Articles | Volume 7, issue 4
https://doi.org/10.5194/se-7-1145-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/se-7-1145-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Porosity and permeability determination of organic-rich Posidonia shales based on 3-D analyses by FIB-SEM microscopy
Georg H. Grathoff
CORRESPONDING AUTHOR
Department of Geography and Geology, EMA University of Greifswald,
Greifswald, 17489, Germany
Markus Peltz
Department of Geography and Geology, EMA University of Greifswald,
Greifswald, 17489, Germany
Frieder Enzmann
Institute for Geosciences, J. Gutenberg University Mainz, Mainz,
55128, Germany
Stephan Kaufhold
Bundesanstalt für Geowissenschaften und Rohstoffe, Hannover,
30655, Germany
Related authors
Arne Jacob, Markus Peltz, Sina Hale, Frieder Enzmann, Olga Moravcova, Laurence N. Warr, Georg Grathoff, Philipp Blum, and Michael Kersten
Solid Earth, 12, 1–14, https://doi.org/10.5194/se-12-1-2021, https://doi.org/10.5194/se-12-1-2021, 2021
Short summary
Short summary
In this work, we combined different imaging and experimental measuring methods for analysis of cross-scale effects which reduce permeability of tight reservoir rocks. Simulated permeability of digital images of rocks is often overestimated, which is caused by non-resolvable clay content within the pores of a rock. By combining FIB-SEM with micro-XCT imaging, we were able to simulate the true clay mineral abundance to match experimentally measured permeability with simulated permeability.
Christopher J. L. Wilson, Mark Peternell, Filomena Salvemini, Vladimir Luzin, Frieder Enzmann, Olga Moravcova, and Nicholas J. R. Hunter
The Cryosphere, 18, 819–836, https://doi.org/10.5194/tc-18-819-2024, https://doi.org/10.5194/tc-18-819-2024, 2024
Short summary
Short summary
As the temperature increases within a deforming ice aggregate, composed of deuterium (D2O) ice and water (H2O) ice, a set of meltwater segregations are produced. These are composed of H2O and HDO and are located in conjugate shear bands and in compaction bands which accommodate the deformation and weaken the ice aggregate. This has major implications for the passage of meltwater in ice sheets and the formation of the layering recognized in glaciers.
Raphael Dlugosch, Michael Mertineit, Michael Schramm, Melanie Hein, Stephan Kaufhold, and Lisa Richter
Saf. Nucl. Waste Disposal, 2, 51–51, https://doi.org/10.5194/sand-2-51-2023, https://doi.org/10.5194/sand-2-51-2023, 2023
Short summary
Short summary
The fluid content of salt rocks is an important parameter to evaluate their barrier properties. The measurements are time intensive, and the results are highly dependent on the sample selection and preparation. Nuclear magnetic relaxation relaxometry is an established non-invasive petrophysical method, but it has not been used extensively for rock salt to date. The first results show that NMR has promising features with respect to the analysis of the fluid content of salt rocks.
Arne Jacob, Markus Peltz, Sina Hale, Frieder Enzmann, Olga Moravcova, Laurence N. Warr, Georg Grathoff, Philipp Blum, and Michael Kersten
Solid Earth, 12, 1–14, https://doi.org/10.5194/se-12-1-2021, https://doi.org/10.5194/se-12-1-2021, 2021
Short summary
Short summary
In this work, we combined different imaging and experimental measuring methods for analysis of cross-scale effects which reduce permeability of tight reservoir rocks. Simulated permeability of digital images of rocks is often overestimated, which is caused by non-resolvable clay content within the pores of a rock. By combining FIB-SEM with micro-XCT imaging, we were able to simulate the true clay mineral abundance to match experimentally measured permeability with simulated permeability.
Swarup Chauhan, Kathleen Sell, Wolfram Rühaak, Thorsten Wille, and Ingo Sass
Geosci. Model Dev., 13, 315–334, https://doi.org/10.5194/gmd-13-315-2020, https://doi.org/10.5194/gmd-13-315-2020, 2020
Short summary
Short summary
We present CobWeb 1.0, a graphical user interface for analysing tomographic images of geomaterials. CobWeb offers different machine learning techniques for accurate multiphase image segmentation and visualizing material specific parameters such as pore size distribution, relative porosity and volume fraction. We demonstrate a novel approach of dual filtration and dual segmentation to eliminate edge enhancement artefact in synchrotron-tomographic datasets and provide the computational code.
