Articles | Volume 17, issue 3
https://doi.org/10.5194/se-17-407-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/se-17-407-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Feldspar alteration by disequilibrium CO2-H2O fluids in reservoir sandstones: implications for CCS
Natalie J. C. Farrell
CORRESPONDING AUTHOR
Department of Earth and Environmental Sciences, Williamson Building, University of Manchester, Manchester, United Kingdom
Lining Yang
Institute of Marine Sciences (CNR-ISMAR), Bologna, Italy
Michael J. Flowerdew
CASP, Cambridge, United Kingdom
Chris Mark
Department of Geology, Swedish Museum of Natural History, Stockholm, Sweden
School of Earth Sciences, University College Dublin, Ireland
Buhari Ardo
Department of Earth and Environmental Sciences, Williamson Building, University of Manchester, Manchester, United Kingdom
Kevin G. Taylor
Department of Earth and Environmental Sciences, Williamson Building, University of Manchester, Manchester, United Kingdom
Nico Bigaroni
Department of Earth and Environmental Sciences, Williamson Building, University of Manchester, Manchester, United Kingdom
Michael Pointon
CASP, Cambridge, United Kingdom
Lewis Hughes
Department of Earth and Environmental Sciences, Williamson Building, University of Manchester, Manchester, United Kingdom
John Waters
Department of Earth and Environmental Sciences, Williamson Building, University of Manchester, Manchester, United Kingdom
Lee Paul
Department of Earth and Environmental Sciences, Williamson Building, University of Manchester, Manchester, United Kingdom
Cited articles
Abart, R., Petrishcheva, E., and Joachim, B.: Thermodynamic model for growth of reaction rims with lamellar microstructure, American Mineralogist, 97, 231–240, https://doi.org/10.2138/am.2011.3820, 2012.
Akhurst, M., Blanco Sánchez, P. H., Kirk, K., Mosca, I., Pierce, J., Williams, J., Flowerdew, M., Joss, M., Jahanbakhsh, A., Marr, I., Fraga, D., Trusler, M., Farrell, N., Nixon, S., Walker, L., Armstrong, L.-M., Dbouk, W., Manias, P., Teagle, D., Turnock, S., Vakili, S., Minto, J. M., and Roberts, J. J.: IDRIC Frontiers Report: Carbon Capture and Storage (CCS) – Spotlight: CO2 Transport and Storage, https://doi.org/10.2139/ssrn.5505958, 2025.
Alcalde, J., Heinemann, N., Mabon, L., Worden, R. H., De Coninck, H., Robertson, H., Maver, M., Ghanbari, S., Swennenhuis, F., Mann, I., and Walker, T.: Acorn: Developing full-chain industrial carbon capture and storage in a resource- and infrastructure-rich hydrocarbon province, Journal of Cleaner Production, 233, 963–971, https://doi.org/10.1016/j.jclepro.2019.06.087, 2019.
Allen, M. J., Faulkner, D. R., Worden, R. H., Rice-Birchall, E., Katirtsidis, N., and Utley, J. E.: Geomechanical and petrographic assessment of a CO2 storage site: Application to the Acorn CO2 Storage Site, offshore United Kingdom, International Journal of Greenhouse Gas Control, 94, https://doi.org/10.1016/j.ijggc.2019.102923, 2020.
Baines, S. J. and Worden, R. H.: The long-term fate of CO2 in the subsurface: natural analogues for CO2 storage, in: Geological Storage of Carbon Dioxide, edited by: Baines, S. J. and Worden, R. H., Geological Society Special Publication 233, Geological Society, London, UK, 59–85, https://doi.org/10.1144/GSL.SP.2004.233.01.06, 2004.
Benson, S. M. and Cole, D. R.: CO2 sequestration in deep sedimentary formations, Elements, 4, 325–331, https://doi.org/10.2113/gselements.4.5.325, 2008.
