" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>).
Observations and <inline-formula><mml:math id="M82" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M83" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M84" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> data derived from each sample are then compared and
correlated within the sample series and then related to observations made in
the field data and in microscopy. This detailed petrochronological approach
(e.g. Engi et al., 2017) is particularly effective when applied to a
study area that has been mapped and structurally characterized in detail, as
in the present case.</p>

<?xmltex \floatpos{p}?><table-wrap id="Ch1.T1" orientation="landscape"><caption><p id="d1e882">Representative analyses of garnet of the samples.</p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.63}[.63]?><oasis:tgroup cols="24">
     <oasis:colspec colnum="1" colname="col1" align="left" colsep="1"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right" colsep="1"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right" colsep="1"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="right" colsep="1"/>
     <oasis:colspec colnum="12" colname="col12" align="right"/>
     <oasis:colspec colnum="13" colname="col13" align="right"/>
     <oasis:colspec colnum="14" colname="col14" align="right"/>
     <oasis:colspec colnum="15" colname="col15" align="right"/>
     <oasis:colspec colnum="16" colname="col16" align="right" colsep="1"/>
     <oasis:colspec colnum="17" colname="col17" align="right"/>
     <oasis:colspec colnum="18" colname="col18" align="right"/>
     <oasis:colspec colnum="19" colname="col19" align="right"/>
     <oasis:colspec colnum="20" colname="col20" align="right" colsep="1"/>
     <oasis:colspec colnum="21" colname="col21" align="right"/>
     <oasis:colspec colnum="22" colname="col22" align="right"/>
     <oasis:colspec colnum="23" colname="col23" align="right"/>
     <oasis:colspec colnum="24" colname="col24" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Sample</oasis:entry>  
         <oasis:entry namest="col2" nameend="col4" align="center" colsep="1">IC – FG1324 </oasis:entry>  
         <oasis:entry namest="col5" nameend="col8" align="center" colsep="1">IC – FG1315 </oasis:entry>  
         <oasis:entry namest="col9" nameend="col11" align="center" colsep="1">IC – FG12157 </oasis:entry>  
         <oasis:entry namest="col12" nameend="col16" align="center" colsep="1">IC – FG1347 </oasis:entry>  
         <oasis:entry namest="col17" nameend="col20" align="center" colsep="1">IC – FG1249 </oasis:entry>  
         <oasis:entry namest="col21" nameend="col24" align="center">EC – FG1420 </oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Grt</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">Core</oasis:entry>  
         <oasis:entry colname="col6">Rim1</oasis:entry>  
         <oasis:entry colname="col7">Rim2</oasis:entry>  
         <oasis:entry colname="col8">Rim3</oasis:entry>  
         <oasis:entry colname="col9">Core</oasis:entry>  
         <oasis:entry colname="col10">Rim1</oasis:entry>  
         <oasis:entry colname="col11">Rim2</oasis:entry>  
         <oasis:entry colname="col12">Core</oasis:entry>  
         <oasis:entry colname="col13">Rim1</oasis:entry>  
         <oasis:entry colname="col14">Rim2</oasis:entry>  
         <oasis:entry colname="col15">Rim3</oasis:entry>  
         <oasis:entry colname="col16">Rim4</oasis:entry>  
         <oasis:entry colname="col17">Core</oasis:entry>  
         <oasis:entry colname="col18">Rim1</oasis:entry>  
         <oasis:entry colname="col19">Rim2</oasis:entry>  
         <oasis:entry colname="col20">Rim3</oasis:entry>  
         <oasis:entry colname="col21">Core</oasis:entry>  
         <oasis:entry colname="col22">Rim1</oasis:entry>  
         <oasis:entry colname="col23">Rim2</oasis:entry>  
         <oasis:entry colname="col24">Rim3</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry namest="col2" nameend="col4" align="center" colsep="1">Spot analyses (wt %) </oasis:entry>  
         <oasis:entry namest="col5" nameend="col8" align="center">Average composition (wt %) </oasis:entry>  
         <oasis:entry namest="col9" nameend="col11" align="center">Average composition (wt %) </oasis:entry>  
         <oasis:entry namest="col12" nameend="col16" align="center">Average composition (wt %) </oasis:entry>  
         <oasis:entry namest="col17" nameend="col20" align="center">Average composition (wt %) </oasis:entry>  
         <oasis:entry namest="col21" nameend="col24" align="center">Average composition (wt %) </oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">SiO<inline-formula><mml:math id="M85" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">37.75</oasis:entry>  
         <oasis:entry colname="col3">37.93</oasis:entry>  
         <oasis:entry colname="col4">37.74</oasis:entry>  
         <oasis:entry colname="col5">37.70</oasis:entry>  
         <oasis:entry colname="col6">37.96</oasis:entry>  
         <oasis:entry colname="col7">37.81</oasis:entry>  
         <oasis:entry colname="col8">37.44</oasis:entry>  
         <oasis:entry colname="col9">38.17</oasis:entry>  
         <oasis:entry colname="col10">38.43</oasis:entry>  
         <oasis:entry colname="col11">38.74</oasis:entry>  
         <oasis:entry colname="col12">37.75</oasis:entry>  
         <oasis:entry colname="col13">37.88</oasis:entry>  
         <oasis:entry colname="col14">38.18</oasis:entry>  
         <oasis:entry colname="col15">37.75</oasis:entry>  
         <oasis:entry colname="col16">37.33</oasis:entry>  
         <oasis:entry colname="col17">36.91</oasis:entry>  
         <oasis:entry colname="col18">36.62</oasis:entry>  
         <oasis:entry colname="col19">37.80</oasis:entry>  
         <oasis:entry colname="col20">37.98</oasis:entry>  
         <oasis:entry colname="col21">38.29</oasis:entry>  
         <oasis:entry colname="col22">37.57</oasis:entry>  
         <oasis:entry colname="col23">37.77</oasis:entry>  
         <oasis:entry colname="col24">37.61</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">TiO<inline-formula><mml:math id="M86" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">0</oasis:entry>  
         <oasis:entry colname="col3">0.01</oasis:entry>  
         <oasis:entry colname="col4">0.04</oasis:entry>  
         <oasis:entry colname="col5">0.01</oasis:entry>  
         <oasis:entry colname="col6">0.01</oasis:entry>  
         <oasis:entry colname="col7">0.01</oasis:entry>  
         <oasis:entry colname="col8">0.01</oasis:entry>  
         <oasis:entry colname="col9">0.07</oasis:entry>  
         <oasis:entry colname="col10">0.07</oasis:entry>  
         <oasis:entry colname="col11">0.17</oasis:entry>  
         <oasis:entry colname="col12">0.02</oasis:entry>  
         <oasis:entry colname="col13">0.02</oasis:entry>  
         <oasis:entry colname="col14">0.02</oasis:entry>  
         <oasis:entry colname="col15">0.03</oasis:entry>  
         <oasis:entry colname="col16">0.03</oasis:entry>  
         <oasis:entry colname="col17">0.05</oasis:entry>  
         <oasis:entry colname="col18">0.16</oasis:entry>  
         <oasis:entry colname="col19">0.27</oasis:entry>  
         <oasis:entry colname="col20">0.04</oasis:entry>  
         <oasis:entry colname="col21">0.1</oasis:entry>  
         <oasis:entry colname="col22">0.1</oasis:entry>  
         <oasis:entry colname="col23">0.1</oasis:entry>  
         <oasis:entry colname="col24">0.09</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al<inline-formula><mml:math id="M87" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O<inline-formula><mml:math id="M88" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">21.59</oasis:entry>  
         <oasis:entry colname="col3">21.62</oasis:entry>  
         <oasis:entry colname="col4">21.53</oasis:entry>  
         <oasis:entry colname="col5">21.27</oasis:entry>  
         <oasis:entry colname="col6">21.44</oasis:entry>  
         <oasis:entry colname="col7">21.46</oasis:entry>  
         <oasis:entry colname="col8">21.32</oasis:entry>  
         <oasis:entry colname="col9">21.07</oasis:entry>  
         <oasis:entry colname="col10">21.20</oasis:entry>  
         <oasis:entry colname="col11">21.24</oasis:entry>  
         <oasis:entry colname="col12">21.25</oasis:entry>  
         <oasis:entry colname="col13">21.28</oasis:entry>  
         <oasis:entry colname="col14">21.09</oasis:entry>  
         <oasis:entry colname="col15">21.21</oasis:entry>  
         <oasis:entry colname="col16">21.33</oasis:entry>  
         <oasis:entry colname="col17">20.83</oasis:entry>  
         <oasis:entry colname="col18">21.36</oasis:entry>  
         <oasis:entry colname="col19">21.18</oasis:entry>  
         <oasis:entry colname="col20">21.77</oasis:entry>  
         <oasis:entry colname="col21">21.04</oasis:entry>  
         <oasis:entry colname="col22">21.3</oasis:entry>  
         <oasis:entry colname="col23">21.11</oasis:entry>  
         <oasis:entry colname="col24">21.22</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FeO</oasis:entry>  
         <oasis:entry colname="col2">31.16</oasis:entry>  
         <oasis:entry colname="col3">31.12</oasis:entry>  
         <oasis:entry colname="col4">31.77</oasis:entry>  
         <oasis:entry colname="col5">31.46</oasis:entry>  
         <oasis:entry colname="col6">27.94</oasis:entry>  
         <oasis:entry colname="col7">30.03</oasis:entry>  
         <oasis:entry colname="col8">32.07</oasis:entry>  
         <oasis:entry colname="col9">31.23</oasis:entry>  
         <oasis:entry colname="col10">29.05</oasis:entry>  
         <oasis:entry colname="col11">26.83</oasis:entry>  
         <oasis:entry colname="col12">31.30</oasis:entry>  
         <oasis:entry colname="col13">30.19</oasis:entry>  
         <oasis:entry colname="col14">30.82</oasis:entry>  
         <oasis:entry colname="col15">31.96</oasis:entry>  
         <oasis:entry colname="col16">32.07</oasis:entry>  
         <oasis:entry colname="col17">33.06</oasis:entry>  
         <oasis:entry colname="col18">34.23</oasis:entry>  
         <oasis:entry colname="col19">28.79</oasis:entry>  
         <oasis:entry colname="col20">27.12</oasis:entry>  
         <oasis:entry colname="col21">23.98</oasis:entry>  
         <oasis:entry colname="col22">25.57</oasis:entry>  
         <oasis:entry colname="col23">27.04</oasis:entry>  
         <oasis:entry colname="col24">28.47</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MnO</oasis:entry>  
         <oasis:entry colname="col2">0.65</oasis:entry>  
         <oasis:entry colname="col3">0.63</oasis:entry>  
         <oasis:entry colname="col4">0.60</oasis:entry>  
         <oasis:entry colname="col5">0.61</oasis:entry>  
         <oasis:entry colname="col6">0.41</oasis:entry>  
         <oasis:entry colname="col7">0.42</oasis:entry>  
         <oasis:entry colname="col8">0.31</oasis:entry>  
         <oasis:entry colname="col9">1.00</oasis:entry>  
         <oasis:entry colname="col10">0.57</oasis:entry>  
         <oasis:entry colname="col11">0.56</oasis:entry>  
         <oasis:entry colname="col12">0.92</oasis:entry>  
         <oasis:entry colname="col13">0.37</oasis:entry>  
         <oasis:entry colname="col14">0.39</oasis:entry>  
         <oasis:entry colname="col15">0.35</oasis:entry>  
         <oasis:entry colname="col16">0.32</oasis:entry>  
         <oasis:entry colname="col17">2.31</oasis:entry>  
         <oasis:entry colname="col18">0.37</oasis:entry>  
         <oasis:entry colname="col19">0.66</oasis:entry>  
         <oasis:entry colname="col20">0.56</oasis:entry>  
         <oasis:entry colname="col21">3.52</oasis:entry>  
         <oasis:entry colname="col22">1.93</oasis:entry>  
         <oasis:entry colname="col23">0.76</oasis:entry>  
         <oasis:entry colname="col24">0.37</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MgO</oasis:entry>  
         <oasis:entry colname="col2">4.5</oasis:entry>  
         <oasis:entry colname="col3">4.73</oasis:entry>  
         <oasis:entry colname="col4">4.35</oasis:entry>  
         <oasis:entry colname="col5">7.19</oasis:entry>  
         <oasis:entry colname="col6">5.33</oasis:entry>  
         <oasis:entry colname="col7">6.18</oasis:entry>  
         <oasis:entry colname="col8">6.30</oasis:entry>  
         <oasis:entry colname="col9">6.41</oasis:entry>  
         <oasis:entry colname="col10">5.08</oasis:entry>  
         <oasis:entry colname="col11">4.22</oasis:entry>  
         <oasis:entry colname="col12">7.05</oasis:entry>  
         <oasis:entry colname="col13">5.76</oasis:entry>  
         <oasis:entry colname="col14">6.60</oasis:entry>  
         <oasis:entry colname="col15">6.62</oasis:entry>  
         <oasis:entry colname="col16">7.30</oasis:entry>  
         <oasis:entry colname="col17">4.65</oasis:entry>  
         <oasis:entry colname="col18">3.86</oasis:entry>  
         <oasis:entry colname="col19">5.18</oasis:entry>  
         <oasis:entry colname="col20">4.86</oasis:entry>  
         <oasis:entry colname="col21">0.58</oasis:entry>  
         <oasis:entry colname="col22">0.63</oasis:entry>  
         <oasis:entry colname="col23">0.73</oasis:entry>  
         <oasis:entry colname="col24">0.94</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">CaO</oasis:entry>  
         <oasis:entry colname="col2">4.1</oasis:entry>  
         <oasis:entry colname="col3">3.94</oasis:entry>  
         <oasis:entry colname="col4">3.87</oasis:entry>  
         <oasis:entry colname="col5">1.31</oasis:entry>  
         <oasis:entry colname="col6">6.72</oasis:entry>  
         <oasis:entry colname="col7">4.17</oasis:entry>  
         <oasis:entry colname="col8">2.08</oasis:entry>  
         <oasis:entry colname="col9">1.38</oasis:entry>  
         <oasis:entry colname="col10">5.59</oasis:entry>  
         <oasis:entry colname="col11">8.39</oasis:entry>  
         <oasis:entry colname="col12">1.14</oasis:entry>  
         <oasis:entry colname="col13">3.96</oasis:entry>  
         <oasis:entry colname="col14">2.13</oasis:entry>  
         <oasis:entry colname="col15">1.49</oasis:entry>  
         <oasis:entry colname="col16">0.96</oasis:entry>  
         <oasis:entry colname="col17">1.77</oasis:entry>  
         <oasis:entry colname="col18">3.27</oasis:entry>  
         <oasis:entry colname="col19">6.35</oasis:entry>  
         <oasis:entry colname="col20">8.38</oasis:entry>  
         <oasis:entry colname="col21">12.45</oasis:entry>  
         <oasis:entry colname="col22">12.83</oasis:entry>  
         <oasis:entry colname="col23">12.47</oasis:entry>  
         <oasis:entry colname="col24">11.36</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Cr<inline-formula><mml:math id="M89" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O<inline-formula><mml:math id="M90" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">0</oasis:entry>  
         <oasis:entry colname="col3">0.00</oasis:entry>  
         <oasis:entry colname="col4">0.00</oasis:entry>  
         <oasis:entry colname="col5">0.00</oasis:entry>  
         <oasis:entry colname="col6">0.00</oasis:entry>  
         <oasis:entry colname="col7">0.00</oasis:entry>  
         <oasis:entry colname="col8">0.00</oasis:entry>  
         <oasis:entry colname="col9">0.04</oasis:entry>  
         <oasis:entry colname="col10">0.04</oasis:entry>  
         <oasis:entry colname="col11">0.04</oasis:entry>  
         <oasis:entry colname="col12">0.00</oasis:entry>  
         <oasis:entry colname="col13">0.00</oasis:entry>  
         <oasis:entry colname="col14">0.00</oasis:entry>  
         <oasis:entry colname="col15">0.00</oasis:entry>  
         <oasis:entry colname="col16">0.00</oasis:entry>  
         <oasis:entry colname="col17">0.03</oasis:entry>  
         <oasis:entry colname="col18">0.04</oasis:entry>  
         <oasis:entry colname="col19">0.03</oasis:entry>  
         <oasis:entry colname="col20">0.03</oasis:entry>  
         <oasis:entry colname="col21">0</oasis:entry>  
         <oasis:entry colname="col22">0</oasis:entry>  
         <oasis:entry colname="col23">0</oasis:entry>  
         <oasis:entry colname="col24">0</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">Total</oasis:entry>  
         <oasis:entry colname="col2">99.75</oasis:entry>  
         <oasis:entry colname="col3">99.97</oasis:entry>  
         <oasis:entry colname="col4">99.90</oasis:entry>  
         <oasis:entry colname="col5">99.56</oasis:entry>  
         <oasis:entry colname="col6">99.81</oasis:entry>  
         <oasis:entry colname="col7">100.08</oasis:entry>  
         <oasis:entry colname="col8">99.52</oasis:entry>  
         <oasis:entry colname="col9">99.37</oasis:entry>  
         <oasis:entry colname="col10">100.03</oasis:entry>  
         <oasis:entry colname="col11">100.18</oasis:entry>  
         <oasis:entry colname="col12">99.41</oasis:entry>  
         <oasis:entry colname="col13">99.47</oasis:entry>  
         <oasis:entry colname="col14">99.24</oasis:entry>  
         <oasis:entry colname="col15">99.41</oasis:entry>  
         <oasis:entry colname="col16">99.33</oasis:entry>  
         <oasis:entry colname="col17">99.62</oasis:entry>  
         <oasis:entry colname="col18">99.90</oasis:entry>  
         <oasis:entry colname="col19">100.27</oasis:entry>  
         <oasis:entry colname="col20">100.73</oasis:entry>  
         <oasis:entry colname="col21">99.95</oasis:entry>  
         <oasis:entry colname="col22">99.93</oasis:entry>  
         <oasis:entry colname="col23">99.98</oasis:entry>  
         <oasis:entry colname="col24">100.06</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry namest="col1" nameend="col20" colsep="0">Formulae based on 12 oxygens </oasis:entry>  
         <oasis:entry colname="col21"/>  
         <oasis:entry colname="col22"/>  
         <oasis:entry colname="col23"/>  
         <oasis:entry colname="col24"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Si</oasis:entry>  
         <oasis:entry colname="col2">2.99</oasis:entry>  
         <oasis:entry colname="col3">3.00</oasis:entry>  
         <oasis:entry colname="col4">2.99</oasis:entry>  
         <oasis:entry colname="col5">2.97</oasis:entry>  
         <oasis:entry colname="col6">2.97</oasis:entry>  
         <oasis:entry colname="col7">2.96</oasis:entry>  
         <oasis:entry colname="col8">2.96</oasis:entry>  
         <oasis:entry colname="col9">3.02</oasis:entry>  
         <oasis:entry colname="col10">3.02</oasis:entry>  
         <oasis:entry colname="col11">3.03</oasis:entry>  
         <oasis:entry colname="col12">2.98</oasis:entry>  
         <oasis:entry colname="col13">2.99</oasis:entry>  
         <oasis:entry colname="col14">3.02</oasis:entry>  
         <oasis:entry colname="col15">2.98</oasis:entry>  
         <oasis:entry colname="col16">2.94</oasis:entry>  
         <oasis:entry colname="col17">2.95</oasis:entry>  
         <oasis:entry colname="col18">2.93</oasis:entry>  
         <oasis:entry colname="col19">2.96</oasis:entry>  
         <oasis:entry colname="col20">2.95</oasis:entry>  
         <oasis:entry colname="col21">3.05</oasis:entry>  
         <oasis:entry colname="col22">2.99</oasis:entry>  
         <oasis:entry colname="col23">3.01</oasis:entry>  
         <oasis:entry colname="col24">3.00</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Ti</oasis:entry>  
         <oasis:entry colname="col2">0</oasis:entry>  
         <oasis:entry colname="col3">0.00</oasis:entry>  
         <oasis:entry colname="col4">0.00</oasis:entry>  
         <oasis:entry colname="col5">0.00</oasis:entry>  
         <oasis:entry colname="col6">0.00</oasis:entry>  
         <oasis:entry colname="col7">0.00</oasis:entry>  
         <oasis:entry colname="col8">0.00</oasis:entry>  
         <oasis:entry colname="col9">0.00</oasis:entry>  
         <oasis:entry colname="col10">0.00</oasis:entry>  
         <oasis:entry colname="col11">0.01</oasis:entry>  
         <oasis:entry colname="col12">0.00</oasis:entry>  
         <oasis:entry colname="col13">0.00</oasis:entry>  
         <oasis:entry colname="col14">0.00</oasis:entry>  
         <oasis:entry colname="col15">0.00</oasis:entry>  
         <oasis:entry colname="col16">0.00</oasis:entry>  
         <oasis:entry colname="col17">0.00</oasis:entry>  
         <oasis:entry colname="col18">0.01</oasis:entry>  
         <oasis:entry colname="col19">0.02</oasis:entry>  
         <oasis:entry colname="col20">0.00</oasis:entry>  
         <oasis:entry colname="col21">0.01</oasis:entry>  
         <oasis:entry colname="col22">0.01</oasis:entry>  
         <oasis:entry colname="col23">0.01</oasis:entry>  
         <oasis:entry colname="col24">0.01</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al</oasis:entry>  
         <oasis:entry colname="col2">2.02</oasis:entry>  
         <oasis:entry colname="col3">2.01</oasis:entry>  
         <oasis:entry colname="col4">2.01</oasis:entry>  
         <oasis:entry colname="col5">1.97</oasis:entry>  
         <oasis:entry colname="col6">1.98</oasis:entry>  
         <oasis:entry colname="col7">1.98</oasis:entry>  
         <oasis:entry colname="col8">1.99</oasis:entry>  
         <oasis:entry colname="col9">1.97</oasis:entry>  
         <oasis:entry colname="col10">1.96</oasis:entry>  
         <oasis:entry colname="col11">1.96</oasis:entry>  
         <oasis:entry colname="col12">1.97</oasis:entry>  
         <oasis:entry colname="col13">1.98</oasis:entry>  
         <oasis:entry colname="col14">1.96</oasis:entry>  
         <oasis:entry colname="col15">1.98</oasis:entry>  
         <oasis:entry colname="col16">1.98</oasis:entry>  
         <oasis:entry colname="col17">1.96</oasis:entry>  
         <oasis:entry colname="col18">2.01</oasis:entry>  
         <oasis:entry colname="col19">1.96</oasis:entry>  
         <oasis:entry colname="col20">1.99</oasis:entry>  
         <oasis:entry colname="col21">1.98</oasis:entry>  
         <oasis:entry colname="col22">2.00</oasis:entry>  
         <oasis:entry colname="col23">1.98</oasis:entry>  
         <oasis:entry colname="col24">1.99</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Fe</oasis:entry>  
         <oasis:entry colname="col2">2.07</oasis:entry>  
         <oasis:entry colname="col3">2.06</oasis:entry>  
         <oasis:entry colname="col4">2.12</oasis:entry>  
         <oasis:entry colname="col5">2.07</oasis:entry>  
         <oasis:entry colname="col6">1.83</oasis:entry>  
         <oasis:entry colname="col7">1.96</oasis:entry>  
         <oasis:entry colname="col8">2.12</oasis:entry>  
         <oasis:entry colname="col9">2.07</oasis:entry>  
         <oasis:entry colname="col10">1.91</oasis:entry>  
         <oasis:entry colname="col11">1.76</oasis:entry>  
         <oasis:entry colname="col12">2.06</oasis:entry>  
         <oasis:entry colname="col13">1.99</oasis:entry>  
         <oasis:entry colname="col14">2.04</oasis:entry>  
         <oasis:entry colname="col15">2.11</oasis:entry>  
         <oasis:entry colname="col16">2.11</oasis:entry>  
         <oasis:entry colname="col17">2.21</oasis:entry>  
         <oasis:entry colname="col18">2.29</oasis:entry>  
         <oasis:entry colname="col19">1.89</oasis:entry>  
         <oasis:entry colname="col20">1.76</oasis:entry>  
         <oasis:entry colname="col21">1.60</oasis:entry>  
         <oasis:entry colname="col22">1.70</oasis:entry>  
         <oasis:entry colname="col23">1.80</oasis:entry>  
         <oasis:entry colname="col24">1.90</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Mn</oasis:entry>  
         <oasis:entry colname="col2">0.04</oasis:entry>  
         <oasis:entry colname="col3">0.04</oasis:entry>  
         <oasis:entry colname="col4">0.05</oasis:entry>  
         <oasis:entry colname="col5">0.04</oasis:entry>  
         <oasis:entry colname="col6">0.03</oasis:entry>  
         <oasis:entry colname="col7">0.03</oasis:entry>  
         <oasis:entry colname="col8">0.02</oasis:entry>  
         <oasis:entry colname="col9">0.07</oasis:entry>  
         <oasis:entry colname="col10">0.04</oasis:entry>  
         <oasis:entry colname="col11">0.04</oasis:entry>  
         <oasis:entry colname="col12">0.06</oasis:entry>  
         <oasis:entry colname="col13">0.03</oasis:entry>  
         <oasis:entry colname="col14">0.03</oasis:entry>  
         <oasis:entry colname="col15">0.02</oasis:entry>  
         <oasis:entry colname="col16">0.02</oasis:entry>  
         <oasis:entry colname="col17">0.16</oasis:entry>  
         <oasis:entry colname="col18">0.03</oasis:entry>  
         <oasis:entry colname="col19">0.04</oasis:entry>  
         <oasis:entry colname="col20">0.04</oasis:entry>  
         <oasis:entry colname="col21">0.24</oasis:entry>  
         <oasis:entry colname="col22">0.13</oasis:entry>  
         <oasis:entry colname="col23">0.05</oasis:entry>  
         <oasis:entry colname="col24">0.03</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Mg</oasis:entry>  
         <oasis:entry colname="col2">0.53</oasis:entry>  
         <oasis:entry colname="col3">0.56</oasis:entry>  
         <oasis:entry colname="col4">0.49</oasis:entry>  
         <oasis:entry colname="col5">0.84</oasis:entry>  
         <oasis:entry colname="col6">0.62</oasis:entry>  
         <oasis:entry colname="col7">0.72</oasis:entry>  
         <oasis:entry colname="col8">0.74</oasis:entry>  
         <oasis:entry colname="col9">0.76</oasis:entry>  
         <oasis:entry colname="col10">0.59</oasis:entry>  
         <oasis:entry colname="col11">0.49</oasis:entry>  
         <oasis:entry colname="col12">0.83</oasis:entry>  
         <oasis:entry colname="col13">0.68</oasis:entry>  
         <oasis:entry colname="col14">0.78</oasis:entry>  
         <oasis:entry colname="col15">0.78</oasis:entry>  
         <oasis:entry colname="col16">0.86</oasis:entry>  
         <oasis:entry colname="col17">0.56</oasis:entry>  
         <oasis:entry colname="col18">0.46</oasis:entry>  
         <oasis:entry colname="col19">0.61</oasis:entry>  
         <oasis:entry colname="col20">0.56</oasis:entry>  
         <oasis:entry colname="col21">0.07</oasis:entry>  
         <oasis:entry colname="col22">0.08</oasis:entry>  
         <oasis:entry colname="col23">0.09</oasis:entry>  
         <oasis:entry colname="col24">0.11</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Ca</oasis:entry>  
         <oasis:entry colname="col2">0.35</oasis:entry>  
         <oasis:entry colname="col3">0.33</oasis:entry>  
         <oasis:entry colname="col4">0.33</oasis:entry>  
         <oasis:entry colname="col5">0.11</oasis:entry>  
         <oasis:entry colname="col6">0.56</oasis:entry>  
         <oasis:entry colname="col7">0.35</oasis:entry>  
         <oasis:entry colname="col8">0.18</oasis:entry>  
         <oasis:entry colname="col9">0.12</oasis:entry>  
         <oasis:entry colname="col10">0.47</oasis:entry>  
         <oasis:entry colname="col11">0.70</oasis:entry>  
         <oasis:entry colname="col12">0.10</oasis:entry>  
         <oasis:entry colname="col13">0.34</oasis:entry>  
         <oasis:entry colname="col14">0.18</oasis:entry>  
         <oasis:entry colname="col15">0.13</oasis:entry>  
         <oasis:entry colname="col16">0.08</oasis:entry>  
         <oasis:entry colname="col17">0.15</oasis:entry>  
         <oasis:entry colname="col18">0.28</oasis:entry>  
         <oasis:entry colname="col19">0.53</oasis:entry>  
         <oasis:entry colname="col20">0.70</oasis:entry>  
         <oasis:entry colname="col21">1.06</oasis:entry>  
         <oasis:entry colname="col22">1.09</oasis:entry>  
         <oasis:entry colname="col23">1.06</oasis:entry>  
         <oasis:entry colname="col24">0.97</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"><inline-formula><mml:math id="M91" display="inline"><mml:mo>∑</mml:mo></mml:math></inline-formula> cations</oasis:entry>  
         <oasis:entry colname="col2">8.00</oasis:entry>  
         <oasis:entry colname="col3">8.00</oasis:entry>  