Kathleen Sell, Erik H. Saenger, Andrzej Falenty, Marwen Chaouachi, David Haberthür, Frieder Enzmann, Werner F. Kuhs, and Michael Kersten
Solid Earth, 7, 1243–1258, https://doi.org/10.5194/se-7-1243-2016, https://doi.org/10.5194/se-7-1243-2016, 2016
Annette Kaufhold, Matthias Halisch, Gerhard Zacher, and Stephan Kaufhold
Solid Earth, 7, 1171–1183, https://doi.org/10.5194/se-7-1171-2016, https://doi.org/10.5194/se-7-1171-2016, 2016
Short summary
Short summary
The OPA material has been intensively studied by a variety of multiple scale and non-destructive 3-D X-ray CT investigations, following a consequent top-down approach to identify specific regions of interest. According to the mechanical experiment, it has been observed that the shear failure is located in a clay-rich area. Within the intersecting area of the two main fractures, a so called mylonitic zone with a particle reduction was observed on the open shear failure using CT and SEM techniques.
Tobias Kling, Da Huo, Jens-Oliver Schwarz, Frieder Enzmann, Sally Benson, and Philipp Blum
Solid Earth, 7, 1109–1124, https://doi.org/10.5194/se-7-1109-2016, https://doi.org/10.5194/se-7-1109-2016, 2016
Short summary
Short summary
A method is introduced to implement medical CT data of a fractured sandstone under varying confining pressures into fluid flow simulations to reproduce experimental permeabilities. The simulation results reproduce plausible fracture flow features (e.g. flow channeling, fracture closing/opening) and approximate the actual permeabilities, which are affected by the CT resolution and compositional matrix heterogeneities. Additionally, some recommendations are presented concerning future studies.
Steven Henkel, Dieter Pudlo, Frieder Enzmann, Viktor Reitenbach, Daniel Albrecht, Leonhard Ganzer, and Reinhard Gaupp
Solid Earth, 7, 917–927, https://doi.org/10.5194/se-7-917-2016, https://doi.org/10.5194/se-7-917-2016, 2016
Short summary
Short summary
This study investigates the experimentally induced effects of CO2 storage on underground reservoir sandstones by applying high-resolution computer tomography and standard petrophysical methods. The results of digital rock physic calculations derived from the µ-CT scans are compared with measurements achieved by the standard methods. Both approaches lead to similar results for coarse- and medium-grained sandstones but differ for fine-grained sediments.
Faisal Khan, Frieder Enzmann, and Michael Kersten
Solid Earth, 7, 481–492, https://doi.org/10.5194/se-7-481-2016, https://doi.org/10.5194/se-7-481-2016, 2016
Short summary
Short summary
X-ray microtomography image processing involves artefact reduction and image segmentation. The beam-hardening artefact is removed, applying a new algorithm, which minimizes the offsets of the attenuation data points. For the segmentation, we propose using a non-linear classifier algorithm. Statistical analysis was performed to quantify the improvement in multi-phase classification of rock cores using and without using our advanced beam-hardening correction algorithm.
Related subject area
Sedimentology
What does it take to restore geological models with “natural” boundary conditions?
Impact of stress regime change on the permeability of a naturally fractured carbonate buildup (Latemar, the Dolomites, northern Italy)
Fold localization at pre-existing normal faults: field observations and analogue modelling of the Achental structure, Northern Calcareous Alps, Austria
The influence of extraction of various solvents on chemical properties on Chang 7 shale, Ordos Basin, China
Deep vs. shallow – two contrasting theories? A tectonically activated Late Cretaceous deltaic system in the axial part of the Mid-Polish Trough: a case study from southeast Poland
Miocene high elevation in the Central Alps
What makes seep carbonates ignore self-sealing and grow vertically: the role of burrowing decapod crustaceans
Dawn and dusk of Late Cretaceous basin inversion in central Europe
Simulating permeability reduction by clay mineral nanopores in a tight sandstone by combining computer X-ray microtomography and focussed ion beam scanning electron microscopy imaging
Birth and closure of the Kallipetra Basin: Late Cretaceous reworking of the Jurassic Pelagonian–Axios/Vardar contact (northern Greece)
High-resolution analysis of the physicochemical characteristics of sandstone media at the lithofacies scale
Sediment history mirrors Pleistocene aridification in the Gobi Desert (Ejina Basin, NW China)
Tectonic processes, variations in sediment flux, and eustatic sea level recorded by the 20 Myr old Burdigalian transgression in the Swiss Molasse basin
Miocene basement exhumation in the Central Alps recorded by detrital garnet geochemistry in foreland basin deposits
Can anaerobic oxidation of methane prevent seafloor gas escape in a warming climate?