Bertier, P., Swennen, R., Laenen, B., Lagrou, D., and Dreesen, R.: Experimental identification of CO2–water–rock interactions caused by sequestration of CO2 in Westphalian and Buntsandstein sandstones of the Campine Basin (NE-Belgium), Journal of Geochemical Exploration, 89, 10–14, https://doi.org/10.1016/j.gexplo.2005.11.005, 2006.
Blum, A. E. and Stillings, L. L.: Feldspar dissolution kinetics, in: Chemical Weathering Rates of Silicate Minerals, Reviews in Mineralogy, Vol. 31, edited by: Brantley, S. L., American Mineralogical Society, Washington, DC, USA, 291–351, https://doi.org/10.1515/9781501509650-009, 1995.
Brantley, S. L., Kubicki, J. D. and White, A. F. (Eds.): Kinetics of Water-Rock Interaction, Reviews in Mineralogy and Geochemistry, Vol. 168, Mineralogical Society of America and Geochemical Society, Chantilly, VA, USA, 281 pp., ISBN 9780939950819, 2008.
Carroll, S. A. and Knauss, K. G.: Dependence of labradorite dissolution kinetics on CO2(aq), Al(aq), and temperature, Chemical Geology, 217, 213–225, https://doi.org/10.1016/j.chemgeo.2004.12.008, 2005.
Chakrabarty, A., Mukherjee, S., Karmakar, S., Sanyal, S., and Sengupta, P.: Petrogenesis and in situ U-Pb zircon dates of a suite of granitoid in the northern part of the Central Indian tectonic Zone: Implications for prolonged arc magmatism during the formation of the Columbia supercontinent, Precambrian Research, 387, 106990, https://doi.org/10.1016/j.precamres.2023.106990, 2023.
Chen, Y., Brantley, S. L., and Ilton, E. S.: X-ray photoelectron spectroscopic measurement of the temperature dependence of leaching of cations from the albite surface, Chemical Geology, 163, 115–128, https://doi.org/10.1016/S0009-2541(99)00096-0, 2000.
Ciceri, D., de Oliveira, M., and Allanore, A.: Potassium fertilizer via hydrothermal alteration of K-feldspar ore, Green Chemistry, 19, 5187–5202, https://doi.org/10.1039/C7GC02633A, 2017.
Cole, D. R., Larson, P. B., Riciputi, L. R., and Mora, C. I.: Oxygen isotope zoning profiles in hydrothermally altered feldspars: Estimating the duration of water-rock interaction, Geology, 32, 29–32, https://doi.org/10.1130/G19881.1, 2004.
Collettini, C., Tesei, T., Scuderi, M. M., Carpenter, B. M., and Viti, C.: Beyond Byerlee friction, weak faults and implications for slip behavior, Earth and Planetary Science Letters, 519, 245–263, https://doi.org/10.1016/j.epsl.2019.05.011, 2019.
Correns, C. W.: Experiments on the decomposition of silicates and discussion of chemical weathering, in: Clays and Clay Minerals (National Conference on Clays and Clay Minerals) (Vol. 10, 443–459), Cambridge University Press & Assessment, https://doi.org/10.1346/CCMN.1961.0100139, 1961.
Dove, P. M. and Crerar, D. A.: Kinetics of quartz dissolution in electrolyte solutions using a hydrothermal mixed flow reactor, Geochimica et cosmochimica acta, 54, 955–969, https://doi.org/10.1016/0016-7037(90)90431-J, 1990.
Durst, P. and Vuataz, F. D.: Fluid-rock interactions in hot dry rock reservoirs: a review of the HDR sites and detailed investigations of the Soultz-sous-Forêts system, in: Proceedings of the World Geothermal Congress 2000, Kyushu–Tohoku, Japan, June 2000, 3677–3682, 2000.
Farrell, N. J. C. and Healy, D.: Anisotropic pore fabrics in faulted porous sandstones, Journal of Structural Geology, 104, 125–141, https://doi.org/10.1016/j.jsg.2017.09.010, 2017.
Farrell, N. J. C., Debenham, N., Wilson, L., Wilson, M. J., Healy, D., King, R. C., Holford, S. P., and Taylor, C. W.: The effect of authigenic clays on fault zone permeability, Journal of Geophysical Research: Solid Earth, 126, https://doi.org/10.1029/2021JB022615, 2021.
