Research article 11 Jul 2016
Research article | 11 Jul 2016
Fixation kinetics of chelated and non-chelated zinc in semi-arid alkaline soils: application to zinc management
Theophilus K. Udeigwe et al.
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T. K. Udeigwe, M. B. Eichmann, M. C. Menkiti, and N. Y. O. Kusi
Solid Earth, 7, 311–321, https://doi.org/10.5194/se-7-311-2016, https://doi.org/10.5194/se-7-311-2016, 2016
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Fixation pattern and kinetics of chelated and non-chelated Cu compounds in semiarid soils were examined. 22% more Cu was fixed in the non-chelated system within the first 14 days (difference of only 7% by day 90). The slope of change in Cu in respect to other nutrients was higher in the non-chelated system. Fixation of Cu was better described by the power function and second-order models in the non-chelated and chelated systems, respectively. Findings are vital for improved nutrient management.
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This study extends the application of the portable X-ray fluorescence (PXRF) spectrometry to semiarid urban landscapes. PXRF findings indicated strong positive relationships among elements and between elements and soil constituents, particularly in the non-managed areas with less anthropogenic influences. As, Cr, Fe, Mn, and Ni could be of lithogenic origin, while Cu, Pb, and Zn are due to anthropogenic influences. PXRF proves to be valuable tool for the rapid examination of elemental chemistry.
J. Young, T. K. Udeigwe, D. C. Weindorf, T. Kandakji, P. Gautam, and M. A. Mahmoud
Solid Earth, 6, 393–402, https://doi.org/10.5194/se-6-393-2015, https://doi.org/10.5194/se-6-393-2015, 2015
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Potential management-induced soil salinization in golf courses in semi-arid landscape was evaluated and salinity further examined using the portable x-ray fluorescence (PXRF) spectrometer. Soil electrical conductivity, exchangeable sodium percentage, and sodium adsorption ratio were for the most part significantly higher in the managed areas of the golf facilities. PXRF findings predicted salinity and suggested possible differences in chemical species and sources that contribute to soil salinity
T. K. Udeigwe, M. B. Eichmann, M. C. Menkiti, and N. Y. O. Kusi
Solid Earth, 7, 311–321, https://doi.org/10.5194/se-7-311-2016, https://doi.org/10.5194/se-7-311-2016, 2016
Short summary
Short summary
Fixation pattern and kinetics of chelated and non-chelated Cu compounds in semiarid soils were examined. 22% more Cu was fixed in the non-chelated system within the first 14 days (difference of only 7% by day 90). The slope of change in Cu in respect to other nutrients was higher in the non-chelated system. Fixation of Cu was better described by the power function and second-order models in the non-chelated and chelated systems, respectively. Findings are vital for improved nutrient management.
T. K. Udeigwe, J. Young, T. Kandakji, D. C. Weindorf, M. A. Mahmoud, and M. H. Stietiya
Solid Earth, 6, 415–424, https://doi.org/10.5194/se-6-415-2015, https://doi.org/10.5194/se-6-415-2015, 2015
Short summary
Short summary
This study extends the application of the portable X-ray fluorescence (PXRF) spectrometry to semiarid urban landscapes. PXRF findings indicated strong positive relationships among elements and between elements and soil constituents, particularly in the non-managed areas with less anthropogenic influences. As, Cr, Fe, Mn, and Ni could be of lithogenic origin, while Cu, Pb, and Zn are due to anthropogenic influences. PXRF proves to be valuable tool for the rapid examination of elemental chemistry.
J. Young, T. K. Udeigwe, D. C. Weindorf, T. Kandakji, P. Gautam, and M. A. Mahmoud
Solid Earth, 6, 393–402, https://doi.org/10.5194/se-6-393-2015, https://doi.org/10.5194/se-6-393-2015, 2015
Short summary
Short summary
Potential management-induced soil salinization in golf courses in semi-arid landscape was evaluated and salinity further examined using the portable x-ray fluorescence (PXRF) spectrometer. Soil electrical conductivity, exchangeable sodium percentage, and sodium adsorption ratio were for the most part significantly higher in the managed areas of the golf facilities. PXRF findings predicted salinity and suggested possible differences in chemical species and sources that contribute to soil salinity
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Short summary
Micronutrient fixation leads to the reduction of plant-available portions. This study examined the fixation kinetics of chelated and non-chelated zinc (Zn) in semi-arid soils. About 30 % more Zn was fixed in the non-chelated system in the first 14 days. Slope of change of Zn to Cu (i.e., Cu–Zn) was higher than other micronutrients. Zn fixation kinetics were better described by a power-function model. Tools developed from this study will be used to advance micronutrient management.
Micronutrient fixation leads to the reduction of plant-available portions. This study examined...