Fault-controlled dolomitization in the Montagna dei Fiori Anticline (Central Apennines, Italy): record of a dominantly pre-orogenic fluid migration
Precipitation of dolomite from seawater on a Carnian coastal plain (Dolomites, northern Italy): evidence from carbonate petrography and Sr isotopes
The Ogooue Fan (offshore Gabon): a modern example of deep-sea fan on a complex slope profile
Formation of linear planform chimneys controlled by preferential hydrocarbon leakage and anisotropic stresses in faulted fine-grained sediments, offshore Angola
From oil field to geothermal reservoir: assessment for geothermal utilization of two regionally extensive Devonian carbonate aquifers in Alberta, Canada
Sedimentary mechanisms of a modern banded iron formation on Milos Island, Greece
X-ray computed tomography investigation of structures in Opalinus Clay from large-scale to small-scale after mechanical testing
4-D imaging of sub-second dynamics in pore-scale processes using real-time synchrotron X-ray tomography
X-ray CT analyses, models and numerical simulations: a comparison with petrophysical analyses in an experimental CO2 study
Syn-eruptive, soft-sediment deformation of deposits from dilute pyroclastic density current: triggers from granular shear, dynamic pore pressure, ballistic impacts and shock waves
Record of Early Toarcian carbon cycle perturbations in a nearshore environment: the Bascharage section (easternmost Paris Basin)
Shallow water carbonate platforms (Late Aptian–Early Albian, Southern Apennines) in the context of supraregional to global changes: re-appraisal of palaeoecological events as reflectors of carbonate factory response
Phanerozoic environments of black shale deposition and the Wilson Cycle
Particle size distributions by laser diffraction: sensitivity of granular matter strength to analytical operating procedures
Melchior Schuh-Senlis, Guillaume Caumon, and Paul Cupillard
Solid Earth, 15, 945–964, https://doi.org/10.5194/se-15-945-2024, https://doi.org/10.5194/se-15-945-2024, 2024
Short summary
Short summary
This paper presents the application of a numerical method for restoring models of the subsurface to a previous state in their deformation history, acting as a numerical time machine for geological structures. The method is applied to a model based on a laboratory experiment. The results show that using force conditions in the computation of the deformation allows us to assess the value of some previously unknown physical parameters of the different materials inside the model.
Onyedika Anthony Igbokwe, Jithender J. Timothy, Ashwani Kumar, Xiao Yan, Mathias Mueller, Alessandro Verdecchia, Günther Meschke, and Adrian Immenhauser
Solid Earth, 15, 763–787, https://doi.org/10.5194/se-15-763-2024, https://doi.org/10.5194/se-15-763-2024, 2024
Short summary
Short summary
We present a workflow that models the impact of stress regime change on the permeability of fractured Latemar carbonate buildup using a displacement-based linear elastic finite-element method (FEM) and outcrop data. Stress-dependent heterogeneous apertures and effective permeability were calculated and constrained by the study area's stress directions. Simulated far-field stresses at NW–SE subsidence deformation and N–S Alpine deformation increased the overall fracture aperture and permeability.
Willemijn Sarah Maria Theresia van Kooten, Hugo Ortner, Ernst Willingshofer, Dimitrios Sokoutis, Alfred Gruber, and Thomas Sausgruber
Solid Earth, 15, 91–120, https://doi.org/10.5194/se-15-91-2024, https://doi.org/10.5194/se-15-91-2024, 2024
Short summary
Short summary
Extensional deformation creates structures that may be reactivated during subsequent shortening. The Achental structure within the Northern Calcareous Alps fold-and-thrust belt is a natural example of a basin margin that was inverted during Alpine orogeny. We have studied the influence of such inherited inhomogeneities in the field and as an analogue model. We find that oblique shortening can create structures outlining pre-existing faults within a single deformation event.
Yan Cao, Zhijun Jin, Rukai Zhu, and Kouqi Liu
Solid Earth, 14, 1169–1179, https://doi.org/10.5194/se-14-1169-2023, https://doi.org/10.5194/se-14-1169-2023, 2023
Short summary
Short summary
Fourier transform infrared (FTIR) was performed on shale before and after solvent extraction. The extraction yield from shale with THF is higher than other solvents. The organic-C-normalized yield of a mature sample is higher than other samples. The aromaticity of organic matter increases, and the length of organic matter aliphatic chains does not vary monotonically with increasing maturity. The results will help in the selection of organic solvents for oil-washing experiments of shale.
Zbyszek Remin, Michał Cyglicki, and Mariusz Niechwedowicz
Solid Earth, 13, 681–703, https://doi.org/10.5194/se-13-681-2022, https://doi.org/10.5194/se-13-681-2022, 2022
Short summary
Short summary
Traditionally, the axial part of the Polish Basin, i.e. the Mid-Polish Trough, was interpreted as the deepest and most subsiding part of the basin during the Cretaceous times. We interpret this area conversely, as representing a landmass – the Łysogóry–Dobrogea Land. Inversion-related tectonics, uplift on the one hand and enhanced subsidence on the other, drove the development of the Szozdy Delta within the axial part of the basin. New heavy mineral data suggest different burial histories.
