Alkali basalt from the Seifu Seamount in the Sea of Japan: post-spreading magmatism in a back-arc setting
- 1Faculty of Geosciences and Civil Engineering, Kanazawa University, Kanazawa 920-1192, Japan
- 2Lamont-Doherty Earth Observatory, Columbia University, Palisades, NY 10964, USA
- 3Volcanoes and Earth's Interior Research Center, Japan Agency for Marine-Earth Science and Technology, 2–15 Natsushima, Kanagawa, 237-0061, Japan
- 4Center for Northeast Asian Studies, Tohoku University, 41 Kawauchi, Aoba-ku, Sendai 980-8576, Japan
- 5Graduate School of Arts and Sciences, University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-0041, Japan
- 6Department of Business Administration, Senshu University, 2-1-1, Higashimita, Tama-ku, Kawasaki, Kanagawa 214-8580, Japan
- 7Department of Earth and Planetary Systems Science, Graduate School of Science, Hiroshima University, 1-3-2 Kagamiyama, Higashi-Hiroshima City, Hiroshima 739-8511, Japan
- 8School of Natural System, Kanazawa University, Kanazawa 920-1192, Japan
Correspondence: Tomoaki Morishita (firstname.lastname@example.org)
We present geochemical and 40Ar∕39Ar age data for a peridotite xenolith-bearing basalt dredged from the Seifu Seamount (SSM basalt) in the northeast Tsushima Basin, southwest Sea of Japan. An 40Ar∕39Ar plateau age of 8.33±0.15 Ma (2σ) was obtained for the SSM basalt, indicating that it erupted shortly after the termination of back-arc spreading in the Sea of Japan. The SSM basalt is a high-K to shoshonitic alkali basalt that is characterized by light rare earth element enrichment. The trace element features of the basalt are similar to those of ocean island basalt, although the Yb content is much higher, indicating formation by the low-degree partial melting of spinel peridotite. The Nd, Sr, and Pb isotopic compositions of the SSM basalt differ from those of back-arc basin basalts in the Sea of Japan. The Sr–Nd isotopic composition of the SSM basalt suggests its source was depleted mid-ocean ridge mantle containing an enriched mantle (EM1) component. The SSM basalt was formed in a post-back-arc extension setting by the low-degree partial melting of an upwelling asthenosphere that had previously been associated with the main phase of back-arc magmatism.
Numerous studies have investigated the magmatism that occurs during back-arc rifting (e.g., Martinez et al., 2001; Pearce and Stern, 2006). The Sea of Japan is a typical inactive back-arc basin developed between an island arc and a continent (Tamaki and Honza, 1985; Uyeda and Kanamori, 1979), and it is located in the northern part of the western Pacific where back-arc basins are common. Numerous geophysical surveys have been carried out to elucidate the architecture of the Sea of Japan back-arc basin and its formation processes (e.g., Lee et al., 1999; Yoon et al., 2014; Sato et al., 2014). Geophysical data and sampling by the Ocean Drilling Program (ODP) have revealed the mechanisms of formation of the northern Sea of Japan (Tamaki et al., 1992) (Fig. 1). Lithospheric breakup and oceanic spreading began at the eastern margin of the continent at 32–28 Ma, and back-arc magmatism ceased at 18–15 Ma (Tamaki et al., 1992). The basins in this region mainly comprise extended continental and oceanic crust (Tamaki et al., 1992). A chain of seamounts and islands is distributed in these basins (Fig. 1). Volcanic rocks from seamounts in the Yamato Basin have ages of 13–6 Ma (Kaneoka et al., 1990; Kaneoka and Yuasa, 1988), whereas volcanism on Ulleung Island in the Tsushima Basin (Ulleung Basin) is much younger (< 2 Ma; Kim et al., 1999).
One basaltic sample containing mantle xenoliths was dredged from Seifu Seamount (herein called the SSM basalt) in the northeast Tsushima Basin in the southwest Sea of Japan (Fig. 1) (Ninomiya et al., 2007). Peridotites from back-arc basins have rarely been reported (Ichiyama et al., 2013; Ohara, 2006). Such xenoliths could provide insights into the architecture and history of the Sea of Japan basins. To evaluate the significance of these xenoliths, we report petrological, geochemical, and geochronological data for this mantle xenolith-bearing alkali basalt sample that was first described by Ninomiya et al. (2007).