         <oasis:entry colname="col4">7.99</oasis:entry>  
         <oasis:entry colname="col5">8.00</oasis:entry>  
         <oasis:entry colname="col6">8.00</oasis:entry>  
         <oasis:entry colname="col7">8.00</oasis:entry>  
         <oasis:entry colname="col8">8.00</oasis:entry>  
         <oasis:entry colname="col9">8.00</oasis:entry>  
         <oasis:entry colname="col10">8.00</oasis:entry>  
         <oasis:entry colname="col11">8.00</oasis:entry>  
         <oasis:entry colname="col12">8.00</oasis:entry>  
         <oasis:entry colname="col13">8.00</oasis:entry>  
         <oasis:entry colname="col14">8.00</oasis:entry>  
         <oasis:entry colname="col15">8.00</oasis:entry>  
         <oasis:entry colname="col16">8.00</oasis:entry>  
         <oasis:entry colname="col17">8.00</oasis:entry>  
         <oasis:entry colname="col18">8.00</oasis:entry>  
         <oasis:entry colname="col19">8.00</oasis:entry>  
         <oasis:entry colname="col20">8.00</oasis:entry>  
         <oasis:entry colname="col21">8.00</oasis:entry>  
         <oasis:entry colname="col22">8.00</oasis:entry>  
         <oasis:entry colname="col23">8.00</oasis:entry>  
         <oasis:entry colname="col24">8.00</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry namest="col1" nameend="col20" colsep="0">Molecular proportions of garnet endmembers </oasis:entry>  
         <oasis:entry colname="col21"/>  
         <oasis:entry colname="col22"/>  
         <oasis:entry colname="col23"/>  
         <oasis:entry colname="col24"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Alm</oasis:entry>  
         <oasis:entry colname="col2">0.69</oasis:entry>  
         <oasis:entry colname="col3">0.69</oasis:entry>  
         <oasis:entry colname="col4">0.70</oasis:entry>  
         <oasis:entry colname="col5">0.68</oasis:entry>  
         <oasis:entry colname="col6">0.60</oasis:entry>  
         <oasis:entry colname="col7">0.64</oasis:entry>  
         <oasis:entry colname="col8">0.69</oasis:entry>  
         <oasis:entry colname="col9">0.69</oasis:entry>  
         <oasis:entry colname="col10">0.63</oasis:entry>  
         <oasis:entry colname="col11">0.59</oasis:entry>  
         <oasis:entry colname="col12">0.68</oasis:entry>  
         <oasis:entry colname="col13">0.66</oasis:entry>  
         <oasis:entry colname="col14">0.67</oasis:entry>  
         <oasis:entry colname="col15">0.69</oasis:entry>  
         <oasis:entry colname="col16">0.69</oasis:entry>  
         <oasis:entry colname="col17">0.72</oasis:entry>  
         <oasis:entry colname="col18">0.75</oasis:entry>  
         <oasis:entry colname="col19">0.62</oasis:entry>  
         <oasis:entry colname="col20">0.58</oasis:entry>  
         <oasis:entry colname="col21">0.54</oasis:entry>  
         <oasis:entry colname="col22">0.57</oasis:entry>  
         <oasis:entry colname="col23">0.60</oasis:entry>  
         <oasis:entry colname="col24">0.63</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Prp</oasis:entry>  
         <oasis:entry colname="col2">0.18</oasis:entry>  
         <oasis:entry colname="col3">0.19</oasis:entry>  
         <oasis:entry colname="col4">0.17</oasis:entry>  
         <oasis:entry colname="col5">0.28</oasis:entry>  
         <oasis:entry colname="col6">0.20</oasis:entry>  
         <oasis:entry colname="col7">0.24</oasis:entry>  
         <oasis:entry colname="col8">0.24</oasis:entry>  
         <oasis:entry colname="col9">0.25</oasis:entry>  
         <oasis:entry colname="col10">0.20</oasis:entry>  
         <oasis:entry colname="col11">0.16</oasis:entry>  
         <oasis:entry colname="col12">0.27</oasis:entry>  
         <oasis:entry colname="col13">0.22</oasis:entry>  
         <oasis:entry colname="col14">0.26</oasis:entry>  
         <oasis:entry colname="col15">0.26</oasis:entry>  
         <oasis:entry colname="col16">0.28</oasis:entry>  
         <oasis:entry colname="col17">0.18</oasis:entry>  
         <oasis:entry colname="col18">0.15</oasis:entry>  
         <oasis:entry colname="col19">0.20</oasis:entry>  
         <oasis:entry colname="col20">0.18</oasis:entry>  
         <oasis:entry colname="col21">0.02</oasis:entry>  
         <oasis:entry colname="col22">0.03</oasis:entry>  
         <oasis:entry colname="col23">0.03</oasis:entry>  
         <oasis:entry colname="col24">0.04</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Grs</oasis:entry>  
         <oasis:entry colname="col2">0.12</oasis:entry>  
         <oasis:entry colname="col3">0.11</oasis:entry>  
         <oasis:entry colname="col4">0.11</oasis:entry>  
         <oasis:entry colname="col5">0.04</oasis:entry>  
         <oasis:entry colname="col6">0.19</oasis:entry>  
         <oasis:entry colname="col7">0.11</oasis:entry>  
         <oasis:entry colname="col8">0.06</oasis:entry>  
         <oasis:entry colname="col9">0.04</oasis:entry>  
         <oasis:entry colname="col10">0.16</oasis:entry>  
         <oasis:entry colname="col11">0.24</oasis:entry>  
         <oasis:entry colname="col12">0.03</oasis:entry>  
         <oasis:entry colname="col13">0.11</oasis:entry>  
         <oasis:entry colname="col14">0.06</oasis:entry>  
         <oasis:entry colname="col15">0.04</oasis:entry>  
         <oasis:entry colname="col16">0.03</oasis:entry>  
         <oasis:entry colname="col17">0.05</oasis:entry>  
         <oasis:entry colname="col18">0.09</oasis:entry>  
         <oasis:entry colname="col19">0.17</oasis:entry>  
         <oasis:entry colname="col20">0.23</oasis:entry>  
         <oasis:entry colname="col21">0.36</oasis:entry>  
         <oasis:entry colname="col22">0.37</oasis:entry>  
         <oasis:entry colname="col23">0.35</oasis:entry>  
         <oasis:entry colname="col24">0.32</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Sps</oasis:entry>  
         <oasis:entry colname="col2">0.01</oasis:entry>  
         <oasis:entry colname="col3">0.01</oasis:entry>  
         <oasis:entry colname="col4">0.01</oasis:entry>  
         <oasis:entry colname="col5">0.01</oasis:entry>  
         <oasis:entry colname="col6">0.01</oasis:entry>  
         <oasis:entry colname="col7">0.01</oasis:entry>  
         <oasis:entry colname="col8">0.01</oasis:entry>  
         <oasis:entry colname="col9">0.02</oasis:entry>  
         <oasis:entry colname="col10">0.01</oasis:entry>  
         <oasis:entry colname="col11">0.01</oasis:entry>  
         <oasis:entry colname="col12">0.02</oasis:entry>  
         <oasis:entry colname="col13">0.01</oasis:entry>  
         <oasis:entry colname="col14">0.01</oasis:entry>  
         <oasis:entry colname="col15">0.01</oasis:entry>  
         <oasis:entry colname="col16">0.01</oasis:entry>  
         <oasis:entry colname="col17">0.05</oasis:entry>  
         <oasis:entry colname="col18">0.01</oasis:entry>  
         <oasis:entry colname="col19">0.01</oasis:entry>  
         <oasis:entry colname="col20">0.01</oasis:entry>  
         <oasis:entry colname="col21">0.08</oasis:entry>  
         <oasis:entry colname="col22">0.04</oasis:entry>  
         <oasis:entry colname="col23">0.02</oasis:entry>  
         <oasis:entry colname="col24">0.01</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S4">
  <title>Petrography and mineral chemistry</title>
<sec id="Ch1.S4.SS1">
  <title>Methods</title>
<sec id="Ch1.S4.SS1.SSS1">
  <title>SEM</title>
      <p id="d1e2835">Backscattered electron images (BSEs) were acquired using the Zeiss EVO50 SEM
at the Institute of Geological Sciences (University of Bern) using an
accelerating voltage of 15 to 25 KeV, a beam current of 500 pA, and a working
distance of 10 mm. Cathodoluminescence (CL) pictures were obtained with the
same operative conditions but with 10 KeV accelerating voltage and a
working distance of 9.5 mm.</p>
</sec>
<sec id="Ch1.S4.SS1.SSS2">
  <title>EPMA analyses</title>
      <p id="d1e2844">EPMA analyses were performed using a JEOL JXA-8200 superprobe at the
Institute of Geological Sciences (University of Bern). Point-mode analyses
and X-ray compositional maps were acquired using wavelength-dispersive
spectrometers. For X-ray mapping the procedure described in
Lanari et al. (2013) was followed. It consists in measuring point-mode
analyses first and then acquiring X-ray compositional maps on the same area.
For point analyses, analytical conditions included 15 KeV accelerating voltage,
10 to 20 nA specimen current, 40 s dwell times (including 2 <inline-formula><mml:math id="M92" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10 s
of background measurement), and a beam ø from 1 to 5 <inline-formula><mml:math id="M93" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m. Lower
current and higher beam size were used for minerals containing Ca, Na, and K
such as phengite and plagioclase. Nine oxide compositions were measured,
using synthetic and natural standards: wollastonite–orthoclase–almandine
(SiO<inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, anorthite–almandine (Al<inline-formula><mml:math id="M95" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O<inline-formula><mml:math id="M96" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, anorthite (CaO),
almandine (FeO), forsterite–spinel (MgO),
orthoclase–phlogopite
(K<inline-formula><mml:math id="M97" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O), albite (Na<inline-formula><mml:math id="M98" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O), ilmenite (TiO<inline-formula><mml:math id="M99" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, and tephroite (MnO).
For X-ray maps, analytical conditions included 15 KeV accelerating voltage, 100 nA specimen current, and dwell times of 150–250 ms. Nine elements (Si, Ti,
Al, Fe, Mn, Mg, Na, Ca, and K) were measured at the specific wavelength in
two passes. Intensity X-ray maps were standardized to concentration maps of
oxide weight percentage using spot analyses as the internal standard. X-ray maps
were processed using XMapTools 2.2.1 (Lanari et al., 2014).</p>
</sec>
</sec>
<sec id="Ch1.S4.SS2">
  <title>Results: sample description</title>
      <p id="d1e2932">Five samples from the IC and two samples from the EC were analysed. These
were collected from internal (SE) to external areas (NW) of the Sesia Zone.
A brief account is given here, with characteristic images shown in Fig. 2.
Supplement S1 contains detailed descriptions and GPS locations.</p>
      <p id="d1e2935">The samples of the IC (FG1324, FG1315, FG12157, FG1347, and FG1249) are
mica schists with eclogite facies assemblages comprising quartz, phengite,
garnet, <inline-formula><mml:math id="M100" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> paragonite <inline-formula><mml:math id="M101" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> glaucophane <inline-formula><mml:math id="M102" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> omphacite <inline-formula><mml:math id="M103" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> chloritoid, with accessory allanite <inline-formula><mml:math id="M104" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> rutile. The main fabric in all
of these samples is an eclogite facies foliation (Fig. 2a). Evidence of
several deformation stages occurring before or after the main eclogite
facies foliation is preserved in several samples as microlithons, commonly
of phengite, omphacite, glaucophane, or chloritoid oriented at high angles
relative to the main foliation, which wraps around them or is overgrown by
them (Fig. 2b). Further evidence of several metamorphic stages occurring at
eclogite facies conditions is reflected in growth zones of garnet
(Giuntoli et al., 2018). Pre-Alpine relics include garnet
cores (Fig. 2c) and zircon (cores <inline-formula><mml:math id="M105" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> first rims; Sect. 6.4 and 6.5).</p>
      <p id="d1e2981">Retrograde stages of blueschist or greenschist facies assemblages related to
decompression are locally present in samples. The blueschist facies stage
produced pleochroic crossite rims around glaucophane (Fig. 2d). The
greenschist facies stage produced symplectites of actinolite <inline-formula><mml:math id="M106" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> albite <inline-formula><mml:math id="M107" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> chlorite around glaucophane and omphacite, chlorite at the expense
of garnet, epidote, or clinozoisite rims around allanite, and titanite rims
formed around rutile (Fig. 2e, f).</p>
      <p id="d1e2998">Sample FG1420, collected in the EC, is a garnet orthogneiss that shows a HP
greenschist foliation marked by phengite, chlorite, and titanite; the
foliation wraps garnet porphyroblasts that preserve a relic internal
foliation (Fig. 2g). Permian magmatic relics of pleochroic allanite are
surrounded by an Alpine corona of epidote grains (Fig. 2h). Some hundred
metres to the north, another sample (FG12107) of the EC was collected. This
is a leucogneiss characterized by the same metamorphic fabric and
parageneses as the previous sample, except that garnet and magmatic allanite
are missing.</p>
</sec>
<sec id="Ch1.S4.SS3">
  <title>Results: growth zones of garnet and phengite</title>
      <p id="d1e3007">Garnet and phengite display features in the IC samples that differ from
those in the EC samples. To highlight and describe these, two main samples
are compared in the following paragraphs: FG1249 (IC) and FG1420 (EC). A
more complete account of garnet textures and mineral inclusions in the IC is
shown in Giuntoli et al. (2018).</p>
      <p id="d1e3010">In the IC samples, garnet consists of a core followed by several rims with a
grain size of up to several millimetres (Fig. 3a, b). The compositional map of
the grossular endmember fraction (<inline-formula><mml:math id="M108" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Grs</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> in sample FG1249 shows a
porphyroclastic core (Alm<inline-formula><mml:math id="M109" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">72</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M110" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">18</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M111" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">5</mml:mn></mml:msub></mml:math></inline-formula>Sps<inline-formula><mml:math id="M112" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">5</mml:mn></mml:msub></mml:math></inline-formula>; Table 1) with
internal fractures sealed by garnet of higher <inline-formula><mml:math id="M113" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Grs</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (Fig. 3b). A first
rim (Rim1<inline-formula><mml:math id="M114" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>Alm<inline-formula><mml:math id="M115" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">76</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M116" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">15</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M117" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">9</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> overgrows the core and displays
higher grossular contents. This Rim1 is followed by Rim2, which again
records an increase in <inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Grs</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (Alm<inline-formula><mml:math id="M119" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">62</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M120" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">20</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">18</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. Rim2
resorbs parts of Rim1, externally and internally, and the
core. Rim3 is peripheral and shows the highest Ca contents
(Alm<inline-formula><mml:math id="M122" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">58</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M123" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">19</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">23</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e3183">Sample FG1315 is characterized by a porphyroclastic core
(Alm<inline-formula><mml:math id="M125" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">69</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M126" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">28</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> with lobate edges and resorption features
(details in Giuntoli et al. 2018 and Engi et al. 2018) surrounded
by several rim generations: Rim1 (Alm<inline-formula><mml:math id="M128" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">61</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M129" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">21</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M130" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">19</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, Rim2
(Alm<inline-formula><mml:math id="M131" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">65</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M132" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">24</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M133" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">11</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, and Rim3 (Alm<inline-formula><mml:math id="M134" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">70</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M135" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">24</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M136" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">6</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>.
Atoll garnets, a few hundred microns in size, are observed in this sample.
The shells of the atoll garnet have similar zoning patterns and compositions
as the rim generations just described. In sample FG12157 the garnet core
(Alm<inline-formula><mml:math id="M137" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">70</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M138" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">26</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M139" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is rimmed by two growth zones: Rim1
(Alm<inline-formula><mml:math id="M140" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">64</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M141" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">20</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M142" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">16</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and Rim2 (Alm<inline-formula><mml:math id="M143" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">59</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M144" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">24</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M145" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">17</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>.
In sample FG1347, the garnet core (Alm<inline-formula><mml:math id="M146" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">69</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M147" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">28</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M148" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is
enclosed by three rims (Rim1: Alm<inline-formula><mml:math id="M149" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">66</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M150" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">23</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M151" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">11</mml:mn></mml:msub></mml:math></inline-formula>; Rim2:
Alm<inline-formula><mml:math id="M152" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">68</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M153" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">26</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M154" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">6</mml:mn></mml:msub></mml:math></inline-formula>; Rim3: Alm<inline-formula><mml:math id="M155" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">70</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M156" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">26</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M157" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. The
exception is sample FG1324, in which garnet shows a single growth zone of
homogeneous composition (Alm<inline-formula><mml:math id="M158" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">70</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M159" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">18</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M160" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">11</mml:mn></mml:msub></mml:math></inline-formula>Sps<inline-formula><mml:math id="M161" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e3555">In the EC, sample FG1420 shows garnet with completely different features. As
shown in Fig. 3d, the <inline-formula><mml:math id="M162" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Sps</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> map highlights concentric zoning (values of
Alm<inline-formula><mml:math id="M163" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">54</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M164" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M165" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">36</mml:mn></mml:msub></mml:math></inline-formula>Sps<inline-formula><mml:math id="M166" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">8</mml:mn></mml:msub></mml:math></inline-formula> for the core,
Alm<inline-formula><mml:math id="M167" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">57</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M168" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M169" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">37</mml:mn></mml:msub></mml:math></inline-formula>Sps<inline-formula><mml:math id="M170" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:math></inline-formula> for Rim1,
Alm<inline-formula><mml:math id="M171" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">60</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M172" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M173" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">35</mml:mn></mml:msub></mml:math></inline-formula>Sps<inline-formula><mml:math id="M174" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> for Rim2, and
Alm<inline-formula><mml:math id="M175" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">63</mml:mn></mml:msub></mml:math></inline-formula>Prp<inline-formula><mml:math id="M176" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:math></inline-formula>Grs<inline-formula><mml:math id="M177" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">32</mml:mn></mml:msub></mml:math></inline-formula>Sps<inline-formula><mml:math id="M178" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:math></inline-formula> for Rim3), with no visible resorption
features (further compositional endmember maps are shown in Supplement S2).</p>
      <p id="d1e3716">To link the growth zones of garnet to the main assemblage observed in the
mineral matrix, microstructural relations, overprinting criteria, and mutual
inclusions were employed, based on optical microscopy, SEM, and
compositional maps. In particular, garnet in sample FG1249 contains
inclusions of paragonite, phengite, and quartz between Rim1 and Rim2 (Fig. 3a). Rutile inclusions of a few microns are present in Rim2 and 3. Late
chlorite fractures dissect the entire garnet. Garnet in sample FG1420 is
wrapped by the main external foliation and includes an internal foliation
marked by quartz, epidote, and titanite (Fig. 3c).</p>
      <p id="d1e3719">Phengite in IC samples displays a uniform composition except along grain
boundaries, where lower Si and <inline-formula><mml:math id="M179" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> contents are found, indicating
retrograde overprinting (e.g. Fig. 3e; Group1 Si <inline-formula><mml:math id="M180" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.36 apfu (atoms per formula unit),
<inline-formula><mml:math id="M181" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M182" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.83; Group2 Si <inline-formula><mml:math id="M183" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.3 apfu, <inline-formula><mml:math id="M184" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
<inline-formula><mml:math id="M185" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.68 in sample FG1249; Table 2).</p>
      <p id="d1e3784">In the EC, two distinct generations of phengite are distinguished based on
their microtextural position: the first one describes the main foliation and
is characterized by high Si values (Fig. 3f; Group1 Si <inline-formula><mml:math id="M186" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.4
apfu, <inline-formula><mml:math id="M187" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M188" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.61 in sample FG1420), and the second phengite
generation (Group2 Si <inline-formula><mml:math id="M189" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.32 apfu, <inline-formula><mml:math id="M190" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M191" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.61) rims the first one and occurs in fold hinges that deform the main
foliation.</p>
</sec>
</sec>
<sec id="Ch1.S5">
  <title>Thermobarometry</title>
<sec id="Ch1.S5.SS1">
  <title>Methods</title>
<sec id="Ch1.S5.SS1.SSS1">
  <title>Whole-rock major element compositions</title>
      <p id="d1e3856">Major element compositions were analysed using X-ray fluorescence (XRF)
spectrometry at the University of Lausanne (Switzerland). Representative
quantities of samples were crushed and then pulverized in a tungsten carbide
mill. The powder was dried for 2 h at 105 <inline-formula><mml:math id="M192" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Loss of
ignition was then determined by weight difference after heating to
1050 <inline-formula><mml:math id="M193" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for 3 h.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><caption><p id="d1e3879"><bold>(a)</bold> Mineral phases in sample FG1249 (compare with Fig. 2c).
<bold>(b)</bold> <inline-formula><mml:math id="M194" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Grs</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> map highlights the porphyroclastic cores
showing fractures sealed by higher <inline-formula><mml:math id="M195" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Grs</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> garnet and
three rims (further garnet endmember maps for the samples are available in
Giuntoli et al., 2018). <bold>(c)</bold> Mineral phases in sample FG1420 (compare
with Fig. 2g). <bold>(d)</bold> Garnet displaying concentric zoning related to a decrease
in <inline-formula><mml:math id="M196" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Sps</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. (Further garnet endmember maps for the
samples are available in the Supplement S2). <bold>(e)</bold> Phengite groups in sample
FG1249 (details in text). <bold>(f)</bold> Phengite groups in sample FG1420 (details in
text). Note larger phengite flakes of Group2 localized in fold hinges.</p></caption>
            <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f03.jpg"/>