Emilija Krsnik, Katharina Methner, Marion Campani, Svetlana Botsyun, Sebastian G. Mutz, Todd A. Ehlers, Oliver Kempf, Jens Fiebig, Fritz Schlunegger, and Andreas Mulch
Solid Earth, 12, 2615–2631, https://doi.org/10.5194/se-12-2615-2021, https://doi.org/10.5194/se-12-2615-2021, 2021
Short summary
Short summary
Here we present new surface elevation constraints for the middle Miocene Central Alps based on stable and clumped isotope geochemical analyses. Our reconstructed paleoelevation estimate is supported by isotope-enabled paleoclimate simulations and indicates that the Miocene Central Alps were characterized by a heterogeneous and spatially transient topography with high elevations locally exceeding 4000 m.
Jean-Philippe Blouet, Patrice Imbert, Sutieng Ho, Andreas Wetzel, and Anneleen Foubert
Solid Earth, 12, 2439–2466, https://doi.org/10.5194/se-12-2439-2021, https://doi.org/10.5194/se-12-2439-2021, 2021
Short summary
Short summary
Biochemical reactions related to hydrocarbon seepage are known to induce carbonates in marine sediments. Seep carbonates may act as seals and force lateral deviations of rising hydrocarbons. However, crustacean burrows may act as efficient vertical fluid channels allowing hydrocarbons to pass through upward, thereby allowing the vertical growth of carbonate stacks over time. This mechanism may explain the origin of carbonate columns in marine sediments throughout hydrocarbon provinces worldwide.
Thomas Voigt, Jonas Kley, and Silke Voigt
Solid Earth, 12, 1443–1471, https://doi.org/10.5194/se-12-1443-2021, https://doi.org/10.5194/se-12-1443-2021, 2021
Short summary
Short summary
Basin inversion in central Europe is believed to have started during Late Cretaceous (middle Turonian) and probably proceeded until the Paleogene. Data from different marginal troughs in central Europe point to an earlier start of basin inversion (in the Cenomanian). The end of inversion is overprinted by general uplift but had probably already occurred in the late Campanian to Maastrichtian. Both the start and end of inversion occurred with low rates of uplift and subsidence.
Arne Jacob, Markus Peltz, Sina Hale, Frieder Enzmann, Olga Moravcova, Laurence N. Warr, Georg Grathoff, Philipp Blum, and Michael Kersten
Solid Earth, 12, 1–14, https://doi.org/10.5194/se-12-1-2021, https://doi.org/10.5194/se-12-1-2021, 2021
Short summary
Short summary
In this work, we combined different imaging and experimental measuring methods for analysis of cross-scale effects which reduce permeability of tight reservoir rocks. Simulated permeability of digital images of rocks is often overestimated, which is caused by non-resolvable clay content within the pores of a rock. By combining FIB-SEM with micro-XCT imaging, we were able to simulate the true clay mineral abundance to match experimentally measured permeability with simulated permeability.
Lydia R. Bailey, Filippo L. Schenker, Maria Giuditta Fellin, Miriam Cobianchi, Thierry Adatte, and Vincenzo Picotti
Solid Earth, 11, 2463–2485, https://doi.org/10.5194/se-11-2463-2020, https://doi.org/10.5194/se-11-2463-2020, 2020
Short summary
Short summary
The Kallipetra Basin, formed in the Late Cretaceous on the reworked Pelagonian–Axios–Vardar contact in the Hellenides, is described for the first time. We document how and when the basin evolved in response to tectonic forcings and basin inversion. Cenomanian extension and basin widening was followed by Turonian compression and basin inversion. Thrusting occurred earlier than previously reported in the literature, with a vergence to the NE, at odds with the regional SW vergence of the margin.
Adrian Linsel, Sebastian Wiesler, Jens Hornung, and Matthias Hinderer
Solid Earth, 11, 1511–1526, https://doi.org/10.5194/se-11-1511-2020, https://doi.org/10.5194/se-11-1511-2020, 2020
Short summary
Short summary
We present a high-resolution 3D analysis of the physicochemical characteristics of two sandstone cubes at the submeter scale. Our study provides insight into the spatial distribution and the controlling factors of small-scale heterogeneity in sandstone media. A comprehensive physicochemical data set is provided, which may help to evaluate the degree of uncertainty that should be considered in field-scale property models.
Georg Schwamborn, Kai Hartmann, Bernd Wünnemann, Wolfgang Rösler, Annette Wefer-Roehl, Jörg Pross, Marlen Schlöffel, Franziska Kobe, Pavel E. Tarasov, Melissa A. Berke, and Bernhard Diekmann
Solid Earth, 11, 1375–1398, https://doi.org/10.5194/se-11-1375-2020, https://doi.org/10.5194/se-11-1375-2020, 2020
Short summary
Short summary
We use a sediment core from the Gobi Desert (Ejina Basin, NW China) to illustrate the landscape history of the area. During 2.5 million years a sediment package of 223 m thickness has been accumulated. Various sediment types document that the area turned from a playa environment (shallow water environment with multiple flooding events) to an alluvial–fluvial environment after the arrival of the Heihe in the area. The river has been diverted due to tectonics.