Pouclet et al. (1995) summarized the magmatic history of the circum-Sea of Japan region, including the southwest Japan arc, northeast China, and back-arc basins (Japan Basin, Ulleung Basin, and Yamato Basin). Alkali basalt magmatism became common in the southwest Japan arc after the termination of extension in the Sea of Japan at < 4 Ma. Kim and Yoon (2017) suggested that seamounts in the Tsushima Basin were formed by post-back-arc spreading based on geochemical data for the alkali basalt samples studied by Lee et al. (2011). Sato et al. (2002) proposed that post-back-arc spreading magmatism during the last stages of back-arc basin spreading and after the cessation of spreading is a common process in the latter stages of back-arc development. Ishizuka et al. (2009) also investigated post-back-arc spreading magmatism in the Shikoku Basin of the Izu–Bonin arc–back-arc system. In this paper, we discuss the origin of the SSM basalt in the context of post-back-arc magmatism.
The Seifu Seamount is located at the northeastern margin of Tsushima Basin, which is a junction of three basins that are located between continental crustal fragments (Fig. 1). Tsushima Basin is now geomorphologically connected to the southwestern margin of the Japan Basin by the Ulleung Interplain Gap (UIG) and is separated from Yamato Basin by the Yamato Rise and Oki Bank. The studied basalt sample was dredged from the Seifu Seamount by the KT85-15 cruise of R/V Tansei Maru of the Ocean Research Institute, University of Tokyo, in 1985 (dredge station no. KT85-15 D-3; 38∘12.20′–12.80′ N and 132∘34.70′ E) (Shimamura et al., 1987). Lee et al. (1999) proposed that the basement of Tsushima Basin is thick oceanic crust formed by incomplete extension of continental crust, which was caused by the westward propagation of extension during the opening of the Sea of Japan. Tsushima Basin was opened in a N–S direction, as evidenced by the NE–SW orientation of ridge-like features parallel to the Yamato Basin spreading axis (Lee et al., 1999). Kim et al. (2011) showed that a chain of seamounts buried by sediments occurs along the UIG and proposed that the ages of the UIG seamounts are the same as those of the Yamato Seamount Chain. The Seifu Seamount is located in the Japan Basin in the most E-NE region of the UIG seamount chain.
The basalt sample contains peridotite xenoliths of variable size from a few millimeters to < 3 cm, although rare xenoliths are up to 10 cm in size, along with associated xenocrysts (Ninomiya et al., 2007) (Fig. 2). Ninomiya et al. (2007) divided the peridotite xenoliths into two types based on mineral chemistry (Types I and II). Type I xenoliths were interpreted to be residues after relatively high degrees of open system melting caused by light-rare-earth-element-enriched (LREE-enriched) fluids and melts, whereas Type II xenoliths have characteristics similar to subcontinental lithospheric mantle.
The basalt has a porphyritic texture, and the phenocrysts are mainly olivine, with small amounts of plagioclase, orthopyroxene, clinopyroxene, and spinel. Plagioclase phenocrysts are anhedral with albite twinning, oscillatory zoning, and dusty zones, and they are sometimes surrounded by tiny plagioclase crystals that are the same size as crystals in the groundmass. Orthopyroxene phenocrysts are rimmed by fine-grained mineral aggregates, which are similar to the orthopyroxenes in the peridotite xenoliths, indicating the orthopyroxene phenocrysts are xenocrysts. Spinel phenocrysts are up to 0.5 mm in size, anhedral, and rounded. The groundmass is crystalline, has an intersertal texture, and consists mainly of euhedral plagioclase, with small amounts of olivine that is partly serpentinized–altered, opaque minerals (ilmenite and titanomagnetite), apatite, and clinopyroxene (Fig. 2). Locally, the plagioclase crystals in the groundmass exhibit a weakly developed trachytic texture.