          </fig>

</sec>
<sec id="Ch1.S5.SS1.SSS2">
  <title>Garnet thermobarometry using GrtMod</title>
      <p id="d1e3945">Garnet growth zones were carefully selected after detailed microstructural
and compositional analysis of the high-resolution X-ray maps to extract
representative compositions that are used as input for modelling. Following
the strategy proposed by Lanari et al. (2017), the composition of each
growth zone was obtained directly from the quantitative maps by sampling
chemically homogeneous areas amongst different garnet grains. Each
composition was then assigned to a specific growth zone that is assumed to
be uniform in the following. The regularity of the chemical zoning observed
in garnet (Giuntoli et al., 2018) supports the grain boundary
equilibrium model adopted here (Lanari and Engi, 2017). Minor
heterogeneities observed in each growth zone (&lt; 0.01 in XAlm and
XGrs; &lt; 0.005 in XPrp and XSps) may be due to kinetic effects during
growth; they do not affect the results of the equilibrium model.</p>
      <p id="d1e3948">To model the complex garnet textures adequately, fractionation and
resorption processes must be taken into account in approximating the
evolution of the reactive bulk composition. The latter is strongly affected
by fractionation (i.e. the removal of refractive garnet, e.g.
Evans, 2004; Konrad-Schmolke et al., 2008) and by resorption,
which can shift the reactive bulk composition back toward the garnet
composition (Lanari and Engi, 2017). The program GrtMod
(Lanari et al., 2017) was specially developed to deal with samples
in which garnet experienced a complex history involving several stages of
growth, resorption, and/or pseudomorphic replacement. In essence, the program
refines the reactive bulk composition used in free-energy minimization at
each stage predicted if previously grown garnet was preserved or only partly
dissolved. GrtMod uses an iterative approach that refines the <inline-formula><mml:math id="M197" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M198" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>
conditions for successive garnet growth zones. For each inversion (i.e. a
single growth stage), a solution was deemed acceptable if the least-squares
residual value (the cost function <inline-formula><mml:math id="M199" display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> used by Lanari et al.,
2017) was &lt; 0.05, reflecting a sufficiently close match between the
modelled and observed garnet compositions. In the IC samples, resorption and
fractionation were constrained according to the volumetric proportion of
each growth zone, as estimated from the thin section and the compositional
maps. No resorption was permitted in the program for sample FG1420, as
garnet textures in the compositional maps show no evidence of this process.
To model the rim generation in the IC samples the “go fast mode” function
(Lanari et al., 2017) was used, with an initial starting <inline-formula><mml:math id="M200" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M201" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>
guess
of 650 <inline-formula><mml:math id="M202" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C and 1.6 GPa. The initial starting guess is an essential
technicality used for reasons discussed by Lanari et al. (2017,
Sects. 5.2.3 and 6.3); the specific purpose is to avoid local minima in
optimization. This function searches a solution around the starting guess
and follows the gradient in the objective function; there cannot be local
minima at high pressure for this range of bulk rock composition (see Fig. 8
in Lanari et al., 2017). The MnO component was used in the
thermodynamic computations of the relatively rich Mn garnet in sample
FG1420. In sample FG1249, MnO was used to model the garnet core but was
ignored in the models of the following rims because the concentration found
in garnet is low (&lt; 1 wt % MnO; Table1). In the remaining samples,
MnO was ignored (&lt; 1 wt %), and the system considered in modelling
was simplified to
SiO<inline-formula><mml:math id="M203" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>-TiO<inline-formula><mml:math id="M204" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>-Al<inline-formula><mml:math id="M205" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O<inline-formula><mml:math id="M206" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>-FeO-MgO-CaO-Na<inline-formula><mml:math id="M207" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O-K<inline-formula><mml:math id="M208" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O-H<inline-formula><mml:math id="M209" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O.
The thermodynamic database used was the same as the one used to compute the isochemical
phase diagrams (see below).</p>

<?xmltex \floatpos{p}?><table-wrap id="Ch1.T2" specific-use="star" orientation="landscape"><caption><p id="d1e4067">Representative analyses of phengite of the samples.
<inline-formula><mml:math id="M210" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> is the standard deviation associated with the average
composition analysis.</p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.95}[.95]?><oasis:tgroup cols="16">
     <oasis:colspec colnum="1" colname="col1" align="left" colsep="1"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right" colsep="1"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right" colsep="1"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right" colsep="1"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right" colsep="1"/>
     <oasis:colspec colnum="11" colname="col11" align="right"/>
     <oasis:colspec colnum="12" colname="col12" align="right" colsep="1"/>
     <oasis:colspec colnum="13" colname="col13" align="right"/>
     <oasis:colspec colnum="14" colname="col14" align="right"/>
     <oasis:colspec colnum="15" colname="col15" align="right"/>
     <oasis:colspec colnum="16" colname="col16" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Sample</oasis:entry>  
         <oasis:entry namest="col2" nameend="col4" align="center" colsep="1">IC – FG1324 </oasis:entry>  
         <oasis:entry namest="col5" nameend="col6" align="center" colsep="1">IC – FG1315 </oasis:entry>  
         <oasis:entry namest="col7" nameend="col8" align="center" colsep="1">IC – FG12157 </oasis:entry>  
         <oasis:entry namest="col9" nameend="col10" align="center" colsep="1">IC – FG1347 </oasis:entry>  
         <oasis:entry namest="col11" nameend="col12" align="center" colsep="1">IC – FG1249 </oasis:entry>  
         <oasis:entry namest="col13" nameend="col16" align="center">EC – FG1420 </oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Ph</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">Average</oasis:entry>  
         <oasis:entry colname="col6"/>  
         <oasis:entry colname="col7">Average</oasis:entry>  
         <oasis:entry colname="col8"/>  
         <oasis:entry colname="col9">Average</oasis:entry>  
         <oasis:entry colname="col10"/>  
         <oasis:entry colname="col11">Average</oasis:entry>  
         <oasis:entry colname="col12"/>  
         <oasis:entry colname="col13">Average</oasis:entry>  
         <oasis:entry colname="col14"/>  
         <oasis:entry colname="col15">Average</oasis:entry>  
         <oasis:entry colname="col16"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">composition</oasis:entry>  
         <oasis:entry colname="col6"/>  
         <oasis:entry colname="col7">composition</oasis:entry>  
         <oasis:entry colname="col8"/>  
         <oasis:entry colname="col9">composition</oasis:entry>  
         <oasis:entry colname="col10"/>  
         <oasis:entry colname="col11">composition</oasis:entry>  
         <oasis:entry colname="col12"/>  
         <oasis:entry colname="col13">comp. (wt %)</oasis:entry>  
         <oasis:entry colname="col14"/>  
         <oasis:entry colname="col15">comp. (wt %)</oasis:entry>  
         <oasis:entry colname="col16"/>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">wt %</oasis:entry>  
         <oasis:entry namest="col2" nameend="col4" align="center" colsep="1">Spot analysis (wt %) </oasis:entry>  
         <oasis:entry colname="col5">wt %</oasis:entry>  
         <oasis:entry colname="col6"><inline-formula><mml:math id="M211" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col7">wt %</oasis:entry>  
         <oasis:entry colname="col8"><inline-formula><mml:math id="M212" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col9">wt %</oasis:entry>  
         <oasis:entry colname="col10"><inline-formula><mml:math id="M213" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col11">wt %</oasis:entry>  
         <oasis:entry colname="col12"><inline-formula><mml:math id="M214" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col13">High Si</oasis:entry>  
         <oasis:entry colname="col14"><inline-formula><mml:math id="M215" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col15">Low Si</oasis:entry>  
         <oasis:entry colname="col16"><inline-formula><mml:math id="M216" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">SiO<inline-formula><mml:math id="M217" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">51.34</oasis:entry>  
         <oasis:entry colname="col3">49.24</oasis:entry>  
         <oasis:entry colname="col4">51.99</oasis:entry>  
         <oasis:entry colname="col5">50.89</oasis:entry>  
         <oasis:entry colname="col6">0.55</oasis:entry>  
         <oasis:entry colname="col7">49.61</oasis:entry>  
         <oasis:entry colname="col8">0.58</oasis:entry>  
         <oasis:entry colname="col9">49.43</oasis:entry>  
         <oasis:entry colname="col10">0.62</oasis:entry>  
         <oasis:entry colname="col11">49.57</oasis:entry>  
         <oasis:entry colname="col12">0.79</oasis:entry>  
         <oasis:entry colname="col13">50.82</oasis:entry>  
         <oasis:entry colname="col14">0.87</oasis:entry>  
         <oasis:entry colname="col15">48.54</oasis:entry>  
         <oasis:entry colname="col16">0.86</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">TiO<inline-formula><mml:math id="M218" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">0.41</oasis:entry>  
         <oasis:entry colname="col3">0.53</oasis:entry>  
         <oasis:entry colname="col4">0.53</oasis:entry>  
         <oasis:entry colname="col5">0.26</oasis:entry>  
         <oasis:entry colname="col6">0.15</oasis:entry>  
         <oasis:entry colname="col7">0.31</oasis:entry>  
         <oasis:entry colname="col8">0.06</oasis:entry>  
         <oasis:entry colname="col9">0.23</oasis:entry>  
         <oasis:entry colname="col10">0.05</oasis:entry>  
         <oasis:entry colname="col11">0.24</oasis:entry>  
         <oasis:entry colname="col12">0.08</oasis:entry>  
         <oasis:entry colname="col13">0.15</oasis:entry>  
         <oasis:entry colname="col14">0.04</oasis:entry>  
         <oasis:entry colname="col15">0.13</oasis:entry>  
         <oasis:entry colname="col16">0.03</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al<inline-formula><mml:math id="M219" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O<inline-formula><mml:math id="M220" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">26.67</oasis:entry>  
         <oasis:entry colname="col3">26.82</oasis:entry>  
         <oasis:entry colname="col4">26.83</oasis:entry>  
         <oasis:entry colname="col5">28.15</oasis:entry>  
         <oasis:entry colname="col6">0.40</oasis:entry>  
         <oasis:entry colname="col7">27.58</oasis:entry>  
         <oasis:entry colname="col8">0.35</oasis:entry>  
         <oasis:entry colname="col9">29.78</oasis:entry>  
         <oasis:entry colname="col10">0.50</oasis:entry>  
         <oasis:entry colname="col11">27.92</oasis:entry>  
         <oasis:entry colname="col12">0.52</oasis:entry>  
         <oasis:entry colname="col13">27.45</oasis:entry>  
         <oasis:entry colname="col14">0.69</oasis:entry>  
         <oasis:entry colname="col15">30.17</oasis:entry>  
         <oasis:entry colname="col16">0.76</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FeO</oasis:entry>  
         <oasis:entry colname="col2">1.67</oasis:entry>  
         <oasis:entry colname="col3">1.39</oasis:entry>  
         <oasis:entry colname="col4">1.64</oasis:entry>  
         <oasis:entry colname="col5">1.49</oasis:entry>  
         <oasis:entry colname="col6">0.11</oasis:entry>  
         <oasis:entry colname="col7">2.09</oasis:entry>  
         <oasis:entry colname="col8">0.43</oasis:entry>  
         <oasis:entry colname="col9">1.40</oasis:entry>  
         <oasis:entry colname="col10">0.14</oasis:entry>  
         <oasis:entry colname="col11">1.30</oasis:entry>  
         <oasis:entry colname="col12">0.42</oasis:entry>  
         <oasis:entry colname="col13">3.21</oasis:entry>  
         <oasis:entry colname="col14">0.25</oasis:entry>  
         <oasis:entry colname="col15">2.63</oasis:entry>  
         <oasis:entry colname="col16">0.28</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MnO</oasis:entry>  
         <oasis:entry colname="col2">0.00</oasis:entry>  
         <oasis:entry colname="col3">0.00</oasis:entry>  
         <oasis:entry colname="col4">0.00</oasis:entry>  
         <oasis:entry colname="col5">0.06</oasis:entry>  
         <oasis:entry colname="col6">0.01</oasis:entry>  
         <oasis:entry colname="col7">0.19</oasis:entry>  
         <oasis:entry colname="col8">0.04</oasis:entry>  
         <oasis:entry colname="col9">0.06</oasis:entry>  
         <oasis:entry colname="col10">0.01</oasis:entry>  
         <oasis:entry colname="col11">0.05</oasis:entry>  
         <oasis:entry colname="col12">0.01</oasis:entry>  
         <oasis:entry colname="col13">0.08</oasis:entry>  
         <oasis:entry colname="col14">0.01</oasis:entry>  
         <oasis:entry colname="col15">0.08</oasis:entry>  
         <oasis:entry colname="col16">0.01</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MgO</oasis:entry>  
         <oasis:entry colname="col2">3.00</oasis:entry>  
         <oasis:entry colname="col3">3.37</oasis:entry>  
         <oasis:entry colname="col4">3.45</oasis:entry>  
         <oasis:entry colname="col5">3.68</oasis:entry>  
         <oasis:entry colname="col6">0.14</oasis:entry>  
         <oasis:entry colname="col7">3.65</oasis:entry>  
         <oasis:entry colname="col8">0.15</oasis:entry>  
         <oasis:entry colname="col9">3.29</oasis:entry>  
         <oasis:entry colname="col10">0.16</oasis:entry>  
         <oasis:entry colname="col11">3.45</oasis:entry>  
         <oasis:entry colname="col12">0.18</oasis:entry>  
         <oasis:entry colname="col13">2.85</oasis:entry>  
         <oasis:entry colname="col14">0.25</oasis:entry>  
         <oasis:entry colname="col15">2.30</oasis:entry>  
         <oasis:entry colname="col16">0.21</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">CaO</oasis:entry>  
         <oasis:entry colname="col2">0.00</oasis:entry>  
         <oasis:entry colname="col3">0.00</oasis:entry>  
         <oasis:entry colname="col4">0.00</oasis:entry>  
         <oasis:entry colname="col5">0.00</oasis:entry>  
         <oasis:entry colname="col6">0.00</oasis:entry>  
         <oasis:entry colname="col7">0.19</oasis:entry>  
         <oasis:entry colname="col8">0.04</oasis:entry>  
         <oasis:entry colname="col9">0.01</oasis:entry>  
         <oasis:entry colname="col10">0.00</oasis:entry>  
         <oasis:entry colname="col11">0.01</oasis:entry>  
         <oasis:entry colname="col12">0.00</oasis:entry>  
         <oasis:entry colname="col13">0.00</oasis:entry>  
         <oasis:entry colname="col14">0.00</oasis:entry>  
         <oasis:entry colname="col15">0.00</oasis:entry>  
         <oasis:entry colname="col16">0.01</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Na<inline-formula><mml:math id="M221" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O</oasis:entry>  
         <oasis:entry colname="col2">0.62</oasis:entry>  
         <oasis:entry colname="col3">0.86</oasis:entry>  
         <oasis:entry colname="col4">0.74</oasis:entry>  
         <oasis:entry colname="col5">0.77</oasis:entry>  
         <oasis:entry colname="col6">0.09</oasis:entry>  
         <oasis:entry colname="col7">0.66</oasis:entry>  
         <oasis:entry colname="col8">0.08</oasis:entry>  
         <oasis:entry colname="col9">0.71</oasis:entry>  
         <oasis:entry colname="col10">0.11</oasis:entry>  
         <oasis:entry colname="col11">0.87</oasis:entry>  
         <oasis:entry colname="col12">0.14</oasis:entry>  
         <oasis:entry colname="col13">0.44</oasis:entry>  
         <oasis:entry colname="col14">0.11</oasis:entry>  
         <oasis:entry colname="col15">0.32</oasis:entry>  
         <oasis:entry colname="col16">0.08</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">K<inline-formula><mml:math id="M222" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O</oasis:entry>  
         <oasis:entry colname="col2">10.16</oasis:entry>  
         <oasis:entry colname="col3">10.14</oasis:entry>  
         <oasis:entry colname="col4">10.33</oasis:entry>  
         <oasis:entry colname="col5">10.24</oasis:entry>  
         <oasis:entry colname="col6">0.17</oasis:entry>  
         <oasis:entry colname="col7">9.97</oasis:entry>  
         <oasis:entry colname="col8">0.19</oasis:entry>  
         <oasis:entry colname="col9">10.35</oasis:entry>  
         <oasis:entry colname="col10">0.21</oasis:entry>  
         <oasis:entry colname="col11">9.97</oasis:entry>  
         <oasis:entry colname="col12">0.26</oasis:entry>  
         <oasis:entry colname="col13">10.56</oasis:entry>  
         <oasis:entry colname="col14">0.26</oasis:entry>  
         <oasis:entry colname="col15">10.77</oasis:entry>  
         <oasis:entry colname="col16">0.25</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">Total</oasis:entry>  
         <oasis:entry colname="col2">93.87</oasis:entry>  
         <oasis:entry colname="col3">92.35</oasis:entry>  
         <oasis:entry colname="col4">95.51</oasis:entry>  
         <oasis:entry colname="col5">95.54</oasis:entry>  
         <oasis:entry colname="col6">–</oasis:entry>  
         <oasis:entry colname="col7">94.26</oasis:entry>  
         <oasis:entry colname="col8">–</oasis:entry>  
         <oasis:entry colname="col9">95.25</oasis:entry>  
         <oasis:entry colname="col10">–</oasis:entry>  
         <oasis:entry colname="col11">93.37</oasis:entry>  
         <oasis:entry colname="col12">–</oasis:entry>  
         <oasis:entry colname="col13">95.56</oasis:entry>  
         <oasis:entry colname="col14">–</oasis:entry>  
         <oasis:entry colname="col15">94.93</oasis:entry>  
         <oasis:entry colname="col16">–</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry namest="col1" nameend="col15" colsep="0">Formulae based on 11 oxygens </oasis:entry>  
         <oasis:entry colname="col16"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Si</oasis:entry>  
         <oasis:entry colname="col2">3.46</oasis:entry>  
         <oasis:entry colname="col3">3.38</oasis:entry>  
         <oasis:entry colname="col4">3.44</oasis:entry>  
         <oasis:entry colname="col5">3.37</oasis:entry>  
         <oasis:entry colname="col6">0.02</oasis:entry>  
         <oasis:entry colname="col7">3.35</oasis:entry>  
         <oasis:entry colname="col8">0.02</oasis:entry>  
         <oasis:entry colname="col9">3.29</oasis:entry>  
         <oasis:entry colname="col10">0.03</oasis:entry>  
         <oasis:entry colname="col11">3.36</oasis:entry>  
         <oasis:entry colname="col12">0.03</oasis:entry>  
         <oasis:entry colname="col13">3.40</oasis:entry>  
         <oasis:entry colname="col14">0.04</oasis:entry>  
         <oasis:entry colname="col15">3.27</oasis:entry>  
         <oasis:entry colname="col16">0.04</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Ti</oasis:entry>  
         <oasis:entry colname="col2">0.02</oasis:entry>  
         <oasis:entry colname="col3">0.03</oasis:entry>  
         <oasis:entry colname="col4">0.03</oasis:entry>  
         <oasis:entry colname="col5">0.01</oasis:entry>  
         <oasis:entry colname="col6">0.00</oasis:entry>  
         <oasis:entry colname="col7">0.02</oasis:entry>  
         <oasis:entry colname="col8">0.00</oasis:entry>  
         <oasis:entry colname="col9">0.01</oasis:entry>  
         <oasis:entry colname="col10">0.00</oasis:entry>  
         <oasis:entry colname="col11">0.01</oasis:entry>  
         <oasis:entry colname="col12">0.00</oasis:entry>  
         <oasis:entry colname="col13">0.01</oasis:entry>  
         <oasis:entry colname="col14">0.00</oasis:entry>  
         <oasis:entry colname="col15">0.01</oasis:entry>  
         <oasis:entry colname="col16">0.00</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al</oasis:entry>  
         <oasis:entry colname="col2">2.12</oasis:entry>  
         <oasis:entry colname="col3">2.17</oasis:entry>  
         <oasis:entry colname="col4">2.09</oasis:entry>  
         <oasis:entry colname="col5">2.20</oasis:entry>  
         <oasis:entry colname="col6">0.01</oasis:entry>  
         <oasis:entry colname="col7">2.19</oasis:entry>  
         <oasis:entry colname="col8">0.03</oasis:entry>  
         <oasis:entry colname="col9">2.34</oasis:entry>  
         <oasis:entry colname="col10">0.03</oasis:entry>  
         <oasis:entry colname="col11">2.23</oasis:entry>  
         <oasis:entry colname="col12">0.04</oasis:entry>  
         <oasis:entry colname="col13">2.16</oasis:entry>  
         <oasis:entry colname="col14">0.05</oasis:entry>  
         <oasis:entry colname="col15">2.39</oasis:entry>  
         <oasis:entry colname="col16">0.05</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Fe</oasis:entry>  
         <oasis:entry colname="col2">0.09</oasis:entry>  
         <oasis:entry colname="col3">0.08</oasis:entry>  
         <oasis:entry colname="col4">0.09</oasis:entry>  
         <oasis:entry colname="col5">0.08</oasis:entry>  
         <oasis:entry colname="col6">0.00</oasis:entry>  
         <oasis:entry colname="col7">0.12</oasis:entry>  
         <oasis:entry colname="col8">0.02</oasis:entry>  
         <oasis:entry colname="col9">0.08</oasis:entry>  
         <oasis:entry colname="col10">0.01</oasis:entry>  
         <oasis:entry colname="col11">0.07</oasis:entry>  
         <oasis:entry colname="col12">0.02</oasis:entry>  
         <oasis:entry colname="col13">0.18</oasis:entry>  
         <oasis:entry colname="col14">0.01</oasis:entry>  
         <oasis:entry colname="col15">0.15</oasis:entry>  
         <oasis:entry colname="col16">0.02</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Mn</oasis:entry>  
         <oasis:entry colname="col2">0.00</oasis:entry>  
         <oasis:entry colname="col3">0.00</oasis:entry>  
         <oasis:entry colname="col4">0.00</oasis:entry>  
         <oasis:entry colname="col5">0.00</oasis:entry>  
         <oasis:entry colname="col6">0.00</oasis:entry>  
         <oasis:entry colname="col7">0.01</oasis:entry>  
         <oasis:entry colname="col8">0.00</oasis:entry>  
         <oasis:entry colname="col9">0.00</oasis:entry>  
         <oasis:entry colname="col10">0.00</oasis:entry>  
         <oasis:entry colname="col11">0.00</oasis:entry>  
         <oasis:entry colname="col12">0.00</oasis:entry>  
         <oasis:entry colname="col13">0.00</oasis:entry>  
         <oasis:entry colname="col14">0.00</oasis:entry>  
         <oasis:entry colname="col15">0.01</oasis:entry>  
         <oasis:entry colname="col16">0.00</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Mg</oasis:entry>  
         <oasis:entry colname="col2">0.30</oasis:entry>  
         <oasis:entry colname="col3">0.35</oasis:entry>  
         <oasis:entry colname="col4">0.34</oasis:entry>  
         <oasis:entry colname="col5">0.36</oasis:entry>  
         <oasis:entry colname="col6">0.01</oasis:entry>  
         <oasis:entry colname="col7">0.37</oasis:entry>  
         <oasis:entry colname="col8">0.02</oasis:entry>  
         <oasis:entry colname="col9">0.33</oasis:entry>  
         <oasis:entry colname="col10">0.02</oasis:entry>  
         <oasis:entry colname="col11">0.35</oasis:entry>  
         <oasis:entry colname="col12">0.02</oasis:entry>  
         <oasis:entry colname="col13">0.28</oasis:entry>  
         <oasis:entry colname="col14">0.03</oasis:entry>  
         <oasis:entry colname="col15">0.23</oasis:entry>  
         <oasis:entry colname="col16">0.02</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Ca</oasis:entry>  
         <oasis:entry colname="col2">0.00</oasis:entry>  
         <oasis:entry colname="col3">0.00</oasis:entry>  
         <oasis:entry colname="col4">0.00</oasis:entry>  
         <oasis:entry colname="col5">0.00</oasis:entry>  
         <oasis:entry colname="col6">0.00</oasis:entry>  
         <oasis:entry colname="col7">0.01</oasis:entry>  
         <oasis:entry colname="col8">0.00</oasis:entry>  
         <oasis:entry colname="col9">0.00</oasis:entry>  
         <oasis:entry colname="col10">0.00</oasis:entry>  
         <oasis:entry colname="col11">0.00</oasis:entry>  
         <oasis:entry colname="col12">0.00</oasis:entry>  
         <oasis:entry colname="col13">0.00</oasis:entry>  
         <oasis:entry colname="col14">0.00</oasis:entry>  
         <oasis:entry colname="col15">0.00</oasis:entry>  
         <oasis:entry colname="col16">0.00</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Na</oasis:entry>  
         <oasis:entry colname="col2">0.08</oasis:entry>  
         <oasis:entry colname="col3">0.11</oasis:entry>  
         <oasis:entry colname="col4">0.10</oasis:entry>  
         <oasis:entry colname="col5">0.10</oasis:entry>  
         <oasis:entry colname="col6">0.01</oasis:entry>  
         <oasis:entry colname="col7">0.09</oasis:entry>  
         <oasis:entry colname="col8">0.01</oasis:entry>  
         <oasis:entry colname="col9">0.09</oasis:entry>  
         <oasis:entry colname="col10">0.01</oasis:entry>  
         <oasis:entry colname="col11">0.11</oasis:entry>  
         <oasis:entry colname="col12">0.02</oasis:entry>  
         <oasis:entry colname="col13">0.06</oasis:entry>  
         <oasis:entry colname="col14">0.01</oasis:entry>  
         <oasis:entry colname="col15">0.04</oasis:entry>  
         <oasis:entry colname="col16">0.01</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">K</oasis:entry>  
         <oasis:entry colname="col2">0.87</oasis:entry>  
         <oasis:entry colname="col3">0.89</oasis:entry>  
         <oasis:entry colname="col4">0.87</oasis:entry>  
         <oasis:entry colname="col5">0.87</oasis:entry>  
         <oasis:entry colname="col6">0.01</oasis:entry>  
         <oasis:entry colname="col7">0.86</oasis:entry>  
         <oasis:entry colname="col8">0.02</oasis:entry>  
         <oasis:entry colname="col9">0.88</oasis:entry>  
         <oasis:entry colname="col10">0.02</oasis:entry>  
         <oasis:entry colname="col11">0.86</oasis:entry>  
         <oasis:entry colname="col12">0.02</oasis:entry>  
         <oasis:entry colname="col13">0.90</oasis:entry>  
         <oasis:entry colname="col14">0.02</oasis:entry>  
         <oasis:entry colname="col15">0.93</oasis:entry>  
         <oasis:entry colname="col16">0.02</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"><inline-formula><mml:math id="M223" display="inline"><mml:mo>∑</mml:mo></mml:math></inline-formula> cations</oasis:entry>  
         <oasis:entry colname="col2">6.94</oasis:entry>  
         <oasis:entry colname="col3">7.01</oasis:entry>  
         <oasis:entry colname="col4">6.97</oasis:entry>  
         <oasis:entry colname="col5">7.00</oasis:entry>  
         <oasis:entry colname="col6">–</oasis:entry>  
         <oasis:entry colname="col7">7.01</oasis:entry>  
         <oasis:entry colname="col8">–</oasis:entry>  
         <oasis:entry colname="col9">7.02</oasis:entry>  
         <oasis:entry colname="col10">–</oasis:entry>  
         <oasis:entry colname="col11">7.00</oasis:entry>  
         <oasis:entry colname="col12">–</oasis:entry>  
         <oasis:entry colname="col13">6.99</oasis:entry>  
         <oasis:entry colname="col14">–</oasis:entry>  
         <oasis:entry colname="col15">7.02</oasis:entry>  
         <oasis:entry colname="col16">–</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">XMg</oasis:entry>  
         <oasis:entry colname="col2">0.76</oasis:entry>  
         <oasis:entry colname="col3">0.81</oasis:entry>  
         <oasis:entry colname="col4">0.79</oasis:entry>  
         <oasis:entry colname="col5">0.82</oasis:entry>  
         <oasis:entry colname="col6">0.012</oasis:entry>  
         <oasis:entry colname="col7">0.76</oasis:entry>  
         <oasis:entry colname="col8">0.04</oasis:entry>  
         <oasis:entry colname="col9">0.81</oasis:entry>  
         <oasis:entry colname="col10">0.02</oasis:entry>  
         <oasis:entry colname="col11">0.83</oasis:entry>  
         <oasis:entry colname="col12">0.05</oasis:entry>  
         <oasis:entry colname="col13">0.61</oasis:entry>  
         <oasis:entry colname="col14">0.03</oasis:entry>  
         <oasis:entry colname="col15">0.61</oasis:entry>  
         <oasis:entry colname="col16">0.03</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S5.SS1.SSS3">
  <title>Isochemical phase diagrams (pseudosections)</title>
      <p id="d1e5499">Isochemical equilibrium phase diagrams were computed using the Gibbs free
energy minimization algorithm Theriak–Domino (de Capitani and Brown, 1987; de
Capitani and Petrakakis, 2010). The
thermodynamic database of Berman (1988) with subsequent updates
collected in JUN92.bs (distributed with Theriak–Domino 3 December 2012;
Supplement S3) was used, together with the following solution models:
Berman (1990) for garnet, Fuhrman and Lindsley (1988) for
feldspar, Meyre et al. (1997) for omphacite, Keller et
al. (2005) for white mica, and ideal mixing models for amphibole
(Mäder and Berman, 1992; Mäder et al., 1994), epidote, and
chlorite (Hunziker, 2003). All Gibbs free energy minimizations were carried
out assuming an excess in pure H<inline-formula><mml:math id="M224" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O fluid. The amount of H<inline-formula><mml:math id="M225" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O
component predicted at HP is in line with the measured loss of
ignition
(1.4–2.7 wt %) in the present-day samples. Note that for the pre-Alpine
HT computations no melt model was used. Fe<inline-formula><mml:math id="M226" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> was ignored because of the
lack of analytical data and suitable ferric endmembers in solid solution
models.<?xmltex \hack{\newpage}?></p>
</sec>
<sec id="Ch1.S5.SS1.SSS4">
  <title>Chlorite and white mica multi-equilibrium</title>
      <p id="d1e5539">To constrain the <inline-formula><mml:math id="M227" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M228" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions of retrograde stages, multi-equilibrium
computations of the high-variance assemblages involving chlorite and white
mica were carried out, using the standard state properties and solid
solution models of Vidal et al. (2005, 2006) for chlorite,
Dubacq et al. (2010) for phengite, and the program
ChlMicaEqui (Lanari, 2012). The activity of H<inline-formula><mml:math id="M229" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O was set
to unity. Three methods were successively employed:
<list list-type="order"><list-item>
      <p id="d1e5567"><italic>Chlorite</italic> <inline-formula><mml:math id="M230" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> <italic>quartz</italic> <inline-formula><mml:math id="M231" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:msub><mml:mi>H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi>O</mml:mi></mml:mrow></mml:math></inline-formula> <italic>thermometry</italic>. The chlorite formation temperature and XFe<inline-formula><mml:math id="M232" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> were
estimated at a fixed pressure of 1 GPa from the combination of four
equilibria involving five chlorite endmembers, quartz, and H<inline-formula><mml:math id="M233" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O
(Lanari et al., 2012; Vidal et al., 2016).</p></list-item><list-item>
      <p id="d1e5623"><italic>White mica</italic> <inline-formula><mml:math id="M234" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> <italic>quartz</italic> <inline-formula><mml:math id="M235" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:msub><mml:mi>H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi>O</mml:mi></mml:mrow></mml:math></inline-formula> <italic>barometry</italic>. A divariant <inline-formula><mml:math id="M236" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M237" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> equilibrium line was estimated for each white
mica analysis (assuming XFe<inline-formula><mml:math id="M238" display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 0) from the convergence of three
equilibria involving five phengite endmembers, quartz, and H<inline-formula><mml:math id="M239" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O
(Dubacq et al., 2010).</p></list-item><list-item>
      <p id="d1e5696"><italic>Chlorite</italic> <inline-formula><mml:math id="M240" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> <italic>white mica</italic> <inline-formula><mml:math id="M241" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> <italic>quartz</italic> <inline-formula><mml:math id="M242" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msub><mml:mi>H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi>O</mml:mi></mml:mrow></mml:math></inline-formula> <italic>thermobarometry</italic>. <inline-formula><mml:math id="M243" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M244" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> of formation for each chlorite and white mica
couple, as well as their respective XFe<inline-formula><mml:math id="M245" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> values, were estimated by minimizing
the square root of the sum of (<inline-formula><mml:math id="M246" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>G</mml:mi><mml:mi mathvariant="normal">reaction</mml:mi></mml:msub><mml:msup><mml:mo>)</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> for six
equilibria (see Supplement S4).</p></list-item></list>
For the sake of clarity, only 64 equilibria (excluding the
pyrophyllite <inline-formula><mml:math id="M247" display="inline"><mml:mo>⋅</mml:mo></mml:math></inline-formula> 1H<inline-formula><mml:math id="M248" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O endmember) are shown in the <inline-formula><mml:math id="M249" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M250" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> diagrams.
The starting guess for <inline-formula><mml:math id="M251" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M252" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> was taken from the result of
chlorite <inline-formula><mml:math id="M253" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M254" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M255" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O thermometry and white mica <inline-formula><mml:math id="M256" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M257" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M258" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O
barometry. This multi-equilibrium approach relies on the assumption of local
thermodynamic equilibrium between the selected chlorite and white mica at
the <inline-formula><mml:math id="M259" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M260" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions of convergence. Chlorite and white mica couples in which microtextural evidence suggested equilibrium, notably where
sharp contacts were observed between these sheet silicates, were
chosen.</p>
</sec>
</sec>
<sec id="Ch1.S5.SS2">
  <title>Bulk rock and reactive bulk composition</title>
      <p id="d1e5900">For samples FG1324 and FG1420 the original bulk rock compositions obtained
using XRF were used to compute isochemical phase diagrams. In samples FG1315,
FG12157, FG1347, and FG1249, however, the unmodified bulk rock composition
cannot be used for modelling because a significantly high volume fraction of
garnet is present (5–10 vol %), including a pre-Alpine core and Alpine
rim generations. To compute equilibrium diagrams properly, the reactive
bulk rock composition was approximated using the program GrtMod
(see Sect. 5.1.2). Each isochemical phase diagram is thus valid for a
single <inline-formula><mml:math id="M261" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M262" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> stage only. To select the reactive bulk composition of this
specific stage, a link must be established between the particular garnet
generation that formed in equilibrium with the mineral phases present in the
matrix and the mineral phases. We established this link using petrographic observations, including
textural equilibrium criteria, compositional zoning (visible in
compositional maps), and inclusion relationships. Specifically, we
determined that the garnet growth zones that coexisted with the mineral
matrix are as follows: garnet Rim3 for sample FG1315, Rim1 for sample
FG12157, Rim3 for sample FG1347, and Rim2 for sample FG1249. The
corresponding reactive bulk compositions used for the modelling are provided
in the Supplement S5.</p>
</sec>
<sec id="Ch1.S5.SS3">
  <title>Results: garnet thermobarometry and phase diagrams</title>
      <p id="d1e5923">Figure 4 shows isochemical <inline-formula><mml:math id="M263" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M264" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> phase diagrams for each sample. The plots show
the results of garnet thermobarometry (GrtMod), garnet isopleths
(<inline-formula><mml:math id="M265" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Grs</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M266" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Alm</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M267" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Prp</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in sample FG1324), and <inline-formula><mml:math id="M268" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and Si
(apfu) isopleths for phengite. For sample FG1420, results of chlorite–white mica thermobarometry are also displayed. A summary of mineral
compositional data for the main phases, the modelling method used, the XRF
analyses of major elements of each sample, and details of the GrtMod results
are available as Supplement S5–S7 and S8, respectively. Each sample from
the IC and EC is presented separately below.</p>
<sec id="Ch1.S5.SS3.SSS1">
  <title>IC – FG1324 omphacite, garnet, glaucophane, and rutile mica schist</title>
      <p id="d1e5990">Garnet isopleths (Alm, Grs, Prp) intersect in two areas of the <inline-formula><mml:math id="M269" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M270" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> diagram:
at 1.65–1.75 GPa and 600–650 <inline-formula><mml:math id="M271" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C and at 1.9–2 GPa and
<inline-formula><mml:math id="M272" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 550 <inline-formula><mml:math id="M273" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Assuming equilibrium between garnet and
phengite, these conditions can be further constrained by matching this
result with the Si and <inline-formula><mml:math id="M274" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> isopleths of phengite (measured values:
3.38–3.46 and 0.76–0.81, respectively). Phengite isopleths match the garnet
composition at 1.65–1.75 GPa and 600–650 <inline-formula><mml:math id="M275" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (Fig. 4a). Under these
conditions, some discrepancies between observations and modelled assemblages
are noted for this sample: paragonite instead of glaucophane is predicted to
be stable in the model (probably because no solid solution model for sodic
amphiboles is available in the thermodynamic database used). Also, 6 vol %
biotite is predicted to be stable, whereas none was observed in thin
section.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><caption><p id="d1e6055">Equilibrium phase diagrams of the studied samples computed
with Theriak–Domino, assuming a free H<inline-formula><mml:math id="M276" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O fluid,
between 1.3 and 2 GPa and between 400 and 700 <inline-formula><mml:math id="M277" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for <bold>(a–e)</bold> and
between 0.3 and 1.5 GPa and between 200 and 600 <inline-formula><mml:math id="M278" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for <bold>(f)</bold>. The error bars
departing from filled ellipses show the <inline-formula><mml:math id="M279" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M280" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> uncertainty related to the
analytical error of the garnet composition.</p></caption>
            <?xmltex \igopts{width=298.753937pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f04.jpg"/>

