Articles | Volume 11, issue 2
https://doi.org/10.5194/se-11-307-2020
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the Creative Commons Attribution 4.0 License.
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https://doi.org/10.5194/se-11-307-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Tracing fluid transfers in subduction zones: an integrated thermodynamic and δ18O fractionation modelling approach
Alice Vho
CORRESPONDING AUTHOR
Institute of Geological Sciences, University of Bern, 3012 Bern,
Switzerland
Pierre Lanari
Institute of Geological Sciences, University of Bern, 3012 Bern,
Switzerland
Daniela Rubatto
Institute of Geological Sciences, University of Bern, 3012 Bern,
Switzerland
Institut de Sciences de la Terre, University of Lausanne, 1015
Lausanne, Switzerland
Jörg Hermann
Institute of Geological Sciences, University of Bern, 3012 Bern,
Switzerland
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Kilian Lecacheur, Olivier Fabbri, Francesca Piccoli, Pierre Lanari, Philippe Goncalves, and Henri Leclère
Eur. J. Mineral., 36, 767–795, https://doi.org/10.5194/ejm-36-767-2024, https://doi.org/10.5194/ejm-36-767-2024, 2024
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In this study, we analyze a peculiar eclogite from the Western Alps, which not only recorded a classical subduction-to-exhumation path but revealed evidence of Ca-rich fluid–rock interaction. Chemical composition and modeling show that the rock experienced peak metamorphic conditions followed by Ca-rich pulsed fluid influx occurring consistently under high-pressure conditions. This research enhances our understanding of fluid–rock interactions in subduction settings.
Hugo Dominguez, Nicolas Riel, and Pierre Lanari
Geosci. Model Dev., 17, 6105–6122, https://doi.org/10.5194/gmd-17-6105-2024, https://doi.org/10.5194/gmd-17-6105-2024, 2024
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Predicting the behaviour of magmatic systems is important for understanding Earth's matter and heat transport. Numerical modelling is a technique that can predict complex systems at different scales of space and time by solving equations using various techniques. This study tests four algorithms to find the best way to transport the melt composition. The "weighted essentially non-oscillatory" algorithm emerges as the best choice, minimising errors and preserving system mass well.
Julien Reynes, Jörg Hermann, Pierre Lanari, and Thomas Bovay
Eur. J. Mineral., 35, 679–701, https://doi.org/10.5194/ejm-35-679-2023, https://doi.org/10.5194/ejm-35-679-2023, 2023
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Garnet is a high-pressure mineral that may incorporate very small amounts of water in its structure (tens to hundreds of micrograms per gram H2O). In this study, we show, based on analysis and modelling, that it can transport up to several hundred micrograms per gram of H2O at depths over 80 km in a subduction zone. The analysis of garnet from the various rock types present in a subducted slab allowed us to estimate the contribution of garnet in the deep cycling of water in the earth.
Mona Lueder, Renée Tamblyn, and Jörg Hermann
Eur. J. Mineral., 35, 243–265, https://doi.org/10.5194/ejm-35-243-2023, https://doi.org/10.5194/ejm-35-243-2023, 2023
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Although rutile does not have water in its chemical formula, it can contain trace amounts. We applied a new measurement protocol to study water incorporation into rutile from eight geological environments. H2O in natural rutile can be linked to six crystal defects, most importantly to Ti3+ and Fe3+. Quantifying the H2O in the individual defects can help us understand relationships of trace elements in rutile and might give us valuable information on the conditions under which the rock formed.
Veronica Peverelli, Alfons Berger, Martin Wille, Thomas Pettke, Pierre Lanari, Igor Maria Villa, and Marco Herwegh
Solid Earth, 13, 1803–1821, https://doi.org/10.5194/se-13-1803-2022, https://doi.org/10.5194/se-13-1803-2022, 2022
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This work studies the interplay of epidote dissolution–precipitation and quartz dynamic recrystallization during viscous granular flow in a deforming epidote–quartz vein. Pb and Sr isotope data indicate that epidote dissolution–precipitation is mediated by internal/recycled fluids with an additional external fluid component. Microstructures and geochemical data show that the epidote material is redistributed and chemically homogenized within the deforming vein via a dynamic granular fluid pump.
Veronica Peverelli, Tanya Ewing, Daniela Rubatto, Martin Wille, Alfons Berger, Igor Maria Villa, Pierre Lanari, Thomas Pettke, and Marco Herwegh
Geochronology, 3, 123–147, https://doi.org/10.5194/gchron-3-123-2021, https://doi.org/10.5194/gchron-3-123-2021, 2021
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This work presents LA-ICP-MS U–Pb geochronology of epidote in hydrothermal veins. The challenges of epidote dating are addressed, and a protocol is proposed allowing us to obtain epidote U–Pb ages with a precision as good as 5 % in addition to the initial Pb isotopic composition of the epidote-forming fluid. Epidote demonstrates its potential to be used as a U–Pb geochronometer and as a fluid tracer, allowing us to reconstruct the timing of hydrothermal activity and the origin of the fluid(s).
