the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Revisiting Gassmann-type relationships within Biot poroelastic theory
Yury Alkhimenkov
Yury Y. Podladchikov
Gassmann's equations have long served as a cornerstone of geophysics and rock physics, widely regarded as exact within their domain of applicability. However, recent studies have questioned their validity, arguing that Gassmann's derivation involves a logical error and that an additional solid modulus is needed even for monomineralic materials. In this work, we present a general derivation of the extended Biot poroelasticity equations, grounded in conservation laws and classical irreversible thermodynamics (CIT). We show that the formulations of Gassmann (1951), Brown and Korringa (1975), Detournay and Cheng (1993), and Rice and Cleary (1976) emerge as special cases of this unified framework. While previous studies have analyzed the thermodynamic admissibility of standard Biot and Gassmann models, we extend this analysis to the more general theory by explicitly incorporating the off-diagonal terms arising from the second partial derivatives (Hessian) of internal energy. A key finding is that Gassmann's self-similarity condition – that porosity remains unchanged under equal changes in fluid and total pressure – is a sufficient but unnecessary condition for the derivation of Gassmann-type relationship between undrained and drained bulk moduli. It holds if and only if the matrix of the second partial derivatives of internal energy is diagonal. When the off-diagonal terms in this matrix are retained, a generalized form of Gassmann's equations is required, which we derive. To promote transparency and support further research, we provide symbolic Maple routines with thermodynamic consistency checks, ensuring full reproducibility and accessibility.
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Gassmann's equations (Gassmann, 1951), developed several decades ago, are fundamental in geophysics for analyzing the elastic properties of fluid-saturated porous media. These equations provide a means to predict seismic velocities and mechanical behavior in such materials. However, despite their widespread use, recent studies have questioned the logical consistency of Gassmann's derivation, suggesting that it contains a logical error (Thomsen, 2023a, b, 2024, 2025). This has highlighted the need for an extended, transparent, and thermodynamically consistent framework to ensure reliability in geophysical modeling and interpretation.
This paper presents a structured, transparent, and fully reproducible derivation of the extended Biot poroelastic equations, with the formulations of Gassmann (1951), Detournay and Cheng (1993), Brown and Korringa (1975), and Rice and Cleary (1976) emerging as special cases. Our approach is rooted in fundamental conservation laws and classical irreversible thermodynamics (CIT) (Lebon et al., 2008). While earlier works have demonstrated the thermodynamic admissibility of the standard Biot and Gassmann models (Coussy et al., 1998; Yarushina and Podladchikov, 2015), we extend this analysis to a broader class of models by evaluating the full Hessian matrix (i.e., matrix of second partial derivatives) of internal energy.
We respond directly to the critiques presented in Thomsen (2023a, b, 2024, 2025), adopting the CIT formalism as described in Lebon et al. (2008) and extended to poromechanics by Yarushina and Podladchikov (2015). We demonstrate the thermodynamic admissibility of the extended Biot equations by incorporating entropy production constraints and the internal-variable formalism of CIT. Internal consistency is verified through both theoretical analysis and numerical evaluation. In particular, we emphasize the interplay between thermodynamic forces and fluxes, entropy production, and the admissibility of constitutive laws.
The paper is structured as follows: we begin by reviewing the foundational equations of classical irreversible thermodynamics, highlighting the roles of thermodynamic forces and fluxes. We then derive the evolution equations for the extended Biot poroelastic system, followed by formulations of the Detournay–Cheng (DC), Brown–Korringa (GK), and Gassmann models. Afterwards, we revisit Gassmann's assumptions and delineate the specific conditions under which they remain valid. We also directly address the critiques raised in Thomsen (2023a, b, 2024, 2025) regarding the validity of Gassmann's equations.
To ensure full reproducibility, we provide symbolic Maple routines with detailed line-by-line commentary, enabling transparent derivation and verification. This framework also supports future extensions, including multiphase flow and viscous deformation mechanisms. All Maple scripts are available in a symbolic archive via a permanent DOI on Zenodo: https://doi.org/10.5281/zenodo.15777522 (Alkhimenkov and Podladchikov, 2025).
One can distinguish between two related but distinct tasks in the formulation of coupled (poroelastic) theories: (i) identifying the appropriate set of state variables that fully describe the coupled mechanical behavior and (ii) deriving the material parameters that link these variables. Task (i) is particularly challenging and has been addressed by numerous researchers; a comprehensive review is beyond the scope of this article. In this work, we build on those earlier studies and assume from the outset that the correct variables have been identified.
Task (ii), while relatively more straightforward, remains essential: various modifications of poroelastic theory have been proposed, often based on simplifying assumptions that affect how material parameters are defined and interpreted. The main novelty of this article is the consideration of the full Hessian matrix of second derivatives of internal energy, including the off-diagonal terms (which are often neglected in classical formulations), which enables us to derive a generalized set of Gassmann-type relations. Furthermore, we demonstrate that, under appropriate mappings between poroelastic coefficients, several classical poroelastic theories can be viewed as equivalent.
General pattern of the derivation
To derive the extended Biot poroelastic equations, one typically combines the following components:
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Conservation laws
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Conservation of linear momentum for the total stress,
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Conservation of mass for the solid phase,
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Conservation of mass for the fluid phase.
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Fluid dynamics
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Darcy's law for the Darcy flux qD (assuming low-Reynolds-number flow).
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Isothermal constitutive relations
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A solid density–pressure constitutive law (equation of state),
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A fluid density–pressure constitutive law (equation of state),
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A porosity constitutive law (e.g., pore compressibility),
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Stress–strain relation for the deviatoric components of the stress and strain tensors.
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By expressing the solid and fluid densities, along with the medium's porosity, in terms of pressures and fluxes via these constitutive laws, one obtains the extended Biot poroelastic equations. Under additional simplifying assumptions, the formulation reduces to the classical Biot poroelastic equations (Biot, 1962), the Brown and Korringa equations (Brown and Korringa, 1975), the Rice and Cleary (1976) equations, and Gassmann's equations (Gassmann, 1951) as limiting cases. In the case of Biot poroviscoelasticity, viscous effects are incorporated through the specific choice of the porosity evolution law (Yarushina and Podladchikov, 2015), which can include time-dependent or rate-sensitive terms. To ensure thermodynamic consistency, these constitutive relations are derived within the framework of classical irreversible thermodynamics, which we describe in the following section.
4.1 Local entropy production
In the context of classical irreversible thermodynamics (CIT) (Lebon et al., 2008), the hypothesis of local thermodynamic equilibrium (LTE) implies that energy is well defined as a single-value function at each state of the system. Moreover, for a unit mass of a solid skeleton, in agreement with the main assumption of CIT, the infinitesimal change in internal energy Us follows its equilibrium relationship via the corresponding changes in entropy Ss per unit mass, density ρs, and the elastic part of porosity (Yarushina and Podladchikov, 2015):
where T is the absolute temperature, ps is the solid pressure conjugated to solid density change, is the thermodynamic variable (pressure) conjugated to porosity change (to be defined), is the solid volume fraction, superscript “e” represents reversible (elastic) change (, with ϕf being the medium's porosity), and can be viewed as analogy to pressure as conjugate variable to volume change. The individual terms in this energy balance are interpreted as
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TdSs: heat stored in internal energy Us,
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: energy change due to compressibility of solid grains (volumetric Hooke's law),
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: poroelastic effects (reversible part of the energy change due to the changes in porosity).