          </fig>

</sec>
<sec id="Ch1.S5.SS3.SSS2">
  <title>IC – FG1315 garnet, epidote, and rutile quartz–mica schist</title>
      <p id="d1e6118">The garnet core is found to be stable at 0.82 GPa and 750 <inline-formula><mml:math id="M281" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C,
with a crystallization of <inline-formula><mml:math id="M282" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 14 vol % (details available in
Supplement S5 and S8). The first garnet rim is predicted stable at
<inline-formula><mml:math id="M283" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.5 GPa and 650 <inline-formula><mml:math id="M284" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, with a resorption of
<inline-formula><mml:math id="M285" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.7 vol % garnet core and crystallization of
<inline-formula><mml:math id="M286" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 5.5 vol % Rim1. The second and third garnet rims are found
to be stable at similar conditions: 1.9 GPa and 650 <inline-formula><mml:math id="M287" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C and 1.8 GPa
(resorption of 2.3, 2.5 vol % core and Rim1, crystallization of 5.6 vol % Rim2)
and at 670 <inline-formula><mml:math id="M288" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (resorption of 5, 0.4, and 3.1 vol % core, Rim1, and Rim2, plus crystallization of 8.6 vol % Rim3). <inline-formula><mml:math id="M289" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M290" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>
conditions of Rim2 and 3 match with the intersection of Si (3.37–3.40) and
<inline-formula><mml:math id="M291" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (0.80–0.82; Fig. 4b) isopleths of phengite. The predicted
assemblage conforms to the minerals observed in thin section (Supplement S1, S5).</p>
</sec>
<sec id="Ch1.S5.SS3.SSS3">
  <title>IC – FG12157 garnet, glaucophane, epidote, and rutile mica schist</title>
      <p id="d1e6217">In this model, <inline-formula><mml:math id="M292" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 7 vol % of garnet is modelled to be stable at 0.6 GPa and 900 <inline-formula><mml:math id="M293" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C; its composition corresponds to the garnet core.
The first garnet rim is predicted to be stable at 1.6 GPa – 650 <inline-formula><mml:math id="M294" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
(resorption of <inline-formula><mml:math id="M295" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.4 vol % garnet core and crystallization
of <inline-formula><mml:math id="M296" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 10.8 vol % Rim1), in agreement with the intersection of
phengite isopleths for the observed values of Si (3.34–3.38) and <inline-formula><mml:math id="M297" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
(0.76–0.82; Fig. 4c). Crossite rims around glaucophane in this sample mark a
decompression stage; this may correlate with the second rim in garnet,
which is found to be stable at 1.4 GPa and 650 <inline-formula><mml:math id="M298" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (resorption of
1.5 vol % core, 7.3 vol % Rim1, and crystallization of 10.6 vol %
Rim2). An amount of 4–6 % biotite is predicted to be stable, but none is observed in
thin section.</p>
</sec>
<sec id="Ch1.S5.SS3.SSS4">
  <title>IC – FG1347 chloritoid, garnet, and rutile mica schist</title>
      <p id="d1e6287">The garnet core is modelled to be stable at 0.8 GPa and 780 <inline-formula><mml:math id="M299" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, with a
crystallization of <inline-formula><mml:math id="M300" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 17.7 vol %. The three garnet rims show
similar <inline-formula><mml:math id="M301" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M302" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions: 1.9 GPa, 590 <inline-formula><mml:math id="M303" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (resorption of
<inline-formula><mml:math id="M304" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.6 vol % garnet core and crystallization of
<inline-formula><mml:math id="M305" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2.8 vol % Rim1); 1.8 GPa, 600 <inline-formula><mml:math id="M306" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (resorption of
3.2 vol % core, 1.4 vol % Rim1, and crystallization of 5 vol % Rim2); 2.0 GPa , 600 <inline-formula><mml:math id="M307" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (crystallization of 2 vol % Rim3). <inline-formula><mml:math id="M308" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M309" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>
estimates for the garnet rims are in perfect agreement with the intersection
of phengite isopleths at Si apfu (3.29–3.33) and <inline-formula><mml:math id="M310" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (0.78–0.82; Fig. 4d).
The predicted assemblage matches the minerals observed, except that
kyanite (3 vol % predicted) was not detected in thin section.</p>
</sec>
<sec id="Ch1.S5.SS3.SSS5">
  <title>IC – FG1249 garnet, epidote, and rutile mica schist</title>
      <p id="d1e6394">The garnet core is modelled to be stable at 0.6 GPa and 730 <inline-formula><mml:math id="M311" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, with
crystallization of <inline-formula><mml:math id="M312" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 10 vol % garnet. Rim1 is modelled to be
stable at 0.6 GPa and 620 <inline-formula><mml:math id="M313" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (resorption of <inline-formula><mml:math id="M314" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 vol % garnet core and crystallization of <inline-formula><mml:math id="M315" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 vol % Rim1).
The second rim is related to the peak pressure recorded by this sample (1.63
GPa and 615 <inline-formula><mml:math id="M316" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C with resorption of 0.2 vol % core and 0.05 vol %
Rim1, plus crystallization of 10 vol % Rim2); conditions are in agreement
with the Si apfu (3.35–3.4) and <inline-formula><mml:math id="M317" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (0.77–0.83; Fig. 4e) compositions
of phengite. The last rim recorded may mark the thermal peak at lower
pressure (1.56 GPa, 660 <inline-formula><mml:math id="M318" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) with garnet resorption (6.9 vol %
Rim2) and growth (8.6 vol % Rim3).<?xmltex \hack{\newpage}?></p>
</sec>
<sec id="Ch1.S5.SS3.SSS6">
  <title>EC – FG1420 garnet orthogneiss</title>
      <p id="d1e6473">The garnet core is found to be stable at 0.48 GPa and 490 <inline-formula><mml:math id="M319" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, Rim1 at
0.67 GPa and 500 <inline-formula><mml:math id="M320" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, Rim2 at 0.73 GPa and 510 <inline-formula><mml:math id="M321" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, and
Rim3 at 0.8 GPa and 520 <inline-formula><mml:math id="M322" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, with a total amount of 4.8 vol %
garnet.</p>
      <p id="d1e6512">Two phengite generations are present (Sect. 4.3; Fig. 3f): phengite
describing the main foliation, with higher silica content, displays Si apfu
and <inline-formula><mml:math id="M323" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">Mg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> isopleth intersection at <inline-formula><mml:math id="M324" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.4 GPa and 550 <inline-formula><mml:math id="M325" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. These conditions are not substantiated by the mineral
assemblage, which is predicted to contain omphacite and rutile, but neither
phase was observed in thin section. Also, under these <inline-formula><mml:math id="M326" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M327" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions further
garnet growth is predicted, with a modal increase from 6.5 to &gt; 7.5 vol %, but no garnet is observed with a composition compatible with
these <inline-formula><mml:math id="M328" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M329" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions. We suspect that phengite grew at lower <inline-formula><mml:math id="M330" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M331" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions,
as the appropriate Si apfu values intersect the <inline-formula><mml:math id="M332" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M333" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> results derived from
white mica <inline-formula><mml:math id="M334" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M335" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M336" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O barometry at 0.6–0.8 GPa and 350–400 <inline-formula><mml:math id="M337" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (Fig. 4f; more details in the next section).</p>
      <p id="d1e6632">The second generation of phengite, post-dating the main foliation, shows Si
values for which the isopleths intersect with the results derived from white
mica <inline-formula><mml:math id="M338" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M339" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M340" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O barometry at 0.55–0.75 GPa and 300–350 <inline-formula><mml:math id="M341" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><caption><p id="d1e6669">Multi-equilibrium thermobarometry results for the IC
samples. Panels <bold>(a, c)</bold> and <bold>(e)</bold> show the intersection of the results deriving from
chlorite <inline-formula><mml:math id="M342" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M343" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M344" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O
thermometry with white mica <inline-formula><mml:math id="M345" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M346" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M347" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O
barometry. Panels <bold>(b, d)</bold> and <bold>(f)</bold> show results of
chlorite <inline-formula><mml:math id="M348" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> white mica <inline-formula><mml:math id="M349" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M350" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M351" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O
thermobarometry.</p></caption>
            <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f05.png"/>