Farrell, N. J. C., Yang, L., Flowerdew, M. J., Mark, C., Ardo, B., Taylor, K. G., Bigaroni, N., Pointon, M., Hughes, L., Waters, J., and Paul, L.: XCT images and animations, Figshare, Version 1, https://doi.org/10.6084/m9.figshare.30061294.v1, 2025.
Flowerdew, M. J., Farrell, N., Yang, L., Badenszki, E., Mark, C., Ardo, B., and Taylor, K.: Feldspars in CCS reservoirs: overlooked or unimportant?, in: CCS4G Symposium 2024, London, UK, CCS4G-Symposium-2024-Abstracts.pdf, 2024.
Folk, R. L., Andrews, P. B., and Lewis, D. W.: Detrital sedimentary rock classification and nomenclature for use in New Zealand, New Zealand Journal of Geology and Geophysics, 13, 937–968, https://doi.org/10.1080/00288306.1970.10418211, 1970.
Foroutan, M., Ghazanfari, E., and Amirlatifi, A.: Variation of failure properties, creep response and ultrasonic velocities of sandstone upon injecting CO2-enriched brine, Geomechanics and Geophysics for Geo-Energy and Geo-Resources, 7, https://doi.org/10.1007/s40948-021-00223-y, 2021.
Fuchs, S. J., Espinoza, D. N., Lopano, C. L., Akono, A. T., and Werth, C. J.: Geochemical and geomechanical alteration of siliciclastic reservoir rock by supercritical CO2-saturated brine formed during geological carbon sequestration, International Journal of Greenhouse Gas Control, 88, 251–260, https://doi.org/10.1016/j.ijggc.2019.06.014, 2019.
Fung, P. C., Bird, G. W., McIntyre, N. S., Sanipelli, G. G., and Lopata, V. J.: Aspects of feldspar dissolution, Nuclear Technology, 51, 188–196, https://doi.org/10.13182/NT80-A32600, 1980.
Glasmann, J. R.: The fate of feldspar in Brent Group reservoirs, North Sea: A regional synthesis of diagenesis in shallow, intermediate, and deep burial environments, Geological Society, London, Special Publications, 61, 329–350, https://doi.org/10.1144/GSL.SP.1992.061.01.17, 1992.
Hall, M. R., Rigby, S. P., Dim, P., Bateman, K., Mackintosh, S. J., and Rochelle, C. A.: Post-CO2 injection alteration of the pore network and intrinsic permeability tensor for a Permo‐Triassic sandstone, Geofluids, 16, 249–263, https://doi.org/10.1111/gfl.12146, 2015.
Hangx, S. J. and Spiers, C. J.: Coastal spreading of olivine to control atmospheric CO2 concentrations: A critical analysis of viability, International Journal of Greenhouse Gas Control, 3, 757–767, https://doi.org/10.1016/j.ijggc.2009.07.001, 2009.
Hangx, S., Bakker, E., Bertier, P., Nover, G., and Busch, A.: Chemical–mechanical coupling observed for depleted oil reservoirs subjected to long-term CO2-exposure–A case study of the Werkendam natural CO2 analogue field, Earth and Planetary Science Letters, 428, 230–242, https://doi.org/10.1016/j.epsl.2015.07.044, 2015.
Harlov, D. E., Wirth, R., and Förster, H. J.: An experimental study of dissolution–reprecipitation in fluorapatite: fluid infiltration and the formation of monazite, Contributions to Mineralogy and Petrology, 150, 268–286, https://doi.org/10.1007/s00410-005-0017-8, 2005.
Haseli, P., Majewski, P., Christo, F., Raven, M., Klose, S., and Bruno, F.: Experimental kinetic analysis of potassium extraction from ultrapotassic syenite using NaCl–CaCl2 salt mixture, Acs Omega, 5, 16421–16429, https://doi.org/10.1021/acsomega.0c00549, 2020.