Note that is not defined yet.
4.2 Entropy production for poroelastic loading
In the context of poroelasticity, the most important outcome from Appendix B is an expression for entropy production, , associated with elastic (reversible) porosity change:
where ps is the solid pressure and pf is the fluid pressure. Entropy production must be zero for reversible poroelastic deformation; therefore (!). This implies that (Yarushina and Podladchikov, 2015)
We also notice that , where represents the effective pressure (total pressure is defined as ). For an explanation of the Maple script used in the derivation and analysis of entropy production in a single-phase medium, see Appendix A. Appendix B provides a similar explanation for the entropy production derivation in a two-phase porous medium.
4.3 Internal energy of the solid frame
We begin with the internal energy of representative infinitesimal solid skeleton (frame) linked to material points (grains) of the solid skeleton in a Lagrangian fashion, Us(Vs,ϕs), per unit mass. Here, Vs is the (Lagrangian) solid volume, is the solid volume fraction, and Vt is the (Lagrangian) total volume (including both volumes occupied by porous fluid and grains of solid matrix bounded by a boundary moving with solid velocity of solid grains). A first-order Taylor expansion about an equilibrium state yields
where and . The energy increment ΔUs is
The internal energy Us is a scalar potential defined on a smooth, convex state space, where the Hessian matrix is symmetric:
where H is the Hessian matrix of second derivatives of the internal energy with respect to Vs and ϕs:
The increment of the first derivatives of ΔUs is
For isothermal processes and in agreement with CIT (Eq. 1), ΔUs can be also expressed via mechanical variables only:
By comparing Eqs. (8) and (9), we identify
Therefore, the following linear system holds:
We then use the following equation of state for the fluid for isothermal processes:
where βf is the fluid compressibility. Equations (11) and (12) are used by Yarushina and Podladchikov (2015) (assuming simplified diagonal Hessian matrix H) as constitutive closure relationships (their Eqs. 6–8).
Here, we provide a derivation which is similar to the one proposed by Yarushina and Podladchikov (2015) in terms of underlying constitutive closer relationships. Unlike Yarushina and Podladchikov (2015), we start from the Hessian matrix H and provide a detailed derivation, without skipping any intermediate steps.
5.1 Derivation of the original Biot–Gassmann equations
We consider a simplified diagonal version of the full compliance matrix H (Eq. 11):
We further use the following relation between density increments and solid volume change:
In addition, we use the following identity:
Equation (13) can be now rewritten as
We solve Eq. (16) with respect to and . The resulting expressions are cumbersome and can be directly accessed via the Maple scripts provided:
5.2 The incremental formulation
The next step is the substitution of the resulting equations for and into the mass conservation equations, which is explored below. Now, we transition from differentials into the incremental formulation and use the following identity:
where we adopt material (Lagrangian) time derivatives. We use the following notation: denotes the Lagrangian (material) derivative with respect to solid, and denotes the Lagrangian (material) derivative with respect to fluid, where and are the fluid and solid velocities, respectively. The Einstein summation convention is used: summation is applied over repeated indices.
We rewrite Eq. (12) in a rate form:
We adopt the following approximate relations, which are strictly valid under small strains:
Approximations (21)–(22) are implicitly assumed in Yarushina and Podladchikov (2015). For Eq. (21), this approximation is valid when the relative velocity between fluid and solid phases is small or when the fluid pressure gradient is negligible.
5.3 Conservation of mass in a rate form
Conservation of mass for fluid phase in rate form is
and conservation of mass for the solid phase in rate form is
Equations (23)–(24) can be reformulated for divergences and :
where is the Darcy flux.
5.4 Relations between total, solid, and fluid pressures
Note that the material derivatives of the total pressure, , and the solid pressure, ps, are related via
Equation (27) for solid pressure ps can be simplified by neglecting the porosity derivative term:
5.5 Resulting equations of Biot–Gassmann theory
We then adopt the relation (28) and replace ps in favor of . By simplifying Eqs. (25)–(26), we can write the following relation:
We note that a12=a21, which is explicitly derived rather than imposed (this fact is explored in more detail for the case of the full matrix H and is provided below). Let us define the following compressibilities:
which gives
Then, we introduce α as
which gives
Finally, we introduce B as
By using the definitions (30)–(34), we can rewrite Eq. (29) in the following form:
which is the original Biot poroelastic equation (Biot, 1962) extended to an incremental large-strain formulation (Yarushina and Podladchikov, 2015). Equation (35) reduces exactly to the original Biot formulation (Biot, 1962) if we assume small strains. We also note that the expression (32) for α can be written as
5.6 Key observations
To derive the original Biot–Gassmann poroelasticity relations, one should use the proposed rheological relationship (13) and the two equalities (21) and (22). The relationship (13) implies the following identity:
where the poroelastic constant (compressibility) βϕ is defined as the linear rheological relationship during reversible poroelastic part of deformation.
Equality (1) in Eq. (37) is the primary assumption made by Biot (1962) and by Gassmann (1951) (also used by Yarushina and Podladchikov, 2015). It postulates that equal changes in total and fluid pressure leave porosity unchanged. This assumption is often referred to as the self-similarity hypothesis and is equivalent to assuming that the matrix of second-order derivatives of internal energy, H, is diagonal (see Eq. 13). Equality (2) in Eq. (37) results from the thermodynamic admissibility condition of Yarushina and Podladchikov (2015), which leads to the relation , derived in Sect. 4.2.
We can infer the expression for βϕ introduced in Eq. (37), which directly follows from Eq. (13) once we substitute expressions for H1,1 and H2,2:
The proposed rheological relationship (13) and the equalities (17) and (18) inserted into the mass conservation Eqs. (25) and (26) fully define the original Biot–Gassmann poroelasticity framework (Gassmann, 1951; Biot, 1962). As a consequence, the theory contains three exact constitutive laws: (i) the effective stress law (explored below); (ii) Gassmann relation for the undrained bulk modulus (βu is the undrained compressibility); and (iii) the relation between the effective compressibility βϕ, the solid grains' compressibility βs, and the drained (or dry) frame compressibility βd.
5.7 Effective stress law
Nur and Byerlee (1971) provided an exact expression for the effective stress law, which is widely regarded as a fundamental result in poroelasticity. It is defined by the following relation:
where the drained compressibility, βd, can be measured experimentally as
The exact effective stress law given by Eq. (39) follows directly from the derived poroelastic expressions.
5.8 Resulting equations of Biot–Gassmann theory for bulk moduli
To derive the original Biot poroelastic equations (Biot, 1962) in stiffness form, we invert the coefficient matrix in Eq. (35):
where is the drained bulk modulus (i.e., βd is the drained compressibility). The resulting expression for stiffness is
where . The poroelastic constants used in Eq. (42) are
where the bulk moduli are defined as the reciprocals of the corresponding compliance parameters: and .