          </fig>

</sec>
</sec>
<sec id="Ch1.S5.SS4">
  <title>Results: multi-equilibrium thermobarometry</title>
<sec id="Ch1.S5.SS4.SSS1">
  <title>IC – FG1315 garnet, epidote, and rutile quartz–mica schist</title>
      <p id="d1e6780">Chlorite in this sample is retrograde and records formation temperatures
decreasing from 450 <inline-formula><mml:math id="M352" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C to 300 <inline-formula><mml:math id="M353" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (Fig. 5a). White mica <inline-formula><mml:math id="M354" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M355" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M356" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O barometry suggests pressures comprised between 1.5
and 0.4 GPa for the temperature range of chlorite. Chlorite and white mica
grains in textural equilibrium were used to constrain the equilibrium
conditions at 0.8 <inline-formula><mml:math id="M357" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.2 GPa and 340 <inline-formula><mml:math id="M358" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 50 <inline-formula><mml:math id="M359" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for the
retrograde stage (Fig. 5b; Tables 3 and 4).</p>
</sec>
<sec id="Ch1.S5.SS4.SSS2">
  <title>IC – FG12157 garnet, glaucophane, epidote, and rutile mica schist</title>
      <p id="d1e6854">Chlorite records formation temperatures decreasing from 430 to
310 <inline-formula><mml:math id="M360" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (Fig. 5c). White mica <inline-formula><mml:math id="M361" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M362" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M363" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O barometry
finds pressures between 0.02 and 1 GPa for the temperature range shown by
chlorite. Chlorite and white mica grains in textural equilibrium are used to
approximate equilibrium conditions at 0.54 <inline-formula><mml:math id="M364" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.2 GPa and 394 <inline-formula><mml:math id="M365" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 50 <inline-formula><mml:math id="M366" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for the retrograde stage (Fig. 5d).</p>
</sec>
<sec id="Ch1.S5.SS4.SSS3">
  <title>IC – FG1347 chloritoid, garnet, and rutile mica schist</title>
      <p id="d1e6919">Chlorite registers temperatures from 370 to 250 <inline-formula><mml:math id="M367" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
(Fig. 5e). White mica <inline-formula><mml:math id="M368" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M369" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M370" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O barometry indicates pressures
between 0.02 and 1 GPa for the temperature range of chlorite. Chlorite and
white mica grains record 0.78 <inline-formula><mml:math id="M371" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.2 GPa and 341 <inline-formula><mml:math id="M372" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 50 <inline-formula><mml:math id="M373" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for the retrograde stage (Fig. 5f).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T3" specific-use="star"><caption><p id="d1e6981">Representative analyses of chlorite used in the
multi-equilibrium calculations</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="10">
     <oasis:colspec colnum="1" colname="col1" align="left" colsep="1"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right" colsep="1"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right" colsep="1"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right" colsep="1"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Sample</oasis:entry>  
         <oasis:entry namest="col2" nameend="col3" align="center" colsep="1">IC – FG1315 </oasis:entry>  
         <oasis:entry namest="col4" nameend="col5" align="center" colsep="1">IC – FG12157 </oasis:entry>  
         <oasis:entry namest="col6" nameend="col7" align="center" colsep="1">IC – FG1347 </oasis:entry>  
         <oasis:entry namest="col8" nameend="col10" align="center">EC – FG1420 </oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Chl</oasis:entry>  
         <oasis:entry namest="col2" nameend="col3" align="center" colsep="1">  </oasis:entry>  
         <oasis:entry namest="col4" nameend="col5" align="center" colsep="1">  </oasis:entry>  
         <oasis:entry namest="col6" nameend="col7" align="center">  </oasis:entry>  
         <oasis:entry colname="col8">Grp1</oasis:entry>  
         <oasis:entry colname="col9">Grp2</oasis:entry>  
         <oasis:entry colname="col10">Grp3</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">Chl-</oasis:entry>  
         <oasis:entry colname="col3">Chl-</oasis:entry>  
         <oasis:entry colname="col4">Chl-</oasis:entry>  
         <oasis:entry colname="col5">Chl-</oasis:entry>  
         <oasis:entry colname="col6">Chl-</oasis:entry>  
         <oasis:entry colname="col7">Chl-</oasis:entry>  
         <oasis:entry colname="col8">Chl-</oasis:entry>  
         <oasis:entry colname="col9">Chl-</oasis:entry>  
         <oasis:entry colname="col10">Chl-</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">35093</oasis:entry>  
         <oasis:entry colname="col3">35092</oasis:entry>  
         <oasis:entry colname="col4">204162</oasis:entry>  
         <oasis:entry colname="col5">204794</oasis:entry>  
         <oasis:entry colname="col6">214479</oasis:entry>  
         <oasis:entry colname="col7">215870</oasis:entry>  
         <oasis:entry colname="col8">910650</oasis:entry>  
         <oasis:entry colname="col9">547806</oasis:entry>  
         <oasis:entry colname="col10">881538</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">SiO<inline-formula><mml:math id="M374" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">25.64</oasis:entry>  
         <oasis:entry colname="col3">26.22</oasis:entry>  
         <oasis:entry colname="col4">25.81</oasis:entry>  
         <oasis:entry colname="col5">25.91</oasis:entry>  
         <oasis:entry colname="col6">24.91</oasis:entry>  
         <oasis:entry colname="col7">25.62</oasis:entry>  
         <oasis:entry colname="col8">25.11</oasis:entry>  
         <oasis:entry colname="col9">25.91</oasis:entry>  
         <oasis:entry colname="col10">25.45</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al<inline-formula><mml:math id="M375" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O<inline-formula><mml:math id="M376" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">19.62</oasis:entry>  
         <oasis:entry colname="col3">19.71</oasis:entry>  
         <oasis:entry colname="col4">20.64</oasis:entry>  
         <oasis:entry colname="col5">20.1</oasis:entry>  
         <oasis:entry colname="col6">21.7</oasis:entry>  
         <oasis:entry colname="col7">20.97</oasis:entry>  
         <oasis:entry colname="col8">20.09</oasis:entry>  
         <oasis:entry colname="col9">21.63</oasis:entry>  
         <oasis:entry colname="col10">20.34</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FeO</oasis:entry>  
         <oasis:entry colname="col2">26.29</oasis:entry>  
         <oasis:entry colname="col3">26.68</oasis:entry>  
         <oasis:entry colname="col4">24.53</oasis:entry>  
         <oasis:entry colname="col5">27.34</oasis:entry>  
         <oasis:entry colname="col6">24.96</oasis:entry>  
         <oasis:entry colname="col7">26.45</oasis:entry>  
         <oasis:entry colname="col8">26.87</oasis:entry>  
         <oasis:entry colname="col9">28.98</oasis:entry>  
         <oasis:entry colname="col10">25.53</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MnO</oasis:entry>  
         <oasis:entry colname="col2">0.05</oasis:entry>  
         <oasis:entry colname="col3">0.05</oasis:entry>  
         <oasis:entry colname="col4">0.21</oasis:entry>  
         <oasis:entry colname="col5">0.33</oasis:entry>  
         <oasis:entry colname="col6">0.11</oasis:entry>  
         <oasis:entry colname="col7">0.19</oasis:entry>  
         <oasis:entry colname="col8">0.28</oasis:entry>  
         <oasis:entry colname="col9">0.31</oasis:entry>  
         <oasis:entry colname="col10">0.27</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MgO</oasis:entry>  
         <oasis:entry colname="col2">15.32</oasis:entry>  
         <oasis:entry colname="col3">15.82</oasis:entry>  
         <oasis:entry colname="col4">15.87</oasis:entry>  
         <oasis:entry colname="col5">14.32</oasis:entry>  
         <oasis:entry colname="col6">13.51</oasis:entry>  
         <oasis:entry colname="col7">13.49</oasis:entry>  
         <oasis:entry colname="col8">13.01</oasis:entry>  
         <oasis:entry colname="col9">12.61</oasis:entry>  
         <oasis:entry colname="col10">12.61</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">CaO</oasis:entry>  
         <oasis:entry colname="col2">0.05</oasis:entry>  
         <oasis:entry colname="col3">0.06</oasis:entry>  
         <oasis:entry colname="col4">0.03</oasis:entry>  
         <oasis:entry colname="col5">0.03</oasis:entry>  
         <oasis:entry colname="col6">0.13</oasis:entry>  
         <oasis:entry colname="col7">0.09</oasis:entry>  
         <oasis:entry colname="col8">0.08</oasis:entry>  
         <oasis:entry colname="col9">0.09</oasis:entry>  
         <oasis:entry colname="col10">0.17</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Na<inline-formula><mml:math id="M377" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O</oasis:entry>  
         <oasis:entry colname="col2">0.05</oasis:entry>  
         <oasis:entry colname="col3">0.03</oasis:entry>  
         <oasis:entry colname="col4">0.04</oasis:entry>  
         <oasis:entry colname="col5">0.03</oasis:entry>  
         <oasis:entry colname="col6">0</oasis:entry>  
         <oasis:entry colname="col7">0.03</oasis:entry>  
         <oasis:entry colname="col8">0.02</oasis:entry>  
         <oasis:entry colname="col9">0.03</oasis:entry>  
         <oasis:entry colname="col10">0.03</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">K<inline-formula><mml:math id="M378" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O</oasis:entry>  
         <oasis:entry colname="col2">0.07</oasis:entry>  
         <oasis:entry colname="col3">0.06</oasis:entry>  
         <oasis:entry colname="col4">0.02</oasis:entry>  
         <oasis:entry colname="col5">0.03</oasis:entry>  
         <oasis:entry colname="col6">0.15</oasis:entry>  
         <oasis:entry colname="col7">0.22</oasis:entry>  
         <oasis:entry colname="col8">0.03</oasis:entry>  
         <oasis:entry colname="col9">0.03</oasis:entry>  
         <oasis:entry colname="col10">0.06</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">Total</oasis:entry>  
         <oasis:entry colname="col2">87.09</oasis:entry>  
         <oasis:entry colname="col3">88.63</oasis:entry>  
         <oasis:entry colname="col4">87.15</oasis:entry>  
         <oasis:entry colname="col5">88.09</oasis:entry>  
         <oasis:entry colname="col6">85.47</oasis:entry>  
         <oasis:entry colname="col7">87.06</oasis:entry>  
         <oasis:entry colname="col8">85.49</oasis:entry>  
         <oasis:entry colname="col9">89.59</oasis:entry>  
         <oasis:entry colname="col10">84.46</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry namest="col1" nameend="col10" colsep="0">Atom site distribution (14 anhydrous-oxygen basis including Fe<inline-formula><mml:math id="M379" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula>) </oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Si (T1 <inline-formula><mml:math id="M380" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> T2)</oasis:entry>  
         <oasis:entry colname="col2">2.68</oasis:entry>  
         <oasis:entry colname="col3">2.71</oasis:entry>  
         <oasis:entry colname="col4">2.70</oasis:entry>  
         <oasis:entry colname="col5">2.69</oasis:entry>  
         <oasis:entry colname="col6">2.65</oasis:entry>  
         <oasis:entry colname="col7">2.72</oasis:entry>  
         <oasis:entry colname="col8">2.73</oasis:entry>  
         <oasis:entry colname="col9">2.70</oasis:entry>  
         <oasis:entry colname="col10">2.78</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al (T2)</oasis:entry>  
         <oasis:entry colname="col2">1.32</oasis:entry>  
         <oasis:entry colname="col3">1.29</oasis:entry>  
         <oasis:entry colname="col4">1.30</oasis:entry>  
         <oasis:entry colname="col5">1.31</oasis:entry>  
         <oasis:entry colname="col6">1.34</oasis:entry>  
         <oasis:entry colname="col7">1.28</oasis:entry>  
         <oasis:entry colname="col8">1.27</oasis:entry>  
         <oasis:entry colname="col9">1.30</oasis:entry>  
         <oasis:entry colname="col10">1.22</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al (M1)</oasis:entry>  
         <oasis:entry colname="col2">0.32</oasis:entry>  
         <oasis:entry colname="col3">0.29</oasis:entry>  
         <oasis:entry colname="col4">0.30</oasis:entry>  
         <oasis:entry colname="col5">0.31</oasis:entry>  
         <oasis:entry colname="col6">0.34</oasis:entry>  
         <oasis:entry colname="col7">0.28</oasis:entry>  
         <oasis:entry colname="col8">0.27</oasis:entry>  
         <oasis:entry colname="col9">0.30</oasis:entry>  
         <oasis:entry colname="col10">0.22</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Mg (M1)</oasis:entry>  
         <oasis:entry colname="col2">0.28</oasis:entry>  
         <oasis:entry colname="col3">0.33</oasis:entry>  
         <oasis:entry colname="col4">0.35</oasis:entry>  
         <oasis:entry colname="col5">0.27</oasis:entry>  
         <oasis:entry colname="col6">0.24</oasis:entry>  
         <oasis:entry colname="col7">0.31</oasis:entry>  
         <oasis:entry colname="col8">0.30</oasis:entry>  
         <oasis:entry colname="col9">0.27</oasis:entry>  
         <oasis:entry colname="col10">0.30</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Fe<inline-formula><mml:math id="M381" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> (M1)</oasis:entry>  
         <oasis:entry colname="col2">0.20</oasis:entry>  
         <oasis:entry colname="col3">0.26</oasis:entry>  
         <oasis:entry colname="col4">0.27</oasis:entry>  
         <oasis:entry colname="col5">0.21</oasis:entry>  
         <oasis:entry colname="col6">0.21</oasis:entry>  
         <oasis:entry colname="col7">0.32</oasis:entry>  
         <oasis:entry colname="col8">0.33</oasis:entry>  
         <oasis:entry colname="col9">0.32</oasis:entry>  
         <oasis:entry colname="col10">0.32</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">V (M1)</oasis:entry>  
         <oasis:entry colname="col2">0.20</oasis:entry>  
         <oasis:entry colname="col3">0.12</oasis:entry>  
         <oasis:entry colname="col4">0.09</oasis:entry>  
         <oasis:entry colname="col5">0.21</oasis:entry>  
         <oasis:entry colname="col6">0.21</oasis:entry>  
         <oasis:entry colname="col7">0.10</oasis:entry>  
         <oasis:entry colname="col8">0.10</oasis:entry>  
         <oasis:entry colname="col9">0.11</oasis:entry>  
         <oasis:entry colname="col10">0.16</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Mg (M2 <inline-formula><mml:math id="M382" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M3)</oasis:entry>  
         <oasis:entry colname="col2">2.10</oasis:entry>  
         <oasis:entry colname="col3">2.10</oasis:entry>  
         <oasis:entry colname="col4">2.13</oasis:entry>  
         <oasis:entry colname="col5">1.95</oasis:entry>  
         <oasis:entry colname="col6">1.90</oasis:entry>  
         <oasis:entry colname="col7">1.83</oasis:entry>  
         <oasis:entry colname="col8">1.80</oasis:entry>  
         <oasis:entry colname="col9">1.69</oasis:entry>  
         <oasis:entry colname="col10">1.75</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Fe (M2 <inline-formula><mml:math id="M383" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M3)</oasis:entry>  
         <oasis:entry colname="col2">1.46</oasis:entry>  
         <oasis:entry colname="col3">1.61</oasis:entry>  
         <oasis:entry colname="col4">1.64</oasis:entry>  
         <oasis:entry colname="col5">1.57</oasis:entry>  
         <oasis:entry colname="col6">1.62</oasis:entry>  
         <oasis:entry colname="col7">1.87</oasis:entry>  
         <oasis:entry colname="col8">1.94</oasis:entry>  
         <oasis:entry colname="col9">2.03</oasis:entry>  
         <oasis:entry colname="col10">1.85</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al (M2 <inline-formula><mml:math id="M384" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M3)</oasis:entry>  
         <oasis:entry colname="col2">0.41</oasis:entry>  
         <oasis:entry colname="col3">0.26</oasis:entry>  
         <oasis:entry colname="col4">0.19</oasis:entry>  
         <oasis:entry colname="col5">0.44</oasis:entry>  
         <oasis:entry colname="col6">0.43</oasis:entry>  
         <oasis:entry colname="col7">0.24</oasis:entry>  
         <oasis:entry colname="col8">0.21</oasis:entry>  
         <oasis:entry colname="col9">0.24</oasis:entry>  
         <oasis:entry colname="col10">0.34</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al (M4)</oasis:entry>  
         <oasis:entry colname="col2">0.36</oasis:entry>  
         <oasis:entry colname="col3">0.56</oasis:entry>  
         <oasis:entry colname="col4">0.76</oasis:entry>  
         <oasis:entry colname="col5">0.41</oasis:entry>  
         <oasis:entry colname="col6">0.60</oasis:entry>  
         <oasis:entry colname="col7">0.84</oasis:entry>  
         <oasis:entry colname="col8">0.83</oasis:entry>  
         <oasis:entry colname="col9">0.82</oasis:entry>  
         <oasis:entry colname="col10">0.84</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">XMg</oasis:entry>  
         <oasis:entry colname="col2">0.59</oasis:entry>  
         <oasis:entry colname="col3">0.57</oasis:entry>  
         <oasis:entry colname="col4">0.56</oasis:entry>  
         <oasis:entry colname="col5">0.55</oasis:entry>  
         <oasis:entry colname="col6">0.54</oasis:entry>  
         <oasis:entry colname="col7">0.49</oasis:entry>  
         <oasis:entry colname="col8">0.48</oasis:entry>  
         <oasis:entry colname="col9">0.45</oasis:entry>  
         <oasis:entry colname="col10">0.49</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Fe<inline-formula><mml:math id="M385" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> (M4)</oasis:entry>  
         <oasis:entry colname="col2">0.64</oasis:entry>  
         <oasis:entry colname="col3">0.44</oasis:entry>  
         <oasis:entry colname="col4">0.24</oasis:entry>  
         <oasis:entry colname="col5">0.59</oasis:entry>  
         <oasis:entry colname="col6">0.40</oasis:entry>  
         <oasis:entry colname="col7">0.16</oasis:entry>  
         <oasis:entry colname="col8">0.17</oasis:entry>  
         <oasis:entry colname="col9">0.18</oasis:entry>  
         <oasis:entry colname="col10">0.16</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T4" specific-use="star"><caption><p id="d1e7959">Representative analyses of white mica used in the
multi-equilibrium calculations</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="10">
     <oasis:colspec colnum="1" colname="col1" align="left" colsep="1"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right" colsep="1"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right" colsep="1"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right" colsep="1"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Sample</oasis:entry>  
         <oasis:entry namest="col2" nameend="col3" align="center" colsep="1">IC – FG1315 </oasis:entry>  
         <oasis:entry namest="col4" nameend="col5" align="center" colsep="1">IC – FG12157 </oasis:entry>  
         <oasis:entry namest="col6" nameend="col7" align="center" colsep="1">IC – FG1347 </oasis:entry>  
         <oasis:entry namest="col8" nameend="col10" align="center">EC – FG1420 </oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Wm</oasis:entry>  
         <oasis:entry namest="col2" nameend="col3" align="center" colsep="1">  </oasis:entry>  
         <oasis:entry namest="col4" nameend="col5" align="center" colsep="1">  </oasis:entry>  
         <oasis:entry namest="col6" nameend="col7" align="center" colsep="1">  </oasis:entry>  
         <oasis:entry colname="col8">Grp1</oasis:entry>  
         <oasis:entry colname="col9">Grp2</oasis:entry>  
         <oasis:entry colname="col10">Grp3</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">Wm-</oasis:entry>  
         <oasis:entry colname="col3">Wm-</oasis:entry>  
         <oasis:entry colname="col4">Wm-</oasis:entry>  
         <oasis:entry colname="col5">Wm-</oasis:entry>  
         <oasis:entry colname="col6">Wm-</oasis:entry>  
         <oasis:entry colname="col7">Wm-</oasis:entry>  
         <oasis:entry colname="col8">Wm-</oasis:entry>  
         <oasis:entry colname="col9">Wm-</oasis:entry>  
         <oasis:entry colname="col10">Wm-</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">20328</oasis:entry>  
         <oasis:entry colname="col3">20330</oasis:entry>  
         <oasis:entry colname="col4">232431</oasis:entry>  
         <oasis:entry colname="col5">231796</oasis:entry>  
         <oasis:entry colname="col6">245987</oasis:entry>  
         <oasis:entry colname="col7">245295</oasis:entry>  
         <oasis:entry colname="col8">883652</oasis:entry>  
         <oasis:entry colname="col9">558805</oasis:entry>  
         <oasis:entry colname="col10">851517</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">SiO<inline-formula><mml:math id="M386" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">48.06</oasis:entry>  
         <oasis:entry colname="col3">48.48</oasis:entry>  
         <oasis:entry colname="col4">48.23</oasis:entry>  
         <oasis:entry colname="col5">47.06</oasis:entry>  
         <oasis:entry colname="col6">49.56</oasis:entry>  
         <oasis:entry colname="col7">49.29</oasis:entry>  
         <oasis:entry colname="col8">50.45</oasis:entry>  
         <oasis:entry colname="col9">50.56</oasis:entry>  
         <oasis:entry colname="col10">49.03</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al<inline-formula><mml:math id="M387" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O<inline-formula><mml:math id="M388" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">28.22</oasis:entry>  
         <oasis:entry colname="col3">28.12</oasis:entry>  
         <oasis:entry colname="col4">30.09</oasis:entry>  
         <oasis:entry colname="col5">29.98</oasis:entry>  
         <oasis:entry colname="col6">31.01</oasis:entry>  
         <oasis:entry colname="col7">29.62</oasis:entry>  
         <oasis:entry colname="col8">28.75</oasis:entry>  
         <oasis:entry colname="col9">28.95</oasis:entry>  
         <oasis:entry colname="col10">27.97</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FeO</oasis:entry>  
         <oasis:entry colname="col2">1.86</oasis:entry>  
         <oasis:entry colname="col3">1.77</oasis:entry>  
         <oasis:entry colname="col4">2.5</oasis:entry>  
         <oasis:entry colname="col5">2.32</oasis:entry>  
         <oasis:entry colname="col6">2.64</oasis:entry>  
         <oasis:entry colname="col7">2.83</oasis:entry>  
         <oasis:entry colname="col8">2.48</oasis:entry>  
         <oasis:entry colname="col9">3.13</oasis:entry>  
         <oasis:entry colname="col10">3.28</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MnO</oasis:entry>  
         <oasis:entry colname="col2">0.04</oasis:entry>  
         <oasis:entry colname="col3">0.06</oasis:entry>  
         <oasis:entry colname="col4">0.27</oasis:entry>  
         <oasis:entry colname="col5">0.2</oasis:entry>  
         <oasis:entry colname="col6">0.06</oasis:entry>  
         <oasis:entry colname="col7">0.06</oasis:entry>  
         <oasis:entry colname="col8">0.09</oasis:entry>  
         <oasis:entry colname="col9">0.1</oasis:entry>  
         <oasis:entry colname="col10">0.13</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MgO</oasis:entry>  
         <oasis:entry colname="col2">3.15</oasis:entry>  
         <oasis:entry colname="col3">3.03</oasis:entry>  
         <oasis:entry colname="col4">2.67</oasis:entry>  
         <oasis:entry colname="col5">2.71</oasis:entry>  
         <oasis:entry colname="col6">2.89</oasis:entry>  
         <oasis:entry colname="col7">2.98</oasis:entry>  
         <oasis:entry colname="col8">2.27</oasis:entry>  
         <oasis:entry colname="col9">2.52</oasis:entry>  
         <oasis:entry colname="col10">2.44</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">CaO</oasis:entry>  
         <oasis:entry colname="col2">0.02</oasis:entry>  
         <oasis:entry colname="col3">0.03</oasis:entry>  
         <oasis:entry colname="col4">0.27</oasis:entry>  
         <oasis:entry colname="col5">0.23</oasis:entry>  
         <oasis:entry colname="col6">0.01</oasis:entry>  
         <oasis:entry colname="col7">0.01</oasis:entry>  
         <oasis:entry colname="col8">0</oasis:entry>  
         <oasis:entry colname="col9">0</oasis:entry>  
         <oasis:entry colname="col10">0</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Na<inline-formula><mml:math id="M389" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O</oasis:entry>  
         <oasis:entry colname="col2">0.52</oasis:entry>  
         <oasis:entry colname="col3">0.58</oasis:entry>  
         <oasis:entry colname="col4">0.47</oasis:entry>  
         <oasis:entry colname="col5">0.6</oasis:entry>  
         <oasis:entry colname="col6">0.49</oasis:entry>  
         <oasis:entry colname="col7">0.58</oasis:entry>  
         <oasis:entry colname="col8">0.37</oasis:entry>  
         <oasis:entry colname="col9">0.28</oasis:entry>  
         <oasis:entry colname="col10">0.26</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">K<inline-formula><mml:math id="M390" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O</oasis:entry>  
         <oasis:entry colname="col2">9.49</oasis:entry>  
         <oasis:entry colname="col3">9.36</oasis:entry>  
         <oasis:entry colname="col4">10.04</oasis:entry>  
         <oasis:entry colname="col5">10.17</oasis:entry>  
         <oasis:entry colname="col6">10.14</oasis:entry>  
         <oasis:entry colname="col7">10.5</oasis:entry>  
         <oasis:entry colname="col8">10.17</oasis:entry>  
         <oasis:entry colname="col9">11.01</oasis:entry>  
         <oasis:entry colname="col10">11.04</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">Total</oasis:entry>  
         <oasis:entry colname="col2">91.36</oasis:entry>  
         <oasis:entry colname="col3">91.43</oasis:entry>  
         <oasis:entry colname="col4">94.54</oasis:entry>  
         <oasis:entry colname="col5">93.27</oasis:entry>  
         <oasis:entry colname="col6">96.8</oasis:entry>  
         <oasis:entry colname="col7">95.87</oasis:entry>  
         <oasis:entry colname="col8">94.58</oasis:entry>  
         <oasis:entry colname="col9">96.55</oasis:entry>  
         <oasis:entry colname="col10">94.15</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry namest="col1" nameend="col10" colsep="0">Atom site distribution (11 anhydrous-oxygen basis including Fe<inline-formula><mml:math id="M391" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula>) </oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Si (T1 <inline-formula><mml:math id="M392" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> T2)</oasis:entry>  
         <oasis:entry colname="col2">3.32</oasis:entry>  
         <oasis:entry colname="col3">3.35</oasis:entry>  
         <oasis:entry colname="col4">3.24</oasis:entry>  
         <oasis:entry colname="col5">3.22</oasis:entry>  
         <oasis:entry colname="col6">3.25</oasis:entry>  
         <oasis:entry colname="col7">3.28</oasis:entry>  
         <oasis:entry colname="col8">3.37</oasis:entry>  
         <oasis:entry colname="col9">3.34</oasis:entry>  
         <oasis:entry colname="col10">3.33</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al (T2)</oasis:entry>  
         <oasis:entry colname="col2">0.68</oasis:entry>  
         <oasis:entry colname="col3">0.65</oasis:entry>  
         <oasis:entry colname="col4">0.76</oasis:entry>  
         <oasis:entry colname="col5">0.78</oasis:entry>  
         <oasis:entry colname="col6">0.75</oasis:entry>  
         <oasis:entry colname="col7">0.72</oasis:entry>  
         <oasis:entry colname="col8">0.63</oasis:entry>  
         <oasis:entry colname="col9">0.66</oasis:entry>  
         <oasis:entry colname="col10">0.67</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">V (M1)</oasis:entry>  
         <oasis:entry colname="col2">0.94</oasis:entry>  
         <oasis:entry colname="col3">0.95</oasis:entry>  
         <oasis:entry colname="col4">0.98</oasis:entry>  
         <oasis:entry colname="col5">0.97</oasis:entry>  
         <oasis:entry colname="col6">0.94</oasis:entry>  
         <oasis:entry colname="col7">0.95</oasis:entry>  
         <oasis:entry colname="col8">1.00</oasis:entry>  
         <oasis:entry colname="col9">0.99</oasis:entry>  
         <oasis:entry colname="col10">1.00</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Mg (M1)</oasis:entry>  
         <oasis:entry colname="col2">0.04</oasis:entry>  
         <oasis:entry colname="col3">0.04</oasis:entry>  
         <oasis:entry colname="col4">0.03</oasis:entry>  
         <oasis:entry colname="col5">0.03</oasis:entry>  
         <oasis:entry colname="col6">0.04</oasis:entry>  
         <oasis:entry colname="col7">0.03</oasis:entry>  
         <oasis:entry colname="col8">0.00</oasis:entry>  
         <oasis:entry colname="col9">0.01</oasis:entry>  
         <oasis:entry colname="col10">0.01</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Fe<inline-formula><mml:math id="M393" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> (M1)</oasis:entry>  
         <oasis:entry colname="col2">0.01</oasis:entry>  
         <oasis:entry colname="col3">0.01</oasis:entry>  
         <oasis:entry colname="col4">0.01</oasis:entry>  
         <oasis:entry colname="col5">0.01</oasis:entry>  
         <oasis:entry colname="col6">0.02</oasis:entry>  
         <oasis:entry colname="col7">0.02</oasis:entry>  
         <oasis:entry colname="col8">0.00</oasis:entry>  
         <oasis:entry colname="col9">0.01</oasis:entry>  
         <oasis:entry colname="col10">0.00</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Al (M2 <inline-formula><mml:math id="M394" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M3)</oasis:entry>  
         <oasis:entry colname="col2">1.63</oasis:entry>  
         <oasis:entry colname="col3">1.64</oasis:entry>  
         <oasis:entry colname="col4">1.63</oasis:entry>  
         <oasis:entry colname="col5">1.64</oasis:entry>  
         <oasis:entry colname="col6">1.64</oasis:entry>  
         <oasis:entry colname="col7">1.60</oasis:entry>  
         <oasis:entry colname="col8">1.64</oasis:entry>  
         <oasis:entry colname="col9">1.60</oasis:entry>  
         <oasis:entry colname="col10">1.58</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Mg (M2 <inline-formula><mml:math id="M395" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M3)</oasis:entry>  
         <oasis:entry colname="col2">0.28</oasis:entry>  
         <oasis:entry colname="col3">0.27</oasis:entry>  
         <oasis:entry colname="col4">0.24</oasis:entry>  
         <oasis:entry colname="col5">0.25</oasis:entry>  
         <oasis:entry colname="col6">0.24</oasis:entry>  
         <oasis:entry colname="col7">0.26</oasis:entry>  
         <oasis:entry colname="col8">0.22</oasis:entry>  
         <oasis:entry colname="col9">0.24</oasis:entry>  
         <oasis:entry colname="col10">0.24</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Fe (M2 <inline-formula><mml:math id="M396" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M3)</oasis:entry>  
         <oasis:entry colname="col2">0.09</oasis:entry>  
         <oasis:entry colname="col3">0.09</oasis:entry>  
         <oasis:entry colname="col4">0.11</oasis:entry>  
         <oasis:entry colname="col5">0.12</oasis:entry>  
         <oasis:entry colname="col6">0.12</oasis:entry>  
         <oasis:entry colname="col7">0.14</oasis:entry>  
         <oasis:entry colname="col8">0.12</oasis:entry>  
         <oasis:entry colname="col9">0.14</oasis:entry>  
         <oasis:entry colname="col10">0.14</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">XMg</oasis:entry>  
         <oasis:entry colname="col2">0.75</oasis:entry>  
         <oasis:entry colname="col3">0.75</oasis:entry>  
         <oasis:entry colname="col4">0.68</oasis:entry>  
         <oasis:entry colname="col5">0.68</oasis:entry>  
         <oasis:entry colname="col6">0.66</oasis:entry>  
         <oasis:entry colname="col7">0.65</oasis:entry>  
         <oasis:entry colname="col8">0.65</oasis:entry>  
         <oasis:entry colname="col9">0.64</oasis:entry>  
         <oasis:entry colname="col10">0.64</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">K (A)</oasis:entry>  
         <oasis:entry colname="col2">0.84</oasis:entry>  
         <oasis:entry colname="col3">0.82</oasis:entry>  
         <oasis:entry colname="col4">0.86</oasis:entry>  
         <oasis:entry colname="col5">0.89</oasis:entry>  
         <oasis:entry colname="col6">0.85</oasis:entry>  
         <oasis:entry colname="col7">0.89</oasis:entry>  
         <oasis:entry colname="col8">0.87</oasis:entry>  
         <oasis:entry colname="col9">0.93</oasis:entry>  
         <oasis:entry colname="col10">0.96</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Na (A)</oasis:entry>  
         <oasis:entry colname="col2">0.07</oasis:entry>  
         <oasis:entry colname="col3">0.08</oasis:entry>  
         <oasis:entry colname="col4">0.06</oasis:entry>  
         <oasis:entry colname="col5">0.08</oasis:entry>  
         <oasis:entry colname="col6">0.06</oasis:entry>  
         <oasis:entry colname="col7">0.07</oasis:entry>  
         <oasis:entry colname="col8">0.05</oasis:entry>  
         <oasis:entry colname="col9">0.04</oasis:entry>  
         <oasis:entry colname="col10">0.03</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">V (A)</oasis:entry>  
         <oasis:entry colname="col2">0.09</oasis:entry>  
         <oasis:entry colname="col3">0.10</oasis:entry>  
         <oasis:entry colname="col4">0.06</oasis:entry>  
         <oasis:entry colname="col5">0.02</oasis:entry>  
         <oasis:entry colname="col6">0.09</oasis:entry>  
         <oasis:entry colname="col7">0.03</oasis:entry>  
         <oasis:entry colname="col8">0.08</oasis:entry>  
         <oasis:entry colname="col9">0.04</oasis:entry>  
         <oasis:entry colname="col10">0.01</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><caption><p id="d1e8925">Chlorite <inline-formula><mml:math id="M397" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> white mica <inline-formula><mml:math id="M398" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M399" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M400" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O
thermobarometry results for the EC sample.</p></caption>
            <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f06.png"/>