3.1 Analytical methods
Obvious crustal and mantle xenolith fragments were removed from the basalt sample before crushing to powder. Whole rock major and trace element compositions of the SSM basalt were determined by electron probe microanalysis (EPMA; JEOL JXA-8800 Superprobe) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) (Agilent 7500S coupled to a MicroLas GeoLas Q-Plus; Ishida et al., 2004) at Kanazawa University, Kanazawa, Japan. For the EMPA and LA-ICP-MS measurements, glass was prepared from the powdered sample with an Ir strip heater (Nicholls, 1974; Stoll et al., 2008), which comprises Cu electrodes connected to a direct current power supply and an Ir strip. Approximately 20 mg of the whole rock powder was fused on the Ir strip. A current of 42–45 A and heating duration of < 30 s were used to make the glass. The fused melt was quenched in an airstream after disconnecting the power supply. No visible residual and quench phases were observed in the glass. Details of this analytical method are described by Tamura et al. (2015).
EMPA was conducted with an accelerating voltage of 15 kV, beam current of 20 nA, and beam diameter of 10 µm. Natural and synthetic mineral standards provided by JEOL were used for all analyses. JEOL software with ZAF (Z is atomic number correction, A is absorption correction, and F is characteristic fluorescence correction) corrections was used for data reduction. X-ray peaks of all elements were counted for 10 s. Sodium and K intensities were monitored during analysis, and no loss of these elements was detected. BHVO-2 glass from the United States Geological Survey (Reference Materials Project; USGS) was analyzed repeatedly to assess data quality. Data precision was better than ±5 % and ±20 % (relative standard deviation) for elements with abundances of > 0.5 wt % and < 0.5 wt %, respectively (Table 1).
Major and trace element data were overall averages of two fused glasses. a Standard deviation (SD) with numbers of analyses (glass ∕ point). The fused glass of BHVO-2 (USGS powdered reference material) was prepared and measured for quality control in the analysis. b Relative deviation (RD) to GeoReM preferred values.
National Institute of Standards and Technology (NIST) SRM 612 standard glass was used as the primary calibration standard during LA-ICP-MS analysis and was analyzed at the beginning of each batch of ≤8 unknowns. A linear drift correction was applied between each calibration standard analysis. The elemental concentrations of NIST SRM 612 are the preferred values of Pearce et al. (1997). Data were also corrected using 29Si as an internal standard based on the Si contents obtained by EMPA, following the protocols of Longerich et al. (1996). NIST SRM 614 and BHVO-2 glasses were analyzed for data quality control purposes. The measured concentrations for NIST SRM 614 and BHVO-2 are within 10 % of previously reported data for these standards, and the precision was better than ±10 % (relative standard deviation) for all the analyzed elements.
The major element composition was also determined by X-ray fluorescence spectrometry (XRF; Rigaku Supermini) at Senshu University, Tokyo, Japan. The powdered sample was dried at 950 ∘C, and a mixture of this and lithium tetraborate (Li2B4O7) flux (1:5 weight ratio) was melted at 1200 ∘C. The analysis was performed using an accelerating voltage of 50 kV and beam current of 4.0 mA. Details of the XRF methodology are given by Sato (2010).
The analytical procedures used for the chemical separation and isotopic analysis of Sr, Nd, and Pb are outlined by Yoshikawa and Nakamura (1993), Shibata and Yoshikawa (2004), and Miyazaki et al. (2003), respectively. Mass spectrometry was conducted with a Thermo Finnigan MAT262 equipped with nine Faraday cups in static multi-collection mode. Normalizing ratios used to correct for isotopic fractionation were 86Sr∕88Sr = 0.1194, 146Nd∕144Nd = 0.7219, and 0.061 per atomic mass unit for Pb isotopes. Measured isotopic ratios for standard materials were 87Sr∕86Sr = 0.710261±0.000018 (2σ) for NIST 987, 143Nd∕144Nd = 0.511842±0.000018 (2σ) for La Jolla, and 206Pb∕204Pb = 16.937±0.006 (2σ), 207Pb∕204Pb = 15.491±0.0048 (2σ), and 208Pb∕204Pb = 36.721±0.026 (2σ) for NIST 981. Total procedural blanks for Sr, Nd, and Pb were < 100, < 10, and < 10 pg, respectively. The geochemical and isotopic data for the SSM basalt are summarized in Table 1.