5.8.1 Original Gassmann's equations
The relation between the undrained bulk modulus Ku (see Eq. 42 under the constraint ) and the drained bulk modulus Kd is known as Gassmann's equation (Gassmann, 1951):
According to Gassmann's theory, the shear modulus of a fluid-saturated rock Gu is equal to the shear modulus of the dry (drained) rock Gd:
The expression (45) is obtained by inverting the coefficient matrix in Eq. (35), leading to the stiffness form given in Eq. (42). An English translation of the original German-language article by Gassmann (1951) is provided in Pelissier et al. (2007). Gassmann's relation (45) can also be rewritten in terms of bulk modulus as
5.8.2 Assumptions behind the derivation of original Gassmann's equations
The following assumptions are made throughout the derivation of Biot's poroelastic equations and Gassmann's equations to ensure the validity of the results:
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The material is assumed to be linearly elastic, and the strains are small.
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The porous medium is considered homogeneous and isotropic and a fully interconnected pore network.
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The interactions between the solid and fluid phases are governed by linear constitutive laws, and the fluid flow obeys Darcy's law (or, equivalently, the fluid is governed by the quasi-static Navier–Stokes equations for a compressible fluid).
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The self-similarity hypothesis: that equal changes in pore (fluid) pressure and confining (total) pressure result in no change in porosity ϕf. This is equivalent to assuming a diagonal compliance matrix H (see Eq. 6).
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The derivation assumes a quasi-static process, such that inertial effects can be neglected.
These assumptions provide a simplified framework for the derivation and are thermodynamically admissible. One of the key assumptions in the original derivation of Gassmann's equations (Gassmann, 1951) is the self-similarity hypothesis – equal changes in total and fluid pressure leave porosity unchanged – explicitly stated in the original article.
6.1 Goal
Recall the structure of the original Biot–Gassmann formulation (35):
This relationship was originally derived under the assumption that the Hessian matrix H is diagonal. Here, we aim to extend this result by retaining the full matrix H, including its off-diagonal terms, and to derive an analogous relationship that preserves the original structure and introduces generalized parameters. To this end, we follow the same steps as outlined in Sect. 5, with the goal of obtaining Gassmann-type relationships for the extended Biot poroelastic theory.
6.2 Derivation
We now consider the full compliance matrix H (Eq. 6):
Note that H12=H21 due to the structure of the matrix H: the off-diagonal component H12 corresponds to the second mixed partial derivative of internal energy, firstly with respect to Vs and then to ϕf, and must be equal to H21, which is the derivative taken in the opposite order. This symmetry holds because the internal energy is assumed to be a smooth (twice continuously differentiable) scalar function of its state variables (this is also known as the symmetry of second derivatives). Then, we follow the same steps as in Sect. 5 by using identities (14)–(15) and arrive at the following equations:
which are cumbersome and can be found in the Maple script. We then use identities (21)–(22). Following the steps provided in Sect. 5, we substitute the resulting equations for (Eq. 50) and (Eq. 51), rewritten in a rate form, into the mass conservation Eqs. (25)–(26).
6.3 Resulting equations of the extended Biot poroelastic theory
We again adopt the relation (28) and express ps in terms of . Substituting Eqs. (50)–(51) into the mass conservation Eqs. (25)–(26) yields
We note that , which is not imposed by symmetry but emerges naturally from the substitution of Eq. (49) into the mass conservation Eqs. (25)–(26). This symmetry is a direct consequence of the algebra.
Following the approach of Sect. 5, we now define the compressibilities. Firstly, we define
which gives
Then, we introduce αEB as
which gives
Finally, we introduce BEB as
where is defined by the following relation: . By using the definitions (53)–(57), we can rewrite Eq. (52) in the following form:
which is the incremental form of the large-strain extended Biot poroelastic formulation. Note that we did not define a particular expression for H1,2, which can be set arbitrarily via the introduction of a new parameter .
To derive the extended Biot poroelasticity relations, we used only the proposed rheological relationship (49) and the two equalities (21) and (22). The relationship (49) denotes the following identity:
where the poroelastic constant (compressibility) can be defined as a coefficient in front of effective pressure :
Therefore, Eq. (59) can now be written as
To further simplify the notation, we can introduce and solve for H1,2 with the following equation:
which gives
Substituting Eq. (63) in the expression for B (Eq. 57) gives the simplified relation:
We also note that the expression (55) for αEB can be written as
Furthermore, Eq. (62) can now be rewritten as
6.4 Relations between poroelastic parameters and H
We can write the relations between poroelastic parameters and H as follows:
and
The relations between poroelastic parameters (Eq. 54), (Eq. 67), (Eq. 68), αEB (Eq. 55), and BEB (Eq. 57, in which and are substituted) are fully expressed in terms of the components of the Hessian matrix H.
6.5 Gassmann-type relation
The equations for the undrained compressibility in the framework of the extended Biot poroelastic formulation is
which has a structure similar to the original Gassmann Eq. (45).
In this section, we assume that small strains enable a direct comparison with other classical poroelasticity models, which are typically formulated within the infinitesimal deformation framework.
7.1 Comparison against the poroelasticity model of Detournay and Cheng (1993)
7.1.1 Rheology
Detournay and Cheng (1993) postulate linear rheological relationships that connect the volumetric response of the porous medium to increments in fluid and effective pressures:
These expressions describe how the total volume Vt and pore volume Vp deform in response to changes in fluid pressure pf and effective pressure , where is the total pressure. The mechanical interpretation of the four compressibilities , , , and has been defined in Detournay and Cheng (1993). Note that, by invoking the Betti–Maxwell reciprocal theorem, Detournay and Cheng (1993) suggest that and .
7.1.2 Geometry and kinematics
Detournay and Cheng (1993) use exact relations that connect the total, solid, and pore volumetric responses with porosity changes. Assuming control volumes and using finite changes, the following identities hold:
7.1.3 Porosity evolution and solid volume change
Combining the rheological relations (70) with the geometric identities (71)–(72) yields compact expressions for the porosity variation and the solid volume strain (Detournay and Cheng, 1993):
where .
The resulting representation of Detournay and Cheng (1993) is
The inverse form, expressing the time evolution of pressure fields in terms of mechanical and hydraulic divergence rates, reads as follows:
The poroelastic constants used in Eqs. (75)–(76) are (, , )
This expression has a similar structure to the original Gassmann Eq. (45). We emphasize that these expressions arise naturally as a special case of the present extended Biot poroelastic formulation, which is shown below. In particular, the Detournay–Cheng model assumes small strains and constant poroelastic parameters, whereas, in our framework, large-strain incremental formulation is adopted; thus, porosity evolution is present, and the coupling coefficient BEB(ϕf) varies with porosity.
7.2 Comparison against the poroelasticity models of Brown and Korringa (1975) and Rice and Cleary (1976)
The poroelasticity formulation of Brown and Korringa (1975) can be rewritten using the notation introduced by Thomsen (2025), in terms of the drained bulk modulus , the “mean” grain modulus , and the overall modulus of the heterogeneous solid constituent of the rock .