          </fig>

</sec>
<sec id="Ch1.S5.SS4.SSS4">
  <title>EC – FG1420 garnet orthogneiss</title>
      <p id="d1e8970">The chlorite and white mica multi-equilibrium technique was used to
constrain the equilibrium conditions of three successive stages of
retrogression using couples linked to different microstructural positions
that developed after the main foliation. These show equilibrium conditions
at 0.87 <inline-formula><mml:math id="M401" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.2 GPa and 354 <inline-formula><mml:math id="M402" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 50 <inline-formula><mml:math id="M403" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C in fold hinges, in
pressure shadows at 0.6 <inline-formula><mml:math id="M404" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.2 GPa and 331 <inline-formula><mml:math id="M405" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 50 <inline-formula><mml:math id="M406" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, and
in static overgrowths over the main foliation at 0.42 <inline-formula><mml:math id="M407" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.2 GPa and 231 <inline-formula><mml:math id="M408" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 50 <inline-formula><mml:math id="M409" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (Fig. 6).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7" specific-use="star"><caption><p id="d1e9045">Backscattered electron photos illustrating some of the
allanite crystals in the studied samples (<bold>a–h</bold> thin sections; <bold>b–g</bold> grain
mounts). <bold>(a)</bold> Allanite grain elongate in the eclogite foliation with phengite
and paragonite. It is rimmed by epidote and a simplectite of paragonite and
chlorite. <bold>(b)</bold> Allanite displaying several growth zones and a dark outermost
rim of epidote. Note the phengite inclusion and laser ablation pits (32 <inline-formula><mml:math id="M410" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m). <bold>(c)</bold> Allanite displaying several growth zones, the innermost of
which are intergrown with paragonite. The tiny dark inclusions are phengite and paragonite with fine grain size. <bold>(d)</bold> Monazite with lobate edges preserved at
the core of an allanite grain. <bold>(e)</bold> Allanite intergrown with garnet and
wrapped by a darker epidote rim. <bold>(f)</bold> Allanite including garnet, rutile, and
phengite. <bold>(g)</bold> Allanite preserved at the core of epidote. Inclusions of
paragonite and phengite are present at the boundary allanite–epidote rim.
<bold>(h)</bold> Magmatic allanite with epidote crystals as satellites; some of the
latter display cores of metamorphic allanite.</p></caption>
            <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f07.jpg"/>

          </fig>

</sec>
</sec>
</sec>
<sec id="Ch1.S6">
  <title>Texture and geochronology of allanite and zircon</title>
<sec id="Ch1.S6.SS1">
  <title>Methods</title>
<sec id="Ch1.S6.SS1.SSS1">
  <title>Allanite geochronology</title>
      <p id="d1e9110">Allanite was first investigated in detail in thin section (see Sect. 7),
but for more efficient dating purposes, allanite grains were separated using
high-voltage pulsed-power disintegration (Selfrag device at University of
Bern; e.g. Rudashevsky et al., 1995) followed by magnetic separation
and heavy liquids, hand-picked, mounted in acryl or epoxy, and polished to
equatorial section. The grains were imaged using SEM (BSE) to document the
internal texture and compositional zoning. Allanite dating was performed
using a LA-ICP-MS GeoLas Pro 193 nm ArF excimer laser coupled to an Elan
Dynamic Reaction Cell (DRC-e) ICP-MS (Institute of Geological Sciences, University of Bern). The
analytical procedure followed is described in detail in Burn et al. (2017). In particular, pre-ablation was performed for four to five pulses using an
energy density of 2.5 J cm<inline-formula><mml:math id="M411" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, a repetition rate of 1 Hz, and spot sizes
of 40 and 32 <inline-formula><mml:math id="M412" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m. Ablation was performed using an energy density of 2.5 J cm<inline-formula><mml:math id="M413" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, a repetition rate of 9 Hz, and spot sizes of 32 and 24 <inline-formula><mml:math id="M414" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m.
He (1 L min<inline-formula><mml:math id="M415" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) and H<inline-formula><mml:math id="M416" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> (0.08 L min<inline-formula><mml:math id="M417" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) were used as aerosol transport. The instrument
setting was optimized for heavy masses, and oxide production
(ThO<inline-formula><mml:math id="M418" display="inline"><mml:msup><mml:mi/><mml:mo>+</mml:mo></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M419" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Th<inline-formula><mml:math id="M420" display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mo>+</mml:mo></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> was decreased to be lower than 0.5 %. NIST SRM 610
measurements were performed for quantification of U and Th concentrations.
Plešovice (Sláma et al., 2008) zircon was used as the primary
standard. Cima d'Asta Pluton (CAP) allanite was used as a secondary standard.
The acquisition series were approximately 1 h to minimize instrumental
drift,
including between 8 and 12 unknown analyses bracketed by eight analyses of the
primary standard Plešovice used for U–Th–Pb ratio calibration,
SRM 610
for trace element calibration, and three analyses of the secondary
reference material CAP<inline-formula><mml:math id="M421" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula>. Data reduction was performed with the in-house
program Trinity (Burn et al., 2017). Data for the secondary
standards are reported in Supplement S9. Uncertainties given in the text
and figures do not include the systematic uncertainties as defined by
Horstwood et al. (2016) because the value appears to be quite
variable depending on the reference material used (see Burn et al.,
2017). In theory, the total uncertainties may be slightly underestimated,
whereas the low mean square weighted deviation (MSWD) values rather suggest
that the total uncertainties are slightly overestimated.</p>
</sec>
<sec id="Ch1.S6.SS1.SSS2">
  <title>Zircon geochronology</title>
      <p id="d1e9228">Individual grains of zircon were separated as described for allanite and
investigated using SEM, using CL imaging to document
their internal textures. Zircon dates were obtained using the same LA-ICP-MS
instrument, following the measurement procedures described by
Kunz et al. (2017). Ablation was conducted with an energy
density of 2.5 J cm<inline-formula><mml:math id="M422" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, a repetition rate of 9 Hz, and spot sizes of 32 or 16 <inline-formula><mml:math id="M423" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m. Samples were bracketed
by the zircon standard GJ-1 (Jackson et al., 2004) and NIST SRM 612 measurements for quantification of U, Th, and other
trace element concentrations, using <inline-formula><mml:math id="M424" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">29</mml:mn></mml:msup></mml:math></inline-formula>Si as an internal standard. For
accuracy and long-term reproducibility, Plešovice was measured as the
secondary zircon standard giving a <inline-formula><mml:math id="M425" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M426" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M427" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">238</mml:mn></mml:msup></mml:math></inline-formula>U weighted mean age of
339.2 <inline-formula><mml:math id="M428" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.6 Ma (<inline-formula><mml:math id="M429" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 34; error 2<inline-formula><mml:math id="M430" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula>). Acquisition series took
approximately 1 h to minimize instrumental drift and were composed of
the following: two SRM glasses, three GJ-1 zircon, six to eight zircon unknowns,
three to four
Plešovice zircon, six to eight zircon unknowns, three GJ-1 zircon, and two SRM glasses.
Data reduction was performed with Iolite 2.5 (Paton et al., 2010, 2011) with data reduction scheme “Visual age” (Petrus and Kamber,
2012). All dates reported in this study are concordant within their
uncertainty; no common Pb correction was applied.</p>
</sec>
</sec>
<sec id="Ch1.S6.SS2">
  <title>Results: allanite textures and their microstructural relations</title>
      <p id="d1e9316">In the samples of the IC, allanite prisms are elongate in the eclogite
foliation, showing mutual intergrowth relations with phengite, garnet,
paragonite, and rutile, which define this main foliation (Fig. 7a). In
samples FG1324, FG1315, and FG1347 allanite crystals are characterized by
one main growth zone. Some thin (&lt; 20–30 <inline-formula><mml:math id="M431" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m) allanite rims as well as epidote or clinozoisite rims that appear dark in BSE
photos
are observed (Fig. 7a, b); where present, these mark a retrograde greenschist
overprint. In samples FG12157 and FG1249, BSE pictures show one or more
allanite rims characterized by lower brightness (Fig. 7b, c). These rims may
reflect minor retrograde stages that weakly altered the eclogite facies
assemblage as well. Again, a peripheral epidote rim is present. Monazite is
occasionally observed as a relic in allanite cores in samples FG1324,
FG1315, FG1347, and FG1249. Monazite shows lobate edges and is surrounded by
symplectites (micrometres in size) of allanite and apatite or by discrete
crystals of apatite and allanite (Fig. 7d). These features suggest prograde
growth of allanite and apatite at the expense of monazite, a common
allanite-forming reaction (e.g. Janots et al., 2008).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T5" specific-use="star"><caption><p id="d1e9329">Constraints linking age data to pressure and temperature
based on mineral inclusions in allanite; uncertainties of age data are
2<inline-formula><mml:math id="M432" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula>. Allanite age data based on Tera–Wasserburg intercepts.
Zircon <inline-formula><mml:math id="M433" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M434" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M435" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">238</mml:mn></mml:msup></mml:math></inline-formula>U dates are
given as the minimum and maximum range of individual analysis.
Groups are discussed in Sect. 7.</p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.95}[.95]?><oasis:tgroup cols="9">
     <oasis:colspec colnum="1" colname="col1" align="left" colsep="1"/>
     <oasis:colspec colnum="2" colname="col2" align="center"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="justify" colwidth="85.358268pt"/>
     <oasis:colspec colnum="9" colname="col9" align="justify" colwidth="85.358268pt"/>
     <oasis:thead>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">Sample</oasis:entry>

         <oasis:entry colname="col3">Group</oasis:entry>

         <oasis:entry colname="col4">Age Aln (2<inline-formula><mml:math id="M436" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry colname="col5">Age Zrn</oasis:entry>

         <oasis:entry colname="col6"><inline-formula><mml:math id="M437" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col7"><inline-formula><mml:math id="M438" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col8">Constraints</oasis:entry>

         <oasis:entry colname="col9">Name</oasis:entry>

       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
       <?xmltex \rotentry?>
         <oasis:entry rowsep="1" colname="col1" morerows="4">IC</oasis:entry>

         <oasis:entry colname="col2">FG1324</oasis:entry>

         <oasis:entry colname="col3">1</oasis:entry>

         <oasis:entry colname="col4">77.2 <inline-formula><mml:math id="M439" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7.3</oasis:entry>

         <oasis:entry colname="col5">77–63</oasis:entry>

         <oasis:entry colname="col6">1.65–1.75 GPa</oasis:entry>

         <oasis:entry colname="col7">600–650</oasis:entry>

         <oasis:entry colname="col8">Inclusion of Ph, Grt</oasis:entry>

         <oasis:entry colname="col9">Omp, Grt, Gln, and Rt<?xmltex \hack{\hfill\break}?>mica schist</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">FG1315</oasis:entry>

         <oasis:entry colname="col3">2</oasis:entry>

         <oasis:entry colname="col4">65.4 <inline-formula><mml:math id="M440" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3.5</oasis:entry>

         <oasis:entry colname="col5">68-58</oasis:entry>

         <oasis:entry colname="col6">1.75–1.9 GPa</oasis:entry>

         <oasis:entry colname="col7">650–670</oasis:entry>

         <oasis:entry colname="col8">Inclusion of Ph, Grt<?xmltex \hack{\hfill\break}?>(Rim1, 2, and 3), Pg</oasis:entry>

         <oasis:entry colname="col9">Grt, Ep, and Rt Qz-<?xmltex \hack{\hfill\break}?>mica schist</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">FG12157</oasis:entry>

         <oasis:entry colname="col3">2</oasis:entry>

         <oasis:entry colname="col4">64.5 <inline-formula><mml:math id="M441" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4.3</oasis:entry>

         <oasis:entry colname="col5">65-60</oasis:entry>

         <oasis:entry colname="col6">1.55–1.65 GPa</oasis:entry>

         <oasis:entry colname="col7">630–670</oasis:entry>

         <oasis:entry colname="col8">Inclusion of Ph</oasis:entry>

         <oasis:entry colname="col9">Grt, Gln, Ep, and Rt<?xmltex \hack{\hfill\break}?>mica schist</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">FG1347</oasis:entry>

         <oasis:entry colname="col3">3</oasis:entry>

         <oasis:entry colname="col4">55.7 <inline-formula><mml:math id="M442" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4.5</oasis:entry>

         <oasis:entry colname="col5">56 <inline-formula><mml:math id="M443" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4</oasis:entry>

         <oasis:entry colname="col6">1.8–2 GPa</oasis:entry>

         <oasis:entry colname="col7">580–610</oasis:entry>

         <oasis:entry colname="col8">Inclusion of Ph, Pg, Rt</oasis:entry>

         <oasis:entry colname="col9">Cld, Grt, and Rt<?xmltex \hack{\hfill\break}?>mica schist</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col2">FG1249</oasis:entry>

         <oasis:entry colname="col3">1</oasis:entry>

         <oasis:entry colname="col4">72.5 <inline-formula><mml:math id="M444" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.4</oasis:entry>

         <oasis:entry colname="col5">–</oasis:entry>

         <oasis:entry colname="col6">1.55–1.65 GPa</oasis:entry>

         <oasis:entry colname="col7">580–630</oasis:entry>

         <oasis:entry colname="col8">Inclusion of Ph, Pg</oasis:entry>

         <oasis:entry colname="col9">Grt, Ep, and Rt<?xmltex \hack{\hfill\break}?>mica schist</oasis:entry>

       </oasis:row>
       <oasis:row>
       <?xmltex \rotentry?>
         <oasis:entry colname="col1" morerows="1">EC</oasis:entry>

         <oasis:entry colname="col2">FG1420</oasis:entry>

         <oasis:entry colname="col3">4</oasis:entry>

         <oasis:entry colname="col4">73.7 <inline-formula><mml:math id="M445" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8.2</oasis:entry>

         <oasis:entry colname="col5">–</oasis:entry>

         <oasis:entry colname="col6">0.5–0.8 GPa</oasis:entry>

         <oasis:entry colname="col7">400–500</oasis:entry>

         <oasis:entry colname="col8">Inclusion of Ph, Pg, Ttn</oasis:entry>

         <oasis:entry colname="col9">Grt orthogneiss</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">FG12107</oasis:entry>

         <oasis:entry colname="col3">4</oasis:entry>

         <oasis:entry colname="col4">62.8 <inline-formula><mml:math id="M446" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3.3</oasis:entry>

         <oasis:entry colname="col5">–</oasis:entry>

         <oasis:entry colname="col6">no <inline-formula><mml:math id="M447" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col7">no <inline-formula><mml:math id="M448" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col8">Inclusion of Ph, Pg</oasis:entry>

         <oasis:entry colname="col9">Ep, Ph, and Ab<?xmltex \hack{\hfill\break}?>leucogneiss</oasis:entry>

       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table></table-wrap>

      <p id="d1e9731">Various mineral inclusions are found in allanite grains, as summarized in
Table 5. In detail, allanite in sample FG1324 shows intergrowths with garnet
(Fig. 7e), suggesting synchronous growth of the two minerals. Phengite
inclusions analysed in allanite show the same chemical composition as those
marking the main foliation (representative mineral analyses are available in
Supplement S5). Based on these features and the alignment in the foliation,
allanite is interpreted to have grown syn-kinematically in the foliation and
at the same time as garnet. In sample FG1315 allanite includes phengite,
paragonite, and garnet (Fig. 7a, f); the latter is similar in composition to
the Alpine HP rims and atoll garnet. Phengite inclusions have the same
composition as phengite marking the main foliation and as phengite included
in atoll garnet. Due to the relationships of these mutual inclusions in this
sample, allanite growth again appears to be related to the development of
the main foliation. In samples FG1347 and FG1249 allanite includes phengite
and paragonite; in FG12157 allanite includes only phengite. These micas have the same
composition as those defining the eclogite foliation (Fig. 7b–d). In the
cases of FG1249 and FG1347, allanite also shows intergrowths with both white
micas (Fig. 7c).</p>
      <p id="d1e9734">In the EC, allanite is rare and, where present, is typically magmatic; it
appears dark brown and pleochroic in the optical microscope, with a grain
size of some millimetres (Fig. 2h; Giuntoli and Engi, 2016). In only
two samples was metamorphic allanite found, preserved in the core of epidote
crystals (FG1420, FG12107). The metamorphic allanite has a grain size of less
than 50 <inline-formula><mml:math id="M449" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m and is colourless or pale yellow in polarized light, with low
interference colour and undulose extinction in crossed polarized light.
Sample FG1420 shows both magmatic and metamorphic allanites (Fig. 7g, h).
Allanite includes paragonite, with phengite and titanite occurring both in
the epidote rim and at the allanite–epidote boundary (Fig. 7g). Very few
tiny monazite grains (a few micrometres) are found in the core of metamorphic
allanite. Sample FG12107 also shows similar epidote crystals preserving
metamorphic allanite in their core, as in sample FG1420. Magmatic allanite
preserved in sample FG1420 occurs as mm-size grains that are fractured and
appear much brighter in BSE pictures than metamorphic allanite (Figs. 2h, 7h). Epidote crystals form satellites around magmatic allanite, suggesting
partial breakdown (Fig. 7h). Note that these epidote crystals retain a
BSE bright core of newly grown (Alpine) metamorphic allanite.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8" specific-use="star"><caption><p id="d1e9747">Results of the IC samples plotted in the Tera–Wasserburg
and <inline-formula><mml:math id="M450" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">232</mml:mn></mml:msup></mml:math></inline-formula>Th <inline-formula><mml:math id="M451" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M452" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb<inline-formula><mml:math id="M453" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:math></inline-formula><inline-formula><mml:math id="M454" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula><inline-formula><mml:math id="M455" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">208</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M456" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M457" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb<inline-formula><mml:math id="M458" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:math></inline-formula>
isochron diagram with intercept and isochron age, respectively, and initial
common lead composition estimations.</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f08.jpg"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9" specific-use="star"><caption><p id="d1e9832">Results of the EC samples plotted in the Tera–Wasserburg
and <inline-formula><mml:math id="M459" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">232</mml:mn></mml:msup></mml:math></inline-formula>Th <inline-formula><mml:math id="M460" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M461" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb<inline-formula><mml:math id="M462" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:math></inline-formula><inline-formula><mml:math id="M463" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula><inline-formula><mml:math id="M464" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">208</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M465" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M466" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb<inline-formula><mml:math id="M467" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:math></inline-formula>
isochron diagram with intercept and isochron age, respectively, and estimated
initial common lead composition.</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f09.jpg"/>