We undertook 40Ar∕39Ar dating of the SSM basalt. The sample was crushed into grains that were < 2 mm in size, from which fresh groundmass was separated. Samples were wrapped in Al foil and loaded into an Al capsule (70 mm in length and 10 mm in diameter) with flux monitors EB-1 biotite (91.4±0.5 Ma; Iwata, 1997), K2SO4, and CaF2. The samples were irradiated for 24 h in the Japan Material Testing Reactor (JMTR). During irradiation, the samples were shielded by Cd foil in order to reduce thermal neutron-induced 40Ar production from 40K (Saito, 1994). The Ar extraction and isotopic analyses were conducted at the Radioisotope Center, University of Tokyo, Tokyo, Japan. During step heating, the gas was extracted in eight steps between 600 and 1300 ∘C. The dating method has been described by Ebisawa et al. (2004).
SiO2, TiO2, and total alkali contents (Na2O+K2O) of the SSM basalt are 49 wt %, 1.9 wt %, and 5.8 wt % (Na2O = 4.0 wt % and K2O = 1.8 wt %), respectively. The SSM basalt is classified as an alkali basalt in a total alkalis vs. SiO2 diagram (Miyashiro, 1978) (Fig. 3) and low-Ti basalt (TiO2 < 2.5 wt %, Ti∕Y < 500; Xu et al., 2001). The MgO content and ratio (FeO* = total FeO) are 6.4 and 1.5 , respectively.
A primitive-mantle-normalized trace element pattern is shown in Fig. 4. The SSM basalt is characterized by LREE enrichment and no apparent anomalies in Eu and high-field-strength elements (HFSEs) relative to neighboring REE, whereas Rb and Th exhibit slight negative anomalies. The (Nb∕La)PM and (Ta∕La)PM ratios are both ca. 1.5 (Fig. 5a), and the LaPM and (La∕Yb)PM ratios are 54 and 9, respectively. The trace element pattern of the SSM basalt is similar to those of ocean island basalt (OIB). However, the YbPM content is distinctly higher than those of OIB (Fig. 5b).
Isotopic analyses of the unleached and leached sample (6M HCl) were undertaken to evaluate the effects of alteration (Table 2). Although these isotopic compositions are slightly different, alteration has not significantly affected the isotopic data. The 143Nd∕144Nd and 87Sr∕86Sr ratios of the leached sample are 0.512903 and 0.703476, respectively (Fig. 6). The Pb isotopic ratios of the SSM basalt are 206Pb∕204Pb = 17.664, 207Pb∕204Pb = 15.434, and 208Pb∕204Pb = 37.308 (Fig. 6).
The 40Ar∕39Ar age spectrum of the SSM basalt has a plateau age of 8.33±0.15 Ma (2σ) in six fractions at lower temperatures (Fig. 7 and Table 3), with an initial 40Ar∕36Ar ratio obtained from an inverse isochron that corresponds to the atmospheric ratio (295.5; Fig. 7).
* Washed by 6M HCl. Total procedural blanks for Sr, Nd, and Pb were less than 100, 10, and 10 pg, respectively.
4.1 Timing of SSM basaltic magmatism
Basalt samples were recovered from the Sea of Japan by the ODP Leg 127–128 cruises in the Yamato Basin (Sites 794 and 797) and Japan Basin (Site 795) (e.g., Tamaki et al., 1992) (Fig. 1). 40Ar∕39Ar dating of these basalts indicated formation during back-arc magmatism at 21–18 Ma (Yamato Basin) and 25–15 Ma (Japan Basin) (Kaneoka et al., 1992). Back-arc basin basaltic (BABB) magmatism caused the extension of continental crust until 15 Ma (e.g., Kaneoka et al., 1992; Tamaki et al., 1992). 40Ar∕39Ar dating of andesitic rocks from the Yamato Basin seamounts yielded ages of 17–11 Ma (Kaneoka et al., 1990). The age of the SSM basalt (8.3 Ma) indicates formation shortly after the termination of Sea of Japan opening and is clearly older than volcanism on Ulleung and Jeju islands (< 2 Ma).