The drained compressibility is defined as (Brown and Korringa, 1975; Thomsen, 2025)
where pe is the effective (or differential) pressure, . The compressibility with respect to pore pressure at constant total stress is (Brown and Korringa, 1975; Thomsen, 2025)
The undrained compressibility is (Brown and Korringa, 1975; Thomsen, 2025)
Brown and Korringa (1975) and Thomsen (2025) introduce the following compressibilities for the pore volume:
Thus, the variation in pore volume can be written as (Brown and Korringa, 1975; Thomsen, 2025)
Finally, the undrained compressibility can be written as
Thomsen (2025) used the following identity:
Brown and Korringa (1975) also showed that . Finally, the resulting expression of Brown and Korringa (1975) for the undrained compressibility in the notation provided by Thomsen (2025) is
or, in terms of bulk moduli, which can be explicitly written as (, , , , ) (Thomsen, 2025),
where
and BBK can be calculated from the equality (92).
7.3 Equivalence of the Brown–Korringa (BK) model and Detournay–Cheng (DC) model
The Detournay–Cheng (DC) model is fully equivalent to the Brown–Korringa model if a proper mapping between the poroelastic parameters is established (i.e., and to and ). Using the assignments
we find that the two models (the DC model and the Brown–Korringa model) are algebraically identical. When , it immediately follows that , and the two models reduce to the classical Biot–Gassmann formulation.
The algebraic equivalence between these formulations can also be established by the following exact relation:
This analysis shows that the Brown–Korringa model is distinct from the Detournay–Cheng formulation in terms of the parameter definitions and the physical interpretation and experimental measurability of the poroelastic coefficients.
7.4 Equivalence of the present extended Biot formulation and the Detournay–Cheng (DC) model
Here we show that the present extended Biot formulation contains the Detournay–Cheng (DC) model as a special case. Indeed, if we set and choose
the present extended Biot formulation will be exactly equivalent to the Detournay–Cheng (DC) model in the small-strain regime. We refer to the provided Maple script for more details.
7.5 Equivalence of the present extended Biot formulation and the Brown–Korringa (BK) model
Here we show that the present extended Biot formulation contains the Brown–Korringa (BK) model as a special case. Indeed, if we set , use identity (94), and choose
the present extended Biot formulation will be exactly equivalent to the Brown–Korringa (BK) model in the small-strain regime. We refer to the provided Maple script for more details.
The conservation of linear momentum is given by
where is the deviatoric stress tensor, δij is the Kronecker delta, and . The total density is given by , where ρs and ρf are the solid and fluid densities, respectively. The vector gi denotes the components of gravitational acceleration.
Viscous fluid flow through the porous medium is governed by Darcy's law:
where k is the permeability of the medium and ηf is the fluid shear viscosity.
The matrix of coefficients in Eq. (58) can be inverted, yielding
where the abbreviated definition is used and the parameters are functions of porosity ϕf, meaning that BEB=BEB(ϕf).
Deviatoric stresses are related to solid velocity gradients through the following relationship:
where Gu is the undrained shear modulus of the saturated porous medium (it is assumed that the dry or drained shear modulus is equivalent to Gu; i.e., Gd=Gu) and
is the Jaumann objective stress rate. The tensor denotes the antisymmetric part of the solid velocity gradient.
The poroelastic constants in expression (100) can be defined in terms of compliance parameters as
where corresponds to the drained (or dry) compressibility and denotes the undrained compressibility. Note that the porosity ϕf evolves according to the evolution Eq. (66), which in turn affects the poroelastic parameter BEB=BEB(ϕf) at each loading increment. Finally, we can use the Carman–Kozeny relationship to model permeability evolution as a function of porosity (where ϕ0 is the reference porosity of the medium and k0 is the reference permeability), given by
Equations (98)–(106) fully represent the quasi-static extended Biot poroelasticity formulation.
Alkhimenkov (2023) performed a numerical validation of Gassmann's equations considering a 3D numerical setup and relatively complex pore geometry that included narrow regions (cracks) and large pore space (Fig. 1a–b). The numerical model consisted of a solid phase representing the grain matrix and a pore space. The model was cubic, with dimensions of . The pore space comprised cracks, modeled as flat cylinders, connected to an internal cubic cavity, as illustrated in Fig. 1a–b. The material properties used in the simulations are listed in Table 1, while the geometrical characteristics of the pore space are provided in Table 2.
Alkhimenkov (2023) applied a 3D finite-element method to resolve the conservation of linear momentum coupled with the stress–strain relations for the solid phase and the quasi-static linearized compressible Navier–Stokes momentum equation for the fluid phase. The resulting system of equations was solved using a direct PARDISO solver (Schenk and Gärtner, 2004). Alkhimenkov (2023) conducted a convergence study showing that, for finer resolution, the result of the numerical solution converges towards the result obtained from the original Gassmann's equation. Such a convergence analysis validates the accuracy of Gassmann's equation for a particular (but arbitrary) pore geometry. Furthermore, the pore geometry that was used did not contain any special features (among all possible geometries) that were tailored to make it consistent with Gassmann's equations (Alkhimenkov, 2024). There are also other 3D numerical studies that consider different geometries of the pore space and that are consistent with Gassmann's equations (Alkhimenkov et al., 2020a, b; Alkhimenkov and Quintal, 2022a, b).
Here we extend the results of Alkhimenkov (2023) for a denser finite-element mesh (achieving 2 025 916 elements)) and report the convergence study showing that, for finer resolution, the result of the numerical solution converges towards the result obtained from the original Gassmann's equation (Fig. 1c–d).
10.1 Physical interpretation of the present extended Biot's poroelastic framework
The derived extended Biot's poroelastic equations describe the coupled mechanical and fluid flow behavior of a fluid-saturated porous medium under general conditions. Specifically, they account for the interaction between solid matrix deformation and changes in pore fluid pressure. Classical Biot's equations (Biot, 1962) and Gassmann's equations (Gassmann, 1951) are special cases of the presented theory. Gassmann's equations provide a relation between the bulk moduli of the drained (or dry) and undrained fluid-saturated rock, offering insight into how fluid properties and porosity influence the mechanical response of the material.
10.2 Other derivations of Gassmann's equations
Gassmann's equations are directly related to the quasi-static formulation of poroelasticity developed by Biot (1941) and later extended to dynamic settings by Biot (1956, 1962). While the conceptual foundation of elastodynamic poroelasticity, such as the presence of the fast P-wave, slow P-wave, and shear wave in fluid-saturated porous media, was introduced by Frenkel (1944) (see also Pride and Garambois, 2005), rigorous derivations of the poroelastic parameters were provided subsequently by Biot (1941), Biot and Willis (1957), and Biot (1962).
Numerous researchers have re-derived Gassmann's equations using various approaches or examined specific aspects of these equations within the poroelasticity framework (Brown and Korringa, 1975; Rice and Cleary, 1976; Korringa, 1981; Burridge and Keller, 1981; Bourbié et al., 1987; Zimmerman, 1990; Berryman and Milton, 1991; Detournay and Cheng, 1993, Berryman, 1999; Smith et al., 2003; Lopatnikov and Cheng, 2004; Gurevich, 2007; Fortin and Guéguen, 2021). Some modifications of small-strain poroelasticity to include non-reciprocal effects are given by Sahay (2013) and Müller and Sahay (2019). While the full list of contributors to the field is extensive and beyond the scope of this paper, we acknowledge their foundational work.