Helgeson, H. C., Murphy, W. M., and Aagaard, P.: Thermodzhuynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. II. Rate constants, effective surface area, and the hydrolysis of feldspar, Geochimica et Cosmochimica Acta, 48, 2405–2432, https://doi.org/10.1016/0016-7037(84)90294-1, 1984.
Hellmann, R., Wirth, R., Daval, D., Barnes, J. P., Penisson, J. M., Tisserand, D., Epicier, T., Florin, B., and Hervig, R. L.: Unifying natural and laboratory chemical weathering with interfacial dissolution–reprecipitation: a study based on the nanometer-scale chemistry of fluid–silicate interfaces, Chemical Geology, 294, 203–216, https://doi.org/10.1016/j.chemgeo.2011.12.002, 2012.
IPCC: Special Report on Carbon Dioxide Capture and Storage, Cambridge University Press, Cambridge, 431, ISBM 978-0-521-86643-9, 2005.
Juanes, R., Spiteri, E. J., Orr Jr, F. M., and Blunt, M. J.: Impact of relative permeability hysteresis on geological CO2 storage, Water Resources Research, 42, https://doi.org/10.1029/2005WR004806, 2006.
Knauss, K. G. and Wolery, T. J.: Dependence of albite dissolution kinetics on pH and time at 25 °c and 70 °c, Geochimica et Cosmochimica Acta, 50, 2481–2497, https://doi.org/10.1016/0016-7037(86)90031-1, 1986.
Liu, S. K., Han, C., Liu, J. M., and Li, H.: Hydrothermal decomposition of potassium feldspar under alkaline conditions, Rsc Advances, 5, 93301–93309, https://doi.org/10.1039/C5RA17212H, 2015.
Lu, P., Fu, Q., Seyfried Jr, W. E., Hedges, S. W., Soong, Y., Jones, K., and Zhu, C.: Coupled alkali feldspar dissolution and secondary mineral precipitation in batch systems–2: New experiments with supercritical CO2 and implications for carbon sequestration, Appl. Geochem., 30, 75–90, https://doi.org/10.1016/j.apgeochem.2012.04.005, 2013.
Ma, X., Ma, H., and Yang, J.: Sintering preparation and release properties of K2MgSi3O8 slow-release fertilizer using biotite acid-leaching residues as silicon source, Industrial & Engineering Chemistry Research, 55, 10926–10931, https://doi.org/10.1021/acs.iecr.6b02991, 2016.
Moore, J., Adams, M., Allis, R., Lutz, S., and Rauzi, S.: Mineralogical and geochemical consequences of the long-term presence of CO2 in natural reservoirs: an example from the Springerville–St. Johns Field, Arizona, and New Mexico, USA, Chemical Geology, 217, 365–385, https://doi.org/10.1016/j.chemgeo.2004.12.019, 2005.
Mora, C. I., Riciputi, L. R., Cole, D. R., and Walker, K. D.: High-temperature hydrothermal alteration of the Boehls Butte anorthosite: origin of a bimodal plagioclase assemblage, Contributions to Mineralogy and Petrology, 157, 781–795, https://doi.org/10.1007/s00410-008-0364-3, 2009.
Niedermeier, D. R., Putnis, A., Geisler, T., Golla-Schindler, U., and Putnis, C. V.: The mechanism of cation and oxygen isotope exchange in alkali feldspars under hydrothermal conditions, Contributions to Mineralogy and Petrology, 157, 65–76, https://doi.org/10.1007/s00410-008-0320-2, 2009.
Nightingale, M., Johnson, G., Shevalier, M., Hutcheon, I., Perkins, E., and Mayer, B.: Impact of injected CO2 on reservoir mine ralogy during CO2-EOR, Energy Procedia, 1, 3399–3406, https://doi.org/10.1016/j.egypro.2009.02.129, 2020.
Norberg, N., Neusser, G., Wirth, R., and Harlov, D.: Microstructural evolution during experimental albitization of K-rich alkali feldspar, Contributions to Mineralogy and Petrology, 162, 531–546, https://doi.org/10.1007/s00410-011-0610-y, 2011.
