Articles | Volume 9, issue 1
https://doi.org/10.5194/se-9-223-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/se-9-223-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
27 Feb 2018
Research article |
| 27 Feb 2018
| 27 Feb 2018
Structural disorder of graphite and implications for graphite thermometry
Martina Kirilova
CORRESPONDING AUTHOR
Department of Geology, University of Otago, P.O. Box 56, Dunedin 9054,
New Zealand
Virginia Toy
Department of Geology, University of Otago, P.O. Box 56, Dunedin 9054,
New Zealand
Jeremy S. Rooney
Department of Chemistry, University of Otago, P.O. Box 56, Dunedin
9054, New Zealand
Carolina Giorgetti
Dipartimento di Scienze della Terra, Università degli Studi La
Sapienza, Rome, Italy
Keith C. Gordon
Department of Chemistry, University of Otago, P.O. Box 56, Dunedin
9054, New Zealand
Cristiano Collettini
Dipartimento di Scienze della Terra, Università degli Studi La
Sapienza, Rome, Italy
Toru Takeshita
Faculty of Science, Earth and Planetary Sciences, Hokkaido
University, Sapporo, Japan
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32 citations as recorded by crossref.
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32 citations as recorded by crossref.
- Frictional Heating Processes and Energy Budget During Laboratory Earthquakes J. Aubry et al. 10.1029/2018GL079263
- XRD graphitization degrees: a review of the published data and new calculations, correlations, and applications A. Vlahov 10.52321/GeolBalc.50.1.11
- Graphitic material in fault zones: Implications for fault strength and carbon cycle S. Cao & F. Neubauer 10.1016/j.earscirev.2019.05.008
- Deformation characteristics and peak temperatures of the Sanbagawa Metamorphic and Shimanto Accretionary complexes on the central Kii Peninsula, SW Japan Y. Shimura et al. 10.1016/j.jseaes.2021.104791
- Deformational Temperatures Across the Lesser Himalayan Sequence in Eastern Bhutan and Their Implications for the Deformation History of the Main Central Thrust D. Grujic et al. 10.1029/2019TC005914
- Raman analysis of a shocked planetary surface analogue: Implications for habitability on Mars M. McHugh et al. 10.1002/jrs.6263
- Raman spectroscopy in thrust-stacked carbonates: an investigation of spectral parameters with implications for temperature calculations in strained samples L. Kedar et al. 10.5194/se-13-1495-2022
- Frictional slip weakening and shear-enhanced crystallinity in simulated coal fault gouges at slow slip rates C. Fan et al. 10.5194/se-11-1399-2020
- Carbonaceous Materials in the Fault Zone of the Longmenshan Fault Belt: 1. Signatures within the Deep Wenchuan Earthquake Fault Zone and Their Implications L. Kuo et al. 10.3390/min8090385
- Co-Carbonization of Discard Coal with Waste Polyethylene Terephthalate towards the Preparation of Metallurgical Coke S. Bambalaza et al. 10.3390/ma16072782
- Raman spectroscopy as a tool to determine the thermal maturity of organic matter: Application to sedimentary, metamorphic and structural geology D. Henry et al. 10.1016/j.earscirev.2019.102936
- Fluid-mediated, brittle–ductile deformation at seismogenic depth – Part 2: Stress history and fluid pressure variations in a shear zone in a nuclear waste repository (Olkiluoto Island, Finland) F. Prando et al. 10.5194/se-11-489-2020
- Deserpentinization in Subduction Zones as a Source of Oxidation in Arcs: a Reality Check K. Evans & B. Frost 10.1093/petrology/egab016
- Graphene epoxy spray on 3D-printed acrylonitrile butadiene styrene substrates as O2 gas barrier N. Tran et al. 10.1016/j.apsusc.2019.143745
- Microdiamond in a low-grade metapelite from a Cretaceous subduction complex, western Kyushu, Japan T. Nishiyama et al. 10.1038/s41598-020-68599-7
- The Graphite Occurrences of Northern Norway, a Review of Geology, Geophysics, and Resources H. Gautneb et al. 10.3390/min10070626
- New Energetic Metal‐Organic Framework (E‐MOF) based on a sodium(I)‐containing energetic metal salt incorporating guanidinium ions G. Zhang et al. 10.1002/zaac.202100270
- Structural and thermal evolution of the eastern Aar Massif: insights from structural field work and Raman thermometry L. Nibourel et al. 10.1186/s00015-020-00381-3
- Towards a kerogen-to-graphite kinetic model by means of Raman spectroscopy A. Schito et al. 10.1016/j.earscirev.2022.104292
- Evolving temperature field in a fossil subduction channel during the transition from subduction to collision (Tauern Window, Eastern Alps) P. Groß et al. 10.1111/jmg.12572
- Frictional strength, electrical conductivity, and microstructure of calcite–graphite mixtures sheared at a subseismic slip rate J. Chen et al. 10.1016/j.tecto.2023.230085
- Unraveling sedimentary precursors and metal enrichment of high-grade metamorphosed manganese-rich rocks from the Borborema Province, northeastern Brazil F. Santos et al. 10.1016/j.oregeorev.2021.104283
- Drastic effect of shearing on graphite microtexture: attention and application to Earth science Y. Kouketsu et al. 10.1186/s40645-019-0271-4
- Graphite thermometry by interactive fitting of Raman spectra G. Rantitsch 10.1016/j.coal.2023.104232
- Increased biomass and carbon burial 2 billion years ago triggered mountain building J. Parnell & C. Brolly 10.1038/s43247-021-00313-5
- Shear‐Enhanced Electrical Conductivity of Synthetic Quartz‐Graphite Gouges: Implications for Electromagnetic Observations in Carbonaceous Shear Zones J. Chen et al. 10.1029/2023JB027716
- Exhumation of the Ronda Peridotite During Hyper‐Extension: New Structural and Thermal Constraints From the Nieves Unit (Western Betic Cordillera, Spain) E. Bessière et al. 10.1029/2020TC006271
- XRD-based crystallinity degrees and formation temperature of graphite in some regional-metamorphic rocks from the Central and Eastern Rhodopes, Bulgaria: a test of the new graphitization degree GD(0–30) scale A. Vlahov 10.52321/GeolBalc.51.2.63
- Geothermometric constraints on the thermal architecture, metamorphism, and exhumation of the Northern Range, Trinidad I. Gennaro et al. 10.1111/jmg.12697
- The effect of strain on the crystallinity of carbonaceous matter: Application of Raman spectroscopy to deformation experiments B. Moris-Muttoni et al. 10.1016/j.tecto.2023.230126
- Diagenetic and shear-induced transitions of frictional strength of carbon-bearing faults and their implications for earthquake rupture dynamics in subduction zones S. Kaneki & T. Hirono 10.1038/s41598-019-44307-y
- Carbon ordering in an aseismic shear zone: Implications for Raman geothermometry and strain tracking L. Kedar et al. 10.1016/j.epsl.2020.116536
Discussed (preprint)
Latest update: 23 Apr 2024
Short summary
Graphite crystallinity “irreversibly” increases with temperature and it has been calibrated as a thermometer recording peak temperatures experienced by a rock. To examine the possibility of mechanical modifications of graphite structure and the impacts on graphite thermometry we performed deformation experiments. Raman spectroscopy demonstrates a reduction in crystallinity due to mechanical reworking in the brittle field. This finding clearly compromises the validity of the graphite thermometry.
Graphite crystallinity “irreversibly” increases with temperature and it has been calibrated...