We refer the reader to Sevostianov (2020), which presents a comprehensive overview of Gassmann's equations. In addition, several books may be useful for readers interested in poroelasticity and its applications, including Bourbié et al. (1987), Zimmerman (1990), Wang (2000), Ulm and Coussy (2003), Coussy (2004, 2011), Guéguen and Boutéca (2004), Dormieux et al. (2006), Cheng (2016), and Mavko et al. (2020).
Figure 1Panels (a)–(b) show sketches illustrating the model geometry. Panel (c) shows the numerical solution of Ku, the analytical solution via Gassmann's Eq. (47), and the analytical solution via Eq. (92) as a function of the numerical resolution. Panel (d) shows the error magnitudes between (i) the numerically evaluated bulk modulus Ku and the analytically evaluated bulk modulus via Gassmann's Eq. (47) and (ii) the numerically evaluated bulk modulus and the analytically evaluated bulk modulus via Eq. (92).
10.2.1 Thermodynamically admissible conditions for the diagonal structure of matrix H
The main assumptions behind the applicability of Gassmann's Eqs. (45)–(47) are (i) linear elasticity, (ii) small strains, (iii) an isotropic homogeneous frame material and isotropic homogeneous solid grains, (iv) an isotropic dry response (although Gassmann's original publication includes an extension to anisotropy), and (v) the self-similarity hypothesis: the assumption that equal changes in pore (fluid) pressure and confining (total) pressure leave the porosity unchanged (Korringa, 1981; Alkhimenkov, 2024).
Assumption (v) may hold for isotropic homogeneous frame materials (Korringa, 1981), but it must be derived rigorously. In the framework of the present study, this condition is satisfied when the compliance matrix H is diagonal, and it is required for the thermodynamic admissibility of the model (see Appendix B). As stated there: “the constraint of zero dissipation (entropy production) during reversible poroelastic deformation provides an essential constraint on the poroelastic constitutive equation for porosity evolution.”
10.2.2 When the solid compressibilities coincide ()
Strictly speaking, the most general model should always use the full matrix H (Eq. 6). However, in certain special cases, such as isotropic and homogeneous rock frames, additional constraints may hold. Several researchers have pointed out that, for monomineralic isotropic materials, the self-similarity hypothesis is valid and that Gassmann's equations therefore apply and are exact (Brown and Korringa, 1975; Korringa, 1981).
In general, various poroelastic constants can be computed numerically (Alkhimenkov, 2023), derived analytically using effective medium theory (Yarushina and Podladchikov, 2015), or measured experimentally in laboratory settings (Makhnenko and Podladchikov, 2018).
The distinction between the solid compressibilities lies in the structure of the matrix H, which depends on the particular choice of rheological relationships. The definitions (Detournay and Cheng, 1993)
are only necessary when the rock microstructure allows the bulk frame, solid grains, and pore space to deform differently under unjacketed loading (Makhnenko and Podladchikov, 2018) (Ks is the bulk modulus of solid grains). Note that the rheological assumptions in the Brown–Korringa (BK) model differ from those in the Detournay–Cheng (DC) and the presented extended Biot formulations. As a result, the interpretation and estimation of the parameters in Eq. (107) differ between models.
-
The poroelastic parameters (Eq. 107) can be computed numerically with arbitrary precision. Numerical studies conducted in 3D confirm that, for isotropic (or cubic) monomineralic rock frames with isotropic grains and a fully interconnected pore space, the three parameters in Eq. (107) are equal (Alkhimenkov, 2023, 2024).
-
These parameters can also be measured experimentally in laboratory settings, enabling practical application. In many practical situations, the differences between these parameters (Eq. 107) are small, and one can safely adopt a single solid modulus Ks. The condition typically holds when the rock has a monomineralic, isotropic, and uniform skeleton and a fully interconnected pore network and when it is subjected to pressures below the onset of micro-fracturing or mineral phase transitions. Under such assumptions, the unjacketed compression test measures the intrinsic mineral bulk modulus, and both the whole-specimen () and pore-volume () moduli may collapse (as suggested by several studies) to , reducing the DC model to the original Biot–Gassmann formulation. That is, under unjacketed conditions, the entire solid surface is subjected to a uniform pressure increment Δp, and, if the rock is microscopically isotropic and homogeneous, both the solid grains and bulk framework undergo uniform volumetric strain, resulting in no change in porosity (Tarokh and Makhnenko, 2019). Typical examples include dense quartz sands, clean limestones below micro-crack initiation stress, and synthetic rock samples.
-
Even for the multi-mineral skeleton, the differences between these parameters (Eq. 107) are small, which is shown in the 3D numerical study by Alkhimenkov (2025) and in laboratory settings (Makhnenko and Podladchikov, 2018).
-
Finally, these parameters can also be derived using effective medium theory. This is the most rigorous way to establish under which conditions the three poroelastic parameters are equivalent. The application of effective medium theory is outside the scope of the present study but remains an important direction for future work.
We note that, when a rock frame consists of two or more minerals with different elastic properties (e.g., shales, poorly consolidated sandstones, or cracked carbonates), the distinction in the BK framework is present. In such cases, the assumptions underlying the self-similarity hypothesis break down, and Gassmann's equations serve only as a (very good) approximation within the framework of the extended Biot formulation (Alkhimenkov, 2025).
To further assess the magnitude of the off-diagonal components of the matrix H, we perform a Taylor expansion of (without imposing any assumption on mono- or multi-mineral composition of the frame):
which demonstrates that the off-diagonal terms of H are small.
10.3 Comparison of Gassmann's equations and Thomsen's alternative formulation
Thomsen (2023b) argued that the original derivation of Gassmann's equations contains a logical error, namely an incorrect application of Love's theorem to hydraulically open and closed systems. In the present derivation, we rely on classical irreversible thermodynamics and do not rely on any assumptions regarding whether the porous material system is open or closed.
Thomsen (2023b) provided an updated version of these relations (see also Brown and Korringa, 1975):
where is a new parameter referred to as the “mean” bulk modulus (Thomsen, 2023b). Note the similarity between expressions (47) and (109). Thomsen's relation introduces one additional parameter, , beyond the original Gassmann Eq. (47). Thomsen (2023b) also provided ways to evaluate , including
where BBK (Skempton coefficient) is directly observable in quasi-static experiments. Alternatively, expression (110) can be rewritten as
Importantly, Thomsen's formulation reduces to Gassmann's when .
Thomsen (2023b) argued that this additional parameter must be independently measured, even for monomineralic rocks, and that Eq. (109) should be used instead of the original Gassmann relation (47). As follows from Eq. (111), evaluating requires an independent measurement of the Skempton coefficient BBK. Thomsen (2023b) further noted that the porosity ϕf is not constant under equal changes in fluid pressure pf and total pressure and argued that, for monomineralic rocks, generally differs from . This implies a sensitivity of porosity variation, either increasing or decreasing, depending on the sign of .
We note the following:
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Gassmann explicitly stated the self-similarity hypothesis in his original article (Gassmann, 1951). Therefore, claims of a logical error (Thomsen, 2023b) in the derivation are unfounded.
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The claims made by Thomsen (2023b) are not supported by rigorous theoretical developments (e.g., exact solutions in effective medium theory) that explicitly demonstrate that for monomineralic rocks.