Pessu, F., Macente, A., Sanni, O., and Piazolo, S.: The importance of whole system considerations for sustainable, long-term CO2 injection and storage: Interplay between infrastructure-related corrosion and reservoir rock chemistry effects on the evolution of the CO2 storage capacity, International Journal of Greenhouse Gas Control, 148, 104520, https://doi.org/10.1016/j.ijggc.2025.104520, 2025.
Pinnock, S. J., Clitheroe, A. R. J., and Rose, P. T. S.: The Captain Field, Block 13/22a, UK North Sea, TS39, Geological Society of London Memoirs, 20, https://doi.org/10.1144/GSL.MEM.2003.020.01.35, 2003.
Putnis, A.: Mineral replacement reactions, Reviews in Mineralogy and Geochemistry, 70, 87–124, https://doi.org/10.2138/rmg.2009.70.3, 2009.
Putnis, C. V., Geisler, T., Schmid-Beurmann, P., Stephan, T., and Giampaolo, C.: An experimental study of the replacement of leucite by analcime, American Mineralogist, 92, 19–26, https://doi.org/10.2138/am.2007.2249, 2007.
Rathnaweera, T. D., Ranjith, P. G., Perera, M. S. A., Haque, A., Lashin, A., Al Arifi, N., Chandrasekharam, D., Yang, S. Q., Xu, T., Wang, S. H., and Yasar, E.: CO2-induced mechanical behaviour of Hawkesbury sandstone in the Gosford basin: An experimental study, Materials Science and Engineering: A, 641, 123–137, https://doi.org/10.1016/j.msea.2015.05.029, 2015.
Ringrose, P.: How to store CO2 underground: Insights from early-mover CCS projects, SpringerBriefs in Earth Sciences, Springer International Publishing, Cham, Switzerland, 129, https://doi.org/10.1007/978-3-030-33113-9, 2020.
Rochelle, C. A., Czernichowski-Lauriol, I., and Milodowski, A. E.: The impact of chemical reactions on CO2 storage in geological formations: a brief review, Geological Society of London Memoirs, 233, https://doi.org/10.1144/GSL.SP.2004.233.01.07, 2004.
Rosenqvist, J., Kilpatrick, A. D., Yardley, B. W., and Rochelle, C. A.: Alkali feldspar dissolution in response to injection of carbon dioxide, Applied Geochemistry, 109, 104419104419, https://doi.org/10.1016/j.apgeochem, 2019.
Ross, G. D., Todd, A. C., Tweedie, J. A., and Will, A. G.: The dissolution effects of CO2-brine systems on the permeability of UK and North Sea calcareous sandstones, in: SPE Improved Oil Recovery Conference (SPE-10685), SPE, https://doi.org/10.2118/10685-MS, 1982.
Rutter, E. H.: A discussion on natural strain and geological structure-the kinetics of rock deformation by pressure solution, Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 283, 203–219, https://doi.org/10.1098/rsta.1976.0079, 1976.
Sayegh, S. G., Krause, F. F., Girard, M., and DeBree, C.: Rock/fluid interactions of carbonated brines in a sandstone reservoir: Pembina Cardium, Alberta, Canada, SPE formation evaluation, 5, 399–405, https://doi.org/10.2118/19392-PA, 1990.
Scholz, C. H.: Static fatigue of quartz, Journal of Geophysical Research, 77, 2104–2114, https://doi.org/10.1029/JB077i011p02104, 1972.
Seisenbayev, N., Absalyamova, M., Alibekov, A., and Lee, W.: Reactive transport modeling and sensitivity analysis of CO2–rock–brine interactions at Ebeity Reservoir, West Kazakhstan, Sustainability, 15, 14434, https://doi.org/10.3390/su151914434, 2023.
Shell: Peterhead CCS Project: Geochemical Reactivity Report, Doc. No. PCCS-05-PT-ZR-3323-00001, produced by Shell U. K. Limited for the UK CCS Commercialisation Programme, Goldeneye CO2 storage project, 2015.
