Articles | Volume 8, issue 2
https://doi.org/10.5194/se-8-307-2017
https://doi.org/10.5194/se-8-307-2017
Method article
 | 
10 Mar 2017
Method article |  | 10 Mar 2017

Measurement of geologic nitrogen using mass spectrometry, colorimetry, and a newly adapted fluorometry technique

Benjamin W. Johnson, Natashia Drage, Jody Spence, Nova Hanson, Rana El-Sabaawi, and Colin Goldblatt

Related authors

Chempath 1.0: An open-source pathway analysis program for photochemical models
Daniel Garduno Ruiz, Colin Goldblatt, and Anne-Sofie Ahm
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-163,https://doi.org/10.5194/gmd-2024-163, 2024
Preprint under review for GMD
Short summary
Effects of ozone levels on climate through Earth history
Russell Deitrick and Colin Goldblatt
Clim. Past, 19, 1201–1218, https://doi.org/10.5194/cp-19-1201-2023,https://doi.org/10.5194/cp-19-1201-2023, 2023
Short summary
The Palaeoclimate and Terrestrial Exoplanet Radiative Transfer Model Intercomparison Project (PALAEOTRIP): experimental design and protocols
Colin Goldblatt, Lucas Kavanagh, and Maura Dewey
Geosci. Model Dev., 10, 3931–3940, https://doi.org/10.5194/gmd-10-3931-2017,https://doi.org/10.5194/gmd-10-3931-2017, 2017
Short summary
Diminished greenhouse warming from Archean methane due to solar absorption lines
B. Byrne and C. Goldblatt
Clim. Past, 11, 559–570, https://doi.org/10.5194/cp-11-559-2015,https://doi.org/10.5194/cp-11-559-2015, 2015
Short summary
Radiative forcings for 28 potential Archean greenhouse gases
B. Byrne and C. Goldblatt
Clim. Past, 10, 1779–1801, https://doi.org/10.5194/cp-10-1779-2014,https://doi.org/10.5194/cp-10-1779-2014, 2014

Related subject area

Geochemistry
Basic chemical composition combination rules and quantitative criterion of red beds
Guangjun Cui, Jin Liao, Linghua Kong, Cuiying Zhou, Zhen Liu, Lei Yu, and Lihai Zhang
Solid Earth, 15, 1185–1201, https://doi.org/10.5194/se-15-1185-2024,https://doi.org/10.5194/se-15-1185-2024, 2024
Short summary
Magnesium isotope fractionation processes during seafloor serpentinization and implications for serpentinite subduction
Sune G. Nielsen, Frieder Klein, Horst R. Marschall, Philip A. E. Pogge von Strandmann, and Maureen Auro
Solid Earth, 15, 1143–1154, https://doi.org/10.5194/se-15-1143-2024,https://doi.org/10.5194/se-15-1143-2024, 2024
Short summary
Evolution of fluid redox in a fault zone of the Pic de Port Vieux thrust in the Pyrenees Axial Zone (Spain)
Delphine Charpentier, Gaétan Milesi, Pierre Labaume, Ahmed Abd Elmola, Martine Buatier, Pierre Lanari, and Manuel Muñoz
Solid Earth, 15, 1065–1086, https://doi.org/10.5194/se-15-1065-2024,https://doi.org/10.5194/se-15-1065-2024, 2024
Short summary
Mapping geochemical anomalies by accounting for the uncertainty of mineralization-related elemental associations
Jian Wang, Renguang Zuo, and Qinghai Liu
Solid Earth, 15, 731–746, https://doi.org/10.5194/se-15-731-2024,https://doi.org/10.5194/se-15-731-2024, 2024
Short summary
Rare Earth element distribution on the Fuerteventura Basal Complex (Canary Islands, Spain): a geochemical and mineralogical approach
Marc Campeny, Inmaculada Menéndez, Luis Quevedo, Jorge Yepes, Ramón Casillas, Agustina Ahijado, Jorge Méndez-Ramos, and José Mangas
Solid Earth, 15, 639–656, https://doi.org/10.5194/se-15-639-2024,https://doi.org/10.5194/se-15-639-2024, 2024
Short summary

Cited articles

Ader, M., Thomazo, C., Sansjofre, P., Busigny, V., Papineau, D., Laffont, R., Cartigny, P., and Halverson, G. P.: Interpretation of the nitrogen isotopic composition of Precambrian sedimentary rocks: Assumptions and perspectives, Chem. Geol., 429, 93–110, 2016.
Barry, P. and Hilton, D.: Release of subducted sedimentary nitrogen throughout Earth's mantle, Geochemical Perspectives Letters, 2, 148–159, 2016.
Barry, P., Hilton, D., Halldórsson, S., Hahm, D., and Marti, K.: High precision nitrogen isotope measurements in oceanic basalts using a static triple collection noble gas mass spectrometer, Geochem. Geophys. Geosys., 13, 1–16, https://doi.org/10.1029/2011GC003878, 2012.
Bebout, G. and Fogel, M.: Nitrogen-isotope compositions of metasedimentary rocks in the Catalina Schist, California: implications for metamorphic devolatilization history, Geochim. Cosmochim. Ac., 56, 2839–2849, https://doi.org/10.1016/0016-7037(92)90363-N, 1992.
Boyd, S. R.: Determination of the ammonium content of potassic rocks and minerals by capacitance manometry: a prelude to the calibration of FTIR microscopes, Chem. Geol., 137, 57–66, https://doi.org/10.1016/S0009-2541(96)00150-7, 1997.
Download
Short summary
Contrary to canonical notions, recent research suggests that N can cycle throughout the solid Earth over geologic time. Such cycling may directly affect climate and biologic productivity. Due to low concentrations in rocks and minerals, analysis and interpretation are difficult. Therefore, we adapted a fluorometry technique used in aquatic chemistry for use on geologic samples. We compare fluorometry to mass spectrometry and present discussion of the abundance of N in continental crust.