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Several 3D numerical studies confirm that the self-similarity hypothesis holds for homogeneous isotropic (or cubic) dry responses and isotropic solid-grain materials. This has been verified numerically for both cubic and transversely isotropic symmetries (Alkhimenkov et al., 2020a, b; Alkhimenkov and Quintal, 2022a, b; Alkhimenkov, 2023, 2024).
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A recent 3D numerical study of a heterogeneous frame material composed of two solids with different bulk and shear moduli (Alkhimenkov, 2025) showed that the difference is below 0.11 GPa, practically insignificant.
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Laboratory experiments show that, even for the multi-mineral skeleton, the differences between and are small (Makhnenko and Podladchikov, 2018).
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This all suggests that, in relatively homogeneous rock samples, the distinction between different solid-grain moduli has negligible practical impact.
-
The mechanics of rocks includes additional important aspects such as nonlinearity in their mechanical response, differences in mechanical properties under extension versus compression (which can differ by several percent), intrinsic anisotropy of the solid grains, effective anisotropy of the rock sample, and irreversible damage under applied loads. All of these factors contribute to a much more complex mechanical behavior of rocks. These additional constraints may have a significantly greater impact on rock response than potential deviations from the self-similarity hypothesis.
Alkhimenkov (2023) conducted a numerical convergence study demonstrating that (where Ks is the solid bulk modulus) for monomineralic rock as the resolution increases. In this study, was computed independently using Eq. (111), with the Skempton coefficient BBK also calculated. Consequently, the result of expression (109) converges to the original Gassmann relation (47) in the monomineralic isotropic (or cubic symmetry) case where (within numerical precision), thereby validating the original Gassmann formulation for a particular pore space and solid material geometry.
10.4 Limitations
Often, natural rocks are composed of multiple minerals that are anisotropic, and they typically exhibit some degree of intrinsic anisotropy. They may also contain a combination of compliant cracks (e.g., grain contacts) and stiff pores, which respond differently under mechanical loading. Additionally, a rock's heterogeneity can violate the assumptions of a representative volume element. It is also well established that elastic moduli can vary by several percent under compression versus extension. These deviations from ideal small-strain elasticity suggest the need for additional effective parameters, and thus more experimental (or numerical) measurements, to accurately characterize fully saturated and realistic rock samples.
This study has presented a structured, transparent, and thermodynamically admissible derivation of the quasi-static extended Biot's poroelasticity framework. The well-known classical Gassmann equations and Biot poroelastic formulation (fundamental tools for characterizing the poroelastic mechanical behavior of fluid-saturated porous media) are derived here as special cases of the general theory. While the thermodynamic admissibility of the original Biot equations has previously been demonstrated, the present work extends this admissibility to a more general model using the framework of classical irreversible thermodynamics. We emphasize clarity, accessibility, and full reproducibility throughout the derivation. The main novelty of this study is the development of the extended Biot's poroelasticity framework, which incorporates off-diagonal components of the Hessian matrix. The relations between the new set of poroelastic parameters are fully expressed in terms of the components of the Hessian matrix H.
By strictly adhering to conservation laws and thermodynamic principles, we have also addressed recent claims by Leon Thomsen regarding the validity of Gassmann's formulation. In particular, we have shown that the key self-similarity assumption (that porosity remains unchanged under equal changes in fluid and total pressure) is a sufficient but unnecessary condition for the derivation of a Gassmann-type relationship between undrained and drained bulk moduli. Indeed the extended Gassmann poroelastic Eq. (69) is derived in this contribution without relying on Gassmann's assumption of self-similarity.
To promote transparency and support future developments, we provide symbolic Maple routines. These materials ensure full reproducibility of the derivations and offer a practical foundation for extending the framework to more complex scenarios, such as multiphase fluid systems and related phenomena.
The following Maple script provides a step-by-step derivation of the entropy production for a one-dimensional system using the principles of classical irreversible thermodynamics. It uses the volume-specific formulation for mass conservation and the principles of local thermodynamic equilibrium (LTE) to establish the relationship between different thermodynamic fluxes and forces. The script calculates the entropy production, Q[s], and demonstrates the impact of various choices for flux definitions. Below is a detailed explanation of each step in the script.
Below, we provide a detailed explanation of each line in the script.
Initialization and mass conservation
Conservation of energy
Entropy balance
Listing A5This line represents the entropy balance. Here, dsdt is the time derivative of specific entropy, q[s](x) is the entropy flux, and Q[s] is the entropy production rate per unit volume. This equation states that the change in entropy is equal to the negative divergence of the entropy flux plus the entropy production term.
Local thermodynamic equilibrium (LTE)
Solving for entropy production
Choice for energy flux
Flux definitions
Final expression for entropy production
The final expression for entropy production Q[s] is simplified to
B1 General representation of classical irreversible thermodynamics
Porous materials can be modeled as two-phase systems composed of a solid skeleton and a saturating fluid. These phases exchange mass, momentum, and energy, leading to complex coupled processes that are naturally described using the framework of classical irreversible thermodynamics (CIT) (Gyarmati, 1970; Jou et al., 1996; Lebon et al., 2008; Yarushina and Podladchikov, 2015). In this formulation, conservation equations for mass, momentum, entropy, and energy are expressed in the Eulerian frame as follows:
where vj, s, and e denote the velocity, specific entropy, and specific total energy per unit mass, respectively. The term ρ denotes (phase-specific) density, and ϕ denotes the phase volume fraction (e.g., porosity for the fluid). The term ∇j representsthe partial derivative with respect to spatial coordinates, while , , , and correspond to the fluxes of mass, momentum, entropy, and energy, respectively. The terms Qp, , Qs, and Qe represent the corresponding production rates due to irreversible processes (Yarushina and Podladchikov, 2015).
Entropy production (TQs)
Solving the local entropy production equation for Qs and multiplying both sides by the absolute temperature T, we obtain
This expression represents the entropy production, which must be non-negative according to the second law of thermodynamics. Notably, this formulation assumes local thermodynamic equilibrium separately for the solid and fluid phases. This is a weaker assumption than Biot's original model (Biot, 1962), which postulated a single internal energy potential for the entire two-phase system in the linear poroelastic regime (Yarushina and Podladchikov, 2015).
B2 Thermodynamic constraints on fluxes and productions
CIT requires that the total entropy production of the system remains non-negative. This condition applies both to the intra-phase and inter-phase entropy production within a porous medium. Mathematically, this is expressed as
Here, represents the intra-phase entropy production within each phase (e.g., due to viscosity, heat conduction, or internal diffusion), while represents the entropy production arising from inter-phase interactions (e.g., interactions between the solid skeleton and the fluid phase). To satisfy CIT, each contribution must be non-negative:
B3 Extended thermodynamic admissibility
Building on the principles of classical irreversible thermodynamics (CIT) (Lebon et al., 2008) and the nonlinear viscoelastoplastic framework of Yarushina and Podladchikov (2015), the derivation of the extended Biot poroelastic equations must satisfy the conditions of thermodynamic admissibility. Specifically, the entropy production Qs must remain non-negative, and the constitutive relations must be formulated such that they are consistent with the second law of thermodynamics for all admissible thermodynamic paths.