Michael C. Jollands, Hugh St.C. O'Neill, Andrew J. Berry, Charles Le Losq, Camille Rivard, and Jörg Hermann
Eur. J. Mineral., 33, 113–138, https://doi.org/10.5194/ejm-33-113-2021, https://doi.org/10.5194/ejm-33-113-2021, 2021
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How, and how fast, does hydrogen move through crystals? We consider this question by adding hydrogen, by diffusion, to synthetic crystals of olivine doped with trace amounts of chromium. Even in a highly simplified system, the behaviour of hydrogen is complex. Hydrogen can move into and through the crystal using various pathways (different defects within the crystal) and hop between these pathways too.
Felix Hentschel, Emilie Janots, Claudia A. Trepmann, Valerie Magnin, and Pierre Lanari
Eur. J. Mineral., 32, 521–544, https://doi.org/10.5194/ejm-32-521-2020, https://doi.org/10.5194/ejm-32-521-2020, 2020
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We analysed apatite–allanite/epidote coronae around monazite and xenotime in deformed Permian pegmatites from the Austroalpine basement. Microscopy, chemical analysis and EBSD showed that these coronae formed by dissolution–precipitation processes during deformation of the host rocks. Dating of monazite and xenotime confirmed the magmatic origin of the corona cores, while LA-ICP-MS dating of allanite established a date of ~ 60 Ma for corona formation and deformation in the Austroalpine basement.
Emmanuelle Ricchi, Christian A. Bergemann, Edwin Gnos, Alfons Berger, Daniela Rubatto, Martin J. Whitehouse, and Franz Walter
Solid Earth, 11, 437–467, https://doi.org/10.5194/se-11-437-2020, https://doi.org/10.5194/se-11-437-2020, 2020
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This study investigates Cenozoic deformation during cooling and exhumation of the Tauern metamorphic and structural dome, Eastern Alps, through Th–Pb dating of fissure monazite-(Ce). Fissure (or hydrothermal) monazite-(Ce) typically crystallizes in a temperature range of 400–200 °C. Three major episodes of monazite growth occurred at approximately 21, 17, and 12 Ma, corroborating previous crystallization and cooling ages.
Laura Stutenbecker, Peter M. E. Tollan, Andrea Madella, and Pierre Lanari
Solid Earth, 10, 1581–1595, https://doi.org/10.5194/se-10-1581-2019, https://doi.org/10.5194/se-10-1581-2019, 2019
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The Aar and Mont Blanc regions in the Alps are large granitoid massifs characterized by high topography. We analyse when these granitoids were first exhumed to the surface. We test this by tracking specific garnet grains, which are exclusively found in the granitoid massifs, in the sediments contained in the alpine foreland basin. This research ties in with ongoing debates on the timing and mechanisms of mountain building.
Francesco Giuntoli, Pierre Lanari, and Martin Engi
Solid Earth, 9, 167–189, https://doi.org/10.5194/se-9-167-2018, https://doi.org/10.5194/se-9-167-2018, 2018
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Continental high-pressure terranes in orogens offer insight into deep recycling and transformation processes that occur in subduction zones. These remain poorly understood, and currently debated ideas need testing. We document complex garnet zoning in eclogitic mica schists from the Sesia Zone (western Italian Alps). These retain evidence of two orogenic cycles and provide detailed insight into resorption, growth, and diffusion processes induced by fluid pulses under high-pressure conditions.
Francesco Giuntoli, Pierre Lanari, Marco Burn, Barbara Eva Kunz, and Martin Engi
Solid Earth, 9, 191–222, https://doi.org/10.5194/se-9-191-2018, https://doi.org/10.5194/se-9-191-2018, 2018
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Subducted continental terranes commonly comprise an assembly of subunits that reflect the different tectono-metamorphic histories they experienced in the subduction zone. Our challenge is to unravel how, when, and in which part of the subduction zone these subunits were juxtaposed. Our study documents when and in what conditions re-equilibration took place. Results constrain the main stages of mineral growth and deformation, associated with fluid influx that occurred in the subduction channel.