Philippos Garefalakis and Fritz Schlunegger
Solid Earth, 10, 2045–2072, https://doi.org/10.5194/se-10-2045-2019, https://doi.org/10.5194/se-10-2045-2019, 2019
Short summary
Short summary
The controls on the 20 Myr old Burdigalian transgression in the Swiss Molasse basin have been related to a reduction in sediment flux, a rise in global sea level, or tectonic processes in the adjacent Alps. Here, we readdress this problem and extract stratigraphic signals from the Upper Marine Molasse deposits in Switzerland. In conclusion, we consider rollback tectonics to be the main driving force controlling the transgression, which is related to a deepening and widening of the basin.
Laura Stutenbecker, Peter M. E. Tollan, Andrea Madella, and Pierre Lanari
Solid Earth, 10, 1581–1595, https://doi.org/10.5194/se-10-1581-2019, https://doi.org/10.5194/se-10-1581-2019, 2019
Short summary
Short summary
The Aar and Mont Blanc regions in the Alps are large granitoid massifs characterized by high topography. We analyse when these granitoids were first exhumed to the surface. We test this by tracking specific garnet grains, which are exclusively found in the granitoid massifs, in the sediments contained in the alpine foreland basin. This research ties in with ongoing debates on the timing and mechanisms of mountain building.
Christian Stranne, Matt O'Regan, Martin Jakobsson, Volker Brüchert, and Marcelo Ketzer
Solid Earth, 10, 1541–1554, https://doi.org/10.5194/se-10-1541-2019, https://doi.org/10.5194/se-10-1541-2019, 2019
Mahtab Mozafari, Rudy Swennen, Fabrizio Balsamo, Hamdy El Desouky, Fabrizio Storti, and Conxita Taberner
Solid Earth, 10, 1355–1383, https://doi.org/10.5194/se-10-1355-2019, https://doi.org/10.5194/se-10-1355-2019, 2019
Short summary
Short summary
The dolomitized intervals of the Lower Jurassic deposits exposed in the Montagna dei Fiori Anticline (Central Apennines, Italy) have been investigated. Accordingly, two fault-related dolomitization events were recognised and interpreted as having occurred before and during the Apenninic orogeny. The analyses suggest significant involvement of evaporitic fluids in both events, most likely derived from the underlying Upper Triassic Burano Formation in the detachment level.
Maximilian Rieder, Wencke Wegner, Monika Horschinegg, Stefanie Klackl, Nereo Preto, Anna Breda, Susanne Gier, Urs Klötzli, Stefano M. Bernasconi, Gernot Arp, and Patrick Meister
Solid Earth, 10, 1243–1267, https://doi.org/10.5194/se-10-1243-2019, https://doi.org/10.5194/se-10-1243-2019, 2019
Short summary
Short summary
The formation of dolomite (CaMg(CO3)2), an abundant mineral in Earth's geological record, is still incompletely understood. We studied dolomites embedded in a 100 m thick succession of coastal alluvial clays of Triassic age in the southern Alps. Observation by light microscopy and Sr isotopes suggests that dolomites may spontaneously from concentrated evaporating seawater, in coastal ephemeral lakes or tidal flats along the western margin of the Triassic Tethys sea.
Salomé Mignard, Thierry Mulder, Philippe Martinez, and Thierry Garlan
Solid Earth, 10, 851–869, https://doi.org/10.5194/se-10-851-2019, https://doi.org/10.5194/se-10-851-2019, 2019
Short summary
Short summary
A large quantity a continental material is transported to the oceans by the world rivers. Once in the ocean, these particles can be transported down the continental shelf thanks to underwater avalanches. The repetition of such massive events can form very important sedimentary deposits at the continent–ocean transition. Data obtained during an oceanic cruise in 2010 allowed us to study such a system located offshore of Gabon and to evaluate the importance sediment transport in this area.
Sutieng Ho, Martin Hovland, Jean-Philippe Blouet, Andreas Wetzel, Patrice Imbert, and Daniel Carruthers
Solid Earth, 9, 1437–1468, https://doi.org/10.5194/se-9-1437-2018, https://doi.org/10.5194/se-9-1437-2018, 2018
Short summary
Short summary
A newly discovered type of hydrocarbon leakage structure is investigated following the preliminary works of Ho (2013; et al. 2012, 2013, 2016): blade-shaped gas chimneys instead of classical cylindrical ones. These so-called
Linear Chimneysare hydraulic fractures caused by overpressured hydrocarbon fluids breaching cover sediments along preferential directions. These directions are dictated by anisotropic stresses induced by faulting in sediments and pre-existing salt-diapiric structures.