From Eq. (37), and taking into account the requirement that entropy production must be non-negative, the inelastic porosity equation takes the form (Yarushina and Podladchikov, 2015)
where ηϕ stands for the effective bulk viscosity. After simplifying and collecting terms (see Appendix B), the total entropy production becomes
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: entropy production due to poroviscous deformation (effective viscosity ηϕ and effective pressure ).
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: entropy production due to viscous dissipation in the solid phase.
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: entropy production due to viscous dissipation in fluid flow (Darcy flow).
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: entropy production due to heat conduction (Fourier's law).
The non-negative nature of each term ensures the overall positivity of entropy production, thereby confirming the thermodynamic validity of the system of extended Biot's poroviscoelastic equations.
A more detailed derivation is given below (see also the discussions provided by Yarushina and Podladchikov, 2015). Additionally, symbolic Maple routines used to reproduce and validate the theoretical results presented in this article are available in a permanent DOI repository (Zenodo) (Alkhimenkov and Podladchikov, 2024).
The software developed and used in this study is licensed under the MIT License. The latest version of the symbolic Maple routines is available from a permanent DOI repository (Zenodo) at https://doi.org/10.5281/zenodo.15777522 (Alkhimenkov and Podladchikov, 2025). The repository contains code examples and can be readily used to reproduce the results presented in the article. The codes are written in the Maple programming language. The latest version of the symbolic Maple routines is available from Zenodo at https://doi.org/10.5281/zenodo.15777522 (Alkhimenkov and Podladchikov, 2025) or https://doi.org/10.5281/zenodo.13942952 (Alkhimenkov and Podladchikov, 2024).
No data were required for this article.
YA designed the original study, contributed to the development the symbolic routines, and wrote the article. YP contributed to the early work on the derivation of original Biot's and Gassmann's equations, assisted with the study design, developed the early versions of symbolic routines, helped interpret the results, edited the article, and supervised the work.
The contact author has declared that neither of the authors has any competing interests.
Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this paper. While Copernicus Publications makes every effort to include appropriate place names, the final responsibility lies with the authors. Views expressed in the text are those of the authors and do not necessarily reflect the views of the publisher.
Yury Alkhimenkov gratefully acknowledges support from the Swiss National Science Foundation, grant no. P500PN_206722.
This research has been supported by the Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung, nccr – on the move (grant no. P500PN_206722).
This paper was edited by Taras Gerya and reviewed by Viktoriya Yarushina and one anonymous referee.
Alkhimenkov, Y.: Numerical validation of Gassmann’s equations, Geophysics, 88, A25–A29, 2023. a, b, c, d, e, f, g, h
Alkhimenkov, Y.: Reply to the Discussion, Geophysics, 89, X5–X7, 2024. a, b, c, d
Alkhimenkov, Y.: Numerical Evaluation of Brown and Korringa (1975) and Gassmann's Equations in Multi-Mineral Porous Media, Geophysics, 90, 1–37, 2025. a, b, c
Alkhimenkov, Y. and Podladchikov, Y.: Biot_Gassmann, Zenodo [code], https://doi.org/10.5281/zenodo.13942952, 2024. a, b
Alkhimenkov, Y. and Podladchikov, Y.: Revisiting Gassmann-Type Relationships within Biot Poroelastic Theory – Symbolic Derivations and Thermodynamic Validation, Zenodo [code], https://doi.org/10.5281/zenodo.15777522 (last access: 30 June 2025), 2025. a, b, c
Alkhimenkov, Y. and Quintal, B.: An accurate analytical model for squirt flow in anisotropic porous rocks – Part 1: Classical geometry, Geophysics, 87, MR85–MR103, 2022a. a, b
Alkhimenkov, Y. and Quintal, B.: An accurate analytical model for squirt flow in anisotropic porous rocks – Part 2: Complex geometry, Geophysics, 87, MR291–MR302, 2022b. a, b
Alkhimenkov, Y., Caspari, E., Gurevich, B., Barbosa, N. D., Glubokovskikh, S., Hunziker, J., and Quintal, B.: Frequency-dependent attenuation and dispersion caused by squirt flow: Three-dimensional numerical study, Geophysics, 85, MR129–MR145, 2020a. a, b
Alkhimenkov, Y., Caspari, E., Lissa, S., and Quintal, B.: Azimuth-, angle- and frequency-dependent seismic velocities of cracked rocks due to squirt flow, Solid Earth, 11, 855–871, https://doi.org/10.5194/se-11-855-2020, 2020b. a, b
Berryman, J. G.: Origin of Gassmann’s equations, Geophysics, 64, 1627–1629, 1999. a
Berryman, J. G. and Milton, G. W.: Exact results for generalized Gassmann’s equations in composite porous media with two constituents, Geophysics, 56, 1950–1960, 1991. a
Biot and Willis, D.: The elastic coeff cients of the theory of consolidation, J. Appl. Mech., 15, 594–601, 1957. a
Biot, M.: Theory of Propagation of Elastic Waves in a Fluid-Saturated Porous Solid. I. Low-Frequency Range, The Journal of the Acoustical Society of America, 28, 168–178, 1956. a
Biot, M. A.: General theory of three-dimensional consolidation, J. Appl. Phys., 12, 155–164, 1941. a, b
Biot, M. A.: Mechanics of deformation and acoustic propagation in porous media, J. Appl. Phys., 33, 1482–1498, 1962. a, b, c, d, e, f, g, h, i, j
Bourbié, T., Coussy, O., and Zinszner, B.: Acoustics of porous media, Editions Technip, Houston, London: Gulf Pub. Co., Paris: Éditions Technip, ISBN 978-0872010253, 1987. a, b
Brown, R. J. and Korringa, J.: On the dependence of the elastic properties of a porous rock on the compressibility of the pore fluid, Geophysics, 40, 608–616, 1975. a, b, c, d, e, f, g, h, i, j, k, l, m, n, o
Burridge, R. and Keller, J. B.: Poroelasticity equations derived from microstructure, The Journal of the Acoustical Society of America, 70, 1140–1146, 1981. a
Cheng, A. H.-D.: Poroelasticity, Springer, 2016. a
Coussy, O.: Poromechanics, John Wiley & Sons, ISBN 9780470849200, https://doi.org/10.1002/0470092718, 2004. a
Coussy, O.: Mechanics and physics of porous solids, John Wiley & Sons, 296 pp., ISBN 978-0-470-72135-3, 2011. a
Coussy, O., Dormieux, L., and Detournay, E.: From mixture theory to Biot’s approach for porous media, International Journal of Solids and Structures, 35, 4619–4635, 1998. a
Detournay, E. and Cheng, A. H.-D.: Fundamentals of poroelasticity, in: Analysis and design methods, Elsevier, 113–171, https://doi.org/10.1016/b978-0-08-040615-2.50011-3, 1993. a, b, c, d, e, f, g, h, i, j, k