Related subject area
Subject area: Tectonic plate interactions, magma genesis, and lithosphere deformation at all scales | Editorial team: Geochemistry, mineralogy, petrology, and volcanology | Discipline: Petrology
Contribution of carbonatite and recycled oceanic crust to petit-spot lavas on the western Pacific Plate
Yttrium speciation in subduction-zone fluids from ab initio molecular dynamics simulations
Post-entrapment modification of residual inclusion pressure and its implications for Raman elastic thermobarometry
Anatomy of the magmatic plumbing system of Los Humeros Caldera (Mexico): implications for geothermal systems
Alkali basalt from the Seifu Seamount in the Sea of Japan: post-spreading magmatism in a back-arc setting
Magmatic sulfides in high-potassium calc-alkaline to shoshonitic and alkaline rocks
Kazuto Mikuni, Naoto Hirano, Shiki Machida, Hirochika Sumino, Norikatsu Akizawa, Akihiro Tamura, Tomoaki Morishita, and Yasuhiro Kato
Solid Earth, 15, 167–196, https://doi.org/10.5194/se-15-167-2024, https://doi.org/10.5194/se-15-167-2024, 2024
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Plate tectonics theory is the motion of rocky plates (lithosphere) over ductile zones (asthenosphere). The causes of the lithosphere–asthenosphere boundary (LAB) are controversial; however, petit-spot volcanism supports the presence of melt at the LAB. We conducted geochemistry, geochronology, and geochemical modeling of petit-spot volcanoes on the western Pacific Plate, and the results suggested that carbonatite melt and recycled oceanic crust induced the partial melting at the LAB.
Johannes Stefanski and Sandro Jahn
Solid Earth, 11, 767–789, https://doi.org/10.5194/se-11-767-2020, https://doi.org/10.5194/se-11-767-2020, 2020
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The capacity of aqueous fluids to mobilize rare Earth elements is closely related to their molecular structure. In this study, first-principle molecular dynamics simulations are used to investigate the complex formation of yttrium with chloride and fluoride under subduction-zone conditions. The simulations predict that yttrium–fluoride complexes are more stable than their yttrium–chloride counterparts but likely less abundant due to the very low fluoride ion concentration in natural systems.
Xin Zhong, Evangelos Moulas, and Lucie Tajčmanová
Solid Earth, 11, 223–240, https://doi.org/10.5194/se-11-223-2020, https://doi.org/10.5194/se-11-223-2020, 2020
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In this study, we present a 1-D visco-elasto-plastic model in a spherical coordinate system to study the residual pressure preserved in mineral inclusions. This allows one to study how much residual pressure can be preserved after viscous relaxation. An example of quartz inclusion in garnet host is studied and it is found that above 600–700 °C, substantial viscous relaxation will occur. If one uses the relaxed residual quartz pressure for barometry, erroneous results will be obtained.
Federico Lucci, Gerardo Carrasco-Núñez, Federico Rossetti, Thomas Theye, John Charles White, Stefano Urbani, Hossein Azizi, Yoshihiro Asahara, and Guido Giordano
Solid Earth, 11, 125–159, https://doi.org/10.5194/se-11-125-2020, https://doi.org/10.5194/se-11-125-2020, 2020
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Understanding the anatomy of active magmatic plumbing systems is essential to define the heat source(s) feeding geothermal fields. Mineral-melt thermobarometry and fractional crystallization (FC) models were applied to Quaternary volcanic products of the Los Humeros Caldera (Mexico). Results point to a magmatic system controlled by FC processes and made of magma transport and storage layers within the crust, with significant implications on structure and longevity of the geothermal reservoir.
Tomoaki Morishita, Naoto Hirano, Hirochika Sumino, Hiroshi Sato, Tomoyuki Shibata, Masako Yoshikawa, Shoji Arai, Rie Nauchi, and Akihiro Tamura
Solid Earth, 11, 23–36, https://doi.org/10.5194/se-11-23-2020, https://doi.org/10.5194/se-11-23-2020, 2020
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We report a peridotite xenolith-bearing basalt dredged from the Seifu Seamount (SSM basalt) in the northeast Tsushima Basin, southwest Sea of Japan, which is one of the western Pacific back-arc basin swarms. An 40Ar / 39Ar plateau age of 8.33 ± 0.15 Ma (2 σ) was obtained for the SSM basalt, indicating that it erupted shortly after the termination of back-arc spreading. The SSM basalt was formed in a post-back-arc extension setting by the low-degree partial melting of an upwelling asthenosphere.
Ariadni A. Georgatou and Massimo Chiaradia
Solid Earth, 11, 1–21, https://doi.org/10.5194/se-11-1-2020, https://doi.org/10.5194/se-11-1-2020, 2020
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We study the petrographical and geochemical occurrence of magmatic sulfide minerals in volcanic rocks for areas characterised by different geodynamic settings, some of which are associated with porphyry (Cu and/or Au) and Au epithermal mineralisation. The aim is to investigate the role of magmatic sulfide saturation processes in depth for ore generation in the surface.
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Short summary
This study presents an approach that combines equilibrium thermodynamic modelling with oxygen isotope fractionation modelling for investigating fluid–rock interaction in metamorphic systems. An application to subduction zones shows that chemical and isotopic zoning in minerals can be used to determine feasible fluid sources and the conditions of interaction. Slab-derived fluids can cause oxygen isotope variations in the mantle wedge that may result in anomalous isotopic signatures of arc lavas.
This study presents an approach that combines equilibrium thermodynamic modelling with oxygen...