        </fig>

</sec>
<sec id="Ch1.S6.SS3">
  <title>Results: allanite U–Th–Pb dating</title>
      <p id="d1e9921">For both IC and EC, only allanite cores were successfully dated. The rims
showed too high common lead (Pb<inline-formula><mml:math id="M468" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> contents, the correction
(Gregory et al., 2007; Burn et al., 2017) of which would lead to large
uncertainties in the age calculation.</p>
      <p id="d1e9936">In the IC and EC, the Tera–Wasserburg and <inline-formula><mml:math id="M469" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">232</mml:mn></mml:msup></mml:math></inline-formula>Th <inline-formula><mml:math id="M470" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M471" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb<inline-formula><mml:math id="M472" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub><mml:msup><mml:mo>-</mml:mo><mml:mn mathvariant="normal">208</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>Pb <inline-formula><mml:math id="M473" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M474" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb<inline-formula><mml:math id="M475" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:math></inline-formula> isochron diagrams are concordant, within the
range of uncertainty, in all the analysed samples (Figs. 8, 9; every ellipse
is a single spot measurement). Ages range between 77 and 56 Ma for the
allanite cores of the IC. In the EC, the magmatic allanite cores in sample
FG1420 yield ages of <inline-formula><mml:math id="M476" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 290 Ma, and the metamorphic cores yield ages of
73.7 <inline-formula><mml:math id="M477" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8.2 Ma. In sample FG12107, the metamorphic allanite cores were
dated to 62.8 <inline-formula><mml:math id="M478" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3.3 Ma. A summary of the Alpine allanite age data from
each sample is listed in Table 5.</p>
      <p id="d1e10026">In detail, the IC Tera–Wasserburg diagrams show <inline-formula><mml:math id="M479" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">207</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M480" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M481" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb
<inline-formula><mml:math id="M482" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> intercepts of 0.84 <inline-formula><mml:math id="M483" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01, 0.823 <inline-formula><mml:math id="M484" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.018, and 0.83 <inline-formula><mml:math id="M485" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.004 for samples FG1324, FG1315, and FG12157, respectively, with a MSWD on the
regression between 1.2 and 2.1 (Fig. 8).
<inline-formula><mml:math id="M486" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb<inline-formula><mml:math id="M487" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:math></inline-formula>–isochron
diagrams display a <inline-formula><mml:math id="M488" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">208</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M489" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M490" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M491" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> intercept of 2.081 <inline-formula><mml:math id="M492" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.027,
2.077 <inline-formula><mml:math id="M493" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.066, and 2.085 <inline-formula><mml:math id="M494" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.028 for samples FG1324, FG1315, and
FG12157, respectively, with a MSWD on the regression between 0.46 and
0.98. These values are close to the predicted values of Stacey and
Kramers (1975) for model lead evolution of this time range (Fig. 1 in Burn,
2016). The exception is sample FG1347, in which the Tera–Wasserburg diagram
shows a <inline-formula><mml:math id="M495" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">207</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M496" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M497" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M498" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> intercept at 0.787 <inline-formula><mml:math id="M499" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.04 (MSWD on the
regression of 2.5) and displays a <inline-formula><mml:math id="M500" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">208</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M501" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M502" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M503" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> intercept on the
<inline-formula><mml:math id="M504" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb<inline-formula><mml:math id="M505" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:math></inline-formula>–isochron diagram at 1.98 <inline-formula><mml:math id="M506" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.082 (MSWD on the
regression of 0.4). These values deviate from the values predicted by
Stacey and Kramers (1975), probably indicating local inheritance.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F10" specific-use="star"><caption><p id="d1e10255">CL images of zircon textures in the samples from the
Internal Complex. Typically detrital cores show more or less resorption and
are followed up by one to five metamorphic rim generations of different CL
responses. The scale bar in all images is 50 <inline-formula><mml:math id="M507" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m. Solid circles
correspond to 32 <inline-formula><mml:math id="M508" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m LA-ICP-MS spots, while dashed circles are
16 <inline-formula><mml:math id="M509" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m spot sizes. The dates are individual
<inline-formula><mml:math id="M510" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M511" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M512" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">238</mml:mn></mml:msup></mml:math></inline-formula>U spot analysis
given in Ma.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f10.jpg"/>

        </fig>

      <p id="d1e10312">In the EC, data for magmatic allanite in sample FG1420 show a
<inline-formula><mml:math id="M513" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">207</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M514" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M515" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M516" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> intercept at 0.85 <inline-formula><mml:math id="M517" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.11 in a Tera–Wasserburg
diagram and display a <inline-formula><mml:math id="M518" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">208</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M519" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M520" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M521" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> intercept at 2.09 <inline-formula><mml:math id="M522" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.7
in a <inline-formula><mml:math id="M523" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb<inline-formula><mml:math id="M524" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:math></inline-formula>–isochron diagram (Fig. 9). These large uncertainties
reflect few (eight) spots analyses. Metamorphic allanites show
<inline-formula><mml:math id="M525" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">207</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M526" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M527" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M528" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> intercepts of 0.825 <inline-formula><mml:math id="M529" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01 and 0.824 <inline-formula><mml:math id="M530" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.006 in Tera–Wasserburg diagrams (MSWD on the regression of 0.7 and 1.2)
and display <inline-formula><mml:math id="M531" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">208</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M532" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M533" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M534" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> intercepts of 2.061 <inline-formula><mml:math id="M535" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.029 and
2.089 <inline-formula><mml:math id="M536" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.022 in <inline-formula><mml:math id="M537" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb<inline-formula><mml:math id="M538" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:math></inline-formula>–isochron diagrams (MSWD on the
regression of 0.4) for samples FG1420 and FG12107, respectively. These values
are close to the predicted values of Stacey and Kramers (1975) for
these time ranges.</p>
</sec>
<sec id="Ch1.S6.SS4">
  <title>Results: zircon textures</title>
      <p id="d1e10531">Internal textures of zircon from the IC reveal complex zoning in CL images
(Fig. 10), showing detrital cores and several phases of resorption and
(metamorphic) overgrowth. Zircon cores commonly preserve a variety of
internal textures, most commonly oscillatory zoning (Fig. 10e, f), which is
typical of zircon-grown form melt. Many cores are affected by resorption,
obliterating earlier features, but some grains show sharp boundaries between
core and rims, and these preserve features of sediment transport such as
broken, rounded, or pitted surfaces (Fig. 10b). The number of rims varies
among and within samples, from two rims in sample FG1257 to a maximum of
five in FG1315. Most zircon grains show a first metamorphic rim with a light
grey to bright CL response, followed by a rim with dark CL appearance. The
third rim is again typically medium grey to bright white in CL. In sample
FG1315, a fourth (dark CL) and fifth (light grey) rim follow, and FG1347
occasionally shows a CL-dark fourth rim. The internal textures of the
different rims are not always clearly distinguishable, either because of
limited width or, in the case of a very dark or bright CL response, limited
contrast. The second metamorphic rim in FG12157 is either uniform or shows
fir-tree zoning (Vavra et al., 1996; Root et al., 2004). In sample FG1347
metamorphic rims are often too thin to distinguish or no texture is
recognizable in the bright CL third rim. The first two rims in sample FG1315
have cloudy textures; the third rim with the bright-CL shows no further
internal textures but sometimes has inclusions and the two outermost rims
commonly are uniform or cloudy in texture. The innermost and outermost
metamorphic rims in samples FG1249 and FG1324 are bright and featureless; the
second dark rim in sample FG1249 shows sector zoning and many inclusions.
The third (medium grey) rim in FG1249 has a cloudy texture.</p>
      <p id="d1e10534">Zircon in the EC displays pre-Alpine magmatic oscillatory
zoning, rarely shows a bright CL rim, is 5–10 <inline-formula><mml:math id="M539" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m in width, and surrounds the core.</p>
</sec>
<sec id="Ch1.S6.SS5">
  <title>Results: zircon U–Pb dating</title>
      <p id="d1e10551">The range of Alpine <inline-formula><mml:math id="M540" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">206</mml:mn></mml:msup></mml:math></inline-formula>Pb <inline-formula><mml:math id="M541" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M542" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">238</mml:mn></mml:msup></mml:math></inline-formula>U zircon dates for each sample
are
summarized in Table 5. Details on the pre-Alpine dates are available in
Kunz et al. (2017). Supplement S10 gives an overview of
pre-Alpine dates as well as individual analyses of Alpine dates. Concordia
plots of individual spot analyses of Alpine zircon are available in
Supplement S11. For the five samples we obtained 27 analyses of detrital
cores, 53 of Permian rims, and 34 of Alpine rims. Detrital zircon cores in
samples from the IC range from <inline-formula><mml:math id="M543" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 793 to 353 Ma and partially
overlap with the first rim in samples FG1324 and FG1249 (Fig. 10), for which
the dates range from <inline-formula><mml:math id="M544" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 450 to 420 Ma. In most samples, at least
two rims are found yielding Carboniferous to Triassic dates from
<inline-formula><mml:math id="M545" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 313 to 222 Ma, as discussed in detail by Kunz et
al. (2017); only one sample (FG1324) shows none of these. Alpine rims, with
a range between 77 and 56 Ma, were measured in all samples except FG1249,
in which the third rim was too thin (10 <inline-formula><mml:math id="M546" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m) to be analysed. No
correlation was found between rim types and ages within samples or amongst
them, and it was not possible to make absolute age distinctions among Alpine
rim generations. This is due to relatively large uncertainty in the ages, as
the narrow rims only allowed small spots for LA-ICP-MS measurements,
decreasing their analytical precision.</p>
      <p id="d1e10608">Th <inline-formula><mml:math id="M547" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> U ratios in detrital zircon cores range between 0.15 and
&gt; 3;
the rim generation with dates between 450 and 420 Ma have low Th <inline-formula><mml:math id="M548" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> U ratios in
sample FG1324 (0.006–0.14) whereas those in sample FG1249 are between 0.1
and 0.5. The Carboniferous to Triassic rims show Th <inline-formula><mml:math id="M549" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> U ratios between 0.002 and 0.4.
The Alpine metamorphic rims show low Th <inline-formula><mml:math id="M550" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> U ratios between 0.001 and 0.01.
<?xmltex \hack{\vspace{-3mm}}?></p>
</sec>
</sec>
<sec id="Ch1.S7">
  <title>Discussion</title>
<sec id="Ch1.S7.SS1">
  <title>Linking time constraints with equilibrium conditions (petrochronology)</title>
      <p id="d1e10652">Preliminary analysis of allanite for U–Th–Pb using LA-ICP-MS was performed in situ (i.e.
using LA-ICP-MS spot analyses) on polished thin sections. However, to obtain
more material for dating, allanite grains were subsequently separated,
mounted on resin mounts, and polished. The main reasons why allanite grains
were separated for dating are as follows.
<list list-type="bullet"><list-item>
      <p id="d1e10657">Grain mounts are more efficient as they enable the selection of more spots to
analyse a single growth zone (at least 1 order of magnitude more spot
analyses per sample than in thin sections).</p></list-item><list-item>
      <p id="d1e10661">Grains mounts produce more likely equatorial cuts because polishing is
optimized to obtain the largest sections possible at a given grain size.
This is essential for LA-ICP-MS analysis of grains with several growth
zones: if sectioning is not near-equatorial, one is more likely to drill
through different growth zones.</p></list-item></list>
We do consider petrographic control before dating to be essential: all
mounts were imaged using SEM with the BSE detector to document allanite
textures. For each sample, both in the thin section and in the mounts, the
allanite grains displayed the same textural patterns, growth zones, and
mineral inclusions on the sample scale (in separates and thin section). The
microtextural features observed in thin sections were readily linked to
those seen in grain mounts (compare Fig. 7a and f). Furthermore, we note
that U–Th–Pb ages from grain mount analyses agree within uncertainty with
the spot analyses made in thin sections.</p>
      <p id="d1e10665">The fundamental task to reconstruct the <inline-formula><mml:math id="M551" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M552" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M553" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths is to establish a strong
link between <inline-formula><mml:math id="M554" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M555" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions, derived from thermodynamic modelling, and
<inline-formula><mml:math id="M556" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> data, derived from age dating. Several criteria were used to achieve this
goal, notably (i) textural evidence, (ii) the presence and composition of
distinctive minerals as inclusions, and (iii) the presence of intergrowths
of allanite with other phases.</p>
      <p id="d1e10711">As described in Sect. 6.2, allanite grains of the IC are intergrown with
the main mineral phases that describe the eclogite facies foliation (Fig. 7;
Table 5). Furthermore, the compositions of mineral inclusions in allanite
matched those found in the matrix and those predicted by thermodynamic
modelling (representative chemical analyses in Supplement S5). Based on these
observations (and details given in Sect. 6.2 for each sample), we infer
growth of allanite coeval with the minerals marking the eclogite facies
foliation in all of the samples analysed from the IC. This link between age
data and <inline-formula><mml:math id="M557" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M558" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions is shown by the red ellipses on the equilibrium
phase diagrams shown in Fig. 4 and on the <inline-formula><mml:math id="M559" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M560" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M561" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths shown in Fig. 11b and c (colour-coded for each sample). Additionally, in four samples of the IC,
the ages obtained for allanite cores and Alpine zircon rims overlap within
uncertainty, suggesting coeval growth of these two accessory minerals.</p>
      <p id="d1e10749">In the EC, metamorphic allanite is rare and preserved only in the core of
epidote (Sect. 6.2; Fig. 7g, h). Epidote is intergrown with white mica,
chlorite, and titanite, marking the retrograde greenschist overprint, which
is constrained by chlorite <inline-formula><mml:math id="M562" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> white mica <inline-formula><mml:math id="M563" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> quartz <inline-formula><mml:math id="M564" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M565" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O thermobarometry
(<inline-formula><mml:math id="M566" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.9 GPa and 350 <inline-formula><mml:math id="M567" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C to 0.4 GPa and 230 <inline-formula><mml:math id="M568" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C;
see Fig. 6). According to these results, metamorphic allanite growth in the
EC predates the retrograde greenschist overprint (red ellipse in Fig. 4f and
purple ellipse in Fig. 11b–c).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F11" specific-use="star"><caption><p id="d1e10811"><inline-formula><mml:math id="M569" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M570" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M571" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths of the study area (Fig. 1). <bold>(a)</bold> Data and
paths from previous studies: proposed pre-Alpine evolution from the data of
Lardeaux and Spalla (1991) and Rebay and Spalla (2001);
Alpine evolution of the Internal Complex from Rubatto et al. (2011), Regis et al. (2014), Konrad-Schmolke and Halama (2014),
and Halama et al. (2014); ages for the External Complex are from
Inger et al. (1996) and Reddy et al. (1999), related to
greenschist facies conditions. <bold>(b)</bold> Data presented in this study. Ellipses
show <inline-formula><mml:math id="M572" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M573" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> constraints for the age data; rectangles refer to retrograde
stages. Error bars show the <inline-formula><mml:math id="M574" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M575" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> uncertainty related to the analytical error
of the garnet composition. <bold>(c)</bold> Interpreted <inline-formula><mml:math id="M576" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M577" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M578" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths. Full lines: Internal Complex;
dashed lines: External Complex.
The star indicates the age data from sample FG12107 (see text for
explanation).</p></caption>
          <?xmltex \igopts{width=455.244094pt}?><graphic xlink:href="https://se.copernicus.org/articles/9/191/2018/se-9-191-2018-f11.jpg"/>

        </fig>

</sec>
<sec id="Ch1.S7.SS2">
  <?xmltex \opttitle{$P$--$T$--$t$ paths of samples}?><title><inline-formula><mml:math id="M579" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M580" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M581" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths of samples</title>
<sec id="Ch1.S7.SS2.SSS1">
  <title>Pre-Alpine conditions in the IC</title>
      <p id="d1e10932">The history of the studied samples is summarized in <inline-formula><mml:math id="M582" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M583" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M584" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> diagrams (Fig. 11)
and compared with relevant data from the literature. The first metamorphic
stage recorded in our samples from the IC is of Permian age; it reflects
granulite facies conditions. Porphyroclastic garnet cores (present in
samples FG1315, FG12157, FG1347, and FG1249) are the only major mineral
relics of this HT stage. Among accessory minerals, late Carboniferous to
Upper Triassic zircon rims (between 313 and 222 Ma) are preserved, and
monazite relics in allanite are most probably Paleozoic as well. The ages of
the Permian zircon cores fit well with those reflecting HT metamorphism in
the Ivrea Zone and Adria-derived units in the western Alps (Vavra et al., 1996, 1999; Ewing et al., 2013; Kunz et al., 2017), thus
supporting the long-held view that the Sesia Zone is closely related to the
Ivrea Zone (e.g. Compagnoni et al., 1977). The single Upper
Triassic date (222 <inline-formula><mml:math id="M585" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 13 Ma) in sample FG1315 is similar to ages
reported by Vavra et al. (1999) from the Ivrea Zone, where they have
been related to fluid alteration. The <inline-formula><mml:math id="M586" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M587" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions for the pre-Alpine HT
stage are constrained between 0.6 and 0.8 GPa and between 700 and 900 <inline-formula><mml:math id="M588" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C from the
garnet cores of the IC samples. These results confirm earlier data for the
IC (0.6–0.9 GPa, <inline-formula><mml:math id="M589" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 850 <inline-formula><mml:math id="M590" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C; Lardeaux and
Spalla, 1991; Rebay and Spalla, 2001; Fig. 11). A retrograde pre-Alpine path
through amphibolite facies conditions is evident in sample FG1249, where a
first garnet rim generation yields <inline-formula><mml:math id="M591" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.6 GPa and 600 <inline-formula><mml:math id="M592" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (Fig. 11b), again in fair agreement with previous data
(0.3–0.5 GPa, 570–670 <inline-formula><mml:math id="M593" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C; Lardeaux and Spalla,
1991; Rebay and Spalla, 2001). A sketch summarizing the chronology and
thermodynamic modelling of garnet in sample FG1249 is shown in
Giuntoli et al. (2018).</p>
</sec>
<sec id="Ch1.S7.SS2.SSS2">
  <title>Pre-Alpine conditions in the EC</title>
      <p id="d1e11035">In the EC, sample FG1420 shows pre-Alpine ages of <inline-formula><mml:math id="M594" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 290 Ma for
the magmatic allanite grains. These age data probably reflect magmatic
crystallization ages of the granitoids; they are in good agreement with
several age data of magmatic zircon and monazite for the Sesia-Dent Blanche
nappe (Fig. 1 in Bussy et al., 1998; Table 2 and Fig. 5 in
Kunz et al., 2017).</p>
</sec>
<sec id="Ch1.S7.SS2.SSS3">
  <title>Alpine conditions in the IC</title>
      <p id="d1e11051">For the Alpine history, our samples from the IC indicate higher <inline-formula><mml:math id="M595" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M596" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> than
in the EC, based on detailed garnet compositional modelling (Lanari et al.
2017). The IC recorded a range of maximum pressures between 1.6 and 2 GPa at
temperatures of 600–670 <inline-formula><mml:math id="M597" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Age constraints based on allanite
dating of five samples from the IC fall into three groups including
<list list-type="bullet"><list-item>
      <p id="d1e11079">Group 1 with ages of <inline-formula><mml:math id="M598" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 73 Ma (from 77.2 <inline-formula><mml:math id="M599" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7.3 Ma to 72.4 <inline-formula><mml:math id="M600" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.4 Ma, based on samples FG1324 and FG1249,
respectively);</p></list-item><list-item>
      <p id="d1e11104">Group 2 at <inline-formula><mml:math id="M601" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 65 Ma (from 65.4 <inline-formula><mml:math id="M602" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3.5Ma to 64.5 <inline-formula><mml:math id="M603" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4.3Ma, based on samples FG1315 and
FG12157);</p></list-item><list-item>
      <p id="d1e11129">Group 3 at 55.7 <inline-formula><mml:math id="M604" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4.5Ma (sample FG1347).</p></list-item></list></p>
      <p id="d1e11139">Metamorphic conditions for Group 1 show 1.6–1.75 GPa and 580–650 <inline-formula><mml:math id="M605" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for the earliest stage. In Group 2, samples FG1315 and FG12157 yield not
only the same age, within analytical uncertainty, but also similar
metamorphic conditions; the pressure difference of 0.1–0.2 GPa is within the
uncertainty of the model, as indicated by error bars in Fig. 11b. Notably,
the same <inline-formula><mml:math id="M606" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M607" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions were derived from garnet rim1 of FG12157 in Group 2
and from garnet rim3 of sample FG1249 in Group 1. Summarizing, Groups 1 and 2
experienced similar <inline-formula><mml:math id="M608" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M609" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions but Group 2 attained these some 5–10 Myr later. Furthermore, the outermost garnet rim in sample FG12157 preserves
evidence of a retrograde stage at 1.4 GPa and 650 <inline-formula><mml:math id="M610" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Sample
FG1347 (Group 3) shows the youngest allanite ages for a similar pressure
range as Groups 1 and 2 but lower temperature conditions (<inline-formula><mml:math id="M611" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 580–600 <inline-formula><mml:math id="M612" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C). It thus appears that the samples from the IC reflect
several stages of allanite growth, probably because rocks of slightly
different bulk composition produced allanite by different metamorphic
reactions (Engi, 2017). Three growth stages captured in our samples are
at <inline-formula><mml:math id="M613" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 73, <inline-formula><mml:math id="M614" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 65, and <inline-formula><mml:math id="M615" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 56 Ma.
The different <inline-formula><mml:math id="M616" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M617" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M618" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths of Groups 1, 2, and 3 are interpreted to represent
different tectonic sheets (Giuntoli and Engi, 2016) that experienced
similar <inline-formula><mml:math id="M619" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M620" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions but at different times (further discussed in Sect. 7.3).</p>
      <p id="d1e11262">Regis et al. (2014; Druer slice) and Konrad-Schmolke and
Halama (2014) suggested similar <inline-formula><mml:math id="M621" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M622" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> paths for different parts of the IC
(Fig. 11c), with the highest pressure reached at <inline-formula><mml:math id="M623" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 85 Ma.
Halama et al. (2014) constrained the development of the retrograde
blueschist facies Tallorno Shear Zone (Konrad-Schmolke et al.,
2011) at 65.0 <inline-formula><mml:math id="M624" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3.0 Ma using Ar–Ar data on phengite. This shear zone
was related to external fluid influx occurring at approximately 1.35 GPa and
550 <inline-formula><mml:math id="M625" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (Konrad-Schmolke and Halama, 2014). These two <inline-formula><mml:math id="M626" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M627" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> paths
are similar to Group 3 of the present study, but the latter are up to 30 Myr younger. Groups 1 and 2 consistently display similar <inline-formula><mml:math id="M628" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M629" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> paths, but
temperatures are 50–100 <inline-formula><mml:math id="M630" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C higher than those determined by
Regis et al. (2014) and Konrad-Schmolke and Halama (2014).
In our samples from the IC, we detected no evidence of pressure cycling such
as documented by Rubatto et al. (2011) further south, in the
Fondo slice (Regis et al., 2014).</p>
</sec>
<sec id="Ch1.S7.SS2.SSS4">
  <title>Alpine conditions in the EC</title>
      <p id="d1e11346">In sample FG1420, metamorphic allanites yield ages of 73.7 <inline-formula><mml:math id="M631" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8.2 Ma associated with
metamorphic conditions of 0.8 GPa and 350–500 <inline-formula><mml:math id="M632" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, a stage constrained by the growth of garnet and phengite, the mica
marking the main foliation. Sample FG12107 yields an allanite growth age of
62.8 <inline-formula><mml:math id="M633" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3.3 Ma (Fig. 11c highlighted by the star). Chlorite and white
mica data from this sample give thermobarometric results in agreement with
FG1420. The proximity of the two samples in the field and their similarity in
<inline-formula><mml:math id="M634" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M635" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions and in textural features of allanite lead us to suggest that
allanite grew at the same metamorphic stage in these two samples. Their
(nominal) ages seem discrepant, but considering the overlapping (2<inline-formula><mml:math id="M636" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula>)
uncertainties, we view them as a single age group (Group 4: <inline-formula><mml:math id="M637" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 63 <inline-formula><mml:math id="M638" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3 Ma).</p>
</sec>
<sec id="Ch1.S7.SS2.SSS5">
  <?xmltex \opttitle{Comparison of $P$--$T$--$t$ data for the IC and EC}?><title>Comparison of <inline-formula><mml:math id="M639" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M640" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M641" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> data for the IC and EC</title>
      <p id="d1e11437">Comparing <inline-formula><mml:math id="M642" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M643" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M644" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> data for the IC and EC, we note that Group 2 (in the IC) and
Group 4 (in the EC) recorded the same age data of ca. 65 Ma, but very
different metamorphic conditions. This implies that the IC and EC at that
time were at a completely different structural position in the subduction
zone: a difference of 1 GPa translates to a <inline-formula><mml:math id="M645" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 30 km vertical
offset between the two complexes, assuming lithostatic pressures. Tectonic
overpressure cannot be ruled out, but it cannot explain the observed
difference in pressures since Group 4 (at 0.8 GPa) also displays
<inline-formula><mml:math id="M646" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 150 <inline-formula><mml:math id="M647" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C lower temperatures compared to Group 2 (at
1.6–1.8 GPa). We conclude that the IC resided in a substantially deeper and
hotter part of the subduction system than the EC <inline-formula><mml:math id="M648" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 65 Myr ago.</p>
      <p id="d1e11492">The retrograde <inline-formula><mml:math id="M649" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M650" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> trajectories in the IC and EC are similar based on our
data for chlorite–white mica equilibria: <inline-formula><mml:math id="M651" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.8 GPa and 340 <inline-formula><mml:math id="M652" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
for samples FG1315, FG1347 (IC), and FG1420 (EC; Fig. 11b). Sample FG12157 recorded a low-pressure stage at slightly higher
temperature (0.54 GPa and 393 <inline-formula><mml:math id="M653" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) compared to the two other
samples of the IC. The EC records two further retrograde stages at 0.60 GPa
and
330 <inline-formula><mml:math id="M654" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C and at 0.42 GPa and 220 <inline-formula><mml:math id="M655" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. However, these
retrograde stages have yet to be precisely dated. Inger et
al. (1996) and Reddy et al. (1999) constrained the greenschist facies
overprint of the EC between 46 and 38 Ma (Rb–Sr using phengite). In
light of our data, we interpret these ages to reflect the greenschist facies
conditions documented in both complexes (constrained between <inline-formula><mml:math id="M656" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.8 GPa and 400 <inline-formula><mml:math id="M657" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C and 0.4 GPa and 300 <inline-formula><mml:math id="M658" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C). The
allanite core ages in Group 4 would then be related to an earlier
deformation event, as the epidote rim marks the greenschist overprint (Figs. 7g, 11c). Zircon fission track ages for the Sesia Zone range from 42 to 26 Ma
(Wagner and Reimer, 1972; Hurford and Hunziker, 1985; Hurford et al., 1989, 1991; Kapferer, 2010; Berger et al., 2012), suggesting
that the terrain crossed the <inline-formula><mml:math id="M659" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 250 <inline-formula><mml:math id="M660" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C isotherm in
this age range during exhumation. For the most internal section of the Sesia
terrain, the overlying Biella Volcanic Suite dated at 32.5 Ma (Kapferer, 2010; Kapferer et al., 2012) provides an age constraint for
the final exhumation to the surface.</p>
</sec>
</sec>
<sec id="Ch1.S7.SS3">
  <title>Tectonic assembly and exhumation of the Sesia Zone</title>
      <p id="d1e11602">The IC shows several tectonic sheets, from several hundred metres to a few
kilometres in thickness (Giuntoli and Engi, 2016), some of which moved
independently in the subduction channel (Rubatto
et al., 2011; Regis et al., 2014) at some stages of the evolution. Some of
the samples we studied, while taken at most a few kilometres apart in the
field, recorded similar <inline-formula><mml:math id="M661" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M662" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> paths at different times, as reflected by the
three age groups identified (Fig. 1b, c). This age difference may reflect
relative tectonic mobility at eclogite facies conditions between such sheets
of basement-derived rocks, which are notoriously difficult to delimit in
this terrain (Giuntoli and Engi, 2016). In addition to tectonic
mobility, the combined effects of deformation and repeated hydration must be
considered as triggers of recrystallization that promoted chemical
equilibration to eclogite facies assemblages (including allanite and zircon,
as discussed below).</p>
      <p id="d1e11619">The differences in the <inline-formula><mml:math id="M663" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M664" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>-conditions (at eclogite facies) documented above
for the IC samples do not indicate trajectories as tortuous as those
suggested by numerical models for ablative subduction (e.g.
Stöckhert and Gerya, 2005; Roda et al., 2012). Our <inline-formula><mml:math id="M665" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M666" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M667" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>
data as well as the nature and geometry of tectonic boundaries mapped by
Giuntoli and Engi (2016) rather indicate progressive accretion at
depths of 50–60 km, probably during final subduction–early exhumation
stages, juxtaposing a series of continental sheets and forming a coherent
complex (the IC; Vitale Brovarone et al., 2013; Regis
et al., 2014). Eclogite facies conditions in the IC evidently prevailed for
an extended period, at least <inline-formula><mml:math id="M668" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 15 Myr.</p>
      <p id="d1e11665">In the IC, the main deformation stages and mineral reactions were related to
pulses of external fluid passing through the rocks, as reported by
Engi et al. (2018) and Giuntoli et al. (2018). Repeated fluid influx occurred under eclogite facies conditions, as
shown by resorption and growth features in garnet and zircon, with hydrous
fluid pervasively rehydrating rocks that had previously been almost
completely dehydrated by upper Paleozoic metamorphism (Engi et al., 2018). Thus Permian kinzigites (granulite facies metapelites) were
transformed back to mica schists during Alpine subduction. As allanite and
zircon ages from these samples are identical within analytical
uncertainties, it appears that this fluid influx also triggered the coeval
growth of accessory phases under eclogite facies conditions. Later and more
localized fluid influx has also been documented in blueschist facies
conditions (Konrad-Schmolke et al., 2011), and this probably
continued to greenschist facies conditions, as reflected by the partial
overprint of the main eclogite assemblages, which is frequently observed in
the IC. Our samples in the IC indicate higher temperatures than have been
previously reported (Fig. 11). This discrepancy may reflect a regional
thermal gradient, namely higher temperatures in more external areas (NW) of
the IC, but we suspect it to be a direct effect of the (re)hydration of
pre-Alpine HT rocks, which is an exothermic process (e.g. Walther and
Orville, 1982; Peacock, 1987; Lyubetskaya and Ague, 2009). Walther and
Orville (1982) analysed the thermal effects of (de)hydration reactions
during regional metamorphism and found them to be substantial. When applied
to the present situation of (re)hydration, heat capacity data indicate that
heating the HT Permian protolith requires <inline-formula><mml:math id="M669" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.0 kJ K<inline-formula><mml:math id="M670" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> kg<inline-formula><mml:math id="M671" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> of
leucogneiss. The enthalpy released upon partial hydration of this protolith
(producing the water content typical of these mica schists, 1.5 wt %
H<inline-formula><mml:math id="M672" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O) adds <inline-formula><mml:math id="M673" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 77 kJ kg<inline-formula><mml:math id="M674" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in enthalpy. Such hydration should
thus result in a temperature increase of some 80<inline-formula><mml:math id="M675" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>. This estimate
lends credibility to the <inline-formula><mml:math id="M676" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M677" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> estimates obtained here, which are indeed 20–80 <inline-formula><mml:math id="M678" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C higher than some maximum temperatures recently reported from
other parts of the Sesia Zone, e.g. 575 <inline-formula><mml:math id="M679" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (Konrad-Schmolke and
Halama, 2014), 570–630 <inline-formula><mml:math id="M680" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for the Druer Slice (Regis
et al., 2014), or &gt; 600 <inline-formula><mml:math id="M681" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for the Ivozio Complex
(Zucali and Spalla, 2011). In addition, Zr-in-rutile data reported
by Kunz et al. (2017, their Table 3) gave 640 <inline-formula><mml:math id="M682" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for
one of the present samples (FG1249), confirming our results by an entirely
independent method.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T6" specific-use="star"><caption><p id="d1e11800">Exhumation velocities for Groups 1 and 3 (IC) from the
highest pressures recorded to the greenschist juxtaposition with the EC
(Stage1) and for the late exhumation to the surface of the Sesia Zone
(INT-EXT; Stage2).</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="6">
     <oasis:colspec colnum="1" colname="col1" align="left" colsep="1"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="center"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:thead>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3">Age at <inline-formula><mml:math id="M683" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.6 GPa</oasis:entry>