Shogenov, K., Shogenova, A., Vizika-Kavvadias, O., and Nauroy, J. F.: Experimental modeling of CO2-fluid-rock interaction: The evolution of the composition and properties of host rocks in the Baltic Region, Earth and Space Science, 2, 262–284, https://doi.org/10.1002/2015EA000105, 2015.
Stewart, N. and Marshall, J. D.: The Goldeneye Field, Blocks 14/29a and 20/4b, UK North Sea, Geological Society of London Memoirs, 52, https://doi.org/10.1144/M52-2018-32, 2020.
Summers, R. and Byerlee, J.: A note on the effect of fault gouge composition on the stability of frictional sliding, in: International Journal of Rock Mechanics and Mining Sciences & Geomechanics Abstracts (Vol. 14, No. 3, 155–160), Pergamon, https://doi.org/10.1016/0148-9062(77)90007-9, 1977.
Teufel, L. W., Rhett, D. W., and Farrell, H. E.: 1991, July. Effect of reservoir depletion and pore pressure drawdown on in situ stress and deformation in the Ekofisk field, North Sea, in: ARMA US Rock Mechanics/Geomechanics Symposium, ARMA-91-063, 1991.
Tullis, J. and Yund, R. A.: A Experimental deformation of dry Westerly granite, Journal of Geophysical Research, 82, 5705–5718, https://doi.org/10.1029/JB082i036p05705, 1977.
Wigley, M., Dubacq, B., Kampman, N., and Bickle, M.: Controls of sluggish, CO2-promoted, hematite and K-feldspar dissolution kinetics in sandstones, Earth and Planetary Science Letters, 362, 76–87, https://doi.org/10.1016/j.epsl.2012.11.045, 2013.
Whitney, D. L. and Evans, B. W.: Abbreviations for names of rock-forming minerals, American Mineralogist, 95, 185–187, https://doi.org/10.2138/am.2010.3371, 2010.
Wollast, R.: Kinetics of the alteration of K-feldspar in buffered solutions at low temperature, Geochimica et Cosmochimica Acta, 31, 635–648, https://doi.org/10.1016/0016-7037(67)90040-3, 1967.
Wheeler, J.: A view of texture dynamics, Terra Nova, 3, 123–136, https://doi.org/10.1111/j.1365-3121.1991.tb00864.x, 1991.
Zeitler, P. K., Enkelmann, E., Thomas, J. B., Watson, E. B., Ancuta, L. D., and Idleman, B. D.: Solubility and trapping of helium in apatite, Geochimica et Cosmochimica Acta, 209, 1–8, https://doi.org/10.1016/j.gca.2017.03.041, 2017.
Zhai, Y., Hellmann, R., Campos, A., Findling, N., Mayanna, S., Wirth, R., Schreiber, A. Cabié, M., Zeng, Q., Liu, S., and Liu, J.: Fertilizer derived from alkaline hydrothermal alteration of K-feldspar: micrometer to nanometer-scale investigation. Applied Geochemistry, 126, https://doi.org/10.1016/j.apgeochem.2020.104828, 2021.
Editorial statement
This manuscript explores an important aspect of CCS, the potential interaction with and consequences of CO2-saturated solution with the host rock. In a series of well-executed experiments it is shown that the effects are, at elevated temperatures, especially severe in feldspars, with potentially significant geomechanical and geochemical implications.
This manuscript explores an important aspect of CCS, the potential interaction with and...
Short summary
Contrary to current CCS (Carbon Capture and Storage) models, reaction experiments conducted at subsurface stress and temperature conditions reveal that feldspars, common, reactive grains in sandstone reservoirs, can undergo significant chemical and mechanical changes when exposed to CO₂ enriched water. These chemo-mechanical processes, including grain fracturing, dissolution, and clay precipitation, can modify fluid pathways and rock strength, potentially reducing reservoir productivity and increasing leakage risk.
Contrary to current CCS (Carbon Capture and Storage) models, reaction experiments conducted at...