All errors are 1σ. After corrections for interfering isotopes from Ca and K as follows: [36Ar ∕ 37Ar]Ca: 0.000433±0.000013, [38Ar ∕ 37Ar]Ca: 0.0000182±0.0000033, [39Ar ∕ 37Ar]Ca: 0.001066±0.000022, [38Ar ∕ 39Ar]K: 0.017169±0.000060, [40Ar ∕ 39Ar]K: not detected. e .
4.2 Origin of the SSM basaltic melt
The trace element pattern of the SSM alkali basalt shows no depletion of Nb and Ta relative to LREE (e.g., Nb) and high REE (HREE) abundances (e.g., YbPM=6) (Fig. 5). The pattern is broadly similar to OIB-type alkali basalts from oceanic islands (e.g., Ulleung Island) and continental regions of east China, whereas the high HREE abundances distinguish the SSM basalt from other alkali basalts in the circum-Sea of Japan area (Fig. 5). Alkali basalts with high Nb ∕ La ratios and HREE abundances have also been reported from the South Korean Plateau, located to the east of the SSM (Lee et al., 2011) (Fig. 5c).
The FeO ∕ MnO ratio of a melt is a proxy for contributions from pyroxenite components in the mantle source (Herzberg, 2011). The FeO ∕ MnO ratio of the SSM basalt is 47, which is consistent with the partial melting of peridotite (50–60). Relatively high HREE abundances in the SSM basalt can be explained by the residual phases in the mantle source. Key elemental ratios, such as plots of Sm∕Yb vs. Nb∕Yb and Zr∕Y vs. Nb∕Yb, (Fig. 8), combined with simple partial melting models, show that garnet was not a residual phase in the mantle source. The formation of the SSM basalt can be explained by low-degree melting of spinel peridotite.
Geochemical contributions from slab-derived components were evaluated by ratios of elements partitioned into aqueous fluids (i.e., Ba) to elements partitioned into silicate melts (i.e., Th, Nb, and Ta), which were normalized to a compatible element in the subducted slab component (i.e., Yb) (Fig. 9). Using this approach, the SSM basalt has a MORB–OIB composition, whereas Sea of Japan BABB magmatism and basalts from southwestern Japan show the addition of slab-derived components.
Due to the very minor contributions from slab components to the SSM basalt source, the SSM basalt can be used to reveal the mantle components beneath the Sea of Japan back-arc region. In isotopic plots, the SSM basalt also has a MORB–OIB composition, whereas Sea of Japan BABB magmatism is characterized by MORB to island arc tholeiite–ocean island tholeiite (E-type) compositions (Allan and Gorton, 2006; Hirahara et al., 2015) (Fig. 7). The Nd–Sr–Pb isotopic compositions of the SSM basalt are depleted and are more similar to the depleted-type (D-type) Sea of Japan BABB magmatism than the other circum-Sea of Japan alkali basalts (Fig. 7). Hirahara et al. (2015) suggested that Sea of Japan BABB magmatism has a composition between DMM and slab-derived components. The D-type basalts were formed from DMM with little or no contribution from slab-derived components. Forward modeling indicated that the melting conditions for the D-type basalts were deeper and hotter than those for MORB (Hirahara et al., 2015). It is concluded that the SSM basalt mantle source was likely depleted MORB mantle (DMM) mixed with an enriched mantle component with EM1-like characteristics (Figs. 7 and 10).
4.3 Tectonic implications of the SSM basalt
The age and geochemistry of the SSM basalt suggest that upwelling of the Sea of Japan back-arc asthenosphere continued after the cessation of back-arc spreading, resulting in low-degree partial melting (Fig. 10). Sato et al. (2002) described post-spreading magmatism that formed seamounts, which comprise enriched basalts, in the back-arc region of the Shikoku Basin that formed during and/or after the last stages of back-arc spreading. Sato et al. (2002) suggested that post-spreading magmatism is a common process in back-arc basins in the western Pacific. For example, in contrast to the spreading-related magmatism (30–15 Ma), enriched basaltic magmatism (Kinan Seamount Chain; Fig. 1: 15–7 Ma) has been identified in the Shikoku Basin in the Izu–Bonin back-arc (Sato et al., 2002; Ishizuka et al., 2009). The age of the SSM basalt (8.3 Ma) is ca. 7 Myr younger than the termination of Sea of Japan spreading (∼15 Ma) and similar to that of post-spreading magmatism in the Shikoku Basin. Ishizuka et al. (2009) suggested that post-back-arc spreading magmatism in the Shikoku Basin was caused by heterogeneities in the upwelling asthenospheric mantle, which produces BABB melts beneath the back-arc spreading center.
