Through geological mapping we find that fault zone internal structure depends on whether or not the fault cuts multiple lithologies, the presence of shale layers, and the orientation of joints and coal cleats at the time of faulting. During faulting, cementation of fractures (i.e. vein formation) is highest where the fractures are most connected. This leads to the counter-intuitive result that the highest-fracture-density part of the network often has the lowest open-fracture connectivity.