Leandra M. Weydt, Claus-Dieter J. Heldmann, Hans G. Machel, and Ingo Sass
Solid Earth, 9, 953–983, https://doi.org/10.5194/se-9-953-2018, https://doi.org/10.5194/se-9-953-2018, 2018
Short summary
Short summary
This study focuses on the assessment of the geothermal potential of two extensive upper Devonian aquifer systems within the Alberta Basin (Canada). Our work provides a first database on geothermal rock properties combined with detailed facies analysis (outcrop and core samples), enabling the identification of preferred zones in the reservoir and thus allowing for a more reliable reservoir prediction. This approach forms the basis for upcoming reservoir studies with a focus on 3-D modelling.
Ernest Chi Fru, Stephanos Kilias, Magnus Ivarsson, Jayne E. Rattray, Katerina Gkika, Iain McDonald, Qian He, and Curt Broman
Solid Earth, 9, 573–598, https://doi.org/10.5194/se-9-573-2018, https://doi.org/10.5194/se-9-573-2018, 2018
Short summary
Short summary
Banded iron formations (BIFs) are chemical sediments last seen in the marine sedimentary record ca. 600 million years ago. Here, we report on the formation mechanisms of a modern BIF analog in the Cape Vani sedimentary basin (CVSB) on Milos Island, Greece, demonstrating that rare environmental redox conditions, coupled to submarine hydrothermal activity and microbial processes, are required for these types of rocks to form in the modern marine biosphere.
Annette Kaufhold, Matthias Halisch, Gerhard Zacher, and Stephan Kaufhold
Solid Earth, 7, 1171–1183, https://doi.org/10.5194/se-7-1171-2016, https://doi.org/10.5194/se-7-1171-2016, 2016
Short summary
Short summary
The OPA material has been intensively studied by a variety of multiple scale and non-destructive 3-D X-ray CT investigations, following a consequent top-down approach to identify specific regions of interest. According to the mechanical experiment, it has been observed that the shear failure is located in a clay-rich area. Within the intersecting area of the two main fractures, a so called mylonitic zone with a particle reduction was observed on the open shear failure using CT and SEM techniques.
Katherine J. Dobson, Sophia B. Coban, Samuel A. McDonald, Joanna N. Walsh, Robert C. Atwood, and Philip J. Withers
Solid Earth, 7, 1059–1073, https://doi.org/10.5194/se-7-1059-2016, https://doi.org/10.5194/se-7-1059-2016, 2016
Short summary
Short summary
State-of-the-art synchrotron x-ray imaging was used to observe micron scale transport processes in real time. The 20 Hz 3-D image acquisition rates give experimental data free from motion artefacts, and suitable for detailed quantitative analysis of the dynamic fluid distribution, flow pathways and processes. The method marks a major breakthrough in our ability to capture both sub-second and lower frequency non-equilibrium process in many geological or engineering systems.
Steven Henkel, Dieter Pudlo, Frieder Enzmann, Viktor Reitenbach, Daniel Albrecht, Leonhard Ganzer, and Reinhard Gaupp
Solid Earth, 7, 917–927, https://doi.org/10.5194/se-7-917-2016, https://doi.org/10.5194/se-7-917-2016, 2016
Short summary
Short summary
This study investigates the experimentally induced effects of CO2 storage on underground reservoir sandstones by applying high-resolution computer tomography and standard petrophysical methods. The results of digital rock physic calculations derived from the µ-CT scans are compared with measurements achieved by the standard methods. Both approaches lead to similar results for coarse- and medium-grained sandstones but differ for fine-grained sediments.
G. A. Douillet, B. Taisne, È Tsang-Hin-Sun, S. K. Müller, U. Kueppers, and D. B. Dingwell
Solid Earth, 6, 553–572, https://doi.org/10.5194/se-6-553-2015, https://doi.org/10.5194/se-6-553-2015, 2015
Short summary
Short summary
Sedimentary beds can exhibit signs of local deformation in pyroclastic strata. Patterns are reviewed and trigger mechanisms interpreted.
During an eruption, basal granular flows can have a fluidized behavior, inducing over- or underpressure at the bed interface. Basal shear can overturn strata. Large blocks ejected ballistically deform the ground when landing. Explosions at the vent produce shock waves that can destabilize a bed. These syn-eruptive triggers are specific to explosive volcanism.
M. Hermoso, D. Delsate, F. Baudin, L. Le Callonnec, F. Minoletti, M. Renard, and A. Faber
Solid Earth, 5, 793–804, https://doi.org/10.5194/se-5-793-2014, https://doi.org/10.5194/se-5-793-2014, 2014
A. Raspini
Solid Earth, 3, 225–249, https://doi.org/10.5194/se-3-225-2012, https://doi.org/10.5194/se-3-225-2012, 2012
J. Trabucho-Alexandre, W. W. Hay, and P. L. de Boer
Solid Earth, 3, 29–42, https://doi.org/10.5194/se-3-29-2012, https://doi.org/10.5194/se-3-29-2012, 2012
F. Storti and F. Balsamo
Solid Earth, 1, 25–48, https://doi.org/10.5194/se-1-25-2010, https://doi.org/10.5194/se-1-25-2010, 2010
Cited articles
Bhandari, A. R., Flemings, P. B., Polito, P. J., Cronin, M. B., and Bryant, S. L.: Anisotropy and stress dependence of permeability in the Barnett Shale, Transp. Porous Med, https://doi.org/10.1007/s11242-015-0482-0, 2015.