Alkali basalts from the South Korean Plateau also have distinctive Nd–Sr isotopic compositions, which are similar to the SSM basalt (Fig. 5a), whereas their Pb isotopic compositions are similar to Sea of Japan BABB magmatism (Fig. 7). The isotopic compositions of the SSM basalt are similar to those of 13–6 Ma trachyandesites from seamounts in the Yamato Basin (Tatsumoto and Nakamura, 1991). Based on geochemical data for South Korean Plateau basalts and the tectonic history of the Tsushima Basin, Kim and Yoon (2017) concluded that these basalts were the product of post-spreading magmatism. However, the age of these basalts is unknown. Numerous submarine volcanoes, including seamounts buried by sediments, were discovered in the Sea of Japan (e.g., Kimura et al., 1987; Kim et al., 2011) (Fig. 1). These submarine volcanoes and seamounts were also likely formed after back-arc spreading ceased.
Based on our study of the SSM basalt coupled with earlier preliminarily works on peridotite xenoliths in the SSM basalt, Ninomiya et al. (2007) suggest that the peridotite xenoliths in the SSM basalt seem not to be directly related to the SSM basalt petrogenesis (Fig. 10). One of the two types of peridotite xenoliths is interpreted as fragments of subcontinental lithospheric mantle that were already located before the Sea of Japan opening. The other type, which is characterized by residue after open system melting caused by the infiltration of LREE-enriched fluids, may be related to back-arc spreading magmatism affected by slab-derived fluids and melts (Fig. 10). Further study of peridotite xenoliths and mafic xenoliths is needed to reconstruct the crust–mantle evolution beneath the Sea of Japan.
Alkali basalts have also been reported from the Philippine Sea Plate (Kinan Seamount Chain; Sato et al., 2002; Ishizuka et al., 2009) and Pacific Plate (petit-spot magmas; Fig. 1; (Hirano et al., 2006; Machida et al., 2009) near the Sea of Japan in the western Pacific. The geochemical characteristics of the SSM basalt are similar to those of the Kinan Seamount Chain but different from those of petit-spot magmas (Figs. 3–6). The involvement of an EM1 component in the mantle source is a minor but pervasive feature in both the Sea of Japan and Shikoku Basin in the western Pacific.
The SSM basalt (8.3 Ma) formed ca. 7 Myr after the termination of Sea of Japan spreading (∼15 Ma). The SSM basalt formed by the low-degree partial melting of spinel peridotite and was the result of post-back-arc spreading magmatism in the Sea of Japan. The SSM basalt mantle source is consistent with being DMM with a minor EM1-like contribution. Geochemical similarities between post-back-arc magmatism in the Sea of Japan and Shikoku Basin of the Philippine Sea suggest the EM1 component is a minor, but widespread, component beneath the western Pacific. Peridotite xenoliths in the SSM basalt do not appear to be directly related to the SSM basalt petrogenesis but will shed light on the crust–mantle evolution beneath the Sea of Japan.
Data are available upon request.
TM and AT prepared the paper with contributions from all co-authors. NH and HS conducted Ar isotope analyses. HS, RN, and AT conducted major and trace element analyses. TS and MY conducted Sr, Nd, and Pb isotope analyses.
The authors declare that they have no conflict of interest.
We are grateful to Captain K. Miki, T. Kato, and the other crew members of the R/V Wakashio Maru, Captain H. Igarashi and crew members of the R/V Tansei Maru, and the scientists that participated on these cruises. Comments from two anonymous reviewers and the editor have greatly improved this paper. We also thank T. Ishii for providing the studied sample.
This research has been supported by Kanazawa University (grant no. SAKIGAKE 2018) and the Ministry of Education Culture, Sports, Science, and Technology of Japan (Grants-in-Aid nos. 16H05741 and 19H01990).
This paper was edited by Johan Lissenberg and reviewed by two anonymous referees.
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