Articles | Volume 9, issue 1
https://doi.org/10.5194/se-9-223-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/se-9-223-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Structural disorder of graphite and implications for graphite thermometry
Martina Kirilova
CORRESPONDING AUTHOR
Department of Geology, University of Otago, P.O. Box 56, Dunedin 9054,
New Zealand
Virginia Toy
Department of Geology, University of Otago, P.O. Box 56, Dunedin 9054,
New Zealand
Jeremy S. Rooney
Department of Chemistry, University of Otago, P.O. Box 56, Dunedin
9054, New Zealand
Carolina Giorgetti
Dipartimento di Scienze della Terra, Università degli Studi La
Sapienza, Rome, Italy
Keith C. Gordon
Department of Chemistry, University of Otago, P.O. Box 56, Dunedin
9054, New Zealand
Cristiano Collettini
Dipartimento di Scienze della Terra, Università degli Studi La
Sapienza, Rome, Italy
Toru Takeshita
Faculty of Science, Earth and Planetary Sciences, Hokkaido
University, Sapporo, Japan
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Discussed (preprint)
Latest update: 23 Nov 2024
Short summary
Graphite crystallinity “irreversibly” increases with temperature and it has been calibrated as a thermometer recording peak temperatures experienced by a rock. To examine the possibility of mechanical modifications of graphite structure and the impacts on graphite thermometry we performed deformation experiments. Raman spectroscopy demonstrates a reduction in crystallinity due to mechanical reworking in the brittle field. This finding clearly compromises the validity of the graphite thermometry.
Graphite crystallinity “irreversibly” increases with temperature and it has been calibrated...