Dormieux, L., Kondo, D., and Ulm, F.-J.: Microporomechanics, John Wiley & Sons, ISBN 9780470031889, 2006. a
Fortin, J. and Guéguen, Y.: Porous and cracked rocks elasticity: Macroscopic poroelasticity and effective media theory, Mathematics and Mechanics of Solids, 26, 1158–1172, 2021. a
Frenkel, J.: On the theory of seismic and seismoelectric phenomena in a moist soil, Journal of Physics, III, 230–241, 1944. a
Gassmann, F.: Über die Elastizität poröser Medien, Vierteljahrsschrift der Naturforschenden Gesellschaft in Zürich, 96, 1–23, 1951. a, b, c, d, e, f, g, h, i, j, k
Guéguen, Y. and Boutéca, M.: Mechanics of fluid-saturated rocks, Elsevier, ISBN 9780123053558, 2004. a
Gurevich, B.: Comparison of the low-frequency predicitons of Biot's and de Boer's poroelasticity theories with Gassmann’s equation, Applied physics letters, 91, 091919, https://doi.org/10.1063/1.2778763, 2007. a
Gyarmati, I.: Non-equilibrium thermodynamics, Springer, 1970. a
Jou, D., Casas-Vázquez, J., Lebon, G., Jou, D., Casas-Vázquez, J., and Lebon, G.: Extended irreversible thermodynamics, Springer, https://doi.org/10.1007/978-90-481-3074-0, 1996. a
Korringa, J.: On the Biot–Gassmann equations for the elastic moduli of porous rocks (Critical comment on a paper by JG Berryman), The Journal of the Acoustical Society of America, 70, 1752–1753, 1981. a, b, c, d
Lebon, G., Jou, D., and Casas-Vázquez, J.: Understanding Non-equilibrium Thermodynamics: Foundations, Applications, Frontiers, Springer, Berlin, Heidelberg, ISBN 978-3-540-74251-7, https://doi.org/10.1007/978-3-540-74252-4, 2008. a, b, c, d, e
Lopatnikov, S. L. and Cheng, A.-D.: Macroscopic Lagrangian formulation of poroelasticity with porosity dynamics, Journal of the Mechanics and Physics of Solids, 52, 2801–2839, 2004. a
Makhnenko, R. Y. and Podladchikov, Y. Y.: Experimental poroviscoelasticity of common sedimentary rocks, J. Geophys. Res.-Sol. Ea., 123, 7586–7603, 2018. a, b, c, d
Mavko, G., Mukerji, T., and Dvorkin, J.: The rock physics handbook, Cambridge University Press, https://doi.org/10.1017/9781108333016, 2020. a
Müller, T. M. and Sahay, P. N.: Elastic potential energy in linear poroelasticity, Geophysics, 84, W1–W20, 2019. a
Nur, A. and Byerlee, J.: An exact effective stress law for elastic deformation of rock with fluids, J. Geophys. Res., 76, 6414–6419, 1971. a
Pelissier, M. A., Hoeber, H., van de Coevering, N., and Jones, I. F.: Classics of elastic wave theory, Society of Exploration Geophysicists, 24, ISBN 9781560801429, https://doi.org/10.1190/1.9781560801931, 2007. a
Pride, S. R. and Garambois, S.: Electroseismic wave theory of Frenkel and more recent developments, Journal of Engineering Mechanics, 131, 898–907, 2005. a
Rice, J. R. and Cleary, M. P.: Some basic stress diffusion solutions for fluid-saturated elastic porous media with compressible constituents, Rev. Geophys., 14, 227–241, 1976. a, b, c, d, e
Sahay, P. N.: Biot constitutive relation and porosity perturbation equation, Geophysics, 78, L57–L67, 2013. a
Schenk, O. and Gärtner, K.: Solving unsymmetric sparse systems of linear equations with PARDISO, Future Generation Computer Systems, 20, 475–487, 2004. a
Sevostianov, I.: Gassmann equation and replacement relations in micromechanics: A review, International Journal of Engineering Science, 154, 103344, https://doi.org/10.1016/j.ijengsci.2020.103344, 2020. a
Smith, T. M., Sondergeld, C. H., and Rai, C. S.: Gassmann fluid substitutions: A tutorial, Geophysics, 68, 430–440, 2003. a
Tarokh, A. and Makhnenko, R. Y.: Remarks on the solid and bulk responses of fluid-filled porous rock, Geophysics, 84, WA83–WA95, 2019. a
Thomsen, L.: Discussion on the logical error in Gassmann poroelasticity: Numerical computations and generalizations, https://doi.org/10.1111/1365-2478.13290, 2023a. a, b, c
Thomsen, L.: A logical error in Gassmann poroelasticity, Geophysical Prospecting, 71, 649–663, https://doi.org/10.1111/1365-2478.13290, 2023b. a, b, c, d, e, f, g, h, i, j, k
Thomsen, L.: Comments on: “Numerical validation of Gassmann’s equations” (Yury Alkhimenkov, 2023, Geophysics, 88, A25–A29), Geophysics, 89, X1–X4, 2024. a, b, c
Thomsen, L.: Understanding Brown and Korringa (1975), Geophysics, 90, 1–21, 2025. a, b, c, d, e, f, g, h, i, j, k, l
Ulm, F. and Coussy, O.: Mechanics and Durability of Solids, no. v. 1 in MIT/Prentice Hall series on civil, environmental, and systems engineering, Prentice Hall, ISBN 9780130479570, 2003. a
Wang, H.: Theory of linear poroelasticity with applications to geomechanics and hydrogeology, Princeton university press, ISBN 9780691037462, 2000. a
Yarushina, V. M. and Podladchikov, Y. Y.: (De) compaction of porous viscoelastoplastic media: Model formulation, J. Geophys. Res.-Sol. Ea., 120, 4146–4170, 2015. a, b, c, d, e, f, g, h, i, j, k, l, m, n, o, p, q, r, s
Zimmerman, R. W.: Compressibility of sandstones, ISBN 9780444555632, 1990. a, b
- Abstract
- Introduction
- Scope of the article
- Derivation of the extended Biot's poroelastic equations
- Thermodynamic admissibility of the extended Biot poroelasticity framework
- Derivation of the original Gassmann and Biot equations
- Derivation of the extended Biot's poroelasticity formulation: general case
- Comparison against previous poroelasticity models
- A closed system of equations of the extended Biot poroelastic framework
- Numerical studies supporting Gassmann's equations for monomineralic frame
- Discussion
- Conclusions
- Appendix A: Explanation of the Maple script for a single-phase medium
- Appendix B: Explanation of the Maple script for two-phase fluid-saturated media
- Code availability
- Data availability
- Author contributions
- Competing interests
- Disclaimer
- Acknowledgements
- Financial support
- Review statement
- References
- Abstract
- Introduction
- Scope of the article
- Derivation of the extended Biot's poroelastic equations
- Thermodynamic admissibility of the extended Biot poroelasticity framework
- Derivation of the original Gassmann and Biot equations
- Derivation of the extended Biot's poroelasticity formulation: general case
- Comparison against previous poroelasticity models
- A closed system of equations of the extended Biot poroelastic framework
- Numerical studies supporting Gassmann's equations for monomineralic frame
- Discussion
- Conclusions
- Appendix A: Explanation of the Maple script for a single-phase medium
- Appendix B: Explanation of the Maple script for two-phase fluid-saturated media
- Code availability
- Data availability
- Author contributions
- Competing interests
- Disclaimer
- Acknowledgements
- Financial support
- Review statement
- References