Cardozo, N. and Allmendinger, R. W.: Spherical projections with OSXSteronet, Comput. Geosci., 51, 193–205, https://doi.org/10.1016/j.cageo.2012.07.021, 2013.
Chalmers, G. R., Bustin, R. M., and Power, I. M.: Characterization of gas shale pore systems by porosimetry, porosimetry, surface area and field emission scanning electron microscopy/transmission electron microscopy image analyses: Examples from the Barnett, Woodford, Haynesville, Marcellus and Doig units, APPG Bulletin, 96, 1099–1119, https://doi.org/10.1306/10171111052, 2012.
Curtis, M. E., Cardott, B. J., Sondergeld, C. H., and Rai, C. S.: Development of organic porosity in the Woodford Shale with increasing thermal maturity, Int. J. Coal Geol., 103, 26–31, https://doi.org/10.1016/j.coal.2012.08.004, 2012.
Desbois, G., Urai, J. L., Hemes, S., Schröppel, B., Schwarz, J.-O., Mac, M., and Weiel, D.: Multi-scale analysis of porosity in diagenetically altered reservoir sandstone from the Permian Rotliegend (Germany), J. Petrol. Sci. Eng., https://doi.org/10.1016/j.petrol.2016.01.019, 2016.
Gasparik, M., Bertier, P., Gensterblum, Y., Ghanizadeh, A., Krooss, B. M., and Littke, R.: Geological controls on the methane storage capacity in organic-rich shales, Int. J. Coal Geol., 123, 34–51, https://doi.org/10.1016/j.coal.2013.06.010, 2014.
Ghanizadeh, A., Amann-Hildenbrand, A., Gasparik, M., Gensterblum, Y., Krooss, B. M., and Littke, R.: Experimental study of fluid transport processes in the matrix system of European organic-rich shales: II. Posidonia Shale (Lower Toarcian, northern Germany)., Int. J. Coal Geol., 123, 20–33, https://doi.org/10.1016/j.coal.2013.06.009, 2014.
Hemes, S., Desbois, G., Urai, J. L., Schröppel, B., and Schwarz, J.-O.: Mutli-scale characterization of porosity in Boom Clay (HADES-level, Mol, Belgium) using a combination of X-ray µ-CT, 2D BIB-SEM and FIB-SEM tomography, Micropor. Mesopor. Mat., 208, 1–20, https://doi.org/10.1016/j.micromeso.2015.01.022, 2015.
Iliev, O. and Laptev, V.: On numerical simulation of flow through oil filters, Comput. Visual Sci., 6, 139–146, https://doi.org/10.1007/s00791-003-0118-8, 2004.
Javadpour, F., Fisher, D., and Unsworth, M.: Nanoscale Gas Flow in Shale Gas Sediments, J. Can. Petrol. Technol., 46, 55–61, https://doi.org/10.2118/07-10-06, 2007.
Kanit, T., Forest, S., Galliet, I., Mounoury, V., and Jeulin, D.: Determination of the size of the representative volume element for random composites: statistical and numerical approach, Int. J. Solids Struct., 40, 3647–3679, https://doi.org/10.1016/S0020-7683(03)00143-4, 2003.
Kaufhold, S., Grathoff, G. H., Halisch, M., Plötze, M., Kus, J., Ufer, K., Dohrmann, R., Ladage, S., and Ostertag-Henning, C.: Comparison of methods for the determination of the pore system of a potential German gas shale, Clay. Clay Miner., https://doi.org/10.1346/CMS-WLS-21.13, 2016.
Keller, L. M., Holzer, L., Wepf, R., and Gasser, P.: 3D geometry and topology of pore pathways in Opalinus clay: Implications for mass transport, Appl. Clay Sci., 52, 85–95, https://doi.org/10.1016/j.clay.2011.02.003, 2011.
Keller, L. M., Holzer, L., Schuetz, P., and Gasser, P.: Pore space relevant for gas permeability in Opalinus clay: Statistical analysis of homogeneity, percolation, and representative volume element, J. Geophys. Res.-Sol. Ea., 118, 2799–2812, https://doi.org/10.1002/jgrb.50228, 2013.
Khan, F., Enzmann, F., Kersten, M., Wiegmann, A., and Steiner, K.: 3D simulation of the permeability tensor in a soil aggregate on basis of nanotomographic imaging and LBE solver, J. Soils Sediments, 12, 86–96, https://doi.org/10.1007/s11368-011-0435-3, 2012.