         <oasis:entry colname="col4">Vertical velocity</oasis:entry>

         <oasis:entry colname="col5">Along sub. inter.</oasis:entry>

         <oasis:entry colname="col6">Along sub. inter.</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">mm year<inline-formula><mml:math id="M684" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col5">60<inline-formula><mml:math id="M685" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> mm year<inline-formula><mml:math id="M686" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col6">45<inline-formula><mml:math id="M687" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> mm year<inline-formula><mml:math id="M688" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>

       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
       <?xmltex \rotentry?>
         <oasis:entry rowsep="1" colname="col1" morerows="3">Stage1</oasis:entry>

         <oasis:entry colname="col2">Group 1</oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M689" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 38 Ma</oasis:entry>

         <oasis:entry colname="col4">0.9</oasis:entry>

         <oasis:entry colname="col5">1.1</oasis:entry>

         <oasis:entry colname="col6">1.3</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">Group 1</oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M690" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 46 Ma</oasis:entry>

         <oasis:entry colname="col4">1.2</oasis:entry>

         <oasis:entry colname="col5">1.4</oasis:entry>

         <oasis:entry colname="col6">1.7</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">Group 3</oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M691" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 38 Ma</oasis:entry>

         <oasis:entry colname="col4">2.7</oasis:entry>

         <oasis:entry colname="col5">3.1</oasis:entry>

         <oasis:entry colname="col6">3.8</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col2">Group 3</oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M692" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 46 Ma</oasis:entry>

         <oasis:entry colname="col4">5.1</oasis:entry>

         <oasis:entry colname="col5">5.9</oasis:entry>

         <oasis:entry colname="col6">7.2</oasis:entry>

       </oasis:row>
       <oasis:row>
       <?xmltex \rotentry?>
         <oasis:entry colname="col1" morerows="1">Stage2</oasis:entry>

         <oasis:entry colname="col2">INT-EXT</oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M693" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 38 Ma</oasis:entry>

         <oasis:entry colname="col4">4</oasis:entry>

         <oasis:entry colname="col5">–</oasis:entry>

         <oasis:entry colname="col6">–</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">INT-EXT</oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M694" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 46 Ma</oasis:entry>

         <oasis:entry colname="col4">1.6</oasis:entry>

         <oasis:entry colname="col5">–</oasis:entry>

         <oasis:entry colname="col6">–</oasis:entry>

       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e12082">A counterclockwise <inline-formula><mml:math id="M695" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M696" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> path is proposed here for the EC. This trajectory is
based on the results of garnet and chlorite–white mica modelling. The path
as shown in Fig. 11 implies that, under nearly isobaric conditions, this area
of the EC experienced cooling by 100–150<inline-formula><mml:math id="M697" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>, possibly related to the
entry of cold material into the subduction channel, as already proposed by
Pognante (1989) for the southern Sesia Zone. Piemonte–Liguria oceanic
units are a likely source of such material, which would be in line with age
data of 58–40 Ma for the HP metamorphism in the Zermatt–Saas Zone (e.g.
Rubatto et al., 1998; de Meyer et al., 2014; Weber et al., 2015) and with
tectonic–kinematic models for the evolution of the Sesia–Dent Blanche
nappes (Angiboust et al., 2014; Manzotti et al., 2014).</p>
      <p id="d1e12108">Summarizing, the major differences between the eclogite facies conditions
recorded in the IC and the epidote blueschist facies conditions in the EC are
now quantitatively constrained by <inline-formula><mml:math id="M698" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M699" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M700" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> data presented in this study (Fig. 11).
Tectonic juxtaposition of these two complexes appears to have occurred
during exhumation probably at 0.7–0.9 GPa and 350–400 <inline-formula><mml:math id="M701" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C since
these are the first joint <inline-formula><mml:math id="M702" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M703" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> conditions found in both complexes around
46–38 Ma (age data from Inger et al., 1996, and Reddy et
al., 1999). These data confirm the proposition by Williams and
Compagnoni (1983) of a first-order tectonic contact (Barmet Shear Zone in
Giuntoli and Engi, 2016; Fig. 1b, c) between the two complexes. Our data
are the first to quantify the <inline-formula><mml:math id="M704" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M705" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> discontinuity at that contact, i.e.
<inline-formula><mml:math id="M706" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 GPa and 100–180 <inline-formula><mml:math id="M707" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. This age range is younger
compared to the age range proposed in the tectonic model by Angiboust et
al. (2014) for the juxtaposition of the two complexes (70–57 Ma, based on
data of Babist et al., 2006; Konrad-Schmolke et al.,
2011; and Halama et al., 2014). Whereas Angiboust et al. (2014)
considered the Tallorno–Chiusella Shear Zone (Babist et
al., 2006; Konrad-Schmolke et al., 2011) to represent the contact between the
IC and EC, more recent mapping (Giuntoli and Engi, 2016) shows that
this contact is located several kilometres further NW, in the Barmet Shear
Zone.</p>
      <p id="d1e12186">The data shown in Fig. 11 allow us to derive average exhumation rates for
the IC (Table 6). Using Groups 1 and 3 as the two anchors, i.e. the
oldest and the youngest groups, a first calculation considers Stage1, the
interval from the highest pressures recorded in these two groups
(<inline-formula><mml:math id="M708" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.6 GPa at <inline-formula><mml:math id="M709" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 73 Ma and <inline-formula><mml:math id="M710" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 GPa
at <inline-formula><mml:math id="M711" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 55 Ma) to the greenschist conditions upon
juxtaposition with the EC (<inline-formula><mml:math id="M712" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.6 GPa at <inline-formula><mml:math id="M713" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 38 Ma,
age from Inger et al., 1996). The mean vertical exhumation
velocity obtained ranges from 0.9 to 2.7 mm year<inline-formula><mml:math id="M714" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (Table 6). If
we take the juxtaposition to be at <inline-formula><mml:math id="M715" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 46 Ma (Reddy et al.,
1999) for the same <inline-formula><mml:math id="M716" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> conditions, values for the mean vertical exhumation
velocity increase to 1.2 and 5.1 mm year<inline-formula><mml:math id="M717" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. Plate convergence
between Adria and Europe was <inline-formula><mml:math id="M718" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 15 mm year<inline-formula><mml:math id="M719" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in the time span of
68–38 Ma (Handy et al., 2010). In the above calculations we considered
subduction angles of 90, 60, and 45<inline-formula><mml:math id="M720" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> and a
thickness of 20 km for the upper crust and 10 km for the lower crust; their
densities were taken as 2.7 and 3.0 g cm<inline-formula><mml:math id="M721" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, respectively, and 3.3 g cm<inline-formula><mml:math id="M722" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for
the upper mantle.</p>
      <p id="d1e12323">For Stage2, the final stage of exhumation of the IC and EC, we obtained mean
vertical exhumation velocities using the juxtaposition conditions
(<inline-formula><mml:math id="M723" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.6 GPa) and ages quoted for the end of Stage1 and 32.5 Ma for the arrival at the surface. That age of the Biella Volcanic Suite
(Kapferer, 2010; Kapferer et al., 2012) is supported by zircon fission
track ages (Berger et al., 2012). Depending on the time of
juxtaposition adopted, at 38 or 46 Ma (Table 6), a mean vertical exhumation
velocity of 4 or 1.6 mm year<inline-formula><mml:math id="M724" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> results. For Stage2, only the vertical
exhumation velocity was computed, and an average density of 2.7 g cm<inline-formula><mml:math id="M725" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>
was assumed. The rate of convergence in the 35–20 Ma period was
<inline-formula><mml:math id="M726" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 13 mm year<inline-formula><mml:math id="M727" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (Handy et al., 2010). Data for Stage2 are taken
as an approximate range of exhumation rates since the last part of the
exhumation was not uniform throughout the Sesia Zone; owing to brittle
structures local differences may be important (e.g. Berger et
al., 2012; Malusà et al., 2006). Furthermore, the values given are
minimum exhumation velocities, as the emplacement of the Biella Volcanic
Suite may have post-dated the arrival of the Sesia Zone at the surface.</p>
      <p id="d1e12376">The Stage1 exhumation rates we obtained for the IC agree with exhumation
velocities proposed for the same complex by Zucali et al. (2002) and Regis et al. (2014) and the mean exhumation rates for
the Sesia Zone proposed by Roda et al. (2012). However, our rates are
up to an order of magnitude lower than those proposed by
Rubatto et al. (2011) and the maximum values of Roda et
al. (2012). Mean exhumation velocities for the final exhumation stage of the
Sesia Zone (Stage2) are in the same range (1.6–4 mm year<inline-formula><mml:math id="M728" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) as those for
Stage1 (0.9–5.1 mm year<inline-formula><mml:math id="M729" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>). Our data show no decrease in exhumation velocity
from early exhumation (i.e. mantle to deep crustal positions) to late stages
(i.e. crustal levels to the surface), such as has been proposed by
Rubatto and Hermann (2001) for ultra-HP terranes.</p>
</sec>
<sec id="Ch1.S7.SS4">
  <title>Implication for the subduction, assembly, and exhumation of continental
fragments</title>
      <p id="d1e12409">Our work highlights that subducted continental terranes can be composed of
several complexes that experienced major differences in their subduction
histories (i.e. <inline-formula><mml:math id="M730" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 GPa in pressure and 100–180 <inline-formula><mml:math id="M731" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
in temperature for the Sesia Zone). These complexes could have been
tectonically juxtaposed during late metamorphic stages (i.e. greenschist
facies conditions) before being jointly exhumed to the surface. Complexes
can be lithologically heterogeneous and may comprise several
tectono-metamorphic subunits (from a few hundred metres to several
kilometres in thickness). These may experience similar <inline-formula><mml:math id="M732" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M733" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> paths but at
different times (5–10 Myr apart). Differences in the <inline-formula><mml:math id="M734" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M735" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M736" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> trajectories would
thus reflect different tectonic sheets and attest to tectonic mobility in
the subduction zone and/or several stages of internal deformation plus
hydration at eclogite facies that triggered a pervasive HP fabric and
assemblage (including datable accessory minerals).</p>
      <p id="d1e12464">To unravel such complex histories in subducted continental terranes,
carefully established field relations, followed by microstructural and
petrochronological analysis need to be combined to
<list list-type="bullet"><list-item>
      <p id="d1e12469">map and identify the major and secondary tectono-metamorphic contacts;</p></list-item><list-item>
      <p id="d1e12473">characterize the different fabrics and the mineral phases defining them;</p></list-item><list-item>
      <p id="d1e12477">quantify the differences existing in <inline-formula><mml:math id="M737" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M738" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>, and <inline-formula><mml:math id="M739" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> for each complex or subunit.</p></list-item></list></p>
      <p id="d1e12501">Finally, the heterogeneity of subducted continental terranes highlighted by
this study should be considered when comparing results to numerical and
analogue models that aim to investigate the mechanisms responsible for the
subduction and exhumation of the continental crust.</p>
</sec>
</sec>
<sec id="Ch1.S8" sec-type="conclusions">
  <title>Conclusions</title>
      <p id="d1e12511">The present paper provides <inline-formula><mml:math id="M740" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M741" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M742" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> data for the central Sesia Zone,
documenting in particular when and under what conditions the two main complexes
of this HP terrain were juxtaposed during the Alpine orogenic cycle.</p>
      <p id="d1e12535">In particular, our data indicate the following.<?xmltex \hack{\newpage}?>
<list list-type="bullet"><list-item>
      <p id="d1e12542">In the Internal Complex the main stages of mineral growth, and probably the
attendant deformation, are related to eclogite facies conditions occurring
between 77 and 55 Ma and triggered by repeated influx of external fluid. It
is during this subduction phase that most of the Permian HT assemblages were
replaced, leaving only sparse relics of essentially dry granulites.</p></list-item><list-item>
      <p id="d1e12546">The Internal Complex encompasses three groups of the samples studied,
probably reflecting different tectonic sheets. These experienced similar
internal deformation and <inline-formula><mml:math id="M743" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M744" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> paths, but at different times, reflecting minor
(kilometre-scale) adjustments in the subduction channel at 50–60 km depth and were
probably juxtaposed during final subduction–early exhumation stages.</p></list-item><list-item>
      <p id="d1e12564">Comparing the two main complexes, diverse metamorphic evolutions emerge
between 77 and 55 Ma, with conditions of 1.6–2 GPa and 600–670 <inline-formula><mml:math id="M745" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
in the Internal Complex, whereas only 0.7–0.9 GPa and <inline-formula><mml:math id="M746" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 500 <inline-formula><mml:math id="M747" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C appear to have been reached in the External Complex.</p></list-item><list-item>
      <p id="d1e12593">The two complexes were juxtaposed between 46 and 38 Ma (Inger et al.,
1996; Reddy et al., 1999) at <inline-formula><mml:math id="M748" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.8 GPa and 350 <inline-formula><mml:math id="M749" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, so
at mid-crustal levels during exhumation.</p></list-item><list-item>
      <p id="d1e12613">The different tectonic sheets of the Internal Complex were initially exhumed
with mean vertical velocities of 0.9–5.1 mm year<inline-formula><mml:math id="M750" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> during Stage1, from the
highest pressures recorded to the greenschist facies conditions attained
upon juxtaposition with the External Complex.</p></list-item><list-item>
      <p id="d1e12629">During Stage2, the final exhumation of the entire Sesia Zone occurred with
mean vertical velocities between 1.6 and 4 mm year<inline-formula><mml:math id="M751" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, but the late stages of
exhumation in the area can display local differences
(Malusà et al., 2006; Berger et al., 2012).</p></list-item></list>
This case study shows that subducted HP continental terranes can be composed
of various complexes, characterized by major differences in their
tectono-metamorphic histories, juxtaposed during exhumation by tectonic
contacts operating under greenschist facies conditions. Such complexes include
several subunits, which in the present case were some hundred metres to a few
kilometres in thickness, that acted as fragments in the subduction zone,
recording slightly different <inline-formula><mml:math id="M752" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M753" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M754" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> paths. The development of the main
fabrics under eclogite facies conditions appears to have been triggered by
external fluid influx. These processes could be dated based on the coeval
growth of allanite and zircon. Petrochronology proved to be a powerful tool
to quantify processes and unravel the metamorphic evolution in a complex
geological setting, essentially because the detailed analytical work on the
microscale could be linked to solid field evidence.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability">

      <p id="d1e12670">Original data underlying the material presented are available by contacting
the authors.</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d1e12673"><bold>The Supplement related to this article is available online at <inline-supplementary-material xlink:href="https://doi.org/10.5194/se-9-191-2018-supplement" xlink:title="zip">https://doi.org/10.5194/se-9-191-2018-supplement</inline-supplementary-material>.</bold></p></supplementary-material>
        </app-group><notes notes-type="competinginterests">

      <p id="d1e12679">The authors declare that they have no conflict of
interest.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e12686">This work was financially supported by the Swiss National Science Foundation
(project 200020-146175). We thank Roberto Compagnoni, Daniele Regis, and
Jörg Hermann for fruitful discussions. We acknowledge constructive
comments and suggestions from Samuel Angiboust and the anonymous referee, and
we are grateful to Patrice Rey for editorial handling.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
Edited by: Patrice Rey<?xmltex \hack{\newline}?>
Reviewed by: Samuel Angiboust and one anonymous referee</p></ack><ref-list>
    <title>References</title>

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  </ref-list><app-group content-type="float"><app><title/>

    </app></app-group></back>
    <!--<article-title-html>Deeply subducted continental fragments – Part 2: Insight from petrochronology in the central Sesia Zone (western Italian Alps)</article-title-html>
<abstract-html><p class="p">Subducted continental terranes commonly comprise an assembly of subunits that
reflect the different tectono-metamorphic histories they experienced in the
subduction zone. Our challenge is to unravel how, when, and in which part of
the subduction zone these subunits were juxtaposed. Petrochronology offers
powerful tools to decipher pressure–temperature–time (<i>P</i>–<i>T</i>–<i>t</i>) histories of
metamorphic rocks that preserve a record of several stages of transformation.
A major issue is that the driving forces for re-equilibration at high
pressure are not well understood. For example, continental granulite terrains
subducted to mantle depths frequently show only partial and localized
eclogitization. The Sesia Zone (NW Italy) is exceptional because it comprises
several continental subunits in which eclogitic rocks predominate and
high-pressure (HP) assemblages almost completely replaced the Permian
granulite protoliths. This field-based study comprises both main complexes of
the Sesia terrane, covering some of the recently recognized tectonic subunits
involved in its assembly; hence our data constrain the HP tectonics that
formed the Sesia Zone. We used a petrochronological approach consisting of
petrographic and microstructural analysis linked with thermodynamic modelling
and U–Th–Pb age dating to reconstruct the <i>P</i>–<i>T</i>–<i>t</i> trajectories of these
tectonic subunits. Our study documents when and under what conditions
re-equilibration took place. Results constrain the main stages of mineral
growth and deformation, associated with fluid influx that occurred in the
subduction channel. In the Internal Complex (IC), pulses of fluid percolated
at eclogite facies conditions between 77 and 55 Ma with the HP conditions
reaching  ∼  2 GPa and 600–670 °C. By contrast, the
External Complex (EC) records a lower pressure peak of  ∼  0.8 GPa for 500 °C at  ∼  63 Ma. The juxtaposition of the
two complexes occurred during exhumation, probably at  ∼  0.8 GPa
and 350 °C; the timing is constrained between 46 and 38 Ma. Mean
vertical exhumation velocities are constrained between 0.9 and 5.1 mm year<sup>−1</sup>
for the IC, up to its juxtaposition with the EC. Exhumation to the surface
occurred before 32 Ma, as constrained by the overlying Biella Volcanic Suite,
at a mean vertical velocity between 1.6 and 4 mm year<sup>−1</sup>. These findings
constrain the processes responsible for the assembly and exhumation of HP continental subunits, thus adding to our understanding of how
continental terranes behave during subduction.</p></abstract-html>
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