Klaver, J., Desbois, G., Urai, J. L., and Littke, R.: BIB-SEM study of pore space morphology in early mature Posidonia Shale from the Hils area, Germany, Int. J. Coal Geol., 103, 12–25, https://doi.org/10.1016/j.coal.2012.06.012, 2012.
Klaver, J., Desbois, G., Littke, R., and Urai, J. L.: BIB-SEM pore characterization of mature and post mature Posidonia Shale samples from Hils area, Germany, Int. J. Coal Geol., 158, 78–89, https://doi.org/10.1016/j.coal.2016.03.003, 2016.
Kuila, U., McCarty, D. K., Derkowski, A., Fischer, T. B., Topór, T., and Prasad, M.: Nano-scale texture and porosity of organic matter and clay minerals in organic-rich mudrocks, Fuel, 135, 359–373, https://doi.org/10.1016/j.fuel.2014.06.036, 2014.
Loucks, R. G., Reed, R. M., Ruppel, S. C., and Hammes, U.: Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrock pores, APPG Bulletin, 96, 1071–1098, https://doi.org/10.1306/08171111061, 2012.
Mathia, E. J., Bowen, L., Thomas, K. M., and Aplin, A. C.: Evolution of porosity and pore types in organic-rich, calcareous, Lower Toarcian Posidonia Shale, Mar. Petrol. Geol., 75, 117–139, https://doi.org/10.1016/j.marpetgeo.2016.04.009, 2016.
Mohnhoff, D., Littke, R., Krooss, B. M., and Weniger, P.: Flow-through extraction of oil and gas shales under controlled stress using organic solvents: Implications for organic matter-related porosity and permeability changes with thermal maturity, Int. J. Coal Geol., 157, 84–99, https://doi.org/10.1016/j.coal.2015.09.010, 2015.
Monteiro, P. J. M., Rycroft, C. H., and Barrenblatt, G. I.: A mathematical model of fluid and gas flow in nanoporous media, P, Natl. Acad. Sci. USA, 109, 20309–20313, https://doi.org/10.1073/pnas.1219009109, 2012.
Münch, B. and Holzer, L.: Contradicting geometrical concepts in pore size analysis attained with electron microscopy and mercury intrusion, Journal of the Amercian Ceramic Society, 91, 4059–4067, https://doi.org/10.1111/j.1551-2916.2008.02736.x, 2008.
Rexer, T. F., Mathia, E. J., Aplin, A. C., and Thomas, K. M.: High-Pressure Methane Adsorption and Charecterization of Pores in Posidonia Shales and Isolated Kerogens, Energy Fuels, 28, 2886–2901, https://doi.org/10.1021/ef402466m, 2014.
Rouquerol, J., Avnir, D., Fairbridge, C. W., Everett, D. H., Haynes, J. M., Pernicone, J. M., Ramsay, J. D. F., Sing, W., and Unger, K. K.: Recommendations for the characterization of porous solids, Pure Appl. Chem., 66, 1739–1758, https://doi.org/10.1351/pac199466081739, 1994.
Sato, M., Bitter, I., Bender, M., Kaufman, A. E., and Nakajima, M.: TEASAR: Tree-Structure Extraction Algorithm for Accurate and Robust Skeletons, Pacific Conference on Computer Graphics and Applications, 8, 281–449, https://doi.org/10.1109/PCCGA.2000.883951, 2000.
Schieber, J.: Shale microfabrics and pore development – an overview with emphasis on the importance of depositional processes, Gas Shale of the Horn River Basin, edited by: Leckie, D. A. and Barclay, J. E., 115–119, 2011.
Schlosser, J., Grathoff, G. H., Ostertag-Henning, C., Kaufhold, S., and Warr, L. N.: Mineralogical changes in organic-rich Posidonia Shales during burial and experimental maturation, Int. J. Coal Geol., 157, 74–83, https://doi.org/10.1016/j.coal.2015.07.008, 2016.
Srodon, J.: X-ray powder diffraction identification of illitic materials, Clay. Clay Miner., 32, 337–349, 1984.
Taylor, W. L., Pollard, D. D., and Aydin, A.: Fluid flow in discrete joint sets: field observations and numerical simulations, J. Geophys. Res., 104, 28983–29006, https://doi.org/10.1029/1999JB900179, 1999.
Wiegmann, A.: Computation of the permeability of porous material from their microstructure by FFF-Stokes, Berichte des Fraunhofer ITWM 129, 2007.
Short summary
This study improves our understanding of the evolution of pores in shales for modelling transport properties. 3-D microscopy on early and postmature Posidonia Shales showed similar porosities and pore size distributions. Large isolated pore clusters are within carbonates and clay minerals. Pores form during maturation in the postmature-matrix-filling organic matter. Modelled permeabilities are lowest perpendicular to bedding. They decrease with increasing maturity and are comparable to experimental data.
This study improves our understanding of the evolution of pores in shales for modelling...